Hydrate-based carbon dioxide capture from simulated integrated gasification combined cycle gas

The equilibrium hydrate formation conditions for CO2/H2 gas mixtures with different CO2 concentrations in 0.29 mol% TBAB aqueous solution are firstly measured.The results illustrate that the equilibrium hydrate formation pressure increases remarkably with the decrease of CO2 concentration in the gas mixture.Based on the phase equilibrium data,a three stages hydrate CO2 separation from integrated gasification combined cycle （IGCC） synthesis gas is investigated.Because the separation efficiency is quite low for the third hydrate separation,a hybrid CO2 separation process of two hydrate stages in conjunction with one chemical absorption process （absorption with MEA） is proposed and studied.The experimental results show H2 concentration in the final residual gas released from the three stages hydrate CO2 separation process was approximately 95.0 mol% while that released from the hybrid CO2 separation process was approximately 99.4 mol%.Thus,the hybrid process is possible to be a promising technology for the industrial application in the future.

船用固体氧化物燃料电池与二冲程低速双燃料发动机集成动力系统的设计与优化

A combined system including a solid oxide fuel cell(SOFC)and an internal combustion engine(ICE)is proposed in this paper.First,a 0-D model of SOFC and a 1-D model of ICE are built as agent models.Second,parameter analysis of the system is conducted based on SOFC and ICE models.Results show that the number of cells,current density,and fuel utilization can influence SOFC and ICE.Moreover,a deep neural network is applied as a data-driven model to conduct optimized calculations efficiently,as achieved by the particle swarm optimization algorithm in this paper.The results demonstrate that the optimal system efficiency of 51.8%can be achieved from a 22.4%/77.6%SOFC-ICE power split at 6000 kW power output.Furthermore,promising improvements in efficiency of 5.1%are achieved compared to the original engine.Finally,a simple economic analysis model,which shows that the payback period of the optimal system is 8.41 years,is proposed in this paper.

Effect of binder on the properties of iron oxide sorbent for hot gas desulfurization

The most difficult problem in hot gas desulfurization in Integrated Coal Gasification Combined Cycle （IGCC） is the pulverization of sulfur removal sorbents.Appropriate binders for hot gas sulfur removal sorbents can solve the pulverization problem.In this paper,six sorbents with binders of different argillaceous minerals were prepared by mechanical mixing method.Desulfurization behavior for hot gas desulfurization sorbents was investigated in a fixed-bed reactor.Result showed that sorbent NTKW2 with binder of clay had a better sulfidation performance.NTKW2 had a more stable performance than other sorbents in the continuous sulfidation-regeneration cycles.Sulfur capacity of sorbent remained the same in each cycle.The desulfurization efficiency and mechanical strength of NTKW2 were the best among the tested sorbents.The behavior of NTKW2 at different temperatures showed different performances,and the best reaction temperature was 550 ℃.Higher heat stability,sulfur capacity and desulfurization efficiency were found on NTKW2 in six continuous sulfidation-regeneration cycles.

Sustainable Design in Space Structures

The sustainable design approach presented in this paper supports an increased commitment to environmental stewardship and conservation, and results in an optimal balance of cost, environmental, societal, and human benefits while meeting the mission and function of the intended space structure. The aim of this paper is to develop the guidelines that could be applied in the design of a space structure in order to achieve the optimal overall lifetime performance of the space structure. Space structures are more than inanimate hunks of metal, glass and fabric. Every space structure that we design as structural engineers is like a child - a child that is conceived with a passionate vision of its form, structure and purpose; nurtured through the schematic design phase and the development of construction documents; and cared for during the labor pains of plan check corrections, requests for information, shop drawing review, and construction observation. Like children, our space structures mature, perform necessary functions during their lives, and eventually, grow old and die. The design of a sustainable space structure is a much more challenging and cross-disciplinary process than in the past and therefore it is necessary that the space structure is viewed as an integrated system and that all members of the design team work in a fully integrated fashion.

Comment： Closing phosphorus cycle from natural waters： re-capturing phosphorus through an integrated water-energy-food strategy

Phosphorus （P） reserve, largely derived from phosphate rock, is essential for crop growth to support the growing world population. However, a significant proportion of phosphorus used as a fertilizer runs into natural waters, causing eutro- phication and ecological damage. Moreover, most P in the food is eventually discharged as waste after being digested by human and animals. Thus, industrial activities have created a one-way flow of non-renewable P from rocks to farms to lakes, rivers and oceans.

Techno-economic assessment of pulverized coal boilers and IGCC power plants with CO_(2) capture

The current studies on power plant technologies suggest that Integrated Gasification Combined Cycle(IGCC)systems are an effective and economic CO_(2) capture technology pathway.In addition,the system in conventional configuration has the advantage of being more“CO_(2) capture ready”than other technologies.Pulverized coal boilers(PC)have,however,proven high technical performance attributes and are economically often most practical technologies.To highlight the pros and cons of both technologies in connection with an integrated CO_(2) capture,a comparative analysis of ultrasupercritical PC and IGCC is carried out in this paper.The technical design,the mass and energy balance and the system optimizations are implemented by using the ECLIPSE chemical plant simulation software package.Built upon these technologies,the CO_(2) capture facilities are incorporated within the system.The most appropriate CO_(2) capture systems for the PC system selected for this work are the oxy-fuel system and the postcombustion scheme using Monoethanolamine solvent scrubber column(MEA).The IGCC systems are designed in two configurations:Water gas shift reactor and Selexol-based separation.Both options generate CO_(2)-rich and hydrogen rich-gas streams.Following the comparative analysis of the technical performance attributes of the above cycles,the economic assessment is carried out using the economic toolbox of ECLIPSE is seamlessly connected to the results of the mass and energy balance as well as the utility usages.The total cost assessment is implemented according to the stepcount exponential costing method using the dominant factors and/or a combination of parameters.Subsequently,based on a set of assumptions,the net present value estimation is implemented to calculate the breakeven electricity selling prices and the CO_(2) avoidance cost.

THE E^(1)_(3) TYPE OF CUBIC SYSTEMS WITH TWO INTEGRAL STRAIGHT LINES

The existence and uniqueness of limit cycle for the E 1 3 type of cubic systems with two integral straight lines has been studied in this paper. It is found that the system has no limit cycle when the two integral straight lines intersect each other; it has a unique limit cycle when the two integral straight lines are paralleled. The sufficient and necessary conditions are also given to guarantee the existence of the unique limit cycle.

Conceptual Process and Analysis of Water-Gas-Shift Membrane Reactor

A new conceptual water-gas-shift(WGS) process is designed for integrated gasification combined cycle(IGCC), using membrane reactor(MR) equipped with H2-permselective zeolite membranes for the WGS reaction.The new process makes it possible to capture CO2 before power generation process by converting CO in the syngas to CO2 which can be collected after WGS reaction. The new process also produces purer H2 for combustion in gas turbine. Conceptual design of the MR, mass and heat balance analysis, and cost estimation of the new process are also provided in this paper.