Cascading faults have been identified as the primary cause of multiple power outages in recent years.With the emergence of integrated energy systems(IES),the conventional approach to analyzing power grid cascading fau...Cascading faults have been identified as the primary cause of multiple power outages in recent years.With the emergence of integrated energy systems(IES),the conventional approach to analyzing power grid cascading faults is no longer appropriate.A cascading fault analysis method considering multi-energy coupling characteristics is of vital importance.In this study,an innovative analysis method for cascading faults in integrated heat and electricity systems(IHES)is proposed.It considers the degradation characteristics of transmission and energy supply com-ponents in the system to address the impact of component aging on cascading faults.Firstly,degradation models for the current carrying capacity of transmission lines,the water carrying capacity and insulation performance of thermal pipelines,as well as the performance of energy supply equipment during aging,are developed.Secondly,a simulation process for cascading faults in the IHES is proposed.It utilizes an overload-dominated development model to predict the propagation path of cascading faults while also considering network islanding,electric-heating rescheduling,and load shedding.The propagation of cascading faults is reflected in the form of fault chains.Finally,the results of cascading faults under different aging levels are analyzed through numerical examples,thereby verifying the effectiveness and rationality of the proposed model and method.展开更多
In the realm of the synthesis of heat-integrated distillation configurations,the conventional approach for exploring more heat integration possibilities typically entails the splitting of a single column into a twocol...In the realm of the synthesis of heat-integrated distillation configurations,the conventional approach for exploring more heat integration possibilities typically entails the splitting of a single column into a twocolumn configuration.However,this approach frequently necessitates tedious enumeration procedures,resulting in a considerable computational burden.To surmount this formidable challenge,the present study introduces an innovative remedy:The proposition of a superstructure that encompasses both single-column and multiple two-column configurations.Additionally,a simultaneous optimization algorithm is applied to optimize both the process parameters and heat integration structures of the twocolumn configurations.The effectiveness of this approach is demonstrated through a case study focusing on industrial organosilicon separation.The results underscore that the superstructure methodology not only substantially mitigates computational time compared to exhaustive enumeration but also furnishes solutions that exhibit comparable performance.展开更多
Observability analysis(OA)is vital to obtaining the available input measurements of state estimation(SE)in an integrated electricity and heating system(IEHS).Considering the thermal quasi-dynamics in pipelines,the mea...Observability analysis(OA)is vital to obtaining the available input measurements of state estimation(SE)in an integrated electricity and heating system(IEHS).Considering the thermal quasi-dynamics in pipelines,the measurement equations in heating systems are dependent on the estimated results,leading to an interdependency between OA and SE.Conventional OA methods require measurement equations be known exactly before SE is performed,and they are not applicable to IEHSs.To bridge this gap,a scenario-based OA scheme for IEHSs is devised that yields reliable analysis results for a predefined set of time-delay scenarios to cope with this interdependency.As its core procedure,the observable state identification and observability restoration are formulated in terms of integer linear programming.Numerical tests are conducted to demonstrate the validity and superiority of the proposed formulation.展开更多
Combined heat and electricity operation with variable mass flow rates promotes flexibility,economy,and sustainability through synergies between electric power systems(EPSs)and district heating systems(DHSs).Such combi...Combined heat and electricity operation with variable mass flow rates promotes flexibility,economy,and sustainability through synergies between electric power systems(EPSs)and district heating systems(DHSs).Such combined operation presents a highly nonlinear and nonconvex optimization problem,mainly due to the bilinear terms in the heat flow model—that is,the product of the mass flow rate and the nodal temperature.Existing methods,such as nonlinear optimization,generalized Benders decomposition,and convex relaxation,still present challenges in achieving a satisfactory performance in terms of solution quality and computational efficiency.To resolve this problem,we herein first reformulate the district heating network model through an equivalent transformation and variable substitution.The reformulated model has only one set of nonconvex constraints with reduced bilinear terms,and the remaining constraints are linear.Such a reformulation not only ensures optimality,but also accelerates the solving process.To relax the remaining bilinear constraints,we then apply McCormick envelopes and obtain an objective lower bound of the reformulated model.To improve the quality of the McCormick relaxation,we employ a piecewise McCormick technique that partitions the domain of one of the variables of the bilinear terms into several disjoint regions in order to derive strengthened lower and upper bounds of the partitioned variables.We propose a heuristic tightening method to further constrict the strengthened bounds derived from the piecewise McCormick technique and recover a nearby feasible solution.Case studies show that,compared with the interior point method and the method implemented in a global bilinear solver,the proposed tightening McCormick method quickly solves the heat–electricity operation problem with an acceptable feasibility check and optimality.展开更多
This paper addresses the application of stochastic optimization approaches to the synthesis of heatintegrated complex distillation system, which is characterized by large-scale combinatorial feature. Conventionaland c...This paper addresses the application of stochastic optimization approaches to the synthesis of heatintegrated complex distillation system, which is characterized by large-scale combinatorial feature. Conventionaland complex columns, thermally coupled (linked) side strippers and side rectifiers as well as heat integration betweenthe different columns are simultaneously considered. The problem is formulated as an MINLP (mixed-integernonlinear programming) problem. A simulated annealing algorithm is proposed to deal with the MINLP problemand a shortcut method is applied to evaluate all required design parameters as well as the total cost function. Twoillustrating examples are presented.展开更多
The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) sepa...The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) separation.In this work,a novel double chemical looping involving both combustion(CLC)and sorption-enhanced reforming(SE-CLR)was proposed towards the co-production of H2 and CO(CLC-SECLRHC)in two separated streams.CLC provides reactant CO_(2) and energy to feed SECLRHC,which generates hydrogen in a higher purity,as well as the calcium cycle to generate CO in a higher purity.Techno-economic assessment of the proposed system was conducted to evaluate its efficiency and economic competitiveness.Studies revealed that the optimal molar ratios of oxygen carrier(OC)/NG and steam/NG for reforming were recommended to be 1.7 and 1.0,respectively.The heat integration within CLC and SECLRHC units can be achieved by circulating hot OCs.The desired temperatures of fuel reactor(FR)and reforming reactor(RR)should be 850C and 600C,respectively.The heat coupling between CLC and SECLRHC units can be realized via a jacket-type reactor,and the NG split ratio for reforming and combustion was 0.53:0.47.Under the optimal conditions,the H2 purity,the H2 yield and the CH4 conversion efficiency were 98.76%,2.31 mol mol-1 and 97.96%,respectively.The carbon and hydrogen utilization efficiency respectively were 58.60% and 72.45%in terms of the total hydrogen in both steam and NG.The exergy efficiency of the overall process reached 70.28%.In terms of the conventional plant capacity(75 × 103 t y^(-1))and current raw materials price(2500$t^(-1)),the payback period can be 6.2 years and the IRR would be 11.5,demonstrating an economically feasible and risk resistant capability.展开更多
This article deals with the design of energy efficient water utilization systems allowing operation split. Practical features such as operating flexibility and capital cost have made the number of sub operations an im...This article deals with the design of energy efficient water utilization systems allowing operation split. Practical features such as operating flexibility and capital cost have made the number of sub operations an important parameter of the problem. By treating the direct and indirect heat transfers separately, target freshwater and energy consumption as well as the operation split conditions are first obtained. Subsequently, a mixed integer non-linear programming (MINLP) model is established for the design of water network and the heat exchanger network (HEN). The proposed systematic approach is limited to a single contaminant. Example from literature is used to illustrate the applicability of the approach.展开更多
Design and control of pressure-swing distillation(PSD) with different heat integration modes for the separation of methyl acetate/methanol azeotrope are explored using Aspen Plus and Aspen Dynamics. First, an optimum ...Design and control of pressure-swing distillation(PSD) with different heat integration modes for the separation of methyl acetate/methanol azeotrope are explored using Aspen Plus and Aspen Dynamics. First, an optimum steady-state separation configuration conditions are obtained via taking the total annual cost(TAC) or total reboiler heat duty as the objective functions. The results show that about 27.68% and 25.40% saving in TAC can be achieved by the PSD with full and partial heat integration compared to PSD without heat integration. Second,temperature control tray locations are obtained according to the sensitivity criterion and singular value decomposition(SVD) analysis and the single-end control structure is effective based on the feed composition sensitivity analysis. Finally, the comparison of dynamic controllability is made among various control structures for PSD with partial and full heat integration. It is shown that both control structures of composition/temperature cascade and pressure-compensated temperature have a good dynamic response performance for PSD with heat integration facing feed flowrate and composition disturbances. However, PSD with full heat integration performs the poor controllability despite of a little bit of economy.展开更多
A double-effect reactive distillation(DERD)process was proposed for the production of propylene glycol methyl ether from propylene oxide and methanol to overcome the shortcoming of low selectivity and high-energy cons...A double-effect reactive distillation(DERD)process was proposed for the production of propylene glycol methyl ether from propylene oxide and methanol to overcome the shortcoming of low selectivity and high-energy consumption in the tubular plug-flow reactor.A single-column reactive distillation(RD)process was conducted under optimized operating conditions based on sensitivity analysis as a reference.The results demonstrated that the proposed DERD process is able to achieve more than 95%selectivity of the desired product.After that,a design approach of the DERD process with an objective of the minimum operating cost was proposed to achieve further energy savings in the RD process.The proposed DERD configuration can provide a large energy-savings by totally utilization of the overhead vapor steam in the high-pressure RD column.A comparison of the single-column RD process revealed that the proposed DERD process can reduce the operating cost and the total annual cost of 25.3%and 30.7%,respectively,even though the total capital cost of DERD process is larger than that of the RD process.展开更多
The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were propos...The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were proposed, through which the overall heat transfer coefficient at different height of column under different operating conditions could be obtained before the experiment. Then the separation of a binary ethanol-water system was carried out experimentally as a case study to verify the heat transfer model and the aforementioned calculation method. The close results between the calculation, the simulation, and the experiments suggested that the proposed model and the calculation method in this paper were accurate and applicable. Meanwhile, it was demonstrated that the HIDiC shows obvious effect of reducing entropy increase and improving thermodynamic efficiency as compared to conventional distillation column.展开更多
In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when int...In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when integrated with the background process and how to optimize the evaporator is shown. From the case studies, it can be seen that sometimes incomplete integration and heat pump evaporation are better than complete integration so should be considered as candidate retrofit schemes.展开更多
A generalized steady-state model is being developed for an internal heat integrated distillation column (IHIDiC). A procedure incorporating the Newton-Raphson method is devised for solving the model equations. Separat...A generalized steady-state model is being developed for an internal heat integrated distillation column (IHIDiC). A procedure incorporating the Newton-Raphson method is devised for solving the model equations. Separation of an ethanol-water binary mixture is simulated and analyzed with the model. Two pinch points are found within the process, making the separation extremely difficult and expensive. Two sharp fronts in the temperature and the composition profiles are being observed. With the introduction of heat integration, satisfactory separation may be obtained in a limited number of stages with lower reflux ratios. Increasing the pressure difference between the rectifying and the stripping sections, however, would bring about a reduced relative volatility between the two components involved, creating adverse separation performances. It is obvious that optimization of the IHIDiC is of prime importance.展开更多
The PRO/Ⅱ process simulation software was applied to carry out simulated calculation of the aromatics fractionation unit and the heat integrated rectification process was proposed for the aromatics fractionation sect...The PRO/Ⅱ process simulation software was applied to carry out simulated calculation of the aromatics fractionation unit and the heat integrated rectification process was proposed for the aromatics fractionation section of the 1.0 Mt/a toluene disproportionation unit at the Zhenhai Refining and Chemical Company. The optimized operating parameters were obtained through the energy utilization analysis,process simulation,heat exchanger calculations and comparisons of utility consumption. The operation of commercialized unit has revealed that the design parameters of each rectification column were consistent with the operation results,and the utility consumption was about 47% lower than the traditional heat integrated process.展开更多
Energy integration and mass integration are important approaches to achieve energy saving and emission reduction in the process industry.Generally,the methods can be classified into two groups,viz.:conceptual design m...Energy integration and mass integration are important approaches to achieve energy saving and emission reduction in the process industry.Generally,the methods can be classified into two groups,viz.:conceptual design methods and mathematical programming methods.The former includes mainly graphical methods based on pinch technology that is operated easily.A feasible solution can be quickly obtained.Conceptual design methods are sequential in nature including two steps,namely:targeting and designing.The latter is based on superstructure optimization,and corresponding algorithm is adopted to solve the model.The trade-offs and connections among the entire network can be established and explored.Multiple factors can be considered and optimized simultaneously by mathematical programming methods.This paper describes the synthesis of heat integrated water allocation networks(HIWAN)based on both conceptual design methods and mathematical programming methods systematically.In addition,the characteristics and shortcomings of the existing research methods are summarized,and the future research direction is prospected.展开更多
Coupling between electricity systems and heating systems are becoming stronger,leading to more flexible and more complex interactions between these systems.The operation of integrated energy systems is greatly affecte...Coupling between electricity systems and heating systems are becoming stronger,leading to more flexible and more complex interactions between these systems.The operation of integrated energy systems is greatly affected,especially when security is concerned.Steady-state analysis methods have been widely studied in recent research,which is far from enough when the slow thermal dynamics of heating networks are introduced.Therefore,an integrated quasi-dynamic model of integrated electricity and heating systems is developed.The model combines a heating network dynamic thermal model and the sequential steady-state models of electricity networks,coupling components,and heating network hydraulics.Based on this model,a simulation method is proposed and quasi-dynamic interactions between electricity systems and heating systems are quantified with the highlights of transport delay.Then the quasi-dynamic interactions were applied using security control to relieve congestion in electricity systems.Results show that both the transport delay and control strategies have significant influences on the quasi-dynamic interactions.展开更多
The so-called indirect evaporative cooling technology is widely used in air conditioning applications.The thermal characterization of tube-type indirect evaporative coolers,however,still presents challenges which need...The so-called indirect evaporative cooling technology is widely used in air conditioning applications.The thermal characterization of tube-type indirect evaporative coolers,however,still presents challenges which need to be addressed to make this technology more reliable and easy to implement.This experimental study deals with the performances of a tube-type indirect evaporative cooler based on an aluminum tube with a 10 mm diameter.In particular,the required tests were carried out considering a range of dry-bulb temperatures between 16℃ and 18℃ and a temperature difference between the wet-bulb and dry-bulb temperature of 2℃∼4℃.The integrated convective heat transfer coefficient inside the tube in the drenching condition has been found to lie in the range between 36.10 and 437.4(W/(m^(2)⋅K)).展开更多
When a historic façade needs to be preserved or when the seismic considerations favor use of a concrete wall system and fire considerations limit exterior thermal insulation,one needs to use interior thermal insu...When a historic façade needs to be preserved or when the seismic considerations favor use of a concrete wall system and fire considerations limit exterior thermal insulation,one needs to use interior thermal insulation systems.Interior thermal insulation systems are less effective than the exterior systems and will not reduce the effect of thermal bridges.Yet they may be successfully used and,in many instances,are recommended as a complement to the exterior insulation.This paper presents one of these cases.It is focused on the most successful applications of capillary active,dynamic interior thermal insulation.This happens when such insulation is integrated with heating,cooling and ventilation,air conditioning(HVAC)system.Starting with a pioneering work of the Technical University in Dresden in development of capillary active interior insulations,we propose a next generation,namely,a bio-fiber thermal insulation.When completing the review,this paper proposes a concept of a joint research project to be undertaken by partners from the US(where improvement of indoor climate in exposed coastal areas is needed),China(indoor climate in non-air conditioned concrete buildings is an issue),and Germany(where the bio-fiber technology has been developed).展开更多
An integrated heat and power system(IHPS)is a promising approach for alleviating wind curtailment problems.In an IHPS,the combined heat and power(CHP)plant is the key component,which supplies both heat and electric lo...An integrated heat and power system(IHPS)is a promising approach for alleviating wind curtailment problems.In an IHPS,the combined heat and power(CHP)plant is the key component,which supplies both heat and electric loads,and couples the thermal system and power system.However,existing research commonly ignores or simplifies the internal composition of CHP plants,which could lead to some unavoidable errors.This paper focuses on the internal composition of CHP plants,and models the physical processes in different components and flexible resources in the CHP plant.Furthermore,a joint dispatch problem of an IHPS with the above CHP plant models is formulated,and an iterative algorithm is developed to handle the nonlinearity in this problem.Case studies are performed based on a real CHP plant in Northern China,and the results indicate that the synergistic effect of different energy resources in the CHP plant is realized by the joint dispatch model,which promotes wind power accommodation and reduces fossil fuel consumption.展开更多
Fully utilizing the flexibility provided by a district heating system(DHS)can promote wind power accommodation for an electric power system(EPS).However,for privacy or communication reasons,existing power and heat dis...Fully utilizing the flexibility provided by a district heating system(DHS)can promote wind power accommodation for an electric power system(EPS).However,for privacy or communication reasons,existing power and heat dispatch methods are not suitable for practical application.In this paper,a general math formulation of the hierarchical dispatch method is proposed to coordinate EPS and DHS operators based on the feasible region of boundary variables(FRBV),and a method based on the simplicial approximation approach is proposed to obtain a conservative FRBV approximation of a DHS.A simulation based on a real 41-node DHS is constructed to determine the factors that may impact the boundaries of the FRBV,and then the performance of the simplicial approximation approach is displayed by visualizing the approximation process for the FRBV,and finally three dispatch methods are compared to show the advantages of the proposed hierarchical dispatch method.展开更多
In this work, the extractive distillation with heat integration process is extended to separate the pressure-insensitive benzene-cyclohexane azeotrope by using furfural as the entrainer. The optimal design of extracti...In this work, the extractive distillation with heat integration process is extended to separate the pressure-insensitive benzene-cyclohexane azeotrope by using furfural as the entrainer. The optimal design of extractive distillation process is established to achieve minimum energy requirement using the multi-objective genetic algorithm, and the results show that energy saving for this heat integration process is 15.7%. Finally, the control design is performed to investigate the system's dynamic performance, and three control structures are studied. The pressure-compensated temperature control scheme is proposed based on the first two control structures, and the dynamic responses reveal that the feed disturbances in both flow rate and benzene composition can be mitigated well.展开更多
基金supported by Shanghai Rising-Star Program(No.22QA1403900)the National Natural Science Foundation of China(No.71804106)the Noncarbon Energy Conversion and Utilization Institute under the Shanghai Class IV Peak Disciplinary Development Program.
文摘Cascading faults have been identified as the primary cause of multiple power outages in recent years.With the emergence of integrated energy systems(IES),the conventional approach to analyzing power grid cascading faults is no longer appropriate.A cascading fault analysis method considering multi-energy coupling characteristics is of vital importance.In this study,an innovative analysis method for cascading faults in integrated heat and electricity systems(IHES)is proposed.It considers the degradation characteristics of transmission and energy supply com-ponents in the system to address the impact of component aging on cascading faults.Firstly,degradation models for the current carrying capacity of transmission lines,the water carrying capacity and insulation performance of thermal pipelines,as well as the performance of energy supply equipment during aging,are developed.Secondly,a simulation process for cascading faults in the IHES is proposed.It utilizes an overload-dominated development model to predict the propagation path of cascading faults while also considering network islanding,electric-heating rescheduling,and load shedding.The propagation of cascading faults is reflected in the form of fault chains.Finally,the results of cascading faults under different aging levels are analyzed through numerical examples,thereby verifying the effectiveness and rationality of the proposed model and method.
文摘In the realm of the synthesis of heat-integrated distillation configurations,the conventional approach for exploring more heat integration possibilities typically entails the splitting of a single column into a twocolumn configuration.However,this approach frequently necessitates tedious enumeration procedures,resulting in a considerable computational burden.To surmount this formidable challenge,the present study introduces an innovative remedy:The proposition of a superstructure that encompasses both single-column and multiple two-column configurations.Additionally,a simultaneous optimization algorithm is applied to optimize both the process parameters and heat integration structures of the twocolumn configurations.The effectiveness of this approach is demonstrated through a case study focusing on industrial organosilicon separation.The results underscore that the superstructure methodology not only substantially mitigates computational time compared to exhaustive enumeration but also furnishes solutions that exhibit comparable performance.
基金supported by National Natural Science Foundation of China(52177086)Fundamental Research Funds for the Central Universities(2023ZYGXZR063).
文摘Observability analysis(OA)is vital to obtaining the available input measurements of state estimation(SE)in an integrated electricity and heating system(IEHS).Considering the thermal quasi-dynamics in pipelines,the measurement equations in heating systems are dependent on the estimated results,leading to an interdependency between OA and SE.Conventional OA methods require measurement equations be known exactly before SE is performed,and they are not applicable to IEHSs.To bridge this gap,a scenario-based OA scheme for IEHSs is devised that yields reliable analysis results for a predefined set of time-delay scenarios to cope with this interdependency.As its core procedure,the observable state identification and observability restoration are formulated in terms of integer linear programming.Numerical tests are conducted to demonstrate the validity and superiority of the proposed formulation.
基金This work was supported by the Science and Technology Program of State Grid Corporation of China(522300190008).
文摘Combined heat and electricity operation with variable mass flow rates promotes flexibility,economy,and sustainability through synergies between electric power systems(EPSs)and district heating systems(DHSs).Such combined operation presents a highly nonlinear and nonconvex optimization problem,mainly due to the bilinear terms in the heat flow model—that is,the product of the mass flow rate and the nodal temperature.Existing methods,such as nonlinear optimization,generalized Benders decomposition,and convex relaxation,still present challenges in achieving a satisfactory performance in terms of solution quality and computational efficiency.To resolve this problem,we herein first reformulate the district heating network model through an equivalent transformation and variable substitution.The reformulated model has only one set of nonconvex constraints with reduced bilinear terms,and the remaining constraints are linear.Such a reformulation not only ensures optimality,but also accelerates the solving process.To relax the remaining bilinear constraints,we then apply McCormick envelopes and obtain an objective lower bound of the reformulated model.To improve the quality of the McCormick relaxation,we employ a piecewise McCormick technique that partitions the domain of one of the variables of the bilinear terms into several disjoint regions in order to derive strengthened lower and upper bounds of the partitioned variables.We propose a heuristic tightening method to further constrict the strengthened bounds derived from the piecewise McCormick technique and recover a nearby feasible solution.Case studies show that,compared with the interior point method and the method implemented in a global bilinear solver,the proposed tightening McCormick method quickly solves the heat–electricity operation problem with an acceptable feasibility check and optimality.
基金Supported by the National Fundamental Research Development Program of China (No. 2000026308).
文摘This paper addresses the application of stochastic optimization approaches to the synthesis of heatintegrated complex distillation system, which is characterized by large-scale combinatorial feature. Conventionaland complex columns, thermally coupled (linked) side strippers and side rectifiers as well as heat integration betweenthe different columns are simultaneously considered. The problem is formulated as an MINLP (mixed-integernonlinear programming) problem. A simulated annealing algorithm is proposed to deal with the MINLP problemand a shortcut method is applied to evaluate all required design parameters as well as the total cost function. Twoillustrating examples are presented.
基金supported by National Natural Science Foundation of China(U1810205)The authors would also like to thank the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province(20220003)Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2021L002)for their support.
文摘The natural gas(NG)reforming is currently one of the low-cost methods for hydrogen production.However,the mixture of H2 and CO_(2) in the produced gas inevitably includes CO_(2) and necessitates the costly CO_(2) separation.In this work,a novel double chemical looping involving both combustion(CLC)and sorption-enhanced reforming(SE-CLR)was proposed towards the co-production of H2 and CO(CLC-SECLRHC)in two separated streams.CLC provides reactant CO_(2) and energy to feed SECLRHC,which generates hydrogen in a higher purity,as well as the calcium cycle to generate CO in a higher purity.Techno-economic assessment of the proposed system was conducted to evaluate its efficiency and economic competitiveness.Studies revealed that the optimal molar ratios of oxygen carrier(OC)/NG and steam/NG for reforming were recommended to be 1.7 and 1.0,respectively.The heat integration within CLC and SECLRHC units can be achieved by circulating hot OCs.The desired temperatures of fuel reactor(FR)and reforming reactor(RR)should be 850C and 600C,respectively.The heat coupling between CLC and SECLRHC units can be realized via a jacket-type reactor,and the NG split ratio for reforming and combustion was 0.53:0.47.Under the optimal conditions,the H2 purity,the H2 yield and the CH4 conversion efficiency were 98.76%,2.31 mol mol-1 and 97.96%,respectively.The carbon and hydrogen utilization efficiency respectively were 58.60% and 72.45%in terms of the total hydrogen in both steam and NG.The exergy efficiency of the overall process reached 70.28%.In terms of the conventional plant capacity(75 × 103 t y^(-1))and current raw materials price(2500$t^(-1)),the payback period can be 6.2 years and the IRR would be 11.5,demonstrating an economically feasible and risk resistant capability.
基金Supported by the Major Project of National Natural Science Foundation of China (No.20409205) and National High Technology Research and Development Program of China (No.G20070040).
文摘This article deals with the design of energy efficient water utilization systems allowing operation split. Practical features such as operating flexibility and capital cost have made the number of sub operations an important parameter of the problem. By treating the direct and indirect heat transfers separately, target freshwater and energy consumption as well as the operation split conditions are first obtained. Subsequently, a mixed integer non-linear programming (MINLP) model is established for the design of water network and the heat exchanger network (HEN). The proposed systematic approach is limited to a single contaminant. Example from literature is used to illustrate the applicability of the approach.
文摘Design and control of pressure-swing distillation(PSD) with different heat integration modes for the separation of methyl acetate/methanol azeotrope are explored using Aspen Plus and Aspen Dynamics. First, an optimum steady-state separation configuration conditions are obtained via taking the total annual cost(TAC) or total reboiler heat duty as the objective functions. The results show that about 27.68% and 25.40% saving in TAC can be achieved by the PSD with full and partial heat integration compared to PSD without heat integration. Second,temperature control tray locations are obtained according to the sensitivity criterion and singular value decomposition(SVD) analysis and the single-end control structure is effective based on the feed composition sensitivity analysis. Finally, the comparison of dynamic controllability is made among various control structures for PSD with partial and full heat integration. It is shown that both control structures of composition/temperature cascade and pressure-compensated temperature have a good dynamic response performance for PSD with heat integration facing feed flowrate and composition disturbances. However, PSD with full heat integration performs the poor controllability despite of a little bit of economy.
基金supported by the National Nature Science Foundation of China(21878315 and 21808223)National Key Research and Development Program of China(2017YFA0206803)+3 种基金Innovation Academy for Green ManufactureCAS(IAGM2020C17)K.C.Wong Education Foundation(GJTD-2018-04)。
文摘A double-effect reactive distillation(DERD)process was proposed for the production of propylene glycol methyl ether from propylene oxide and methanol to overcome the shortcoming of low selectivity and high-energy consumption in the tubular plug-flow reactor.A single-column reactive distillation(RD)process was conducted under optimized operating conditions based on sensitivity analysis as a reference.The results demonstrated that the proposed DERD process is able to achieve more than 95%selectivity of the desired product.After that,a design approach of the DERD process with an objective of the minimum operating cost was proposed to achieve further energy savings in the RD process.The proposed DERD configuration can provide a large energy-savings by totally utilization of the overhead vapor steam in the high-pressure RD column.A comparison of the single-column RD process revealed that the proposed DERD process can reduce the operating cost and the total annual cost of 25.3%and 30.7%,respectively,even though the total capital cost of DERD process is larger than that of the RD process.
基金supported by the National Key Research and Development Program of China(2017YFB0602500)the Foundation for High Level Talents of Hebei (A2017002032).
文摘The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were proposed, through which the overall heat transfer coefficient at different height of column under different operating conditions could be obtained before the experiment. Then the separation of a binary ethanol-water system was carried out experimentally as a case study to verify the heat transfer model and the aforementioned calculation method. The close results between the calculation, the simulation, and the experiments suggested that the proposed model and the calculation method in this paper were accurate and applicable. Meanwhile, it was demonstrated that the HIDiC shows obvious effect of reducing entropy increase and improving thermodynamic efficiency as compared to conventional distillation column.
文摘In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when integrated with the background process and how to optimize the evaporator is shown. From the case studies, it can be seen that sometimes incomplete integration and heat pump evaporation are better than complete integration so should be considered as candidate retrofit schemes.
文摘A generalized steady-state model is being developed for an internal heat integrated distillation column (IHIDiC). A procedure incorporating the Newton-Raphson method is devised for solving the model equations. Separation of an ethanol-water binary mixture is simulated and analyzed with the model. Two pinch points are found within the process, making the separation extremely difficult and expensive. Two sharp fronts in the temperature and the composition profiles are being observed. With the introduction of heat integration, satisfactory separation may be obtained in a limited number of stages with lower reflux ratios. Increasing the pressure difference between the rectifying and the stripping sections, however, would bring about a reduced relative volatility between the two components involved, creating adverse separation performances. It is obvious that optimization of the IHIDiC is of prime importance.
文摘The PRO/Ⅱ process simulation software was applied to carry out simulated calculation of the aromatics fractionation unit and the heat integrated rectification process was proposed for the aromatics fractionation section of the 1.0 Mt/a toluene disproportionation unit at the Zhenhai Refining and Chemical Company. The optimized operating parameters were obtained through the energy utilization analysis,process simulation,heat exchanger calculations and comparisons of utility consumption. The operation of commercialized unit has revealed that the design parameters of each rectification column were consistent with the operation results,and the utility consumption was about 47% lower than the traditional heat integrated process.
文摘Energy integration and mass integration are important approaches to achieve energy saving and emission reduction in the process industry.Generally,the methods can be classified into two groups,viz.:conceptual design methods and mathematical programming methods.The former includes mainly graphical methods based on pinch technology that is operated easily.A feasible solution can be quickly obtained.Conceptual design methods are sequential in nature including two steps,namely:targeting and designing.The latter is based on superstructure optimization,and corresponding algorithm is adopted to solve the model.The trade-offs and connections among the entire network can be established and explored.Multiple factors can be considered and optimized simultaneously by mathematical programming methods.This paper describes the synthesis of heat integrated water allocation networks(HIWAN)based on both conceptual design methods and mathematical programming methods systematically.In addition,the characteristics and shortcomings of the existing research methods are summarized,and the future research direction is prospected.
基金This work was supported in part by the National Natural Science Foundation of China(NSFC)(51537006)European Union’s Horizon 2020 research and innovation programme(774309,MAGNATUDE),WEFO FLEXIS project.
文摘Coupling between electricity systems and heating systems are becoming stronger,leading to more flexible and more complex interactions between these systems.The operation of integrated energy systems is greatly affected,especially when security is concerned.Steady-state analysis methods have been widely studied in recent research,which is far from enough when the slow thermal dynamics of heating networks are introduced.Therefore,an integrated quasi-dynamic model of integrated electricity and heating systems is developed.The model combines a heating network dynamic thermal model and the sequential steady-state models of electricity networks,coupling components,and heating network hydraulics.Based on this model,a simulation method is proposed and quasi-dynamic interactions between electricity systems and heating systems are quantified with the highlights of transport delay.Then the quasi-dynamic interactions were applied using security control to relieve congestion in electricity systems.Results show that both the transport delay and control strategies have significant influences on the quasi-dynamic interactions.
基金This work was supported by Natural Science Basic Research Program of Shaanxi(2021JQ-689).
文摘The so-called indirect evaporative cooling technology is widely used in air conditioning applications.The thermal characterization of tube-type indirect evaporative coolers,however,still presents challenges which need to be addressed to make this technology more reliable and easy to implement.This experimental study deals with the performances of a tube-type indirect evaporative cooler based on an aluminum tube with a 10 mm diameter.In particular,the required tests were carried out considering a range of dry-bulb temperatures between 16℃ and 18℃ and a temperature difference between the wet-bulb and dry-bulb temperature of 2℃∼4℃.The integrated convective heat transfer coefficient inside the tube in the drenching condition has been found to lie in the range between 36.10 and 437.4(W/(m^(2)⋅K)).
文摘When a historic façade needs to be preserved or when the seismic considerations favor use of a concrete wall system and fire considerations limit exterior thermal insulation,one needs to use interior thermal insulation systems.Interior thermal insulation systems are less effective than the exterior systems and will not reduce the effect of thermal bridges.Yet they may be successfully used and,in many instances,are recommended as a complement to the exterior insulation.This paper presents one of these cases.It is focused on the most successful applications of capillary active,dynamic interior thermal insulation.This happens when such insulation is integrated with heating,cooling and ventilation,air conditioning(HVAC)system.Starting with a pioneering work of the Technical University in Dresden in development of capillary active interior insulations,we propose a next generation,namely,a bio-fiber thermal insulation.When completing the review,this paper proposes a concept of a joint research project to be undertaken by partners from the US(where improvement of indoor climate in exposed coastal areas is needed),China(indoor climate in non-air conditioned concrete buildings is an issue),and Germany(where the bio-fiber technology has been developed).
基金supported by the National Key Research and Development Program of China under Grant 2017YFB0902100.
文摘An integrated heat and power system(IHPS)is a promising approach for alleviating wind curtailment problems.In an IHPS,the combined heat and power(CHP)plant is the key component,which supplies both heat and electric loads,and couples the thermal system and power system.However,existing research commonly ignores or simplifies the internal composition of CHP plants,which could lead to some unavoidable errors.This paper focuses on the internal composition of CHP plants,and models the physical processes in different components and flexible resources in the CHP plant.Furthermore,a joint dispatch problem of an IHPS with the above CHP plant models is formulated,and an iterative algorithm is developed to handle the nonlinearity in this problem.Case studies are performed based on a real CHP plant in Northern China,and the results indicate that the synergistic effect of different energy resources in the CHP plant is realized by the joint dispatch model,which promotes wind power accommodation and reduces fossil fuel consumption.
基金This work was supported by the National Key Research and Development Program of China under Grant 2017YFB0902100 and State Grid Corporation of China.
文摘Fully utilizing the flexibility provided by a district heating system(DHS)can promote wind power accommodation for an electric power system(EPS).However,for privacy or communication reasons,existing power and heat dispatch methods are not suitable for practical application.In this paper,a general math formulation of the hierarchical dispatch method is proposed to coordinate EPS and DHS operators based on the feasible region of boundary variables(FRBV),and a method based on the simplicial approximation approach is proposed to obtain a conservative FRBV approximation of a DHS.A simulation based on a real 41-node DHS is constructed to determine the factors that may impact the boundaries of the FRBV,and then the performance of the simplicial approximation approach is displayed by visualizing the approximation process for the FRBV,and finally three dispatch methods are compared to show the advantages of the proposed hierarchical dispatch method.
基金supported by the National Natural Science Foundation of China(grant number 21476261)the Key Research and Development Plan Project of Shandong Province(grant number 2015GGX107004)
文摘In this work, the extractive distillation with heat integration process is extended to separate the pressure-insensitive benzene-cyclohexane azeotrope by using furfural as the entrainer. The optimal design of extractive distillation process is established to achieve minimum energy requirement using the multi-objective genetic algorithm, and the results show that energy saving for this heat integration process is 15.7%. Finally, the control design is performed to investigate the system's dynamic performance, and three control structures are studied. The pressure-compensated temperature control scheme is proposed based on the first two control structures, and the dynamic responses reveal that the feed disturbances in both flow rate and benzene composition can be mitigated well.