Modification of Montmorillonite through Intercalative Polymerization

Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studies. It can disperse easily in epoxy resin to form exfoliated nanocomposites. The nanoscale silicate platelets dispersed in water can be metallized by silver deposition.

The Intercalative Binding Between Rivanol and DNA

Rivanol(RVN) binds to the double helical DNA with a high affinity. Strong hypochromism and appreciable red shifts in the absorption spectra can be observed when RVN binds to CT DNA. The results of absorption spectra, KI quenching studies, fluorescence polarization measurements, competitive binding studies. and thermal denaturation experiments suggested that the interaction between RVN and DNA be intercalative.

An abnormal carbody swaying of intercity EMU train caused by low wheel-rail equivalent conicity and damping force unloading of yaw damper

Low-frequency carbody swaying phenomenon often occurs to railway vehicles due to hunting instability,which seriously deteriorates the ride comfort of passengers.This paper investigates low-frequency carbody swaying through experimental analysis and numerical simulation.In the tests,the carbody acceleration,the wheel-rail profiles,and the dynamic characteristics of dampers were measured to understand the characteristics of the abnormal carbody vibration and to find out its primary contributor.Linear and nonlinear numerical simulations on the mechanism and optimization measures were carried out to solve this carbody swaying issue.The results showed that the carbody swaying is the manifest of carbody hunting instability.The low equivalent conicity and the decrease of dynamic damping of the yaw damper are probably the cause of this phenomenon.The optimization measures to increase the equivalent conicity and dynamic damping of the yaw damper were put forward and verified by on-track tests.The results of this study could enrich the knowledge of carbody hunting and provide a reference for solving abnormal carbody vibrations.

Carbon emissions reduction potentiality for railroad transportation based on life cycle assessment

This study addresses the comparative carbon emissions of different transportation modes within a unified evaluation framework,focusing on their carbon footprints from inception to disposal.Specifically,the entire life cycle carbon emissions of High-Speed Rail(HSR),battery electric vehicles,conventional internal combustion engine vehicles,battery electric buses,and conventional internal combustion engine buses are analyzed.The life cycle is segmented into vehicle manufacturing,fuel or electricity production,operational,and dismantlingrecycling stages.This analysis is applied to the Beijing-Tianjin intercity transportation system to explore emission reduction strategies.Results indicate that HSR demonstrates significant carbon emission reduction,with an intensity of only 24%-32% compared to private vehicles and 47%-89% compared to buses.Notably,HSR travel for Beijing-Tianjin intercity emits only 24% of private vehicle emissions,demonstrating the emission reduction benefits of transportation structure optimization.Additionally,predictive modeling reveals the potential for carbon emission reduction through energy structure optimization,providing a guideline for the development of effective transportation management systems.

Interaction between Ternary Rare Earth Complexes of Cinnamic Acid and Phenanthroline with DNA by Spectroscopy

The interaction of ternary complexes [RE(phen)(cin)_3(H_2O)](RE= Nd (III),Ce(III),Eu(III))with calf thymus DNA was investigated by electronic absorption spectroscopy, ethidium bromide(EB)-DNA quenching fluorescent spectra and resonance light scattering. All experimental results indicate that the three complexes bind to DNA by the electrostatic mode and the intercalative mode. It is predicted that these complexes show high anticancer activity or other biologic activity.

Flame Retardant and Pyrolytic Behaviors of Polyamide 6/Montmorillonite Nanocomposite

Na +-montmorillonite(Na +-MMT) was converted to organic montmorillonite(OMMT) using modifier which was synthesized at authors’ laboratory. PA6/OMMT nanocomposite was prepared via in situ intercalative polymerization. The limiting oxygen index (LOI), UL 94V flame retardancy and thermal stability of PA6/OMMT using thermal gravity analysis (TGA) were measured. The Fourier transform infrared (FTIR) technique was used to analyze the pyrolytic residuum and the cone calorimeter (CONE) was applied to determine a number of combustion parameters which were closely related to fire safety, including heat release rate, mass loss rate, effective combustion heat, total heat release, specific extinction area and the time of ignition. In addition, the elemental composition of the surface pyrolytic residuum and the corresponding X-ray photoelectron spectroscopy (XPS) data were obtained, and the morphology of the residuum from CONE measurement was examined by scanning electron microscope (SEM).

Synthesis,Crystal Structure and DNA-binding Properties of a New Copper(Ⅱ) Schiff Base Complex

A new asymmetric bidentate copper（Ⅱ） complex,CuL 2（HL=2-（（E）-（4-bromophenylimino）methyl）-6-bromo-4-chlorophenol）,has been synthesized and characterized by elemental analyses and single-crystal X-ray diffraction.The complex crystallizes in the monoclinic space group P2 1 /c with a=11.218（3）,b=9.355（3）,c=13.449（4）,β=108.722（4）°,V=1336.8（6）3,Z=2,Dc=2.008 g/cm 3,μ（MoKα）=7.024 mm-1,F（000）=806,S=0.999,the final R=0.0342 and wR=0.0641for2611observed reflections （I〉2σ（I））.The central copper（Ⅱ） is four-coordinate and bonds to two nitrogen and two oxygen atoms from two Schiff base ligands.The complex is linked into a two-dimensional supramolecular structure by weak intermolecular interactions.In addition,DNA-binding properties of the metal complex were investigated using spectrometric titrations and viscosity measurements.The results show that the complex binds with calf-thymus DNA（CT-DNA）,presumably via a partial intercalative mode.The intrinsic binding constant of the Cu（Ⅱ） complex with DNA is 7.335×10 3 M-1.

德国铁路公司与DHL合作模式研究

德国铁路公司和德国快递企业DHL于2005年合作利用铁路运送快件,并取得了良好的合作效果。双方合作的成功实施主要依赖于运输设备的良好改进、智能化信息追踪系统的采用、列车时刻的合理安排及货场的科学选址;通过合作,强化了DHL承担社会责任的形象,提升了德国铁路公司和DHL的服务水平,推进了德国铁路公司的现代物流建设进程;在分析合作背景、合作方式及合作效果的基础上,得出结论:公铁联运是铁路公司和快递企业实现双赢的重要途径,合理的物流园区规划有助于推动多种运输方式顺畅衔接并保证货物高效中转,压缩运输时限、发展集装化运输是创新铁路运输组织的关键。

Studies on the Interaction of Cobalt Mixed-Ligand Coordination Compound Containing Tetrapyrido [3,2-a:2′,3′-c:3″, 2″-h:2■,3■-j] phenazine with DNA

A new monometallic complex [Co(phen)_2tpphz]^(3+) (where tpphz is tetrapyrido [3,2-a:2′,3′-c:3″,2″-h:2′″,3′″-j] phenazine) was synthesized by the reaction of 5, 6-diamino-1,10-phenanthroline with [Co(phen)_2(phendione)]^(3+). It was characterized by elemental analysis, molar conductivity, IR, ~1H NMR, ultraviolet and fluorescence spectroscopy. The interaction of the complex with DNA was also investigated. The complex shows the absorption hypochromicity, fluorescence enhancement, the specific viscosity increased when bound to calf thymus DNA. The cyclic voltammetry (CV) measurement showed a change in peak current with the addition of DNA. All the results provide the support for the intercalative binding mode of the mononuclear complex.

Evaluation and optimization analysis of high-speed rail network structure in Northeast China under the background of northeast revitalization

The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adoption of the operation frequency data of HSR from 12306 website,and based on the HSR connection strength model and social network analysis model,as well as according to the HSR connection strength,HSR network density,centrality,agglomeration subgroup,and other indicators,we analyzed the characteristics of HSR network structure in Northeast China.Results show that the number of HSR cities in Northeast China is small,cities in HSR network generally exhibit weak connectivity,and the existence of HSR network marginalizes cities such as Ulanhot,Baicheng,and Songyuan,which significantly reduce the overall network connectivity of Northeast China.The overall centrality of HSR network in Northeast China is characterized by“one axis,four edges”;specifically,the one axis is located in Harbin-Dalian transportation line and the four edges are located on both sides of the main axis of Harbin-Dalian transportation line.Eight agglomeration subgroups(four double city subgroups and four multi city subgroups)have formed in Northeast China.The core status of Shenyang in HSR network is improved significantly,and“one axis and two wings”HSR network in Liaoning Province is improved significantly.With the gradual expansion of Chaoyang-Fuxin,Dandong-Benxi,and Jilin-Yanji branch networks,the“point axis”HSR network mode in Northeast China has gradually developed and matured.In the future,it is recommended to rely on eight agglomerating subgroups to encrypt HSR network structure,create secondary node central cities,and gradually build a new pattern of opening up in Northeast China.

On the Subtitle Translation of Foreign Movies

The subtitling of foreign movies,a special translation mode,has its own features and technical constraints(space and time).This paper states the criteria for quality subtitling and discusses the theoretical study and problems of subtitle translation.

Intercity Information

Shanghai Xbreaker Sports FactoryShanghai Tongji University Xbreaker Sports Factory is the ultimate indoor sports gymnasium.Established in September 2001, the gymnasium has a bouldering area, a park and lounge. It is the perfect game venue or professional training center for bouldering, skateboarding, rollerskating, and trick cycling.Courses are taught by

ComplexTrans-Global Rail-Road Transportation System Economical and Clustered Individual and Individualised Public Transport also Prevents the Spread of Covid 19

Land transport can no longer meet the requirements.European transport can be described by these words−crowded motorways and cities,dangerous emissions,ubiquitous traffic accidents,delays,expensive railways.Solutions are being sought to transfer a large part of passengers and especially freight transport to(high-speed)rail,and efforts are moving towards electromobility,car-sharing,5G-connectivity,autonomous driving,MaaS(Mobility as a Service)-coordinated transport or hyperloop-type solutions.However,all these solutions have additional challenges and limitations.Solutions are not being searched where they really exist-in the mutual adaptation of road and rail vehicles and their deep cooperation.The ComplexTrans project shows that simply adapting the dimensions and functions of road and rail vehicles can eliminate(or at least significantly reduce)all the problems of existing land transport.The main features of the ComplexTrans system are sufficient parking spaces,reduction of urban and non-urban congestion,electric vehicles with unlimited range and cheaper than standard cars,cheaper and more accessible battery charging,“autonomous ride”,solving the overlap between passenger and freight rail transport and making it self-financing,transferring intercity freight transport to rail,replacing part of continental air transport and many others.The cost-effective and clustered individual transport and individualised public transport of the ComplexTrans system also bring very significant reductions in the risk of transmission of covid-19 and other contagious diseases during transport.

Systematic Research and Innovation Practice on New Concepts of Construction for Xiong'an Railway Station

As the first major transport infirastructure in Xiong'an New Area,Beijing-Xiong an Intercity Railway is an important step for China State Railway Group Co.A Ltd.to quickly implement the major strategic plan of CPC Central Committee and the State Council.for the establishment of Xiong'an New Area.Xiong'an Station with double-floor spacious waiting areas and the wonderfiul integration of overpass and station building is the first modern integrated transport hub of this kind in China.Based on the characteristics of Xiong'an Station and in the light of the relevant new theories,methods and technologies,systematic studies and innovative practices on the new concept of building up a"well-connected,filly-integrated,environmen-frindly,passenger-oriented,economically-efficient,uurally-rich,intelligent and convenient"passenger station are carried oul,which achieve good results of application and help accumulate valuable experiences for the construction of passenger stations of Chinese high-speed railways in the new era.

模拟城际人口流动的量子谐振子模型

The simulation of intercity population mobility helps to deepen the understanding of intercity population mobility and its underlying laws,which has great importance for epidemic prevention and control,social management,and even urban planning.There are many factors that affect intercity population mobility,such as socioeconomic attributes,geographical distance,and industrial structure.The complexity of the coupling among these factors makes it difficult to simulate intercity population mobility.To address this issue,we propose a novel method named the quantum harmonic oscillator model for simulation of intercity population mobility(QHO-IPM).QHO-IPM describes the intercity population mobility as being affected by coupled driving factors that work as a multioscillator-coupled quantum harmonic oscillator system,which is further transformed by the oscillation process of an oscillator,namely,the breaking point of intercity population mobility.The intercity population mobility among seven cities in the Beijing-Tianjin-Hebei region and its surrounding region is taken as an example for verifying the QHO-IPM.The experimental results show that(1)compared with the reference methods(the autoregressive integrated moving average(ARIMA)and long and short-term memory(LSTM)models),the QHO-IPM achieves better simulation performance regarding intercity population mobility in terms of both overall trend and mutation.(2)The simulation error in the QHO-IPM for different-level intercity population mobility is small and stable,which illustrates the weak sensitivity of the QHO-IPM to intercity population mobility under different structures.(3)The discussion regarding the influence degree of different driving factors reveals the significant“one dominant and multiple auxiliary”factor pattern of driving factors on intercity population mobility in the study area.The proposed method has the potential to provide valuable support for understanding intercity population mobility laws and related decision-making on intercity population mobility control.

中国创新型大企业的城市间创新网络研究

Studies investigating innovation networks shaped by large innovative enterprises(LI-ENTs),which play a very important role in intercity diffusion of technology and knowledge,are rather thin on the ground.Using location information of LI-ENTs in China,we performed a headquarter-branch analysis to generate intercity innovation linkages and analyzed the patterns and dynamics of the generated network of knowledge diffusion.Although the network covers 353 cities across China,its spatial distribution is extremely uneven,with a few cities and city-dyads dominating the structure of the network.Furthermore,intercity linkages of innovation within and of urban agglomerations,as well as their central cities,stand out.With regard to network dynamics,the economic development level,innovation ability,and administrative level of cities,as well as the geographical,institutional,and technological proximity between cities are all found to have a positive impact on intercity linkages of innovations,whilst the impact of FDI on the national distribution of Chinese innovative enterprises is negative.Most importantly,the status of cities within the urban agglomeration exerts a significant positive effect in relation to the innovative enterprises’expansions,which reflects that the top-down forces of government and the bottom-up forces of market function together.

Temporal-spatial dynamic characteristics of vehicle emissions on intercity roads in Guangdong Province based on vehicle identity detection data

Estimating intercity vehicle emissions precisely would benefit collaborative control in multiple cities.Considering the variability of emissions caused by vehicles,roads,and traffic,the 24-hour change characteristics of air pollutants(CO,HC,NO_(X),PM_(2.5))on the intercity road network of Guangdong Province by vehicle categories and road links were revealed based on vehicle identity detection data in real-life traffic for each hour in July 2018.The results showed that the spatial diversity of emissions caused by the unbalanced economywas obvious.The vehicle emissions in the Pearl River Delta region(PRD)with a higher economic level were approximately 1–2 times those in the non-Pearl RiverDelta region(non-PRD).Provincial roads with high loads became potential sources of high emissions.Therefore,emission control policies must emphasize the PRD and key roads by travel guidance to achieve greater reduction.Gasoline passenger cars with a large proportion of traffic dominated morning and evening peaks in the 24-hour period and were the dominant contributors to CO and HC emissions,contributing more than 50%in the daytime(7:00–23:00)and higher than 26%at night(0:00–6:00).Diesel trucks made up 10%of traffic,but were the dominant player at night,contributed 50%–90%to NO_(X) and PM_(2.5) emissions,with amarked 24-hour change rule of more than 80%at night(23:00–5:00)and less than 60%during daytime.Therefore,targeted control measures by time-section should be set up on collaborative control.These findings provide time-varying decision support for variable vehicle emission control on a large scale.

Study on the correlation between the hierarchical urban system and high-speed railway network planning in China

This study examines the interrelatedness between the hierarchical structure of China＇s urban system and high-speed railway （HSR） network planning at the national level. As a multi-layered system, the Chinese HSR can be categorized into three sub-networks, namely, the national HSR trunk network, the national HSR extensional network, and the intercity HSR network. By examining the direct HSR network connection, HSR noda（ connection, and HSR operational frequency of 287 prefecture-level cities, this study demonstrates that the hierarchies of China＇s administrative, demographic, and economic urban systems strongly influence HSR network planning. The national HSR trunk network prioritizes the connection of top-level central cities, whereas the extensional network prioritizes cities at the （ower level of the urban system. Moreover, the national HSR system forms the backbone of the HSR network structure based on a national scale, whereas the intercity HSR system satisfies the travel needs within urban agglomerations based on the regional level.

System and prospects of China＇s intercity rail transit technology

City clusters and metropolitan areas in China are flourishing in the midst of the deepening urbanization in the country, thereby resulting in the emergence of intercity rail transit. Intereity railways connect mainline and urban railways for an integrated regional transportation system that underpins and leads the development of city clusters and metropolitan areas. This study explores the development mode and service characteristics of intercity rail transit, as well as proposes overviews on this system and prospects of its future technology in China.