With sustaining change of production mode,layout planning is no longer a thing built once for all.Cellular layout(CL) is becoming a hotspot in the research field of manufacturing system layout.Traditional researches o...With sustaining change of production mode,layout planning is no longer a thing built once for all.Cellular layout(CL) is becoming a hotspot in the research field of manufacturing system layout.Traditional researches on layout planning are mainly concentrating on aspects of layout arithmetic,style and evaluation,etc.Relatively seldom efforts are paid to CL and its specific problems as cell formation(CF),equipment sharing and CL analysis.Through problem analyzing of layout in cellular manufacturing system(CMS),research approach of cell formation,interactive layout and layout analysis threaded with process interconnection relationship(PIR) is proposed.Typical key technologies in CL like CF technology based on similarity analysis of part processes,interactive visual layout technology,layout evaluation technology founded on PIR analysis and algorithm of cell equipment sharing are put forward.Against the background of one enterprise which encounters problems of low utility of key equipments and disperse material logistic,an example of four-cell layout is given.The CL adjustment and analysis results show that equipment with high level of sharing degree should be disposed around the boundary of its main cell,and be near to other sharing cells as possible; process route should be centralized by all means,so equipment adjustment is to be implemented along direction that route intersection can be decreased; giving consideration to the existence of discrete cell,logistic route and its density should be centralized to cells formed.The proposed research can help improve equipment utility and material logistic efficiency of CL,and can be popularized to other application availably.展开更多
Tandem cell with structure of indium tin oxide(ITO)/molybdenum oxide(MoO_(3))/fullerene(C60)/copper phthalocyanine(CuPc)/C60/tris-8-hydroxy-quinolinato aluminum(Alq_(3))/Al was fabricated to study the effect of net ca...Tandem cell with structure of indium tin oxide(ITO)/molybdenum oxide(MoO_(3))/fullerene(C60)/copper phthalocyanine(CuPc)/C60/tris-8-hydroxy-quinolinato aluminum(Alq_(3))/Al was fabricated to study the effect of net carriers at the interconnection layer. The open circuit voltage and short circuit current were found to be 1.15 V and 0.56 mA/cm^(2),respectively. Almost the same performance(1.05 V, 0.58 mA/cm^(2)) of tandem cell with additional recombination layer(ITO/MoO_(3)/C60/Alq_(3)/Al/Ag/MoO_(3)/CuPc/C60/Alq_(3)/Al) demonstrates that the carrier balance is more crucial than carrier recombination. The net holes at the interconnection layer caused by more carrier generation from the back cell on one hand would enhance the recombination with electrons from the front cell and on the other hand would quench the excitons produced in CuPc of the back cell.展开更多
Scalability is an important issue in the design of interconnection networks for massively parallel systems. In this paper a scalable class of interconnection network of Hex-Cell for massively parallel systems is intro...Scalability is an important issue in the design of interconnection networks for massively parallel systems. In this paper a scalable class of interconnection network of Hex-Cell for massively parallel systems is introduced. It is called Multilayer Hex-Cell (MLH). A node addressing scheme and routing algorithm are also presented and discussed. An interesting feature of the proposed MLH is that it maintains a constant network degree regardless of the increase in the network size degree which facilitates modularity in building blocks of scalable systems. The new addressing node scheme makes the proposed routing algorithm simple and efficient in terms of that it needs a minimum number of calculations to reach the destination node. Moreover, the diameter of the proposed MLH is less than Hex-Cell network.展开更多
Interconnectivity is the key characteristic of bone tissue engineering scaffold modulating cell migration,blood vessels invasion and transport of nutrient and waste.However,efforts and understanding of the interconnec...Interconnectivity is the key characteristic of bone tissue engineering scaffold modulating cell migration,blood vessels invasion and transport of nutrient and waste.However,efforts and understanding of the interconnectivity of porous Mg is limited due to the diverse architectures of pore struts and pore size distribution of Mg scaffold systems.In this work,biomimetic hierarchical porous Mg scaffolds with tailored interconnectivity as well as pore size distribution were prepared by template replication of infiltration casting.Mg scaffold with better interconnectivity showed lower mechanical strength.Enlarging interconnected pores would enhance the interconnectivity of the whole scaffold and reduce the change of ion concentration,pH value and osmolality of the degradation microenvironment due to the lower specific surface area.Nevertheless,the degradation rates of five tested Mg scaffolds were no different because of the same geometry of strut unit.Direct cell culture and evaluation of cell density at both sides of four typical Mg scaffolds indicated that cell migration through hierarchical porous Mg scaffolds could be enhanced by not only bigger interconnected pore size but also larger main pore size.In summary,design of interconnectivity in terms of pore size distribution could regulate mechanical strength,microenvironment in cell culture condition and cell migration potential,and beyond that it shows great potential for personalized therapy which could facilitate the regeneration process.展开更多
The various stages and progress in the development of interconnect materials for solid oxide fuel cells (SOFCs )over the last two decades are reviewed. The criteria for the application of materials as interconnects ar...The various stages and progress in the development of interconnect materials for solid oxide fuel cells (SOFCs )over the last two decades are reviewed. The criteria for the application of materials as interconnects are highlighted. Interconnects based on lanthanum chromite ceramics demonstrate many inherent drawbacks and therefore are only useful for SOFCs operating around 1000℃. The advance in the research of anode-supported flat SOFCs facilitates the replacement of ceramic interconnects with metallic ones due to their significantly lowered working temperature. Besides, interconnects made of metals or alloys offer many advantages as compared to their ceramic counterpart. The oxidation response and thermal expansion behaviors of various prospective metallic interconnects are examined and evaluated. The minimization of contact resistance to achieve desired and reliable stack performance during their projected lifetime still remains a highly challenging issue with metallic interconnects. Inexpensive coating materials and techniques may play a key role in promoting the commercialization of SOFC stack whose interconnects are constructed of some current commercially available alloys. Alternatively, development of new metallic materials that are capable of forming stable oxide scales with sluggish growth rate and sufficient electrical conductivity is called for.展开更多
Physical vapor deposition(PVD)can be used to produce high-quality Gd_(2)O_(3)-doped CeO2(GDC)films.Among various PVD methods,reactive sputtering provides unique benefits,such as high deposition rates and easy upscalin...Physical vapor deposition(PVD)can be used to produce high-quality Gd_(2)O_(3)-doped CeO2(GDC)films.Among various PVD methods,reactive sputtering provides unique benefits,such as high deposition rates and easy upscaling for industrial applications.GDC thin films were successfully fabricated through reactive sputtering using a Gd_(0.2)Ce_(0.8)(at%)metallic target,and their application in solid oxide fuel cells,such as buffer layers between yttria-stabilized zirconia(YSZ)/La0.6Sr0.4Co0.2Fe0.8O_(3−δ)and as sublayers in the steel/coating system,was evaluated.First,the direct current(DC)reactive-sputtering behavior of the GdCe metallic target was determined.Then,the GDC films were deposited on NiO-YSZ/YSZ half-cells to investigate the influence of oxygen flow rate on the quality of annealed GDC films.The results demonstrated that reactive sputtering can be used to prepare thin and dense GDC buffer layers without high-temperature sintering.Furthermore,the cells with a sputtered GDC buffer layer showed better electrochemical performance than those with a screen-printed GDC buffer layer.In addition,the insertion of a GDC sublayer between the SUS441 interconnects and the Mn-Co spinel coatings contributed to the reduction of the oxidation rate for SUS441 at operating temperatures,according to the area-specific resistance tests.展开更多
The concept of tandem solar cells(TSCs) is an effective way to substantially further improve the efficiency of solar cells. The excellent optoelectronic properties and bandgap tunability of perovskites make them promi...The concept of tandem solar cells(TSCs) is an effective way to substantially further improve the efficiency of solar cells. The excellent optoelectronic properties and bandgap tunability of perovskites make them promising for constructing efficient TSCs. Currently, TSCs based on perovskite have been extensively studied. Besides, the performance of organic solar cells has been greatly improved recently due to the wider and more efficient spectral utilization. Accordingly, research on perovskite/organic TSCs has garnered significant attention. It has potential application advantages in emerging fields such as wearable devices by virtue of flexibility. In addition, orthogonal solvents can be adopted to realize the separate preparation of subcells with the solution method, which greatly reduces fabrication complexity;moreover, fabrication with less equipment significantly cuts down the device cost. Meanwhile, organics with more adjustability on the optoelectronic properties provide more tuning strategies for high-performance perovskite/organic TSCs. However, comprehensive and timely reviews on the perovskite/organic TSCs are deficient. Therefore, we expect to accomplish a review on this innovative TSCs to facilitate researchers with a deeper understanding of perovskite/organic TSCs. Herein, we firstly review the significant progress of perovskite and organic solar cells. Then, current achievements of perovskite/organic TSCs are summarized and introduced with a particular focus on the device structure design. Finally, we discuss existential challenges and propose effective strategies for future engineering.展开更多
Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-l...Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-layer oxide structure mainly comprising an external layer of CuO followed by(Cu,Mn,Fe)_(3)O_(4)spinel and an internal layer of Cr-rich oxide was thermally developed on the coated steel.The scale area-specific resistances(ASRs)of the coated steels were lower than the scale ASR of the uncoated steel after identical thermal exposure.The external layer of CuO/(Cu,Mn,Fe)_(3)O_(4)spinel not only served as a barrier to reduce the growth rate of Cr-rich oxide internal layer and to suppress the outward diffusion of Cr,but also lowered the surface scale ASRs considerably.展开更多
Lead sulfide quantum dots(PbS QDs) hold unique characteristics, including bandgap tunability, solutionprocessability etc., which make them highly applicable in tandem solar cells(TSCs). In all QD TSCs, its efficiency ...Lead sulfide quantum dots(PbS QDs) hold unique characteristics, including bandgap tunability, solutionprocessability etc., which make them highly applicable in tandem solar cells(TSCs). In all QD TSCs, its efficiency lags much behind to their single junction counterparts due to the deficient interconnection layer(ICL) and defective subcells. To improve TSCs performance, we developed three kinds of ICL structures based on 1.34 and 0.96 e V PbS QDs subcells. The control, 1,2-ethanedithiol capped PbS QDs(PbS-EDT)/Au/tin dioxide(SnO_(2))/zinc oxide(Zn O), utilized SnO_(2) layer to obtain high surface compactness.However, its energy level mismatch causes incomplete recombination. Bypassing it, the second ICL(PbS-EDT/Au/Zn O) removed SnO_(2) and boosted the power conversion efficiency(PCE) from 5.75% to 8.69%. In the third ICL(PbS-EDT/poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine](PTAA)/Au/Zn O), a thin layer of PTAA can effectively fill fissures on the surface of PbS-EDT and also protect the front cells from solvent penetration. This TSC obtained a PCE of 9.49% with an open circuit voltage of 0.91 V, a short circuit current density of 15.47 m A/cm~2, and a fill factor of 67.7%. To the best of our knowledge, this was the highest PCE achieved by all PbS QD TSCs reported to date. These TSCs maintained stable performance for a long working time under ambient conditions.展开更多
Monolithic perovskite/organic tandem solar cells(TSCs)have emerged as promising thin film solar cells.It is recognized that interconnect junction plays a pivotal role in tandem devices.Consequently,wide bandgap Cs_(0....Monolithic perovskite/organic tandem solar cells(TSCs)have emerged as promising thin film solar cells.It is recognized that interconnect junction plays a pivotal role in tandem devices.Consequently,wide bandgap Cs_(0.25)FA_(0.75)Pb(I_(0.6)Br_(0.4))_(3)perovskite top-cell and narrow bandgap PM6:Y6:PC_(61)BM ternary organic bottom-cell were integrated in this study with several kinds of thin metal interconnect layers,which provides feasibility to elaborately manipulate light transmission and carrier tunneling process in interconnect junction.It is confirmed that,in comparison with Au,employing an Ag interconnect layer elevates integrated transmittance of light in longer wavelength regions,mainly because of the alleviated screening effect with a lower free electron concentration,which offers sufficient light harvest for the bottom-cell.Meanwhile,established energy barriers with moderate height afford convenient extraction and recombination for both holes and electrons.Hence,the performance of TSCs is promoted substantially.Moreover,an innovative Ag/Au double interconnect layer is proposed accordingly,which can preserve exceptional conductivity and light transmission and further reduce barrier height,especially for hole tunneling,by optimizing the band alignment between the interconnect layer and bottom-cell.Resultantly,the monolithic perovskite/organic TSC with a striking efficiency of 23.26% is achieved.In a word,this study can pave a general approach toward high-performance TSCs integration.展开更多
为了减弱极端事件对综合能源系统的影响,尽早恢复各类负荷,提高系统弹性。文中提出了一种考虑交通网与配电网级别的区域电-气互联系统(Interconnection Electric and Gas System, IEGS)协同运行的灾后故障抢修策略。首先,通过元胞传输...为了减弱极端事件对综合能源系统的影响,尽早恢复各类负荷,提高系统弹性。文中提出了一种考虑交通网与配电网级别的区域电-气互联系统(Interconnection Electric and Gas System, IEGS)协同运行的灾后故障抢修策略。首先,通过元胞传输模型建立了考虑系统实时恢复指标修正的交通流量分配模型,对交通网的交通流量进行预测;其次,在故障预分配的前提下建立了区域IEGS的故障恢复模型,协调优化维修队、分布式电源、配电网网架等资源,减少停电损失;然后以维修队的最小通行时间矩阵以及由系统实时恢复指标得到的交通网道路修正参数作为传递变量,在维修队开始移动的时间点,重新计算后续的修复计划以及交通网的运行情况,进行多时间断面优化;最后,通过算例仿真进行对比,验证了所提策略的有效性,并分析移动储能装置对故障恢复的影响。展开更多
SUS430 (16% - 17% (mass fraction) Cr) can be used as interconnects for solid oxide fuel cells (SOFCs) that operate at lower temperatures ( 〈 800 ℃ ). However, oxidation of steel can occur readily at elevated...SUS430 (16% - 17% (mass fraction) Cr) can be used as interconnects for solid oxide fuel cells (SOFCs) that operate at lower temperatures ( 〈 800 ℃ ). However, oxidation of steel can occur readily at elevated temperatures leading to the formation of Cr2O3 and spinel (Fe3O4) and thus greatly degrades the performance of the fuel cell. The aim of this work was to reduce oxide growth, in particular, the Cr2O3 phase, through the application of La0.8Sr0.2MnO3-δ (LSM2O) and La0.8Sr0.2FeO3-δ(LSF20) coatings by atmospheric plasma spraying technology (APS). Oxide growth was characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) with an energy dispersive X-ray (EDX) analyzer. During oxidation of fifty 20 h cycles at 800 ℃ in air, the samples with coatings remained very stable, whereas significant spallation and weight loss were observed for the uncoated steel. LSF20 presents apparently advantages in reducing oxidation growth, interface resistance and inhibition of diffusion of chromium. After exposure in air at 800 ℃ for 1000 h, the interfacial resistance of LSF20-coated alloy is lowered by more than 23 times to that of LSM20-coated layer.展开更多
As one of the core parts of two-terminal(2 T) monolithic tandem photovoltaics, the interconnecting layers(ICLs) play a critical role in modulating the carrier transport and recombination between the sub-cells,and thus...As one of the core parts of two-terminal(2 T) monolithic tandem photovoltaics, the interconnecting layers(ICLs) play a critical role in modulating the carrier transport and recombination between the sub-cells,and thus influencing the tandem device performance. Here, for the first time, the relationship between ICLs architecture and 2 T monolithic perovskite/organic tandem device performance has been studied by investigating the change of ICLs composition layer thickness on the ICLs optical and electrical properties, sub-cells EQE properties, and tandem device J-V properties. It is revealed that the ability of ICLs on modulating the sub-cells carrier balance properties is strongly associated with its composited layers thickness, and the tandem device carrier balance properties can be reflected by the relative EQE intensity between the sub-cells. Finally, with a deep understanding of the mechanisms, rational design of ICLs can be made to benefit the tandem device development. Based on the optimized ICL a high PCE of 20.03% is achieved.展开更多
Standard cell placement algorithms have been at the forefront of academic research concerning the physical design stages of VLSI design flows. The penultimate step of a standard cell placement procedure is legalizatio...Standard cell placement algorithms have been at the forefront of academic research concerning the physical design stages of VLSI design flows. The penultimate step of a standard cell placement procedure is legalization. In this step the manufacturability of the design is directly settled, and the quality of the solution, in terms of wirelength, congestion, timing and power consumption is indirectly defined. Since the heavy lifting regarding processing is performed by global placers, fast legalization solutions are protruded in state-of-the-art design flows. In this paper we propose and evaluate a legalization scheme that surpasses in execution speed two of the most widely used legalizers, without not only corrupting the quality of the final solution in terms of interconnection wirelength but improving it in the process.展开更多
Most thin-film photovoltaic modules are constructed on soda-lime glass(SLG)substrates containing alkali oxides,such as Na_(2)O.Na may diffuse from SLG into a module's active layers through P1 lines,an area between...Most thin-film photovoltaic modules are constructed on soda-lime glass(SLG)substrates containing alkali oxides,such as Na_(2)O.Na may diffuse from SLG into a module's active layers through P1 lines,an area between a module's constituent cells where the substrate-side charge transport layer(CTL)is in direct contact with SLG.Na diffusion from SLG is known to cause several important effects inⅡ-Ⅵand chalcogenide solar modules,but it has not been studied in perovskite solar modules(PSMs).In this work,we use complementary microscopy and spectroscopy techniques to show that Na diffusion occurs in the fabrication process of PSMs.Na diffuses vertically inside P1 lines and then laterally from P1 lines into the active area for up to 360 pm.We propose that this process is driven by the high temperatures the devices are exposed to during CTL and perovskite annealing.The diffused Na preferentially binds with Br,forming Br-poor,l-rich perovskite and a species rich in Na and Br(Na-Br)close to P1 lines.Na-Br passivates defect sites,reducing non-radiative recombination in the perovskite and boosting its luminescence by up to 5×.Na-Br is observed to be stable after 12 weeks of device storage,suggesting long-lasting effects of Na diffusion.Our results not only point to a potential avenue to increase PSM performance but also highlight the possibility of unabated Na diffusion throughout a module's lifetime,especially if accelerated by the electric field and elevated temperatures achievable during device operation.展开更多
基金supported by Defence Advanced Research Program of ChinaFoundation Research Program of Beijing Institute of Technology,China (Grant No. 20080342003)
文摘With sustaining change of production mode,layout planning is no longer a thing built once for all.Cellular layout(CL) is becoming a hotspot in the research field of manufacturing system layout.Traditional researches on layout planning are mainly concentrating on aspects of layout arithmetic,style and evaluation,etc.Relatively seldom efforts are paid to CL and its specific problems as cell formation(CF),equipment sharing and CL analysis.Through problem analyzing of layout in cellular manufacturing system(CMS),research approach of cell formation,interactive layout and layout analysis threaded with process interconnection relationship(PIR) is proposed.Typical key technologies in CL like CF technology based on similarity analysis of part processes,interactive visual layout technology,layout evaluation technology founded on PIR analysis and algorithm of cell equipment sharing are put forward.Against the background of one enterprise which encounters problems of low utility of key equipments and disperse material logistic,an example of four-cell layout is given.The CL adjustment and analysis results show that equipment with high level of sharing degree should be disposed around the boundary of its main cell,and be near to other sharing cells as possible; process route should be centralized by all means,so equipment adjustment is to be implemented along direction that route intersection can be decreased; giving consideration to the existence of discrete cell,logistic route and its density should be centralized to cells formed.The proposed research can help improve equipment utility and material logistic efficiency of CL,and can be popularized to other application availably.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11774293, 1207432, and 61874016)。
文摘Tandem cell with structure of indium tin oxide(ITO)/molybdenum oxide(MoO_(3))/fullerene(C60)/copper phthalocyanine(CuPc)/C60/tris-8-hydroxy-quinolinato aluminum(Alq_(3))/Al was fabricated to study the effect of net carriers at the interconnection layer. The open circuit voltage and short circuit current were found to be 1.15 V and 0.56 mA/cm^(2),respectively. Almost the same performance(1.05 V, 0.58 mA/cm^(2)) of tandem cell with additional recombination layer(ITO/MoO_(3)/C60/Alq_(3)/Al/Ag/MoO_(3)/CuPc/C60/Alq_(3)/Al) demonstrates that the carrier balance is more crucial than carrier recombination. The net holes at the interconnection layer caused by more carrier generation from the back cell on one hand would enhance the recombination with electrons from the front cell and on the other hand would quench the excitons produced in CuPc of the back cell.
文摘Scalability is an important issue in the design of interconnection networks for massively parallel systems. In this paper a scalable class of interconnection network of Hex-Cell for massively parallel systems is introduced. It is called Multilayer Hex-Cell (MLH). A node addressing scheme and routing algorithm are also presented and discussed. An interesting feature of the proposed MLH is that it maintains a constant network degree regardless of the increase in the network size degree which facilitates modularity in building blocks of scalable systems. The new addressing node scheme makes the proposed routing algorithm simple and efficient in terms of that it needs a minimum number of calculations to reach the destination node. Moreover, the diameter of the proposed MLH is less than Hex-Cell network.
基金supported by grants from Shenzhen Key Medical Subject(No.SZXK023)Shenzhen“SanMing”Project of Medicine(No.SZSM201612092)+3 种基金Shenzhen Research and Development Projects(No.JCYJ20170307111755218)Guangdong Basic and Applied Basic Research Foundation(No.2019A1515011290)National Key Research and Development Program of China(No.2016YFC1102103)China Postdoctoral Science Foundation(No.2020M672756)
文摘Interconnectivity is the key characteristic of bone tissue engineering scaffold modulating cell migration,blood vessels invasion and transport of nutrient and waste.However,efforts and understanding of the interconnectivity of porous Mg is limited due to the diverse architectures of pore struts and pore size distribution of Mg scaffold systems.In this work,biomimetic hierarchical porous Mg scaffolds with tailored interconnectivity as well as pore size distribution were prepared by template replication of infiltration casting.Mg scaffold with better interconnectivity showed lower mechanical strength.Enlarging interconnected pores would enhance the interconnectivity of the whole scaffold and reduce the change of ion concentration,pH value and osmolality of the degradation microenvironment due to the lower specific surface area.Nevertheless,the degradation rates of five tested Mg scaffolds were no different because of the same geometry of strut unit.Direct cell culture and evaluation of cell density at both sides of four typical Mg scaffolds indicated that cell migration through hierarchical porous Mg scaffolds could be enhanced by not only bigger interconnected pore size but also larger main pore size.In summary,design of interconnectivity in terms of pore size distribution could regulate mechanical strength,microenvironment in cell culture condition and cell migration potential,and beyond that it shows great potential for personalized therapy which could facilitate the regeneration process.
文摘The various stages and progress in the development of interconnect materials for solid oxide fuel cells (SOFCs )over the last two decades are reviewed. The criteria for the application of materials as interconnects are highlighted. Interconnects based on lanthanum chromite ceramics demonstrate many inherent drawbacks and therefore are only useful for SOFCs operating around 1000℃. The advance in the research of anode-supported flat SOFCs facilitates the replacement of ceramic interconnects with metallic ones due to their significantly lowered working temperature. Besides, interconnects made of metals or alloys offer many advantages as compared to their ceramic counterpart. The oxidation response and thermal expansion behaviors of various prospective metallic interconnects are examined and evaluated. The minimization of contact resistance to achieve desired and reliable stack performance during their projected lifetime still remains a highly challenging issue with metallic interconnects. Inexpensive coating materials and techniques may play a key role in promoting the commercialization of SOFC stack whose interconnects are constructed of some current commercially available alloys. Alternatively, development of new metallic materials that are capable of forming stable oxide scales with sluggish growth rate and sufficient electrical conductivity is called for.
基金financially supported by the National Key R&D Program of China (No. 2018YFB1502203-1)the Guangdong Basic and Applied Basic Research Foundation (No. 2021B1515120087)the Stable Supporting Fund of Shenzhen, China (No. GXWD20201230155427003-202007 28114835006)
文摘Physical vapor deposition(PVD)can be used to produce high-quality Gd_(2)O_(3)-doped CeO2(GDC)films.Among various PVD methods,reactive sputtering provides unique benefits,such as high deposition rates and easy upscaling for industrial applications.GDC thin films were successfully fabricated through reactive sputtering using a Gd_(0.2)Ce_(0.8)(at%)metallic target,and their application in solid oxide fuel cells,such as buffer layers between yttria-stabilized zirconia(YSZ)/La0.6Sr0.4Co0.2Fe0.8O_(3−δ)and as sublayers in the steel/coating system,was evaluated.First,the direct current(DC)reactive-sputtering behavior of the GdCe metallic target was determined.Then,the GDC films were deposited on NiO-YSZ/YSZ half-cells to investigate the influence of oxygen flow rate on the quality of annealed GDC films.The results demonstrated that reactive sputtering can be used to prepare thin and dense GDC buffer layers without high-temperature sintering.Furthermore,the cells with a sputtered GDC buffer layer showed better electrochemical performance than those with a screen-printed GDC buffer layer.In addition,the insertion of a GDC sublayer between the SUS441 interconnects and the Mn-Co spinel coatings contributed to the reduction of the oxidation rate for SUS441 at operating temperatures,according to the area-specific resistance tests.
基金financial support from the National Key Research and Development Program of China,China (Grant No.2022YFB4200203)the Key project of Nature Science Foundation of Tianjin,China (22JCZDJC00120)the 111 Project,China(B16027)。
文摘The concept of tandem solar cells(TSCs) is an effective way to substantially further improve the efficiency of solar cells. The excellent optoelectronic properties and bandgap tunability of perovskites make them promising for constructing efficient TSCs. Currently, TSCs based on perovskite have been extensively studied. Besides, the performance of organic solar cells has been greatly improved recently due to the wider and more efficient spectral utilization. Accordingly, research on perovskite/organic TSCs has garnered significant attention. It has potential application advantages in emerging fields such as wearable devices by virtue of flexibility. In addition, orthogonal solvents can be adopted to realize the separate preparation of subcells with the solution method, which greatly reduces fabrication complexity;moreover, fabrication with less equipment significantly cuts down the device cost. Meanwhile, organics with more adjustability on the optoelectronic properties provide more tuning strategies for high-performance perovskite/organic TSCs. However, comprehensive and timely reviews on the perovskite/organic TSCs are deficient. Therefore, we expect to accomplish a review on this innovative TSCs to facilitate researchers with a deeper understanding of perovskite/organic TSCs. Herein, we firstly review the significant progress of perovskite and organic solar cells. Then, current achievements of perovskite/organic TSCs are summarized and introduced with a particular focus on the device structure design. Finally, we discuss existential challenges and propose effective strategies for future engineering.
基金Funded by the Youth Science and Technology Talent Growth Project of Education Department of Guizhou Province(No.KY[2018]145)。
文摘Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-layer oxide structure mainly comprising an external layer of CuO followed by(Cu,Mn,Fe)_(3)O_(4)spinel and an internal layer of Cr-rich oxide was thermally developed on the coated steel.The scale area-specific resistances(ASRs)of the coated steels were lower than the scale ASR of the uncoated steel after identical thermal exposure.The external layer of CuO/(Cu,Mn,Fe)_(3)O_(4)spinel not only served as a barrier to reduce the growth rate of Cr-rich oxide internal layer and to suppress the outward diffusion of Cr,but also lowered the surface scale ASRs considerably.
基金National Natural Science Foundation of China (Grant No. 62374065)Interdisciplinary Research promotion of HUST (No. 2023JCYJ040)+2 种基金Innovation Project of Optics Valley Laboratory (No. OVL2021BG008)Program of Science Technology of Wenzhou City (No. G20210011)financial support from the Innovation and Technology Commission (Grant no. MHP/104/21)。
文摘Lead sulfide quantum dots(PbS QDs) hold unique characteristics, including bandgap tunability, solutionprocessability etc., which make them highly applicable in tandem solar cells(TSCs). In all QD TSCs, its efficiency lags much behind to their single junction counterparts due to the deficient interconnection layer(ICL) and defective subcells. To improve TSCs performance, we developed three kinds of ICL structures based on 1.34 and 0.96 e V PbS QDs subcells. The control, 1,2-ethanedithiol capped PbS QDs(PbS-EDT)/Au/tin dioxide(SnO_(2))/zinc oxide(Zn O), utilized SnO_(2) layer to obtain high surface compactness.However, its energy level mismatch causes incomplete recombination. Bypassing it, the second ICL(PbS-EDT/Au/Zn O) removed SnO_(2) and boosted the power conversion efficiency(PCE) from 5.75% to 8.69%. In the third ICL(PbS-EDT/poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine](PTAA)/Au/Zn O), a thin layer of PTAA can effectively fill fissures on the surface of PbS-EDT and also protect the front cells from solvent penetration. This TSC obtained a PCE of 9.49% with an open circuit voltage of 0.91 V, a short circuit current density of 15.47 m A/cm~2, and a fill factor of 67.7%. To the best of our knowledge, this was the highest PCE achieved by all PbS QD TSCs reported to date. These TSCs maintained stable performance for a long working time under ambient conditions.
基金supported by the Key Project of the Nature Science Foundation of Tianjin(22JCZDJC00120)the 111 Project(B16027)。
文摘Monolithic perovskite/organic tandem solar cells(TSCs)have emerged as promising thin film solar cells.It is recognized that interconnect junction plays a pivotal role in tandem devices.Consequently,wide bandgap Cs_(0.25)FA_(0.75)Pb(I_(0.6)Br_(0.4))_(3)perovskite top-cell and narrow bandgap PM6:Y6:PC_(61)BM ternary organic bottom-cell were integrated in this study with several kinds of thin metal interconnect layers,which provides feasibility to elaborately manipulate light transmission and carrier tunneling process in interconnect junction.It is confirmed that,in comparison with Au,employing an Ag interconnect layer elevates integrated transmittance of light in longer wavelength regions,mainly because of the alleviated screening effect with a lower free electron concentration,which offers sufficient light harvest for the bottom-cell.Meanwhile,established energy barriers with moderate height afford convenient extraction and recombination for both holes and electrons.Hence,the performance of TSCs is promoted substantially.Moreover,an innovative Ag/Au double interconnect layer is proposed accordingly,which can preserve exceptional conductivity and light transmission and further reduce barrier height,especially for hole tunneling,by optimizing the band alignment between the interconnect layer and bottom-cell.Resultantly,the monolithic perovskite/organic TSC with a striking efficiency of 23.26% is achieved.In a word,this study can pave a general approach toward high-performance TSCs integration.
文摘为了减弱极端事件对综合能源系统的影响,尽早恢复各类负荷,提高系统弹性。文中提出了一种考虑交通网与配电网级别的区域电-气互联系统(Interconnection Electric and Gas System, IEGS)协同运行的灾后故障抢修策略。首先,通过元胞传输模型建立了考虑系统实时恢复指标修正的交通流量分配模型,对交通网的交通流量进行预测;其次,在故障预分配的前提下建立了区域IEGS的故障恢复模型,协调优化维修队、分布式电源、配电网网架等资源,减少停电损失;然后以维修队的最小通行时间矩阵以及由系统实时恢复指标得到的交通网道路修正参数作为传递变量,在维修队开始移动的时间点,重新计算后续的修复计划以及交通网的运行情况,进行多时间断面优化;最后,通过算例仿真进行对比,验证了所提策略的有效性,并分析移动储能装置对故障恢复的影响。
文摘SUS430 (16% - 17% (mass fraction) Cr) can be used as interconnects for solid oxide fuel cells (SOFCs) that operate at lower temperatures ( 〈 800 ℃ ). However, oxidation of steel can occur readily at elevated temperatures leading to the formation of Cr2O3 and spinel (Fe3O4) and thus greatly degrades the performance of the fuel cell. The aim of this work was to reduce oxide growth, in particular, the Cr2O3 phase, through the application of La0.8Sr0.2MnO3-δ (LSM2O) and La0.8Sr0.2FeO3-δ(LSF20) coatings by atmospheric plasma spraying technology (APS). Oxide growth was characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) with an energy dispersive X-ray (EDX) analyzer. During oxidation of fifty 20 h cycles at 800 ℃ in air, the samples with coatings remained very stable, whereas significant spallation and weight loss were observed for the uncoated steel. LSF20 presents apparently advantages in reducing oxidation growth, interface resistance and inhibition of diffusion of chromium. After exposure in air at 800 ℃ for 1000 h, the interfacial resistance of LSF20-coated alloy is lowered by more than 23 times to that of LSM20-coated layer.
基金financially supported by the Guangdong Major Project of Basic and Applied Basic Research(2019B030302007)the Ministry of Science and Technology(2017YFA0206600,2019YFA0705900)+6 种基金the Natural Science Foundation of China(51973063,91733302 and 51803060)Guangdong Basic and Applied Basic Research Foundation for Distinguished Young Scholar(2021B1515020028)the Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates(South China University of Technology)(2019B030301003)the Science and Technology Program of Guangzhou,China(201904010147)the funding by State Key Lab of Luminescent Materials and Devices,South China University of Technologythe Fellowship of China Postdoctoral Science Foundation(2020M682703)the National Natural Science Foundation of China(52003090)。
文摘As one of the core parts of two-terminal(2 T) monolithic tandem photovoltaics, the interconnecting layers(ICLs) play a critical role in modulating the carrier transport and recombination between the sub-cells,and thus influencing the tandem device performance. Here, for the first time, the relationship between ICLs architecture and 2 T monolithic perovskite/organic tandem device performance has been studied by investigating the change of ICLs composition layer thickness on the ICLs optical and electrical properties, sub-cells EQE properties, and tandem device J-V properties. It is revealed that the ability of ICLs on modulating the sub-cells carrier balance properties is strongly associated with its composited layers thickness, and the tandem device carrier balance properties can be reflected by the relative EQE intensity between the sub-cells. Finally, with a deep understanding of the mechanisms, rational design of ICLs can be made to benefit the tandem device development. Based on the optimized ICL a high PCE of 20.03% is achieved.
文摘Standard cell placement algorithms have been at the forefront of academic research concerning the physical design stages of VLSI design flows. The penultimate step of a standard cell placement procedure is legalization. In this step the manufacturability of the design is directly settled, and the quality of the solution, in terms of wirelength, congestion, timing and power consumption is indirectly defined. Since the heavy lifting regarding processing is performed by global placers, fast legalization solutions are protruded in state-of-the-art design flows. In this paper we propose and evaluate a legalization scheme that surpasses in execution speed two of the most widely used legalizers, without not only corrupting the quality of the final solution in terms of interconnection wirelength but improving it in the process.
基金the Jardine Foundation and Cambridge Trust for a doctoral scholarshipthe European Union(EU)Horizon 2020 research and innovation program under grant No.764047(ESPResSo)+12 种基金funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No.823717-ESTEEM3.J.F.Oacknowledges funding from the Engineering and Physical Sciences Research Council(EPSRC)Nano Doctoral Training Centre(EP/L015978/1)J.F.O.,G.K.,and R.A.O.acknowledge Attolight and EPSRC(EP/R025193/1)for funding and supporting the SEM-CL systemE.M.T.thanks the EU Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement no.841265.S.D.S.E.M.T.acknowledge funding from the EPSRC(EP/R023980/1)the EPSRC Centre for Advanced Materials for Integrated Energy Systems(CAM-IES,EP/P007767/1)Cambridge Royce facilities grant(EP/P024947/1)S.D.S.acknowledges funding from the Royal Society and Tata Group(UF150033)from the European Research Council under the EU Horizon 2020 research and innovation program under grant No.756962(HYPERION)W.L.and J.L.M.-D.acknowledge support from the EPSRC(EP/L011700/1,EP/N004272/1)the Leverhulme Trust(RPG-2015-017)the Royal Academy of Engineering Chair in Emerging Technologies(CiET1819_24)We wish to acknowledge the support of the Henry Royce Institute(HRI)for F.U.K.through the Royce PhD Equipment Access Scheme enabling access to the NanoSIMS facility at Manchester.The NanoSIMS was funded by UK Research Partnership Investment Funding(UKRPIF)Manchester RPIF Round 2.This work was supported by the HRI,funded through EPSRC grants EP/R00661X/1,EP/S019367/1,EP/P025021/1,and EP/P025498/1
文摘Most thin-film photovoltaic modules are constructed on soda-lime glass(SLG)substrates containing alkali oxides,such as Na_(2)O.Na may diffuse from SLG into a module's active layers through P1 lines,an area between a module's constituent cells where the substrate-side charge transport layer(CTL)is in direct contact with SLG.Na diffusion from SLG is known to cause several important effects inⅡ-Ⅵand chalcogenide solar modules,but it has not been studied in perovskite solar modules(PSMs).In this work,we use complementary microscopy and spectroscopy techniques to show that Na diffusion occurs in the fabrication process of PSMs.Na diffuses vertically inside P1 lines and then laterally from P1 lines into the active area for up to 360 pm.We propose that this process is driven by the high temperatures the devices are exposed to during CTL and perovskite annealing.The diffused Na preferentially binds with Br,forming Br-poor,l-rich perovskite and a species rich in Na and Br(Na-Br)close to P1 lines.Na-Br passivates defect sites,reducing non-radiative recombination in the perovskite and boosting its luminescence by up to 5×.Na-Br is observed to be stable after 12 weeks of device storage,suggesting long-lasting effects of Na diffusion.Our results not only point to a potential avenue to increase PSM performance but also highlight the possibility of unabated Na diffusion throughout a module's lifetime,especially if accelerated by the electric field and elevated temperatures achievable during device operation.