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Interface Engineering of Titanium Nitride Nanotube Composites for Excellent Microwave Absorption at Elevated Temperature 被引量:4
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作者 Cuiping Li Dan Li +4 位作者 Shuai Zhang Long Ma Lei Zhang Jingwei Zhang Chunhong Gong 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期147-160,共14页
Currently,the microwave absorbers usually suffer dreadful electromagnetic wave absorption(EMWA)performance damping at elevated temperature due to impedance mismatching induced by increased conduction loss.Consequently... Currently,the microwave absorbers usually suffer dreadful electromagnetic wave absorption(EMWA)performance damping at elevated temperature due to impedance mismatching induced by increased conduction loss.Consequently,the development of high-performance EMWA materials with good impedance matching and strong loss ability in wide temperature spectrum has emerged as a top priority.Herein,due to the high melting point,good electrical conductivity,excellent environmental stability,EM coupling effect,and abundant interfaces of titanium nitride(TiN)nanotubes,they were designed based on the controlling kinetic diffusion procedure and Ostwald ripening process.Benefiting from boosted heterogeneous interfaces between TiN nanotubes and polydimethylsiloxane(PDMS),enhanced polarization loss relaxations were created,which could not only improve the depletion efficiency of EMWA,but also contribute to the optimized impedance matching at elevated temperature.Therefore,the TiN nanotubes/PDMS composite showed excellent EMWA performances at varied temperature(298-573 K),while achieved an effective absorption bandwidth(EAB)value of 3.23 GHz and a minimum reflection loss(RLmin)value of−44.15 dB at 423 K.This study not only clarifies the relationship between dielectric loss capacity(conduction loss and polarization loss)and temperature,but also breaks new ground for EM absorbers in wide temperature spectrum based on interface engineering. 展开更多
关键词 TiN nanotubes interface engineering Polarization loss Impedance matching Electromagnetic wave absorption performance
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Electrolyte engineering for optimizing anode/electrolyte interface towards superior aqueous zinc-ion batteries:A review
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作者 Hua-ming YU Dong-ping CHEN +6 位作者 Li-jin ZHANG Shao-zhen HUANG Liang-jun ZHOU Gui-chao KUANG Wei-feng WEI Li-bao CHEN Yue-jiao CHEN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第10期3118-3150,共33页
Aqueous zinc-ion batteries(AZIBs) are promising candidates for the large-scale energy storage systems due to their high intrinsic safety,cost-effectiveness and environmental friendliness.However,issues such as dendrit... Aqueous zinc-ion batteries(AZIBs) are promising candidates for the large-scale energy storage systems due to their high intrinsic safety,cost-effectiveness and environmental friendliness.However,issues such as dendrite growth,hydrogen evolution reaction,and interfacial passivation occurring at the anode/electrolyte interface(AEI) have hindered their practical application.Constructing a stable AEI plays a key role in regulating zinc deposition and improving the cycle life of AZIBs.The fundamentals of AEI and the challenges faced by the Zn anode due to unstable interfaces are discussed.A comprehensive summary of electrolyte regulation strategies by electrolyte engineering to achieve a stable Zn anode is provided.The effectiveness evaluation techniques for stable AEI are also analyzed,including the interfacial chemistry and surface morphology evolution of the Zn anode.Finally,suggestions and perspectives for future research are offered about enabling a durable and stable AEI via electrolyte engineering,which may pave the way for developing high-performance AZIBs. 展开更多
关键词 aqueous zinc-ion battery anode/electrolyte interface zinc anode aqueous electrolyte electrolyte engineering electrolyte additives
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Enhanced Electrical Properties of Bi_(2−x)Sb_(x)Te_(3) Nanoflake Thin Films Through Interface Engineering
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作者 Xudong Wu Junjie Ding +8 位作者 Wenjun Cui Weixiao Lin Zefan Xue Zhi Yang Jiahui Liu Xiaolei Nie Wanting Zhu Gustaaf Van Tendeloo Xiahan Sang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第6期359-366,共8页
The structure–property relationship at interfaces is difficult to probe for thermoelectric materials with a complex interfacial microstructure.Designing thermoelectric materials with a simple,structurally-uniform int... The structure–property relationship at interfaces is difficult to probe for thermoelectric materials with a complex interfacial microstructure.Designing thermoelectric materials with a simple,structurally-uniform interface provides a facile way to understand how these interfaces influence the transport properties.Here,we synthesized Bi_(2−x)Sb_(x)Te_(3)(x=0,0.1,0.2,0.4)nanoflakes using a hydrothermal method,and prepared Bi_(2−x)Sb_(x)Te_(3) thin films with predominantly(0001)interfaces by stacking the nanoflakes through spin coating.The influence of the annealing temperature and Sb content on the(0001)interface structure was systematically investigated at atomic scale using aberration-corrected scanning transmission electron microscopy.Annealing and Sb doping facilitate atom diffusion and migration between adjacent nanoflakes along the(0001)interface.As such it enhances interfacial connectivity and improves the electrical transport properties.Interfac reactions create new interfaces that increase the scattering and the Seebeck coefficient.Due to the simultaneous optimization of electrical conductivity and Seebeck coefficient,the maximum power factor of the Bi_(1.8)Sb_(0.2)Te_(3) nanoflake films reaches 1.72 mW m^(−1)K^(−2),which is 43%higher than that of a pure Bi_(2)Te_(3) thin film. 展开更多
关键词 Bi_(2)Te_(3) nanoflakes interface engineering scanning transmission electron microscopy thermoelectric thin film
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Interface engineering of inverted wide-bandgap perovskite solar cells for tandem photovoltaics
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作者 Yang Yang Fengyuan Li +1 位作者 Ruihao Chen Hongqiang Wang 《Energy Materials and Devices》 2024年第1期36-53,共18页
Wide-bandgap perovskite solar cells(WBG PSCs)have garnered significant research attention for their potential in tandem solar cells.However,they face challenges such as high open-circuit voltage losses and severe phas... Wide-bandgap perovskite solar cells(WBG PSCs)have garnered significant research attention for their potential in tandem solar cells.However,they face challenges such as high open-circuit voltage losses and severe phase instability.These issues are primarily owing to the formation of defects,ion migration,and energy level mismatches at the interface of WBG perovskite devices.Meanwhile,inverted PSCs demonstrate superior stability potential and compatibility with tandem devices,making them the most promising application for WBG perovskite materials.Consequently,interface modulation for such devices has become imperative.In this review,from the perspective of applicability in tandem devices,we first provided a concise overview of WBG perovskite research and its efficiency progress in inverted devices.We further discussed interface carrier dynamics and the potential impact of interfaces on such device performance.Afterward,we presented a comprehensive summary of interface engineering in inverted WBG perovskite(1.60 eV-1.80 eV)solar cells.The research particularly explored both the upper and buried interfaces of WBG absorbers in the inverted PSCs,thoroughly investigating interface design strategies and outlining promising research directions.Finally,this review provides insight into the future development of interface engineering for high-performance and large-area WBG PSCs. 展开更多
关键词 wide-bandgap perovskite inverted perovskite solar cells buried interface engineering surface modification
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A Review on Engineering Design for Enhancing Interfacial Contact in Solid-State Lithium–Sulfur Batteries
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作者 Bingxin Qi Xinyue Hong +4 位作者 Ying Jiang Jing Shi Mingrui Zhang Wen Yan Chao Lai 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期219-252,共34页
The utilization of solid-state electrolytes(SSEs)presents a promising solution to the issues of safety concern and shuttle effect in Li–S batteries,which has garnered significant interest recently.However,the high in... The utilization of solid-state electrolytes(SSEs)presents a promising solution to the issues of safety concern and shuttle effect in Li–S batteries,which has garnered significant interest recently.However,the high interfacial impedances existing between the SSEs and the electrodes(both lithium anodes and sulfur cathodes)hinder the charge transfer and intensify the uneven deposition of lithium,which ultimately result in insufficient capacity utilization and poor cycling stability.Hence,the reduction of interfacial resistance between SSEs and electrodes is of paramount importance in the pursuit of efficacious solid-state batteries.In this review,we focus on the experimental strategies employed to enhance the interfacial contact between SSEs and electrodes,and summarize recent progresses of their applications in solidstate Li–S batteries.Moreover,the challenges and perspectives of rational interfacial design in practical solid-state Li–S batteries are outlined as well.We expect that this review will provide new insights into the further technique development and practical applications of solid-state lithium batteries. 展开更多
关键词 Solid-state lithium–sulfur batteries Solid-state electrolytes Electrode/electrolyte interface interfacial engineering Enhancing interfacial contact
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Optimizing the Performance of CsPbI3-Based Perovskite Solar Cells via Doping a ZnO Electron Transport Layer Coupled with Interface Engineering 被引量:5
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作者 Man Yue Jie Su +4 位作者 Peng Zhao Zhenhua Lin Jincheng Zhang Jingjing Chang Yue Hao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2019年第4期605-618,共14页
Interface engineering has been regarded as an effective and noninvasive means to optimize the performance of perovskite solar cells(PSCs).Here,doping engineering of a ZnO electron transport layer(ETL)and CsPbI3/ZnO in... Interface engineering has been regarded as an effective and noninvasive means to optimize the performance of perovskite solar cells(PSCs).Here,doping engineering of a ZnO electron transport layer(ETL)and CsPbI3/ZnO interface engineering via introduction of an interfacial layer are employed to improve the performances of CsPbI3-based PSCs.The results show that when introducing a TiO2 buffer layer while increasing the ZnO layer doping concentration,the open-circuit voltage,power conversion efficiency,and fill factor of the CsPbI3-based PSCs can be improved to 1.31 V,21.06%,and 74.07%,respectively,which are superior to those of PSCs only modified by the TiO2 buffer layer or high-concentration doping of ZnO layer.On the one hand,the buffer layer relieves the band bending and structural disorder of CsPbI3.On the other hand,the increased doping concentration of the ZnO layer improves the conductivity of the TiO2/ZnO bilayer ETL because of the strong interaction between the TiO2 and ZnO layers.However,such phenomena are not observed for those of a PCBM/ZnO bilayer ETL because of the weak interlayer interaction of the PCBM/ZnO interface.These results provide a comprehensive understanding of the CsPbI3/ZnO interface and suggest a guideline to design high-performance PSCs. 展开更多
关键词 All-inorganic CsPbI3 perovskites interface engineERING DOPING ZNO Simulation
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Interface Engineering of NixSy@MnOxHy Nanorods to Efficiently Enhance Overall-Water-Splitting Activity and Stability 被引量:11
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作者 Pan Wang Yuanzhi Luo +4 位作者 Gaixia Zhang Zhangsen Chen Hariprasad Ranganathan Shuhui Sun Zhicong Shi 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第7期246-262,共17页
Exploring highly active and stable transition metal-based bifunctional electrocatalysts has recently attracted extensive research interests for achieving high inherent activity, abundant exposed active sites, rapid ma... Exploring highly active and stable transition metal-based bifunctional electrocatalysts has recently attracted extensive research interests for achieving high inherent activity, abundant exposed active sites, rapid mass transfer, and strong structure stability for overall water splitting. Herein, an interface engineering coupled with shell-protection strategy was applied to construct three-dimensional(3D) core-shell NixSy@MnOxHy heterostructure nanorods grown on nickel foam(NixSy@MnOxHy/NF) as a bifunctional electrocatalyst. NixSy@MnOxHy/NF was synthesized via a facile hydrothermal reaction followed by an electrodeposition process. The X-ray absorption fine structure spectra reveal that abundant Mn-S bonds connect the heterostructure interfaces of N ixSy@MnOxHy, leading to a strong electronic interaction, which improves the intrinsic activities of hydrogen evolution reaction and oxygen evolution reaction(OER). Besides, as an efficient protective shell, the MnOxHy dramatically inhibits the electrochemical corrosion of the electrocatalyst at high current densities, which remarkably enhances the stability at high potentials. Furthermore, the 3D nanorod structure not only exposes enriched active sites, but also accelerates the electrolyte diffusion and bubble desorption. Therefore, NixSy@MnOxHy/NF exhibits exceptional bifunctional activity and stability for overall water splitting, with low overpotentials of 326 and 356 mV for OER at 100 and 500 mA cm^(–2), respectively, along with high stability of 150 h at 100 mA cm^(–2). Furthermore, for overall water splitting, it presents a low cell voltage of 1.529 V at 10 mA cm^(–2), accompanied by excellent stability at 100 mA cm^(–2) for 100 h. This work sheds a light on exploring highly active and stable bifunctional electrocatalysts by the interface engineering coupled with shell-protection strategy. 展开更多
关键词 interface engineering Protective shell Manganese compound Nickel sulfides BIFUNCTIONAL Water splitting
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Recent Advances in Interface Engineering for Electrocatalytic CO_(2) Reduction Reaction 被引量:13
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作者 Junjun Li Sulaiman Umar Abbas +2 位作者 Haiqing Wang Zhicheng Zhang Wenping Hu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第12期499-533,共35页
Electrocatalytic CO_(2) reduction reaction(CO_(2) RR) can store and transform the intermittent renewable energy in the form of chemical energy for industrial production of chemicals and fuels,which can dramatically re... Electrocatalytic CO_(2) reduction reaction(CO_(2) RR) can store and transform the intermittent renewable energy in the form of chemical energy for industrial production of chemicals and fuels,which can dramatically reduce CO_(2) emission and contribute to carbon-neutral cycle. E cient electrocatalytic reduction of chemically inert CO_(2) is challenging from thermodynamic and kinetic points of view. Therefore,low-cost,highly e cient,and readily available electrocatalysts have been the focus for promoting the conversion of CO_(2). Very recently,interface engineering has been considered as a highly e ective strategy to modulate the electrocatalytic performance through electronic and/or structural modulation,regulations of electron/proton/mass/intermediates,and the control of local reactant concentration,thereby achieving desirable reaction pathway,inhibiting competing hydrogen generation,breaking binding-energy scaling relations of intermediates,and promoting CO_(2) mass transfer. In this review,we aim to provide a comprehensive overview of current developments in interface engineering for CO_(2) RR from both a theoretical and experimental stand-point,involving interfaces between metal and metal,metal and metal oxide,metal and nonmetal,metal oxide and metal oxide,organic molecules and inorganic materials,electrode and electrolyte,molecular catalysts and electrode,etc. Finally,the opportunities and challenges of interface engineering for CO_(2) RR are proposed. 展开更多
关键词 interface engineering CO_(2)reduction reaction ELECTROCATALYSIS HETEROSTRUCTURE
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Defect and interface engineering for electrochemical nitrogen reduction reaction under ambient conditions 被引量:5
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作者 Dongxue Guo Shuo Wang +2 位作者 Jun Xu Wenjun Zheng Danhong Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第2期448-468,共21页
Electrochemical nitrogen reduction reaction(e-NRR)under ambient conditions is an emerging strategy to tackle the hydrogen-and energy-intensive operations for traditional Haber-Bosch process in industrial ammonia(NH_(3... Electrochemical nitrogen reduction reaction(e-NRR)under ambient conditions is an emerging strategy to tackle the hydrogen-and energy-intensive operations for traditional Haber-Bosch process in industrial ammonia(NH_(3))synthesis.However,the e-NRR performance is currently impeded by the inherent inertness of N_(2) molecules,the extremely slow kinetics and the overwhelming competition from the hydrogen evolution reaction(HER),all of which cause unsatisfied yield and ammonia selectivity(Faradaic efficiency,FE).Defect and interface engineering are capable of achieving novel physical and chemical properties as well as superior synergistic effects for various electrocatalysts.In this review,we first provide a general introduction to the NRR mechanism.We then focus on the recent progress in defect and interface engineering and summarize how defect and interface can be rationally designed and functioned in NRR catalysts.Particularly,the origin of superior NRR catalytic activity by applying these approaches was discussed from both theoretical and experimental perspectives.Finally,the remaining challenges and future perspectives in this emerging area are highlighted.It is expected that this review will shed some light on designing NRR electrocatalysts with excellent activity,selectivity and stability. 展开更多
关键词 Nitrogen reduction ELECTROCATALYSIS Defect engineering interface engineering Ambient conditions
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Surface/interface engineering of high-efficiency noble metal-free electrocatalysts for energy-related electrochemical reactions 被引量:8
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作者 Hui Zhao Zhong-Yong Yuan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第3期89-104,共16页
To date,much efforts have been devoted to the high-efficiency noble metal-free electrocatalysts for hydrogen-and oxygen-involving energy conversion reactions,due to their abundance,low cost and nultifunctionally.Surfa... To date,much efforts have been devoted to the high-efficiency noble metal-free electrocatalysts for hydrogen-and oxygen-involving energy conversion reactions,due to their abundance,low cost and nultifunctionally.Surface/interface engineering is found to be effective in achieving novel physicochemical properties and synergistic effects in nanomaterials for electrocatalysis.Among various engineering strategies,heteroatom-doping has been regarded as a most promising method to improve the electrocatalytic performance via the regulation of electronic structure of catalysts,and numerous works were reported on the synthesis method and mechanism investigation of heteroatom-doping electrocatalysts,though the heteroatom-doping can only provide limited active sites.Engineering of other defects such as vacancies and edge sites and construction of heterostructure have shown to open up a potential avenue for the development of noble metal-free electrocatalysts.In addition,surface functionalization can attach various molecules onto the surface of materials to easily modify their physical or chemical properties,being as a promising complement or substitute for offering materials with catalytic properties.This paper gives the insights into the diverse strategies of surface/interface engineering of the highefficiency noble metal-free electrocatalysts for energy-related electrochemical reactions.The significant advances are summarized.The unique advantages and mechanisms for specific applications are highlighted.The current challenges and outlook of this growing field are also discussed. 展开更多
关键词 Noble metal-free electrocatalysts Electrocatalysis Surface/interface engineering Metal-air battery Overall water splitting
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Engineering homotype heterojunctions in hard carbon to induce stable solid electrolyte interfaces for sodium-ion batteries 被引量:6
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作者 Chengxin Yu Yu Li +6 位作者 Haixia Ren Ji Qian Shuo Wang Xin Feng Mingquan Liu Ying Bai Chuan Wu 《Carbon Energy》 SCIE CAS CSCD 2023年第1期181-193,共13页
Developing effective strategies to improve the initial Coulombic efficiency(ICE)and cycling stability of hard carbon(HC)anodes for sodium-ion batteries is the key to promoting the commercial application of HC.In this ... Developing effective strategies to improve the initial Coulombic efficiency(ICE)and cycling stability of hard carbon(HC)anodes for sodium-ion batteries is the key to promoting the commercial application of HC.In this paper,homotype heterojunctions are designed on HC to induce the generation of stable solid electrolyte interfaces,which can effectively increase the ICE of HC from 64.7%to 81.1%.The results show that using a simple surface engineering strategy to construct a homotypic amorphous Al_(2)O_(3) layer on the HC could shield the active sites,and further inhibit electrolyte decomposition and side effects occurrence.Particularly,due to the suppression of continuous decomposition of NaPF 6 in ester-based electrolytes,the accumulation of NaF could be reduced,leading to the formation of thinner and denser solid electrolyte interface films and a decrease in the interface resistance.The HC anode can not only improve the ICE but elevate its sodium storage performance based on this homotype heterojunction composed of HC and Al_(2)O_(3).The optimized HC anode exhibits an outstanding reversible capacity of 321.5mAhg^(−1) at 50mAg^(−1).The cycling stability is also improved effectively,and the capacity retention rate is 86.9%after 2000 cycles at 1Ag^(−1) while that of the untreated HC is only 52.6%.More importantly,the improved sodium storage behaviors are explained by electrochemical kinetic analysis. 展开更多
关键词 hard carbon anodes homotype heterojunctions sodium-ion batteries solid electrolyte interface surface engineering
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Electronic modulation and interface engineering of electrospun nanomaterials‐based electrocatalysts toward water splitting 被引量:18
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作者 Wei Song Meixuan Li +1 位作者 Ce Wang Xiaofeng Lu 《Carbon Energy》 CAS 2021年第1期101-128,共28页
Nowdays,electrocatalytic water splitting has been regarded as one of the most efficient means to approach the urgent energy crisis and environmental issues.However,to speed up the electrocatalytic conversion efficienc... Nowdays,electrocatalytic water splitting has been regarded as one of the most efficient means to approach the urgent energy crisis and environmental issues.However,to speed up the electrocatalytic conversion efficiency of their half reactions including hydrogen evolution reaction(HER)and oxygen evolution reaction(OER),electrocatalysts are usually essential to reduce their kinetic energy barriers.Electrospun nanomaterials possess a unique one‐dimensional structure for outstanding electron and mass transportation,large specific surface area,and the possibilities of flexibility with the porous feature,which are good candidates as efficient electrocatalysts for water splitting.In this review,we focus on the recent research progress on the electrospun nanomaterials‐based electrocatalysts for HER,OER,and overall water splitting reaction.Specifically,the insights of the influence of the electronic modulation and interface engineering of these electrocatalysts on their electrocatalytic activities will be deeply discussed and highlighted.Furthermore,the challenges and development opportunities of the electrospun nanomaterials‐based electrocatalysts for water splitting are featured.Based on the achievements of the significantly enhanced performance from the electronic modulation and interface engineering of these electrocatalysts,full utilization of these materials for practical energy conversion is anticipated. 展开更多
关键词 electrocatalysis electronic modulation electrospun nanomaterials interface engineering water splitting
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A critical review on composite solid electrolytes for lithium batteries:Design strategies and interface engineering 被引量:2
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作者 Tianqi Yang Cheng Wang +7 位作者 Wenkui Zhang Yang Xia Hui Huang Yongping Gan Xinping He Xinhui Xia Xinyong Tao Jun Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期189-209,共21页
The rapid development of new energy vehicles and 5G communication technologies has led to higher demands for the safety,energy density,and cycle performance of lithium-ion batteries as power sources.However,the curren... The rapid development of new energy vehicles and 5G communication technologies has led to higher demands for the safety,energy density,and cycle performance of lithium-ion batteries as power sources.However,the currently used liquid carbonate compounds in commercial lithium-ion battery electrolytes pose potential safety hazards such as leakage,swelling,corrosion,and flammability.Solid electrolytes can be used to mitigate these risks and create a safer lithium battery.Furthermore,high-energy density can be achieved by using solid electrolytes along with high-voltage cathode and metal lithium anode.Two types of solid electrolytes are generally used:inorganic solid electrolytes and polymer solid electrolytes.Inorganic solid electrolytes have high ionic conductivity,electrochemical stability window,and mechanical strength,but suffer from large solid/solid contact resistance between the electrode and electrolyte.Polymer solid electrolytes have good flexibility,processability,and contact interface properties,but low room temperature ionic conductivity,necessitating operation at elevated temperatures.Composite solid electrolytes(CSEs) are a promising alternative because they offer light weight and flexibility,like polymers,as well as the strength and stability of inorganic electrolytes.This paper presents a comprehensive review of recent advances in CSEs to help researchers optimize CSE composition and interactions for practical applications.It covers the development history of solid-state electrolytes,CSE properties with respect to nanofillers,morphology,and polymer types,and also discusses the lithium-ion transport mechanism of the composite electrolyte,and the methods of engineering interfaces with the positive and negative electrodes.Overall,the paper aims to provide an outlook on the potential applications of CSEs in solid-state lithium batteries,and to inspire further research aimed at the development of more systematic optimization strategies for CSEs. 展开更多
关键词 Inorganic solid electrolytes Polymer solid electrolytes Composite solid electrolytes interface engineering
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Interface and M^(3+)/M^(2+)Valence Dual-Engineering on Nickel Cobalt Sulfoselenide/Black Phosphorus Heterostructure for Efficient Water Splitting Electrocatalysis 被引量:2
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作者 Tingting Liang Syama Lenus +5 位作者 Yaoda Liu Ya Chen Thangavel Sakthivel Fuyi Chen Fei Ma Zhengfei Dai 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第2期165-174,共10页
The catalyst innovation that aims at noble-metal-free substitutes is one key aspect for future sustainable hydrogen energy deployment.In this paper,a nickel cobalt sulfoselenide/black phosphorus heterostructure(NiCoSe... The catalyst innovation that aims at noble-metal-free substitutes is one key aspect for future sustainable hydrogen energy deployment.In this paper,a nickel cobalt sulfoselenide/black phosphorus heterostructure(NiCoSe|S/BP)was fabricated to realize the highly active and durable water electrolysis through interface and valence dual-engineering.The NiCoSe|S/BP nanostructure was constructed by in-situ growing NiCo hydroxide nanosheet arrays on few-layer BP and subsequently one-step sulfoselenization by SeS2.Besides the conductive merit of BP substrate,holes in p-type BP are capable of oxidizing the Co^(2+)to high-valence and electron-accepting Co^(3+),benefiting the oxygen evolution reaction(OER).Meanwhile,Ni^(3+)/Ni^(2+)ratio in the heterostructure is reduced to maintain the electrical neutrality,which corresponds to the increased electron-donating character for boosting hydrogen evolution reaction(HER).As for HER and OER,the heterostructured NiCoSe|S/BP electrocatalyst exhibits small overpotentials of 172 and 285 mV at 10 mA cm^(-2)(η_(10))in alkaline media,respectively.And overall water splitting has been achieved at a low cell potential of 1.67 V at η_(10) with high stability.Molecular sensing and density functional theory(DFT)calculations are further proposed for understanding the rate-determine steps and enhanced catalytic mechanism.The investigation presents a deep-seated perception for the electrocatalytic performance enhancement of BP-based heterostructure. 展开更多
关键词 black phosphorus interface engineering metal sulfoselenide overall water splitting valence regulation
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Peanut-chocolate-ball-inspired construction of the interface engineering between CdS and intergrown Cd:Boosting both the photocatalytic activity and photocorrosion resistance 被引量:1
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作者 Wending Zhou Feng Li +5 位作者 Xiangfei Yang Wanliang Yang Chun Wang Rui Cao Chengliang Zhou Mengkui Tian 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第1期75-89,I0003,共16页
Interface engineering can improve the charge separation efficiency and inhibit photocorrosion is an emerging direction of developing more efficient and cost-effective photocatalytic systems.Herein,we report the sulfur... Interface engineering can improve the charge separation efficiency and inhibit photocorrosion is an emerging direction of developing more efficient and cost-effective photocatalytic systems.Herein,we report the sulfur-confined intimate Cd S intergrown Cd(Cd S/Cd)Ohmic junction(peanut-chocolate-ball like)for high-efficient H2production with superior anti-photocorrosion ability,which was fabricated from in-situ photoreduction of CdS intergrown Cd2SO4(OH)2(CdS/Cd2SO4(OH)2)prepared through a facile space-controlled-solvothermal method.The ratios of CdS/Cd can be effectively controlled by tunning that of CdS/Cd2SO4(OH)2which were prepared by adjusting the volume of reaction liquid and the remaining space of the reactor.Experiments investigations and density functional theory(DFT)calculations reveal that the Cd S intergrown Cd Ohmic junction interfaces(with appropriate content Cd intergrown on Cd S(19.54 wt%))are beneficial in facilitating the transfer of photogenerated electrons by constructing an interfacial electric field and forming sulfur-confined structures for preventing the positive holes(h+)oxidize the Cd S.This contributes to a high photocatalytic H2production activity of 95.40μmol h-1(about 32.3 times higher than bare Cd S)and possesses outstanding photocatalytic stability over 205 h,much longer than most Cd S-based photocatalysts previously reported.The interface engineering design inspired by the structure of peanut-chocolate-ball can greatly promote the future development of catalytic systems for wider application. 展开更多
关键词 interface engineering Sulfur-confined CdS/Cd intergrown Ohmic junction DFT calculations Photocorrosion resistance
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Interface engineering of porous Fe^(2)P-WO_(2.92) catalyst with oxygen vacancies for highly active and stable large-current oxygen evolution and overall water splitting 被引量:1
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作者 Qimin Peng Qiuting He +3 位作者 Yan Hu Tayirjan Taylor Isimjan Ruobing Hou Xiulin Yang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第2期574-582,共9页
Constructing a low cost,and high-efficiency oxygen evolution reaction(OER)electrocatalyst is of great significance for improving the performance of alkaline electrolyzer,which is still suffering from highenergy consum... Constructing a low cost,and high-efficiency oxygen evolution reaction(OER)electrocatalyst is of great significance for improving the performance of alkaline electrolyzer,which is still suffering from highenergy consumption.Herein,we created a porous iron phosphide and tungsten oxide self-supporting electrocatalyst with oxygen-containing vacancies on foam nickel(Fe_(2)P-WO_(2.92)/NF)through a facile insitu growth,etching and phosphating strategies.The sequence-controllable strategy will not only generate oxygen vacancies and improve the charge transfer between Fe_(2)P and WO_(2.92) components,but also improve the catalyst porosity and expose more active sites.Electrochemical studies illustrate that the Fe_(2)P-WO_(2.92)/NF catalyst presents good OER activity with a low overpotential of 267 mV at 100 mA cm^(-2),a small Tafel slope of 46.3 mV dec^(-1),high electrical conductivity,and reliable stability at high current density(100 mA cm^(-2) for over 60 h in 1.0 M KOH solution).Most significantly,the operating cell voltage of Fe_(2)P-WO_(2.92)/NF‖Pt/C is as low as 1.90 V at 400 mA cm^(-2) in alkaline condition,which is one of the lowest reported in the literature.The electrocatalytic mechanism shows that the oxygen vacancies and the synergy between Fe_(2)P and WO_(2.92) can adjust the electronic structure and provide more reaction sites,thereby synergistically increasing OER activity.This work provides a feasible strategy to fabricate high-efficiency and stable non-noble metal OER electrocatalysts on the engineering interface. 展开更多
关键词 Fe^(2)P-WO_(2.92) interface engineering Oxygen vacancy Oxygen evolution Overall water splitting
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Study on Interface Friction Model for Engineering Materials Testing on Split Hopkinson Pressure Bar Tests 被引量:1
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作者 Yubin Lu Songyan Zhang 《Modern Mechanical Engineering》 2013年第1期27-33,共7页
Split Hopkinson pressure bar (SHPB) has become a frequently used technique to measure the uniaxial compressive stress-strain relation of various engineering materials at high strain-rates. The accuracy of an SHPB test... Split Hopkinson pressure bar (SHPB) has become a frequently used technique to measure the uniaxial compressive stress-strain relation of various engineering materials at high strain-rates. The accuracy of an SHPB test is based on the assumption of uniaxial and uniform stress distribution within the specimen, which, however, is not always satisfied in an actual SHPB test due to the existence of some unavoidable negative factors, e.g., interface friction constrains. Kinetic interface friction tests based on a simple device for engineering materials testing on SHPB tests are performed. A kinetic interface friction model is proposed and validated by implementing it into a numerical model. It shows that the proposed simple device is sufficient to obtain kinetic interface friction results for common SHPB tests. The kinetic friction model should be used instead of the frequently used constant friction model for more accurate numerical simulation of SHPB tests. 展开更多
关键词 KINETIC interface Friction Model SLIDING Velocity Contact SPLIT Hopkinson Pressure Bar (SHPB) engineERING Materials
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Multiple carbon interface engineering to boost oxygen evolution of Ni Fe nanocomposite electrocatalyst
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作者 Yuyan Qiao Yanqiu Pan +7 位作者 Jiangwei Zhang Bin Wang Tingting Wu Wenjun Fan Yucheng Cao Rashid Mehmood Fei Zhang Fuxiang Zhang 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第9期2354-2362,共9页
Interface engineering has been widely investigated to regulate the structure and performance of electrodes and photoelectrodes,but the investigation of multiple carbon interface modifications on the electrocatalytic o... Interface engineering has been widely investigated to regulate the structure and performance of electrodes and photoelectrodes,but the investigation of multiple carbon interface modifications on the electrocatalytic oxygen evolution reaction(OER)is still shortage.Herein,we report remarkable promotion of OER performance on the NiFe‐based nanocomposite electrocatalyst via the synergy of multiple carbon‐based interface engineering.Specifically,carbon nanotubes were in situ grown on carbon fiber paper to improve the interface between CFP and NiFeO_(x)H_(y),and graphite carbon nanoparticles were in situ loaded and partly doped into the NiFeO_(x)H_(y) to modify the intergranular interface charge transfer and electronic structure of NiFeO_(x)H_(y).Consequently,the as‐obtained NiFeO_(x)H_(y)‐C/CNTs/CFP catalyst exhibited significantly enhanced electrocatalytic OER activity with an overpotential of 202 mV at 10 mA cm^(-2) in 1 mol L^(-1) KOH.Our work not only extends application of carbon materials but also provides an alternative strategy to develop highly efficient electrocatalysts. 展开更多
关键词 Electro catalyst Oxygen evolution reaction interface engineering Carbon nanotube NANOCOMPOSITE
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Interface passivation engineering for hybrid perovskite solar cells 被引量:1
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作者 Wenjian Shen Yao Dong +2 位作者 Fuzhi Huang Yi-Bing Cheng Jie Zhong 《Materials Reports(Energy)》 2021年第4期22-33,共12页
The allure of high efficiency and low-temperature solution-processed organic-inorganic hybrid perovskite solar cells(PSCs)are inspiring scientists to seek for its commercialization.Interface passivation engineering ha... The allure of high efficiency and low-temperature solution-processed organic-inorganic hybrid perovskite solar cells(PSCs)are inspiring scientists to seek for its commercialization.Interface passivation engineering has become an effective way to further enhance the efficiency and stability of PSCs by defect passivation,reduces the charge recombination and ion migration initiation and hysteresis control,etc.Herein,we have summarized the effects and recent research progress of interface passivation engineering in PSCs.Interface passivation layers can be realized by using the solution and/or vacuum evaporation processes which are very adaptable to varied materials with different properties and fabrication processes for enhanced photovoltaic performance and stability. 展开更多
关键词 Perovskite solar cells Charges recombination interface passivation engineering Hysteresis effect PSCs stability Solution processes Vacuum evaporation
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Designing interactive glazing through an engineering psychology approach:Six augmented reality scenarios that envision future car human-machine interface
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作者 Wei LIU Yancong ZHU +5 位作者 Ruonan HUANG Takumi OHASHI Jan AUERNHAMMER Xiaonan ZHANG Ce SHI Lu WANG 《Virtual Reality & Intelligent Hardware》 2023年第2期157-170,共14页
Background With an increasing number of vehicles becoming autonomous,intelligent,and connected,paying attention to the future usage of car human-machine interface with these vehicles should become more relevant.Severa... Background With an increasing number of vehicles becoming autonomous,intelligent,and connected,paying attention to the future usage of car human-machine interface with these vehicles should become more relevant.Several studies have addressed car HMI but were less attentive to designing and implementing interactive glazing for every day(autonomous)driving contexts.Methods Reflecting on the literature,we describe an engineering psychology practice and the design of six novel future user scenarios,which envision the application of a specific set of augmented reality(AR)support user interactions.Additionally,we conduct evaluations on specific scenarios and experiential prototypes,which reveal that these AR scenarios aid the target user groups in experiencing a new type of interaction.The overall evaluation is positive with valuable assessment results and suggestions.Conclusions This study can interest applied psychology educators who aspire to teach how AR can be operationalized in a human-centered design process to students with minimal pre-existing expertise or minimal scientific knowledge in engineering psychology. 展开更多
关键词 Augmented reality Interactive glazing engineering psychology Car human-machine interface Human-computer interaction Human-centered design User experience Generation Z
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