In order to clarify the edge and interface effect on the adhesion energy between graphene(Gr)and its substrate,a theoretical model is proposed to study the interaction and strain distribution of Gr/Si system in terms ...In order to clarify the edge and interface effect on the adhesion energy between graphene(Gr)and its substrate,a theoretical model is proposed to study the interaction and strain distribution of Gr/Si system in terms of continuum medium mechanics and nanothermodynamics.We find that the interface separation and adhesion energy are determined by the thickness of Gr and substrate.The disturbed interaction and redistributed strain in the Gr/Si system induced by the effect of surface and interface can make the interface adhesion energy decrease with increasing thickness of Gr and diminishing thickness of Si.Moreover,our results show that the smaller area of Gr is more likely to adhere to the substrate since the edge effect improves the active energy and strain energy.Our predictions can be expected to be a guide for designing high performance of Grbased electronic devices.展开更多
基金This work was supported by the Natural Science Foundation of Guangdong Province(Grant Nos.2019A1515010916 and 2018A030307028)the Featured Innovation Project of Guangdong Education Department(2018KTSCX150)+1 种基金the Maoming Natural Science Foundation of Guangdong,China,(Grant No.2019018001)the Guangdong Province Major Foundation of Fundamental Research(Grant No.517042).
文摘In order to clarify the edge and interface effect on the adhesion energy between graphene(Gr)and its substrate,a theoretical model is proposed to study the interaction and strain distribution of Gr/Si system in terms of continuum medium mechanics and nanothermodynamics.We find that the interface separation and adhesion energy are determined by the thickness of Gr and substrate.The disturbed interaction and redistributed strain in the Gr/Si system induced by the effect of surface and interface can make the interface adhesion energy decrease with increasing thickness of Gr and diminishing thickness of Si.Moreover,our results show that the smaller area of Gr is more likely to adhere to the substrate since the edge effect improves the active energy and strain energy.Our predictions can be expected to be a guide for designing high performance of Grbased electronic devices.
基金supported by the Basic Science (Natural science)Research Project of Higher Education of Jiangsu Province (Grant No.23KJB460019)the National Natural Science Foundation of China (Grant Nos.12302355 and 52075548)+2 种基金the Taishan Scholar Program of Shandong Province (Grant No.tsqn201909068)the Excellent Young Scientists Fund of Shandong Province (Grant No.2022HWYQ-071)the Fundamental Research Funds for the Central Universities (Grant No.20CX06074A)。