Although the internal electric field(IEF)of photocatalysts is acknowledged as a potent driving force for photocharge separation,modulating the IEF intensity to achieve enhanced photocatalytic performances remains a ch...Although the internal electric field(IEF)of photocatalysts is acknowledged as a potent driving force for photocharge separation,modulating the IEF intensity to achieve enhanced photocatalytic performances remains a challenge.Herein,cuprous sulfide nanosheets with different Cu vacancy concentration were employed to study IEF modulation and corresponding direct charge transfer.Among the samples,Cu_(1.8)S nanosheets possessed intensified IEF intensity compared with those of Cu_(2)S and Cu_(1.95)S nanosheets,suggesting that an enhanced IEF intensity could be achieved by introducing more Cu vacancies.This intensified IEF of Cu_(1.8)S nanosheets induced numerous photogenerated electrons to migrate to its surface,and the dissociative electrons were then captured by Cu vacancies,resulting in efficient charge separation spatially.In addition,the Cu vacancies on Cu_(1.8)S nanosheets accumulated electrons as active sites to lower the energy barrier of rate-determining step of CO_(2)photoreduction,leading to the selective conversion of CO_(2)to CO.Herein,the manipulation of IEF intensity through Cu vacancy concentration regulation of cuprous sulfide photocatalysts for efficient charge separation has been discussed,providing a scientific strategy to rationally improve photocata lytic performances for solar energy conversion.展开更多
This article explores the effects of investment upon energy intensity by applying a unique panel data of China's 27 provinces between 2004 and 2013.In addition,it also particularly stuthes other factors,such as en...This article explores the effects of investment upon energy intensity by applying a unique panel data of China's 27 provinces between 2004 and 2013.In addition,it also particularly stuthes other factors,such as energy price,economic structure,and urbanization.The results,based on four econometric regression model results,suggest that in general,the indigenous investment on research and development is a more powerful tool to decrease China's energy intensity regardless of region disparity.The foreign direct investment(FDI) has a prominent but not persistent effect on energy intensity.However,the outward direct investment has not shown its significant impact on energy intensity.At the level of an aggregate economy and China's eastern region,the results demonstrate that FDI improves energy efficiency significantly.For the central and western provinces,FDI does not support the similar conclusion.Based on these analyses,we present the corresponding regional policies for policymakers.展开更多
The purpose of this study is to verify the physiological effect and describe the intensity of training in response to internal and external loads,through Session Rate of Perceived Exertion and Speed High Intensity Dis...The purpose of this study is to verify the physiological effect and describe the intensity of training in response to internal and external loads,through Session Rate of Perceived Exertion and Speed High Intensity Distance in Meters reports,on professional soccer players engaged in weekly training(199 Sessions,43 weeks)and league games(32 official matches).Twenty-two male professional soccer players(n=22)of the Italian national championship under-19 are involved in this study during the season 2014-2015.Daily,Weekly and Monthly RPE(perceived exertion)Session(Borg CR-10 Scale)is a good indicator of the amount of work done:training time multiplied by perceived effort(TL=Training Time×RPE).With Arbitrary units(a.u.)produced by the individual and used for team-based data analysis,we analyze the intensity produced by workout depending on the working time.Furthermore,by means of global positioning system technology(K-Sport,Montelabbate PU,Italy 10 Hz),we statistically established the existing relationship with high intensity speed distance(>16 km/h)and session rate of perceived exertion to describe how the internal(represented by the sum of the stresses that the body undergoes an external load;is strictly subjective)and external loads(the objective quantification of the means used in training km routes,running speed,slope,type of recovery),are correlated(r=0.87,p<0.01,95%CI).The statistical analysis highlights how these methods are suitable to quantifying the high-intensity work done by the soccer player during the workout and the game.展开更多
The hatches for inspecting are usually designed with elliptical holes in airplane structures, so computation of the stress intensity factor of three dimensional crack at elliptical holes is pivotal for damage toleranc...The hatches for inspecting are usually designed with elliptical holes in airplane structures, so computation of the stress intensity factor of three dimensional crack at elliptical holes is pivotal for damage tolerance analysis of these structures. In this paper, weight function is derived for a two dimensional through cracks at elliptical holes by applying a compounding method. Stress intensity factor formulas for an internal surface semi-elliptical crack in elliptical holes are obtained wing the three dimensional weight function method. Stress intensity factors for an internal surface semi-elliptical crack in elliptical holes under remote tension are computed. At the same time, research on how radius of curvature for elliptical holes affect stress intensity factors was conducted. Stress intensity factors decrease when radius of curvature increases. Some results and conclusions which are of practical value are given.展开更多
基金supported by the National Natural Science Foundation of China(52200123)the Open Project of Key Laboratory of Green Chemical Engineering Process of Ministry of Education(GCP2022007)the Scientific Research and Innovation Team Program of Sichuan University of Science and Engineering(SUSE652A014)。
文摘Although the internal electric field(IEF)of photocatalysts is acknowledged as a potent driving force for photocharge separation,modulating the IEF intensity to achieve enhanced photocatalytic performances remains a challenge.Herein,cuprous sulfide nanosheets with different Cu vacancy concentration were employed to study IEF modulation and corresponding direct charge transfer.Among the samples,Cu_(1.8)S nanosheets possessed intensified IEF intensity compared with those of Cu_(2)S and Cu_(1.95)S nanosheets,suggesting that an enhanced IEF intensity could be achieved by introducing more Cu vacancies.This intensified IEF of Cu_(1.8)S nanosheets induced numerous photogenerated electrons to migrate to its surface,and the dissociative electrons were then captured by Cu vacancies,resulting in efficient charge separation spatially.In addition,the Cu vacancies on Cu_(1.8)S nanosheets accumulated electrons as active sites to lower the energy barrier of rate-determining step of CO_(2)photoreduction,leading to the selective conversion of CO_(2)to CO.Herein,the manipulation of IEF intensity through Cu vacancy concentration regulation of cuprous sulfide photocatalysts for efficient charge separation has been discussed,providing a scientific strategy to rationally improve photocata lytic performances for solar energy conversion.
基金supported by the Fundamental Research Funds for the Central Universities:[Grant Number JBK1607K05]
文摘This article explores the effects of investment upon energy intensity by applying a unique panel data of China's 27 provinces between 2004 and 2013.In addition,it also particularly stuthes other factors,such as energy price,economic structure,and urbanization.The results,based on four econometric regression model results,suggest that in general,the indigenous investment on research and development is a more powerful tool to decrease China's energy intensity regardless of region disparity.The foreign direct investment(FDI) has a prominent but not persistent effect on energy intensity.However,the outward direct investment has not shown its significant impact on energy intensity.At the level of an aggregate economy and China's eastern region,the results demonstrate that FDI improves energy efficiency significantly.For the central and western provinces,FDI does not support the similar conclusion.Based on these analyses,we present the corresponding regional policies for policymakers.
文摘The purpose of this study is to verify the physiological effect and describe the intensity of training in response to internal and external loads,through Session Rate of Perceived Exertion and Speed High Intensity Distance in Meters reports,on professional soccer players engaged in weekly training(199 Sessions,43 weeks)and league games(32 official matches).Twenty-two male professional soccer players(n=22)of the Italian national championship under-19 are involved in this study during the season 2014-2015.Daily,Weekly and Monthly RPE(perceived exertion)Session(Borg CR-10 Scale)is a good indicator of the amount of work done:training time multiplied by perceived effort(TL=Training Time×RPE).With Arbitrary units(a.u.)produced by the individual and used for team-based data analysis,we analyze the intensity produced by workout depending on the working time.Furthermore,by means of global positioning system technology(K-Sport,Montelabbate PU,Italy 10 Hz),we statistically established the existing relationship with high intensity speed distance(>16 km/h)and session rate of perceived exertion to describe how the internal(represented by the sum of the stresses that the body undergoes an external load;is strictly subjective)and external loads(the objective quantification of the means used in training km routes,running speed,slope,type of recovery),are correlated(r=0.87,p<0.01,95%CI).The statistical analysis highlights how these methods are suitable to quantifying the high-intensity work done by the soccer player during the workout and the game.
文摘The hatches for inspecting are usually designed with elliptical holes in airplane structures, so computation of the stress intensity factor of three dimensional crack at elliptical holes is pivotal for damage tolerance analysis of these structures. In this paper, weight function is derived for a two dimensional through cracks at elliptical holes by applying a compounding method. Stress intensity factor formulas for an internal surface semi-elliptical crack in elliptical holes are obtained wing the three dimensional weight function method. Stress intensity factors for an internal surface semi-elliptical crack in elliptical holes under remote tension are computed. At the same time, research on how radius of curvature for elliptical holes affect stress intensity factors was conducted. Stress intensity factors decrease when radius of curvature increases. Some results and conclusions which are of practical value are given.
