The title compound, 2,10-di-tert-butylindolo[3,2,1-jk]carbazole （C26H27N, Mr=353.49）, has been synthesized by palladium-catalyzed intramolecular arylation and characterized by 1H NMR, 13C NMR and X-ray crystal struc...The title compound, 2,10-di-tert-butylindolo[3,2,1-jk]carbazole （C26H27N, Mr=353.49）, has been synthesized by palladium-catalyzed intramolecular arylation and characterized by 1H NMR, 13C NMR and X-ray crystal structure determination. The crystal crystallizes in the monoclinic system, space group P21/c with a=13.6409（5）, b=11.6706（4）, c=13.1678（5）, β=100.6180（10）°, V=2060.39（13）3 , Z=4, Dc=1.140 mg/m3 , μ=0.065mm-1 , F（000）=760, the final R=0.0456 and wR=0.1209 for 3012 observed reflections （I 〉 2σ（I））.展开更多
基金supported by the Natural Science Foundation of Shanghai (No.09ZR1409400)Shanghai Committee of Science and Technology (No.10520710100)the Sino-French Institute of ECNU
文摘The title compound, 2,10-di-tert-butylindolo[3,2,1-jk]carbazole （C26H27N, Mr=353.49）, has been synthesized by palladium-catalyzed intramolecular arylation and characterized by 1H NMR, 13C NMR and X-ray crystal structure determination. The crystal crystallizes in the monoclinic system, space group P21/c with a=13.6409（5）, b=11.6706（4）, c=13.1678（5）, β=100.6180（10）°, V=2060.39（13）3 , Z=4, Dc=1.140 mg/m3 , μ=0.065mm-1 , F（000）=760, the final R=0.0456 and wR=0.1209 for 3012 observed reflections （I 〉 2σ（I））.
