In this paper, intrinsic safety and positive security distance control for an up/down elevator which extracts the materials from an underground coal mine is approached. For a better understanding of intrinsic safety a...In this paper, intrinsic safety and positive security distance control for an up/down elevator which extracts the materials from an underground coal mine is approached. For a better understanding of intrinsic safety and positive security, the first part of the paper describes the potential risk the workers are facing while working in dangerous environments like coal mining with “grisou” atmospheres and what the conditions of an unfortunate event to take place are. We presented the diagram and working principle for intrinsic safety equipment used in potential explosive areas based on which we modeled and simulated the intrinsic and positive security distance control in order to get a software solution for it. We created an algorithm and simulated the process in Matlab Simulink. The simulation results done in Matlab Simulink were then entered into a Moeller PLC using a ladder-type programming language. For protection against explosive atmospheres, the PLC is inserted into a metal housing with intrinsic protection and Positive Security.展开更多
Rechargeable Mg batteries(RMBs)have become one of the best subsitutes for lithium-ion batteries due to the high volumetric capacity,abundant resources,and uniform plating behavior of Mg metal anode.However,the safety ...Rechargeable Mg batteries(RMBs)have become one of the best subsitutes for lithium-ion batteries due to the high volumetric capacity,abundant resources,and uniform plating behavior of Mg metal anode.However,the safety hazard induced by the formation of high-modulue Mg dendrites under a high current density(10 mA cm^(-1))was still revealed in recent years.It has forced researchers to re-examine the safety of RMBs.In this review,the intrinsic safety factors of key components in RMBs,such as uneven plating,pitting and flammability of Mg anode,heat release and crystalline water decomposition of cathode,strong corrosion,low oxidition stability and flammability of electrolytes,and soforth,are systematacially summarized.Their origins,formation mechanisms,and possible safety hazards are deeply discussed.To develop high-performance Mg anode,current strategies including designing artificial SEI,three-dimensional substrates,and Mg alloys are summarized.For practical electrolytes,the configurations of boron-centered anions and simple Mg salts and the functionalized solvent with high boiling point and low flammability are suggested to comprehensively design.In addition,the future study should more focus on the investigation on the thermal runaway and decomposition of cathode materials and separa-tors.This review aims to provide fundamental insights into the relationship between electrochemistry and safety,further promoting the sustainable development of RMBs.展开更多
Ionogels have enabled flexible electronic devices for wide-ranging innovative applications in wearable electronics,soft robotics,and intelligent systems.Ionogels for flexible electronics need to essentially tolerate s...Ionogels have enabled flexible electronic devices for wide-ranging innovative applications in wearable electronics,soft robotics,and intelligent systems.Ionogels for flexible electronics need to essentially tolerate stress,temperature,humidity,and solvents that may cause their electrical conductivity,structural stability,processing compatibility and sensibility failure.Herein,we developed a novel in-situ photopolymerization protocol to fabricate intrinsically conductive,self-gated ionogels via ion-restriction dual effects.Highly sensitive and intelligent safety sensors with tunable stretchability,robust chemical stability,favorable printability,and complete recyclability,are programmed from defined microneedle arrays printed by the intrinsically conductive ionogel.Ultrahigh elasticity(~794%elongation),high compression tolerance(~90%deformation),improved mechanical strength(tensile and compressive strength of~2.0 MPa and~16.3 MPa,respectively)and remark-able transparency(>91.1%transmittance),as well as high-temperature sensitivity(-2.07%℃^(-1))and a wide working range(-40 to200℃)can be achieved.In particular,the intrinsic sensing mechanisms of ion-restriction dual effects are unlocked based on DFT calculations and MD simulations,and operando temperature-dependent FTIR,and Raman technolo-gies.Moreover,the real-time intelligent monitoring systems toward physical signals and precise temperature based on the microneedle array-structures sensors are also presented and demonstrate great potential applications for extreme environ-ments,e.g.,fire,deep-sea or aerospace.展开更多
文摘In this paper, intrinsic safety and positive security distance control for an up/down elevator which extracts the materials from an underground coal mine is approached. For a better understanding of intrinsic safety and positive security, the first part of the paper describes the potential risk the workers are facing while working in dangerous environments like coal mining with “grisou” atmospheres and what the conditions of an unfortunate event to take place are. We presented the diagram and working principle for intrinsic safety equipment used in potential explosive areas based on which we modeled and simulated the intrinsic and positive security distance control in order to get a software solution for it. We created an algorithm and simulated the process in Matlab Simulink. The simulation results done in Matlab Simulink were then entered into a Moeller PLC using a ladder-type programming language. For protection against explosive atmospheres, the PLC is inserted into a metal housing with intrinsic protection and Positive Security.
基金supported by the National Key R&D Program of China(No.2023YFB3809500)the National Natural Science Foundation of China(No.U23A20555,52202211)+1 种基金the Ninth Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)the Chongqing Technology Innovation and Application Development Project(No.CSTB2022TIAD-KPX0028).
文摘Rechargeable Mg batteries(RMBs)have become one of the best subsitutes for lithium-ion batteries due to the high volumetric capacity,abundant resources,and uniform plating behavior of Mg metal anode.However,the safety hazard induced by the formation of high-modulue Mg dendrites under a high current density(10 mA cm^(-1))was still revealed in recent years.It has forced researchers to re-examine the safety of RMBs.In this review,the intrinsic safety factors of key components in RMBs,such as uneven plating,pitting and flammability of Mg anode,heat release and crystalline water decomposition of cathode,strong corrosion,low oxidition stability and flammability of electrolytes,and soforth,are systematacially summarized.Their origins,formation mechanisms,and possible safety hazards are deeply discussed.To develop high-performance Mg anode,current strategies including designing artificial SEI,three-dimensional substrates,and Mg alloys are summarized.For practical electrolytes,the configurations of boron-centered anions and simple Mg salts and the functionalized solvent with high boiling point and low flammability are suggested to comprehensively design.In addition,the future study should more focus on the investigation on the thermal runaway and decomposition of cathode materials and separa-tors.This review aims to provide fundamental insights into the relationship between electrochemistry and safety,further promoting the sustainable development of RMBs.
基金supported by the National Key R&D Program of China(2020YFA0709900)the National Natural Science Foundation of China(22175167)the National Key R&D Program of the MOST of China(Grant No.2022YFA1602601).
文摘Ionogels have enabled flexible electronic devices for wide-ranging innovative applications in wearable electronics,soft robotics,and intelligent systems.Ionogels for flexible electronics need to essentially tolerate stress,temperature,humidity,and solvents that may cause their electrical conductivity,structural stability,processing compatibility and sensibility failure.Herein,we developed a novel in-situ photopolymerization protocol to fabricate intrinsically conductive,self-gated ionogels via ion-restriction dual effects.Highly sensitive and intelligent safety sensors with tunable stretchability,robust chemical stability,favorable printability,and complete recyclability,are programmed from defined microneedle arrays printed by the intrinsically conductive ionogel.Ultrahigh elasticity(~794%elongation),high compression tolerance(~90%deformation),improved mechanical strength(tensile and compressive strength of~2.0 MPa and~16.3 MPa,respectively)and remark-able transparency(>91.1%transmittance),as well as high-temperature sensitivity(-2.07%℃^(-1))and a wide working range(-40 to200℃)can be achieved.In particular,the intrinsic sensing mechanisms of ion-restriction dual effects are unlocked based on DFT calculations and MD simulations,and operando temperature-dependent FTIR,and Raman technolo-gies.Moreover,the real-time intelligent monitoring systems toward physical signals and precise temperature based on the microneedle array-structures sensors are also presented and demonstrate great potential applications for extreme environ-ments,e.g.,fire,deep-sea or aerospace.
