Manipulation of the photoluminescence spectra of light-emitting materials doped in three-dimensional （3D） inverse opal photonic crystals is investigated. Quinacrine dihydrochloride molecules doped highly ordered SiO...Manipulation of the photoluminescence spectra of light-emitting materials doped in three-dimensional （3D） inverse opal photonic crystals is investigated. Quinacrine dihydrochloride molecules doped highly ordered SiO2 inverse opal is successfully synthesized by co-assembly combined with double-substrate vertical infiltrate method. The quinacrine dihydrochloride-doped and-undoped SiO2 inverse opals each exhibit an apparent photonic band gap （PBG） in the visible light region. Significant suppression of the emission is observed when the PBG is overlapped with the quinacrine dihydrochloride emission bands. The mechanism of suppression effect of PBG in inverse opal on the fluorescence intensity of quinacrine dihydrochloride molecules is studied.展开更多
Photonic crystal heterostructures containing two materials and/or two lattice constants are synthesized using the colloids of polystyrene and polymethyl methacrylate by a self-assembling technique. These direct hetero...Photonic crystal heterostructures containing two materials and/or two lattice constants are synthesized using the colloids of polystyrene and polymethyl methacrylate by a self-assembling technique. These direct heterostructures with double stop band are infiltrated with zinc oxide by sol-gel method, followed by the removal of the original polymer template by a wet-etching process to result in inverse heterostructures made of zinc oxide. A red shift in the wavelength of stop bands is observed when the crystal is infiltrated with zinc oxide and a blue shift after inversion, in concurrence with the changes in the effective index of the structure. The stop band is also calculated to extract the number of layers and the extinction co-efficient contributing to the heterostructure. This structure made by a room-temperature low-cost technique produces a sparsely-filled zinc oxide crystal with a single refractive index but containing two different periodicities in a layered arrangement that can be used as a lab-on-a-chip for dual- or multi-wavelength sensing applications.展开更多
The upconversion （UC） luminescence and color tunable properties of Tb3＋ ions were investigated by steady spectral under 980 LD excitation in the Cao.15ZrO.8501.85：Yb,Tb inverse opals fabricated by the self-assembl...The upconversion （UC） luminescence and color tunable properties of Tb3＋ ions were investigated by steady spectral under 980 LD excitation in the Cao.15ZrO.8501.85：Yb,Tb inverse opals fabricated by the self-assembly technique in combination with a sol-gel method. The inhibition of UC emission was inspected if the Tb3＋ UC emission band was in the regions of the photonic bandgap, while enhancement of the UC emission occurred if the UC emission band located at the edge of the bandgap. Color modification of the UC emission was successfully obtained by the suppression or enhancement effect of the photonic band gap on the UC emission.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.91122022 and 51172209)the Natural Science Foundation of Zhejiang Province of of China(Grant No.LR12E02001)
文摘Manipulation of the photoluminescence spectra of light-emitting materials doped in three-dimensional （3D） inverse opal photonic crystals is investigated. Quinacrine dihydrochloride molecules doped highly ordered SiO2 inverse opal is successfully synthesized by co-assembly combined with double-substrate vertical infiltrate method. The quinacrine dihydrochloride-doped and-undoped SiO2 inverse opals each exhibit an apparent photonic band gap （PBG） in the visible light region. Significant suppression of the emission is observed when the PBG is overlapped with the quinacrine dihydrochloride emission bands. The mechanism of suppression effect of PBG in inverse opal on the fluorescence intensity of quinacrine dihydrochloride molecules is studied.
文摘Photonic crystal heterostructures containing two materials and/or two lattice constants are synthesized using the colloids of polystyrene and polymethyl methacrylate by a self-assembling technique. These direct heterostructures with double stop band are infiltrated with zinc oxide by sol-gel method, followed by the removal of the original polymer template by a wet-etching process to result in inverse heterostructures made of zinc oxide. A red shift in the wavelength of stop bands is observed when the crystal is infiltrated with zinc oxide and a blue shift after inversion, in concurrence with the changes in the effective index of the structure. The stop band is also calculated to extract the number of layers and the extinction co-efficient contributing to the heterostructure. This structure made by a room-temperature low-cost technique produces a sparsely-filled zinc oxide crystal with a single refractive index but containing two different periodicities in a layered arrangement that can be used as a lab-on-a-chip for dual- or multi-wavelength sensing applications.
基金Project supported by the Natural Science Foundation of Yunnan Province (2010ZC038)the Postdoctoral Science Foundation of China(20110491759)+3 种基金Open Foundation of Key Lab of Advanced Materials in Rare&Precious and Non-ferrous Metals, Ministry of EducationOpen Foundation of Key Lab of Advanced Materials of Yunnan Province (ZDS2010011B)Education Department Foundation of Yunnan Province (2011Y348)Analysis and Measurement Foundation of Kunming University of Science and Technology (2011011)
文摘The upconversion （UC） luminescence and color tunable properties of Tb3＋ ions were investigated by steady spectral under 980 LD excitation in the Cao.15ZrO.8501.85：Yb,Tb inverse opals fabricated by the self-assembly technique in combination with a sol-gel method. The inhibition of UC emission was inspected if the Tb3＋ UC emission band was in the regions of the photonic bandgap, while enhancement of the UC emission occurred if the UC emission band located at the edge of the bandgap. Color modification of the UC emission was successfully obtained by the suppression or enhancement effect of the photonic band gap on the UC emission.
