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Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows Zn Anode with Superior Stability 被引量:1
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作者 Bin Li Pengchao Ruan +9 位作者 Xieyu Xu Zhangxing He Xinyan Zhu Liang Pan Ziyu Peng Yangyang Liu Peng Zhou Bingan Lu Lei Dai Jiang Zhou 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第4期350-363,共14页
Achieving a highly robust zinc(Zn)metal anode is extremely important for improving the performance of aqueous Zn-ion batteries(AZIBs)for advancing“carbon neutrality”society,which is hampered by the uncontrollable gr... Achieving a highly robust zinc(Zn)metal anode is extremely important for improving the performance of aqueous Zn-ion batteries(AZIBs)for advancing“carbon neutrality”society,which is hampered by the uncontrollable growth of Zn dendrite and severe side reactions including hydrogen evolution reaction,corrosion,and passivation,etc.Herein,an interlayer containing fluorinated zincophilic covalent organic framework with sulfonic acid groups(COF-S-F)is developed on Zn metal(Zn@COF-S-F)as the artificial solid electrolyte interface(SEI).Sulfonic acid group(-SO_(3)H)in COF-S-F can effectively ameliorate the desolvation process of hydrated Zn ions,and the three-dimensional channel with fluoride group(-F)can provide interconnected channels for the favorable transport of Zn ions with ion-confinement effects,endowing Zn@COF-S-F with dendrite-free morphology and suppressed side reactions.Consequently,Zn@COF-S-F symmetric cell can stably cycle for 1,000 h with low average hysteresis voltage(50.5 m V)at the current density of 1.5 m A cm^(-2).Zn@COF-S-F|Mn O_(2)cell delivers the discharge specific capacity of 206.8 m Ah g^(-1)at the current density of 1.2 A g^(-1)after 800 cycles with high-capacity retention(87.9%).Enlightening,building artificial SEI on metallic Zn surface with targeted design has been proved as the effective strategy to foster the practical application of high-performance AZIBs. 展开更多
关键词 Aqueous Zn ion batteries Covalent organic framework Interfacial modification Zn ion flux regulation Desolvation effect
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A layered multifunctional framework based on polyacrylonitrile and MOF derivatives for stable lithium metal anode
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作者 Fanfan Liu Peng Zuo +5 位作者 Jing Li Pengcheng Shi Yu Shao Linwei Chen Yihong Tan Tao Ma 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期282-288,I0007,共8页
Composite Li metal anodes based on three-dimensional(3D) porous frameworks have been considered as an effective material for achieving stable Li metal batteries with high energy density.However,uneven Li deposition be... Composite Li metal anodes based on three-dimensional(3D) porous frameworks have been considered as an effective material for achieving stable Li metal batteries with high energy density.However,uneven Li deposition behavior still occurs at the top of 3D frameworks owing to the local accumulation of Li ions.To promote uniform Li deposition without top dendrite growth,herein,a layered multifunctional framework based on oxidation-treated polyacrylonitrile(OPAN) and metal-organic framework(MOF) derivatives was proposed for rationally regulating the distribution of Li ions flux,nucleation sites,and electrical conductivity.Profiting from these merits,the OPAN/carbon nano fiber-MOF(CMOF) composite framework demonstrated a reversible Li plating/stripping behavior for 500 cycles with a stable Coulombic efficiency of around 99.0% at the current density of 2 mA/cm~2.Besides,such a Li composite anode exhibited a superior cycle lifespan of over 1300 h under a low polarized voltage of 18 mV in symmetrical cells.When the Li composite anode was paired with LiFePO_(4)(LFP) cathode,the obtained full cell exhibited a stable cycling over 500 cycles.Moreover,the COMSOL Multiphysics simulation was conducted to reveal the effects on homogeneous Li ions distribution derived from the above-mentioned OPAN/CMOF framework and electrical insulation/conduction design.These electrochemical and simulated results shed light on the difficulties of designing stable and safe Li metal anode via optimizing the 3D frameworks. 展开更多
关键词 Lithium metal anode Layered multifunctional framework ions flux redistribution Electrical insulation/conduction structure Uniform Li deposition
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Investigation of flux dependent sensitivity on single event effect in memory devices 被引量:1
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作者 Jie Luo Tie-shan Wang +8 位作者 Dong-qing Li Tian-qi Liu Ming-dong Hou You-mei Sun Jing-lai Duan Hui-jun Yao Kai Xi Bing Ye Jie Liu 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第7期404-410,共7页
Heavy-ion flux is an important experimental parameter in the ground based single event tests. The flux impact on a single event effect in different memory devices is analyzed by using GEANT4 and TCAD simulation method... Heavy-ion flux is an important experimental parameter in the ground based single event tests. The flux impact on a single event effect in different memory devices is analyzed by using GEANT4 and TCAD simulation methods. The transient radial track profile depends not only on the linear energy transfer (LET) of the incident ion, but also on the mass and energy of the ion. For the ions with the energies at the Bragg peaks, the radial charge distribution is wider when the ion LET is larger. The results extracted from the GEANT4 and TCAD simulations, together with detailed analysis of the device structure, are presented to demonstrate phenomena observed in the flux related experiment. The analysis shows that the flux effect conclusions drawn from the experiment are intrinsically connected and all indicate the mechanism that the flux effect stems from multiple ion-induced pulses functioning together and relies exquisitely on the specific response of the device. 展开更多
关键词 ion flux single event effect GEANT4 simulation memory device
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Characterization of high flux magnetized helium plasma in SCU-PSI linear device 被引量:2
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作者 马小春 曹小岗 +3 位作者 韩磊 张志艳 韦建军 芶富均 《Plasma Science and Technology》 SCIE EI CAS CSCD 2018年第2期104-109,共6页
A high-flux linear plasma device in Sichuan University plasma-surface interaction(SCU-PSI)based on a cascaded arc source has been established to simulate the interactions between helium and hydrogen plasma with the ... A high-flux linear plasma device in Sichuan University plasma-surface interaction(SCU-PSI)based on a cascaded arc source has been established to simulate the interactions between helium and hydrogen plasma with the plasma-facing components in fusion reactors.In this paper,the helium plasma has been characterized by a double-pin Langmuir probe.The results show that the stable helium plasma beam with a diameter of 26 mm was constrained very well at a magnetic field strength of 0.3 T.The core density and ion flux of helium plasma have a strong dependence on the applied current,magnetic field strength and gas flow rate.It could reach an electron density of1.2×10^19m^-3and helium ion flux of 3.2×10^22m^-2s^-1,with a gas flow rate of 4 standard liter per minute,magnetic field strength of 0.2 T and input power of 11 k W.With the addition of-80 Vapplied to the target to increase the helium ion energy and the exposure time of 2 h,the flat top temperature reached about 530°C.The different sizes of nanostructured fuzz on irradiated tungsten and molybdenum samples surfaces under the bombardment of helium ions were observed by scanning electron microscopy.These results measured in the SCU-PSI linear device provide a reference for International Thermonuclear Experimental Reactor related PSI research. 展开更多
关键词 helium plasma beam diameter electron density ion flux nanostructure fuzz
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Studies on the mitogenic effect of transferrin by membrane signal transduction
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作者 LEUNGTM PLLIM 《Cell Research》 SCIE CAS CSCD 1990年第2期217-221,共5页
One of the earliest events leading to cell activation and growth is the hydrolysis of inositol phospholipids producing various membrane signals induced by an interaction between growth factors or hormones with their r... One of the earliest events leading to cell activation and growth is the hydrolysis of inositol phospholipids producing various membrane signals induced by an interaction between growth factors or hormones with their respective receptors on the cell membrane [1]. To demonstrate the mitogenio action of transferrin, our results show that an addition of transferrin to 'serum-deprived' rat hepatoma cells produced a rapid but transient rise in inositol 1, 4, 5-trisphosphate (IP3) level, and at the same time, an increased intraoellular Oa2+ activity and a oytoplasmic alkalinization were observed. These signal transduo-tions further lend support to the mitogenic nature of transferrin. In addition, a possible link between the receptor-mediated endocytosis of transferrin with the generation of intraoellular signals is discussed herewith. 展开更多
关键词 TRANSFERRIN membrane signal cell activation insitol triphosphate calcium ion flux.
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Low Temperature Nitriding of 304 Austenitic Stainless Steel Using RF-ICP Method: the Role of Ion Beam Flux Density
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作者 王庆 巴德纯 +2 位作者 明悦 徐林 郭德宇 《Plasma Science and Technology》 SCIE EI CAS CSCD 2014年第10期960-963,共4页
The significant role of ion beam flux during nitriding 304 austenitic stainless steel has been investigated by using a radio frequency inductively-coupled plasma reactor into which a sample with negative bias voltage ... The significant role of ion beam flux during nitriding 304 austenitic stainless steel has been investigated by using a radio frequency inductively-coupled plasma reactor into which a sample with negative bias voltage was inserted. A milliammeter is used to detect tile current of ions which collide with the sample and optical emission spectroscopy is used to discern the reactive species included in the nitrogen plasma. The nitriding efficiency is indicated by X-ray diffraction and the microhardness test. The reported data reveal that the ion beam flux density as well as the deposition pressure, bias voltage and time can strongly affect the nitriding of stainless steel via tile expanded multiphase microstructure inside the nitrided layer. The increase in the density of ion flux results in an ascent in the intensity of the expanded peak and a simultaneous decline in the intensity of the 3' austenite peak. The evolution trend of ion beam flux density is described as a function of tile operating pressure and the bias voltage. The maxinmm ion flux density has been achieved at 10 Pa pressure and 500 V bias voltage. A reasonable nitriding region has been, consequently, suggested after comparing this work with previously reported results. 展开更多
关键词 plasma nitriding inicrostructure stainless steel SURFACES ions beam flux
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Characteristics of Ions Emitted from Laser-Induced Silver Plasma
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作者 M.S.RAFIQUE M.KHALEEQ-UR-RAHMAN +1 位作者 Shakoor MUNAZZA K.A.BHATTI 《Plasma Science and Technology》 SCIE EI CAS CSCD 2008年第4期450-454,共5页
In this work, study of laser-induced ions is presented. The plasma was produced by focusing a Nd:YAG laser, with a wavelength of 1064 nm, a pulsed width of 9-14 ns, a power of 1.1 MW and energy of 10 mJ, on silver ta... In this work, study of laser-induced ions is presented. The plasma was produced by focusing a Nd:YAG laser, with a wavelength of 1064 nm, a pulsed width of 9-14 ns, a power of 1.1 MW and energy of 10 mJ, on silver target in vacuum (10-3 Torr= 1.3332 Pa). The characteristics of ion streams were investigated by CR-39 detectors located at angles of 0°, 30°, 60° and 90° with respect to normal of the target. The distance between the silver target and each detector was 11 cm. The energy of silver ions was found ranging from 1.5 eV to 1.06E4 eV. There was a high concentration of ions with low energy as compared to those with high energy, showing the energy distribution amongst the ions. The flux of ions was maximum in the axial direction which was decreasing with the angle increase with respect to normal of the target, and finally became minimum in the radial direction. Hence the silver ions have shown anisotropic behaviour. 展开更多
关键词 Nd: YAG laser flux of ions ANISOTROPIC solid state nuclear track detector (SSNTD)
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The effect of non-storm time substorms on the ring current dynamics 被引量:2
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作者 EunJin Jang Chao Yue +2 位作者 QiuGang Zong SuiYan Fu HaoBo Fu 《Earth and Planetary Physics》 CSCD 2021年第3期251-258,共8页
During geomagnetically active times such as geomagnetic storms,large amounts of energy can be released into the Earth’s magnetosphere and change the ring current intensity.Previous studies showed that significant enh... During geomagnetically active times such as geomagnetic storms,large amounts of energy can be released into the Earth’s magnetosphere and change the ring current intensity.Previous studies showed that significant enhancement of the ring current was related to geomagnetic storms,while few studies have examined substorm effects on ring current dynamics.In this study,we examine the ring current variation during non-storm time(SYM-H>−50 nT)substorms,especially during super-substorms(AE>1000 nT).We perform a statistical analysis of ring current plasma pressure and number flux of various ion species under different substorm conditions,based on Van Allen Probe observations.The plasma pressure and ion fluxes of the ring current increased dramatically during supersubstorms,while little change was observed for substorms with AE<1000 nT.The results shown in this study indicate that a non-storm time super-substorm may also have a significant contribution to the ring current. 展开更多
关键词 super-substorms ring current ion fluxes
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Characteristics of the plasma sheath in helium discharge within dielectric tubes
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作者 吴淑群 郭玥 +3 位作者 欧阳帆 周保伟 胡彪 程鹤 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第4期79-92,共14页
To understand the characteristics of the plasma sheath within small tubes,a 2D numerical model of He discharge within dielectric tubes is developed.During plasma propagation for a tube diameter of 0.05 mm,the sheath t... To understand the characteristics of the plasma sheath within small tubes,a 2D numerical model of He discharge within dielectric tubes is developed.During plasma propagation for a tube diameter of 0.05 mm,the sheath thickness in the plasma head is almost equal to the tube radius.It decreases rapidly to several micrometers at an axial distance of 0.05 mm behind the plasma head,and then slightly increases and saturates at the axial position far behind the plasma head.A plasma-gas sheath surrounding the central plasma column is observed for a tube diameter equal to or greater than 0.8 mm.It is replaced by a plasma-wall sheath for smaller tubes.With the decrease in the tube diameter,the sheath thickness far behind the plasma head decreases while the ion flux increases significantly.However,when O_(2)gas with a proportion of 2%is added,both the sheath thickness and ion flux decrease. 展开更多
关键词 plasma sheath plasma modification helium discharge ion flux plasma jet
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Particle flux characteristics of a compact high-field cascaded arc plasma device
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作者 Xiaogang YUAN Haishan ZHOU +7 位作者 Haodong LIU Bo LI Yong WANG Lei CHANG Xin YANG Chuang WANG Lupeng ZHANG Guangnan LUO 《Plasma Science and Technology》 SCIE EI CAS CSCD 2021年第11期59-65,共7页
A new compact cascaded arc device for plasma-wall interaction study is developed at the Institute of Plasma Physics,Chinese Academy of Sciences.A magnetic field up to 0.8 T is achieved to confine plasmas in a 1.2 m lo... A new compact cascaded arc device for plasma-wall interaction study is developed at the Institute of Plasma Physics,Chinese Academy of Sciences.A magnetic field up to 0.8 T is achieved to confine plasmas in a 1.2 m long and 0.1 m diameter vacuum chamber.Gas fluid type analysis in this compact vacuum system was done under high particle flux condition.The gas pressure obtained by calculation was consistent with the measurement result.Continuous argon plasma discharge with ion flux of~0.5×10^(24)m^(-2)s^(-1)is successfully sustained for more than 1h.The effects of magnetic field configuration,gas flow rate,and discharge arc current on the ion flux to target were studied in detail. 展开更多
关键词 cascaded arc plasma plasma-wall interaction ion flux vacuum design linear plasma device
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K^(+)and Na^(+)fluxes in roots of two Chinese Iris populations
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作者 Pinfang LI Biao ZHANG 《Frontiers of Agricultural Science and Engineering》 2014年第2期144-149,共6页
Maintenance of ion homeostasis,particularly the regulation of K^(+)and Na^(+)uptake,is important for all plants to adapt to salinity.Observations on ionic response to salinity and net fluxes of K^(+),Na^(+)in the root... Maintenance of ion homeostasis,particularly the regulation of K^(+)and Na^(+)uptake,is important for all plants to adapt to salinity.Observations on ionic response to salinity and net fluxes of K^(+),Na^(+)in the root exhibited by plants during salt stress have highlighted the need for further investigation.The objectives of this study were to compare salt adaptation of two Chinese Iris(Iris lactea Pall.var.chinensis(Fisch.)Koidz.)populations,and to improve understanding of adaptation to salinity exhibited by plants.Plants used in this study were grown from seeds collected in the Xinjiang Uygur Autonomous Region(Xj)and Beijing Municipality(Bj),China.Hydroponicallygrown seedlings of the two populations were supplied with nutrient solutions containing 0.1(control)and 140 mmol·L^(–1) NaCl.After 12 days,plants were harvested for determination of relative growth rate and K^(+),Na^(+)concentrations.Net fluxes of K^(+),Na^(+)from the apex and along the root axis to 10.8 mm were measured using noninvasive micro-test technique.With 140 mmol·L^(–1) NaCl treatment,shoots for population Xj had larger relative growth rate and higher K^(+)concentration than shoots for population Bj.However,the Na^(+)concentrations in both shoots and roots were lower for Xj than those for Bj.There was a lower net efflux of K^(+)found in population Xj than by Bj in the mature zone(approximately 2.4^(–1)0.8 mm from root tip).However,no difference in the efflux of Na^(+)between the populations was obtained.Population Xj of I.lactea continued to grow normally under NaCl stress,and maintained a higher K^(+)/Na^(+)ratio in the shoots.These traits,which were associated with lower K^(+)leakage,help population Xj adapt to saline environments. 展开更多
关键词 Iris lactea Pall.var.chinensis(Fisch.)Koidz POPULATion K+and Na+ ion flux non-invasive micro-test technique
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K^+ retention in leaf mesophyll, an overlooked component of salinity tolerance mechanism:A case study for barley 被引量:9
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作者 Honghong Wu Min Zhu +2 位作者 Lana Shabala Meixue Zhou Sergey Shabala 《Journal of Integrative Plant Biology》 SCIE CAS CSCD 2015年第2期171-185,共15页
Plant salinity tolerance is a physiologically complex trait, with numerous mechanisms contributing to it. In this work, we show that the ability of leaf mesophyll to retain K+ represents an important and essentially ... Plant salinity tolerance is a physiologically complex trait, with numerous mechanisms contributing to it. In this work, we show that the ability of leaf mesophyll to retain K+ represents an important and essentially overlooked component of a salinity tolerance mechanism. The strong positive correlation between mesophyll K+ retention ability under saline conditions (quantified by the magnitude of NaCl-induced K+ efflux from mesophyll) and the overall salinity tolerance (relative fresh weight and/or survival or damage under salinity stress) was found while screening 46 barley (Hordeum vulgare L.) genotypes contrasting in their salinity tolerance. Genotypes with intrinsically higher leaf K+ content under control conditions were found to possess better K+ retention ability under salinity and, hence, overall higher tolerance. Contrary to previous reports for barley roots, K+ retention in mesophyll was not associated with an increased H+-pumping in tolerant varieties but instead correlated negatively with this trait. These findings are explained by the fact that increased H+ extrusion may be needed to charge balance the activity and provide the driving force for the high affinity HAK/KUP K+ transporters required to restore cytosolic K+ homeostasis in salt-sensitive genotypes. 展开更多
关键词 Cytosolic K+ homeostasis ion flux membrane potential membrane transport tissue tolerance
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Li-MOF-based ions regulator enabling fast-charging and dendrite-free lithium metal anode 被引量:3
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作者 Xiang Han Tiantian Wu +4 位作者 Lanhui Gu Minfeng Chen Jianzhong Song Dan Tian Jizhang Chen 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第2期489-494,共6页
Li metal has been regarded as the holy grail for the next-generation Li-ion battery.Li dendrites issues,however,impede its practical application.In general,prolonging the sand time of Li nucleation and regulating homo... Li metal has been regarded as the holy grail for the next-generation Li-ion battery.Li dendrites issues,however,impede its practical application.In general,prolonging the sand time of Li nucleation and regulating homogeneous Li^(+) flux are effective approaches to suppress the dendrites formation and growth.Regarding this view,a functional polypropylene (PP) separator is developed to regulate ion transportation via a newly designed Li-based metal-organic framework (Li-MOF) coating.The Li-MOF crystallizes in the orthorhombic space group P212121 and features a double-walled three-dimensional (3D) structure with 1D channels.The well-defined intrinsic nanochannels of Li-MOF and the steric-hinerance effect both restrict free migration of anions,contributing to a high Li^(+) transference number of 0.65,which improve the Sand time of Li nucleation.Meanwhile,the Li-MOF coating with uniform porous structure promotes homogeneous Li^(+) flux at the surface of Li metal.Furthermore,the Li-MOF coating layer helps to build solid-electrolyte interphase (SEI) layer that comprises of inorganic Li F and Li_(3)N,which further prohibits the dendrites growth.Consequently,a highly stable Li plating/stripping cycling for over 1000 h is achieved.The functional separator also enables high-performance full lithium metal cells,the high-rate and long-stable cycling performance of Li Ni_(0.8)Mn_(0.1)Co_(0.1)(NMC811)-Li and Li Co O_(2)(LCO)-Li cells further demonstrate the feasibility of this concept. 展开更多
关键词 Lithium-ion battery Li metal anode Metal-organic framework Li ions flux Solid-electrolyte interphase
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Influence of tail-like magnetic field on O^+ ion distribution in the Martian magnetosphere 被引量:1
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作者 史建魁 刘振兴 《Science China(Technological Sciences)》 SCIE EI CAS 2001年第4期421-426,共6页
Based on the comparison with the Earth, using the LB magnetic field model, the distribution of O+ ion originating from the ionosphere in the Martian magnetosphere is theoretically studied under different conditions of... Based on the comparison with the Earth, using the LB magnetic field model, the distribution of O+ ion originating from the ionosphere in the Martian magnetosphere is theoretically studied under different conditions of the tail-like magnetic field. The results show that the tail-like magnetic field has influence on the O+ ion flux in the Martian magnetotail: (i) the O+ ion flux in the Martian tail will increase if the tail-like magnetic field increases; when the tail-like magnetic field increases from 5 nT to 20 nT, the O+ ion flux increases 3 times in the region of 2.8R m in the Martian tail; and (ii) the O+ ion flux decreases with increasing intrinsic moment; when the intrinsic moment increases about 5 times, the flux decreases to one fourth in the region of 2.8R m in the Martian tail. According to the data on the O+ ion flux and theoretical result in this paper, the deduced Martian intrinsic moment is about 2 ×1021 Gcm3. This is consistent with the most recent observation by the USA satellite MGS. 展开更多
关键词 Mars tail-like magnetic field flux of O+ ion intrinsic moment
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Proto Kranz-like leaf traits and cellular ionic regulation are associated with salinity tolerance in a halophytic wild rice
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作者 Miing-Tiem Yong Celymar Angela Solis +11 位作者 Samuel Amatoury Gothandapani Sellamuthu Raja Rajakani Michelle Mak Gayatri Venkataraman Lana Shabala Meixue Zhou Oula Ghannoum Paul Holford Samsul Huda Sergey Shabala Zhong-Hua Chen 《Stress Biology》 2022年第1期587-605,共19页
Species of wild rice(Oryza spp.)possess a wide range of stress tolerance traits that can be potentially utilized in breeding climate-resilient cultivated rice cultivars(Oryza sativa)thereby aiding global food security... Species of wild rice(Oryza spp.)possess a wide range of stress tolerance traits that can be potentially utilized in breeding climate-resilient cultivated rice cultivars(Oryza sativa)thereby aiding global food security.In this study,we conducted a greenhouse trial to evaluate the salinity tolerance of six wild rice species,one cultivated rice cultivar(IR64)and one landrace(Pokkali)using a range of electrophysiological,imaging,and whole-plant physiological techniques.Three wild species(O.latifolia,O.officinalis and O.coarctata)were found to possess superior salinity stress tolerance.The underlying mechanisms,however,were strikingly different.Na+accumulation in leaves of O.latifolia,O.officinalis and O.coarctata were significantly higher than the tolerant landrace,Pokkali.Na+accumulation in mesophyll cells was only observed in O.coarctata,suggesting that O.officinalis and O.latifolia avoid Na+accumulation in mesophyll by allocating Na+to other parts of the leaf.The finding also suggests that O.coarctata might be able to employ Na+as osmolyte without affecting its growth.Further study of Na+allocation in leaves will be helpful to understand the mechanisms of Na+accumulation in these species.In addition,O.coarctata showed Proto Kranz-like leaf anatomy(enlarged bundle sheath cells and lower numbers of mesophyll cells),and higher expression of C4-related genes(e.g.,NADPME,PPDK)and was a clear outlier with respect to salinity tolerance among the studied wild and cultivated Oryza species.The unique phylogenetic relationship of O.coarctata with C4 grasses suggests the potential of this species for breeding rice with high photosynthetic rate under salinity stress in the future. 展开更多
关键词 Gas exchange Gene expression ion flux Na+imaging Oryza sativa Oryza coarctata
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固态锂金属电池中不均匀离子通量介导的正负极耦合失效机制 被引量:5
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作者 郑越 张舒 +8 位作者 马君 孙富 Markus Osenberg AndréHilger Henning Markötter Fabian Wilde Ingo Manke 胡中波 崔光磊 《Science Bulletin》 SCIE EI CAS CSCD 2023年第8期813-825,M0004,共14页
本文通过联用无损三维同步辐射X射线断层扫描成像技术(SXCT)和其他非原位测试技术及有限元模拟,深入研究了LiNi0.8Co0.1Mn0.1O2|Li6PS5Cl|Li全固态电池的衰退机制.研究发现正极电化学-机械力学耦合失效诱导的反应异质性产生不均匀的锂... 本文通过联用无损三维同步辐射X射线断层扫描成像技术(SXCT)和其他非原位测试技术及有限元模拟,深入研究了LiNi0.8Co0.1Mn0.1O2|Li6PS5Cl|Li全固态电池的衰退机制.研究发现正极电化学-机械力学耦合失效诱导的反应异质性产生不均匀的锂离子通量并传输到负极,进而导致不均匀的锂沉积、溶解行为及死锂的产生等.锂负极不均匀的电化学反应行为又反作用于正极并强化其反应异质性,形成一种正负极衰退互相促进的正强化机制.随着电池继续循环,正负极的不均匀反应加剧造成其结构破坏,同时正负极体积缩胀引起电解质巨大塑性变形,最终致使电池失效.对比实验表明采用LiZr_(2)(PO_(4))_(3)(LZP)对正极进行改性,不仅有效抑制了正极的电化学-机械力学耦合失效,而且显著提高了负极锂沉积-溶解均匀性和电解质的结构完整性.该研究首次提出了全固态金属锂电池正负极相互依赖、相互关联的失效机制,为提升全固态金属锂电池性能提供了新思路. 展开更多
关键词 Current density distribution Lithium ion flux Solid-state lithium metal batteries Codependent failure mechanism Cathode deactivation
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Structural behavior of F-in mould flux melt of CaO-SiO2-Al2 O3-Na2O-CaF2 system
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作者 Qiang Gao Yi Min +1 位作者 Cheng-jun Liu Mao-fa Jiang 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2017年第11期1152-1158,共7页
The influence of fluorine on the structure of CaO Si()e-Al2Oa Na2O-CaF2 continuous-casting-type slag was measured by Raman spectroscopy, and the degree of polymerization of mould flux and the structural behavior of ... The influence of fluorine on the structure of CaO Si()e-Al2Oa Na2O-CaF2 continuous-casting-type slag was measured by Raman spectroscopy, and the degree of polymerization of mould flux and the structural behavior of F- in the melt were investigated by classifying and quantifying the structural species of F ions. The results exhibit that the main structural units of Si O tetrahedra are Q1, Q1 and Q2, and the actual measured number of non bridging oxygen ions in the [SiO4 ]-tetrahedra (denoted by NBO/T) in creases from 2. 73 to 3.44 with increasing the molar ratio of F to (F+O) (denoted by XF/X(F-O ) from 0.06 to 0. 19. It means that the degree of polymerization o1 meh structure decreases with an increase in XE/X(F+O). In addition, most of F- ions were distributed in Si-O tetrahedra and Al-O tetrahedra. With increasing XF/X(F+O), the complex structural units Al-Otetrahedra are gradually replaced hy discrete structural units A1F4 because of the breakage of Al-O bonds in Al-Otetrahedra by F ions, and the SiO (bridging oxygen) bonds of SiO tetrahedra are broken to form [SiOnF1-n]-tetrahedra by F ions coordinating with Si4 + . 展开更多
关键词 Mould flux F- ion Melt structure Polymerization degree
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