The ionization spectrum of sulfur dioxide has been successfully studied by using the symmetry-adapted-cluster configuration-interaction （SAC-CI） general-R and SD-R methods and the basis set correlation-consistent po...The ionization spectrum of sulfur dioxide has been successfully studied by using the symmetry-adapted-cluster configuration-interaction （SAC-CI） general-R and SD-R methods and the basis set correlation-consistent polarized valence triple-zeta （cc-pVTZ）. The SAC-CI general-R method reproduces the experimental spectrum well for both the main peaks and the satellite peaks of ionization spectrum of SO2. The sequence of ionic states corresponding to main peaks of SO2 has been re-determined according to the SAC-CI conclusions and it is reordered as X^2A1, A^2B2, B2A2, C^2B1,D^2A1, E^2B2 and F^2A1. Besides, the equilibrium structures and adiabatic ionization potentials （AIPs） of ionic states of main peaks of SO2 are calculated by using the SAC-CI SD-R method.展开更多
The ionization characteristics of the analytes in a low power Ar microwave plasma torch (MPT) was studied. The influence of forward microwave power, the flow rate of carrier gas and matrix element on the degree of ion...The ionization characteristics of the analytes in a low power Ar microwave plasma torch (MPT) was studied. The influence of forward microwave power, the flow rate of carrier gas and matrix element on the degree of ionization were observed. The axial profiles of the degree of the ionization of some elements were determined. The experimental results are very important for developing the new analytical source——microwave plasma torch (MPT).展开更多
A mini-type of plasma source was studied experimentally. The results showed that the plasma density, which was generated by an atmospheric non-equilibrium plasma source, rises with the increase in driving electric-fie...A mini-type of plasma source was studied experimentally. The results showed that the plasma density, which was generated by an atmospheric non-equilibrium plasma source, rises with the increase in driving electric-field and the momentum of gas particles. For a driving electricfield of 56 kV/cm and a gas particles＇ momentum of 10^9 × 10^-22 g·m/s, the ion density can exceed 10^10/cm^3 while the effective volume of the plasma source is only 2.5 cm^2. This study may help develop a method to generate a minitype plasma source with low energy consumption but high ion concentration. This source can be used in chemical industry, environmental engineering and military applications.展开更多
This paper presents the results of an extensive set of calculations about ionization equilibrium and NLTE effects on compact circumstellar HII regions embedded in clouds. In the mode! of a spherically symmetric and is...This paper presents the results of an extensive set of calculations about ionization equilibrium and NLTE effects on compact circumstellar HII regions embedded in clouds. In the mode! of a spherically symmetric and isothermal wind with a steady mass loss, pure hydrogen composition as well as Sobolev approximation, our research indicates that compact HII regions are far away from LTE state. The collisional ionization and photoionization from excited levels have great effects on the size of an HII region, the distribution of departure coefficients and the flux ratio of observed spectral lines. They can be used to explain the infrared line excess and the line deficit problems of YSOs. We conclude that it is unreasonable to infer the spectral type, mass loss rate and foreground extinction of the central star from optically thin line recombination theory.展开更多
针对如何产生均匀和稳定的超声速非平衡等离子体这一科学问题,为进一步探究超声速气流电容耦合射频放电特性,建立了超声速非平衡电离磁流体动力技术实验系统,开展了Ma=3.4条件下,超声速气流边界层与主流中心区的电容耦合射频放电特性研...针对如何产生均匀和稳定的超声速非平衡等离子体这一科学问题,为进一步探究超声速气流电容耦合射频放电特性,建立了超声速非平衡电离磁流体动力技术实验系统,开展了Ma=3.4条件下,超声速气流边界层与主流中心区的电容耦合射频放电特性研究;同时针对超声速放电等离子体的实时诊断问题,基于均匀射频放电模型,联立能量平衡方程,建立等离子体诊断模型对平均电子数密度与电子温度等参数进行诊断。结果表明:超声速气流条件下,通过电容耦合射频可以产生均匀和稳定的放电等离子体;分子数密度是影响超声速气流放电特性的主要因素,同时超声速气流对平均电子温度的影响很小,约为0.46 e V。展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No 10404030)
文摘The ionization spectrum of sulfur dioxide has been successfully studied by using the symmetry-adapted-cluster configuration-interaction （SAC-CI） general-R and SD-R methods and the basis set correlation-consistent polarized valence triple-zeta （cc-pVTZ）. The SAC-CI general-R method reproduces the experimental spectrum well for both the main peaks and the satellite peaks of ionization spectrum of SO2. The sequence of ionic states corresponding to main peaks of SO2 has been re-determined according to the SAC-CI conclusions and it is reordered as X^2A1, A^2B2, B2A2, C^2B1,D^2A1, E^2B2 and F^2A1. Besides, the equilibrium structures and adiabatic ionization potentials （AIPs） of ionic states of main peaks of SO2 are calculated by using the SAC-CI SD-R method.
基金Supported by the National Natural Science Foundation of China
文摘The ionization characteristics of the analytes in a low power Ar microwave plasma torch (MPT) was studied. The influence of forward microwave power, the flow rate of carrier gas and matrix element on the degree of ionization were observed. The axial profiles of the degree of the ionization of some elements were determined. The experimental results are very important for developing the new analytical source——microwave plasma torch (MPT).
基金National High-tech Research & Development Plan(863 Projeet)(No.2008AA062317)National Natural Science Foundation of China(No.50578020)
文摘A mini-type of plasma source was studied experimentally. The results showed that the plasma density, which was generated by an atmospheric non-equilibrium plasma source, rises with the increase in driving electric-field and the momentum of gas particles. For a driving electricfield of 56 kV/cm and a gas particles＇ momentum of 10^9 × 10^-22 g·m/s, the ion density can exceed 10^10/cm^3 while the effective volume of the plasma source is only 2.5 cm^2. This study may help develop a method to generate a minitype plasma source with low energy consumption but high ion concentration. This source can be used in chemical industry, environmental engineering and military applications.
基金Project supported by the National Natural Science Foundation of China and Astrophysical Branch of Chinese Astronomical Committee.
文摘This paper presents the results of an extensive set of calculations about ionization equilibrium and NLTE effects on compact circumstellar HII regions embedded in clouds. In the mode! of a spherically symmetric and isothermal wind with a steady mass loss, pure hydrogen composition as well as Sobolev approximation, our research indicates that compact HII regions are far away from LTE state. The collisional ionization and photoionization from excited levels have great effects on the size of an HII region, the distribution of departure coefficients and the flux ratio of observed spectral lines. They can be used to explain the infrared line excess and the line deficit problems of YSOs. We conclude that it is unreasonable to infer the spectral type, mass loss rate and foreground extinction of the central star from optically thin line recombination theory.
文摘针对如何产生均匀和稳定的超声速非平衡等离子体这一科学问题,为进一步探究超声速气流电容耦合射频放电特性,建立了超声速非平衡电离磁流体动力技术实验系统,开展了Ma=3.4条件下,超声速气流边界层与主流中心区的电容耦合射频放电特性研究;同时针对超声速放电等离子体的实时诊断问题,基于均匀射频放电模型,联立能量平衡方程,建立等离子体诊断模型对平均电子数密度与电子温度等参数进行诊断。结果表明:超声速气流条件下,通过电容耦合射频可以产生均匀和稳定的放电等离子体;分子数密度是影响超声速气流放电特性的主要因素,同时超声速气流对平均电子温度的影响很小,约为0.46 e V。
