An Integrated Analysis on the Synergistic Reduction of Carbon and Pollution Emissions from China’s Iron and Steel Industry

Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions in China,are challenged by the huge demand for steel.Carbon and pollutants often share common emission sources,indicating that emission reduction could be achieved synergistically.Here,we explored the inherent potential of measures to adjust feedstock composition and technological structure and to control the size of the ISI to achieve carbon emission reduction(CER)and pollution emission reduction(PER).We investigated five typical pollutants in this study,namely,petroleum hydrocarbon pollutants and chemical oxygen demand in wastewater,particulate matter,SO_(2),and NO_(x) in off gases,and examined synergies between CER and PER by employing cross elasticity for the period between 2022 and 2035.The results suggest that a reduction of 8.7%-11.7%in carbon emissions and 20%-31%in pollution emissions(except for particulate matter emissions)could be achieved by 2025 under a high steel scrap ratio(SSR)scenario.Here,the SSR and electric arc furnace(EAF)ratio serve critical roles in enhancing synergies between CER and PER(which vary with the type of pollutant).However,subject to a limited volume of steel scrap,a focused increase in the EAF ratio with neglection of the available supply of steel scrap to EAF facilities would lead to an increase carbon and pollution emissions.Although CER can be achieved through SSR and EAF ratio optimization,only when the crude steel production growth rate remains below 2.2%can these optimization measures maintain the emissions in 2030 at a similar level to that in 2021.Therefore,the synergistic effects between PER and CER should be considered when formulating a development route for the ISI in the future.

Operation and Management of Electrical Equipment in Iron and Steel Enterprises

How to ensure the reliable operation of the complex and huge electrical system composed of a large number of electrical equipment in iron and steel enterprises?Combined with working experience,the author introduces four main factors affecting the normal operation of equipment,analyzes five main problems existing in the operation and management of electrical equipment,and puts forward corresponding improvement measures,so as to improve the management level of electrical equipment in iron and steel enterprises.

Regulatory mechanisms of iron homeostasis in maize mediated by ZmFIT

Regulation of iron homeostasis in maize remains unclear,despite the known roles of FER-Like Fe deficiency-induced transcription factor(FIT)in Arabidopsis and rice.ZmFIT,like At FIT and Os FIT,interacts with iron-related transcription factors 2(ZmIRO2).Here,we investigate the involvement of ZmFIT in iron homeostasis.Mutant ZmFIT lines exhibiting symptoms of Fe deficiency had reduced shoot iron content.Transcriptome analysis revealed downregulation of Fe deficiency-responsive genes in the roots of a Zmfit mutant.ZmFIT facilitates the nuclear translocation of ZmIRO2 to activate transcription of downstream genes under Fe-deficient conditions.Our findings suggest that ZmFIT,by interaction with ZmIRO2,mediates iron homeostasis in maize.Notably,the binding and activation mechanisms of ZmFIT resemble those in Arabidopsis but differ from those in rice,whereas downstream genes regulated by ZmFIT show similarities to rice but differences from Arabidopsis.In brief,ZmFIT,orthgologs of Os FIT and At FIT in rice and maize,respectively,regulates iron uptake and homeostasis in maize,but with variations.

Discussion on Abnormal Corrosion and Material Selection of Hot Iron Ladles with Steel Scrap Addition

The abnormal corrosion of hot iron ladles was investigated.The performance,the composition and the structure of bricks for hot iron ladles were analyzed.The results show that(1)compared with the alumina-silicon carbide-carbon bricks for the ladle bottom,those for the ladle wall have more pyrophyllite and the Al2O3 content of 36.32 mass%;their bulk density,apparent porosity and cold compressive strength are lower than the requirement of industry standard;they have poor anti-oxidation performance and are oxidized to form a porous layer during service,which loosens the brick lining structure thus leading to fracture,local wear and structural damage of bricks;(2)without preheating,steel scraps are not completely melted,resulting in slag or steel attachment at the mouth or the bottom of ladles thus increasing damage of ladles;(3)and the residual bricks react with the attached slag to form low melting point phases affecting their hot properties.The refractories for the lining of hot iron ladles must be improved in combination with process changes,not entirely by raw materials replacement to reduce costs.

Baoshan Iron & Steel Company——Large-Scale, Modern Iron & Steel Complex in China

The Shanghai Baoshan Iron and Steel (Group) Co., located in the Baoshan District in northeast Shanghai, borders on the Yangtze River in the north and the Wusong Estuary in the east, and covers an area of 16 square kilometres. It is the largest construction project with imported technology and equipment in China and its

Discussion on Gas Safety Protection Management in Steel Plants

The necessity of establishing gas protection station in iron and steel works is demonstrated,issues of strengthening the management of gas safety protection,studying new technology of gas protection,adapting to the needs of modernization and building large scale and intelligent iron and steel works are discussed.Relevant sug-gestions are also put forward.

Does Environmental Regulation Weaken Industrial Competitiveness?Inspirations from China’s Iron and Steel Sector

China＇s economic growth is heavily influenced by exports, while reconciling environmental regulation and economic growth requires handling the relationship between environmental regulation and industrial competitiveness well. The effects of environmental regulation on industrial competitiveness are largely subject to the institutional design of environmental regulation. Despite numerous studies on the relationship between environmental regulation and industrial competitiveness, a consensus has yet to be reached. Aside from differences in research methodology, these studies failed to give sufficient consideration to the impact of environmental regulation on industrial competitiveness. Such effects can be negative or positive depending on the design of environmental regulatory policy. This paper has investigated the relationship between environmental regulation and the competitiveness of China＇s iron and steel industry and discovered that tighter environmental regulation does not diminish the competitiveness of the iron and steel industry since the policy design of environmental regulation accommodates the tolerance of advanced production capacity and includes a reasonable cost sharing mechanism. This discovery is of important reference for China to develop rational policy design to balance the relationship between environmental regulation and industrial competitiveness.

Impact of material and energy flow variation-based iron /steel ratio on production cost

This paper establishes a model for the production cost of iron and steel enterprise.The variation rule of the production cost versus the iron/steel ratio for two cases, namely,fixed steel production and a fixed amount of molten iron,is analyzed,and the concept of a steel scrap threshold price is proposed.According to the analysis results,when the steel scrap unit price exceeds the steel scrap threshold price, an increase in the iron/steel ratio can reduce the production cost,and vice versa.When the gap between the steel scrap unit price and the steel scrap threshold price is relatively large, the impact of the iron/steel ratio on the production cost is more prominent.According to the calculation example,when steel production is fixed （284 358 t/month）and the steel scrap unit price is 263.2 yuan/t more than the steel scrap threshold price,an increase of 0.01 in the iron/steel ratio causes a monthly production cost reduction of approximately 750 000 yuan （2.63 yuan/t）.When the amount of molten iron is fixed （270 425 t/month）and the steel scrap unit price is 140.7 yuan/t more than the threshold price,an increase of 0.01 in the iron/steel ratio causes a monthly production cost reduction of approximately 430 000 yuan （1.5 yuan/t）.The results indicate that iron and steel enterprise should adjust the production strategy in time when the scrap price fluctuates, and then the production cost will be reduced.

Influence of shape anisotropy on microwave complex permeability in carbonyl iron flakes/epoxy resin composites

To explore the mechanism of carbonyl iron flake composites for microwave complex permeability, this paper investigates the feature of the flakes. The shape anisotropy was certified by the results of the magnetization hysteresis loops and the Mossbauer spectra. Furthermore, the shape anisotropy was used to explain the origin of composite microwave performance, and the calculated results agree with the experiment. It is believed that the shape anisotropy dominates microwave complex permeability, and the natural resonance plays main role in flake.

An analytical method for Fe(Ⅱ) and Fe(Ⅲ) determination in pharmaceutical grade iron sucrose complex and sodium ferric gluconate complex

A robust voltammetric method has been developed and validated for the determination of Fe（Ⅱ） and Fe（Ⅲ） in pharmaceutical iron polysaccharidic complexes. Undesirable low molecular weight iron complexes, at concentration about 3% in the pharmaceutical formulation, can be easily determined with good accuracy and precision. This methodology can be proposed as a viable, environmentally sustainable substitute for the conventional Normal Pulse Polarographic method in US Pharmacopeia, with better analytical figures of merit, and reduced Hg consumption. A deeper insight in Fe（Ⅱ） and Fe（Ⅲ） composition can be gained by the combined use of a new potentiometric technique after chemical decomposition of the complex.

Steel Slag as an Iron Fertilizer for Corn Growth and Soil Improvement in a Pot Experiment

The feasibility of steel slag used as an iron fertilizer was studied in a pot experiment with corn. Slag alone or acidified slag was added to two Fe-deficient calcareous soils at different rates. Results showed that moderate rates (10 and 20 g kg-1) of slag or acidified slag substantially increased corn dry matter yield and Fe uptake. Application of steel slag increased the residual concentration of ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA) extractable Fe in the soils. The increase of extractable Fe was usually proportional to the application rate, and enhanced by the acidification of slag. Steel slag appeared to be a promising and inexpensive source of Fe to alleviate crop Fe chlorosis in Fe-deficient calcareous soils.

Highlights of Recent Advances in Refractories for Iron and Steel Industry in China

Recently procured outstanding achievements in iron and steel industry in China are presented by data or facts in steel output, energy consumption, technical and economical indicators and advanced technologies that are being adopted. The latest achievements in refractonries for this biggest user industry are reviewed, covering new refractories for CDQ coke oven, BF hearth, AOD Lining, long life tundish, SEN for clean steel making and regenerative reheating furnace . The reciprocal relationship is obvious that the rapid development of iron and steel industry has given an impetus to the advance of refractories industry, which in return has contributed greatly to the former.

Some Aspects in the Development of High Performance Refractories for Iron and Steel Making in China

In the past 25 years in China, to meet with the rapid increase in steel production accompanied by adoption of advanced metallurgical technologies, there has been fast development of China＇ s refractories industry in production capacity, in quality improvement and in development of new products. Sophisticated high performance refractory materials mainly based on our rich reserves of magncsite, bauxite and flake graphite have been developed, such as carbon-bonded products, high purity oxide products, bauxite-based low creep and high strength high alumina bricks and LC, ULC and ZC castables. They have been used in blast furnaces, BOFs, EAFs, secondary refining and continuous casting with considerable improvement in service pecformance.

Centrifugal Casting of High Speed Steel/Nodular Cast Iron Compound Roll Collar

The centrifugal casting of compound HSS/nodular cast iron roll collar was studied,and the factors affecting transition zone quality were analyzed.The pouring temperature and interval in pouring are the main factors affecting transition zone quality.By controlling process parameter and flux adding during casting,high quality roll collar was obtained.The cause,why in the casting of HSS part,segregation appears easily,was analyzed and the countermeasure eliminating segregation was put forward,the measure eliminating heat treatment crackling was also put forward.

Optimization for vehicle scheduling in iron and steel works based on semi-trailer swap transport

In order to solve internal logistics problems of iron and steel works,such as low transportation efficiency of vehicles and high transportation cost,the production process and traditional transportation style of iron and steel works were introduced.The internal transport tasks of iron and steel works were grouped based on cluster analysis according to demand time of the transportation.An improved vehicle scheduling model of semi-trailer swap transport among loading nodes and unloading nodes in one task group was set up.The algorithm was designed to solve the vehicle routing problem with simultaneous pick-up and delivery(VRPSPD) problem based on semi-trailer swap transport.A solving program was written by MATLAB software and the method to figure out the optimal path of each grouping was obtained.The dropping and pulling transportation plan of the tractor was designed.And an example of semi-trailer swap transport in iron and steel works was given.The results indicate that semi-trailer swap transport can decrease the numbers of vehicles and drivers by 54.5% and 88.6% respectively compared with decentralized scheduling in iron and steel works,and the total distance traveled reduces by 43.5%.The semi-trailer swap transport can help the iron and steel works develop the production in intension.

Fabrication of plain carbon steel/high chromium white cast iron bimetal by a liquid–solid composite casting process

High-chromium white cast iron （HCWCI） is one of the most widely used engineering materials in the mining and cement industries. However, in some components, such as the pulverizer plates of ash mills, the poor machinability of HCWCI creates difficulties. The bimetal casting technique is a suitable method for improving the machinability of HCWCI by joining an easily machined layer of plain carbon steel （PCS） to its hard part. In this study, the possibility of PCS/HCWCI bimetal casting was investigated using sand casting. The investigation was conducted by optical and electron microscopy and non-destructive, impact toughness, and tensile tests. The hardness and chemical composition profiles on both sides of the interface were plotted in this study. The results indicated that a conventional and low-cost casting technique could be a reliable method for producing PCSYdCWCI bimetal. The interfacial microstructure comprised two distinct lay- ers： a very fine, partially spheroidized pearlite layer and a coarse full pearlite layer. Moreover, characterization of the microstructure revealed that the interface was free of defects.

Complex Precipitation Mechanism of Ti-Nb-V Microalloyed Bainitic Base High Strength Steel

The addition of high Ti（>0.1%） in microalloyed bainitic high strength steel was designed, and the precipitation morphology of steels with different Ti, Nb, and V contents was studied by utilizing transmission electron microscopy（TEM）. Based on the classical nucleation-crystal growth theory and the Johnson-Mehl-Avrami equation, the precipitation thermodynamic and kinetic model of second phase particles in austenite was established in the form of（Nbx,Vy,Tiz）C, and the complex precipitation mechanism of second phase particles was emphatically studied. The experimental results show that the complex precipitation particles could be divided into two categories: the coarser particles with about 100 nm grain size and the independent complex precipitation particles in the form of（Nb,V,Ti）C with 35-50 nm grain size. The latter has a better precipitation strengthening effect, and the calculated PTT curve shows a typical "C" shape. When the deformed storage energy is 3 820 J?mol-1, the fastest precipitation temperature of calculated PTT curve is 925 °C, and the calculated result is essentially consistent with experimental values. The increase of Ti content increased the nose point temperature and expanded the range of fastest precipitation temperature.

Catalytic performance of cerium iron complex oxides for partial oxidation of methane to synthesis gas

The cerium iron complex oxides oxygen carrier was prepared by the co-precipitation method. The reactions between methane and lattice oxygen from the complex oxides were investigated in a fixed micro-reactor system. The reduced oxygen carder could be re-oxidized by air and its initial state could be restored. The characterizations of the oxygen carders were studied using XRD, O2-TPD, and H2-TPR. The results showed that the bulk lattice oxygen of CeO2-Fe2O3 was found to be suitable for the partial oxidation of methane to synthesis gas. There were two kinds of oxygen species on the oxygen carrier： the stronger oxygen species that was responsible for the complete oxidation of methane, and the weaker oxygen species （bulk lattice oxygen） that was responsible for the selective oxidation of methane to CO and H2 at a higher temperature. Then, the lost bulk lattice oxygen could be selectively supplemented by air re-oxidation at an appropriate reaction condition. CeFeO3 appeared on the oxygen carrier after 10 successive redox cycles, however, it was not bad for the selectivity of CO and H2.

Locking compression plate+T-type steel plate for postoperative weight bearing and functional recovery in complex tibial plateau fractures

Complex tibial plateau fractures can seriously affect quality of life and physical and mental health of patients.The anatomical relationship between the proximal tibial bone and soft tissue is complex,resulting in different types of tibial plateau fractures.Violent trauma can lead to displaced fracture,serious soft tissue injury,and potentially,dislocation of the knee joint.Therefore,tibial plateau fractures are extremely unstable.AIM To assess the use of locking compression plate(LCP)+T-type steel plate for postoperative weight bearing and functional recovery of complex tibial plateau fractures.METHODS Ninety-seven patients with complex tibial plateau fractures who underwent surgery at our hospital were selected for retrospective study.Forty-nine patients had been treated with LCP+T-type steel plate limited internal fixation(study group),and 48 patients with bilateral ordinary steel plate support(control group).The operation process index,postoperative rehabilitation related index,Rasmussen score of the knee joint,tibial plateau varus angle(TPA),tibial plateau retroversion angle(PA),and surgical complications of the two groups were compared.RESULTS The operation time and intraoperative bone graft volume in the study group were lower than those in the control group(P<0.05).There were no significant differences in surgical bleeding,anterior external incision length,postoperative drainage,hospital stay duration,and fracture healing time between the groups(P>0.05).There was no significant difference in the TPA and PA angle between the groups immediately and 18 mo after surgery(P>0.05).At 12 mo after surgery,the Rasmussen scale score was higher in the study group than in the control group(P<0.05).There was no significant difference in the Rasmussen scale score at 18 mo after surgery,and the radiology score at 12 and 18 mo after surgery,between the two groups(P>0.05).The postoperative complication rate in the study group(3.77%)was lower than that in the control group(15.09%;P<0.05).CONCLUSION LCP+T-type steel plate internal fixation has advantages in terms of minimizing trauma and enabling early postoperative functional exercise,promoting functional recovery and lower limb weight-bearing,and reducing postoperative complications.

Electrolytic surface hardening of steel, cast iron and aluminium-bronze

Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this original work applied to different materials like steel, cast iron and aluminum-bronze. This paper gives details of microstructural transformations along with hardness value achieved. There is vital scope for this process to become viable for surface hardening and selective hardening of small components.