The effect of trace elements with zero self-interaction coefficient on crystallization temperature of iron carbon alloys was studied and the mathematic equation was developed based on thermodynamics in the present res...The effect of trace elements with zero self-interaction coefficient on crystallization temperature of iron carbon alloys was studied and the mathematic equation was developed based on thermodynamics in the present researeh. With the equation developed in this paper, the effects of nitrogen on crystallization temperature of Fe-3.45C-2.15Si0. 16Mn and Fe-3.45C-2. 15Si-0. 80Mn alloys were discussed.展开更多
Rolling process based on the plastic deformation as a surface strengthening treatment was employed,aiming to improve the wear resistance ability and functional performance of the high carbon equivalent gray cast iron(...Rolling process based on the plastic deformation as a surface strengthening treatment was employed,aiming to improve the wear resistance ability and functional performance of the high carbon equivalent gray cast iron(HCEGCI).The microstructures and tribological performance of the untreated and rolled samples were characterized.In addition,the wear mechanism of HCEGCI samples was also studied via pin-on-disc tests.The experimental results show that the as-rolled samples possess the structure-refined layer of 15μm and work-hardened layer of 0.13 mm.In comparison with the surface hardness of untreated samples,the surface hardness of as-rolled samples increases by 84.6%(from 240HV0.1 to 443HV0.1)and the residual compressive stresses existed within the range of 0.2 mm.The wear rates of as-rolled samples were decreased by 38.4%,37.5%,and 44.4%under different loads of 5 N,10 N,and 15 N,respectively.The wear characteristics of the untreated samples mainly exhibit the peeling wear coupled with partial adhesive and abrasive wear.However,as for the as-rolled samples,the adhesive wear was limited by the structure-refined layer and the micro-crack propagation was controlled by the work-hardened layer.Therefore,the wear resistance of as-rolled samples can be improved significantly due to the low wearing degree of the friction contact zone.展开更多
A mixed-control model was developed to study the transformation character of ferrite formation by a ledge mechanism. A nu- merical two-dimensional diffusion-field model was combined to describe the evolution of the di...A mixed-control model was developed to study the transformation character of ferrite formation by a ledge mechanism. A nu- merical two-dimensional diffusion-field model was combined to describe the evolution of the diffusion field ahead of the migrating austenite/ferrite interface. The calculation results show that the bulk diffusion-controlled model leads to a deviation from experimental results under large solute supersaturation. In the mixed-control model, solute supersaturation and a parameter Z together determine the transformation character, which is quantified by the normalized concentration of carbon in austenite at the austenite/ferfite interface. By comparing with experimental data, thepre-exponential factor of interface mobility, M0, is estimated within the range from 0.10 to 0.60 mol-m·J^-1·s^-1 for the alloys with 0.1 lwt%-0.49wt% C at 700-740℃. For a certain Fe-C alloy, the trend of the transformation character relies on the magnitude of M0 as the transformation temperature decreases.展开更多
文摘The effect of trace elements with zero self-interaction coefficient on crystallization temperature of iron carbon alloys was studied and the mathematic equation was developed based on thermodynamics in the present researeh. With the equation developed in this paper, the effects of nitrogen on crystallization temperature of Fe-3.45C-2.15Si0. 16Mn and Fe-3.45C-2. 15Si-0. 80Mn alloys were discussed.
基金Funded by the National Natural Science Foundation of China(No.51872254)the Yangzhou Hanjiang District Science and Technology Plan Project of China(No.HJM2019006)。
文摘Rolling process based on the plastic deformation as a surface strengthening treatment was employed,aiming to improve the wear resistance ability and functional performance of the high carbon equivalent gray cast iron(HCEGCI).The microstructures and tribological performance of the untreated and rolled samples were characterized.In addition,the wear mechanism of HCEGCI samples was also studied via pin-on-disc tests.The experimental results show that the as-rolled samples possess the structure-refined layer of 15μm and work-hardened layer of 0.13 mm.In comparison with the surface hardness of untreated samples,the surface hardness of as-rolled samples increases by 84.6%(from 240HV0.1 to 443HV0.1)and the residual compressive stresses existed within the range of 0.2 mm.The wear rates of as-rolled samples were decreased by 38.4%,37.5%,and 44.4%under different loads of 5 N,10 N,and 15 N,respectively.The wear characteristics of the untreated samples mainly exhibit the peeling wear coupled with partial adhesive and abrasive wear.However,as for the as-rolled samples,the adhesive wear was limited by the structure-refined layer and the micro-crack propagation was controlled by the work-hardened layer.Therefore,the wear resistance of as-rolled samples can be improved significantly due to the low wearing degree of the friction contact zone.
基金supported by the National Natural Science Foundation of China (Nos.51171087 and 51071089)the Specialized Research Fund for the Doctoral Program of Higher Education (No.20070003006)
文摘A mixed-control model was developed to study the transformation character of ferrite formation by a ledge mechanism. A nu- merical two-dimensional diffusion-field model was combined to describe the evolution of the diffusion field ahead of the migrating austenite/ferrite interface. The calculation results show that the bulk diffusion-controlled model leads to a deviation from experimental results under large solute supersaturation. In the mixed-control model, solute supersaturation and a parameter Z together determine the transformation character, which is quantified by the normalized concentration of carbon in austenite at the austenite/ferfite interface. By comparing with experimental data, thepre-exponential factor of interface mobility, M0, is estimated within the range from 0.10 to 0.60 mol-m·J^-1·s^-1 for the alloys with 0.1 lwt%-0.49wt% C at 700-740℃. For a certain Fe-C alloy, the trend of the transformation character relies on the magnitude of M0 as the transformation temperature decreases.
