STRUCTURE AND PROPERTIES OF ISOBUTYLENE-ISOPRENE RUBBER/SWOLLEN ORGANOCLAY NANOCOMPOSITES PREPARED BY SHEAR MIXING

A new approach was developed to prepare high-performance isobutylene-isoprene rubber/swollen organoclay nanocomposites by shear mixing.Compared with traditional melt compounding method,better dispersion of nanoclay layers in rubber matrix was verified through transmission electron microscopy（TEM） and X-ray diffraction（XRD）.The nanocomposites also exhibit significantly improved mechanical properties and gas barrier property.As a mechanism,the molecules of organic swelling agent play a vital role in accelerating the diffusion and intercalation of the matrix molecules.

Low-temperature characteristicsof rubbers and performance testsof type 120 emergencyvalve diaphragms

Purpose–The type 120 emergency valve is an essential braking component of railway freight trains,butcorresponding diaphragms consisting of natural rubber(NR)and chloroprene rubber(CR)exhibit insufficientaging resistance and low-temperature resistance,respectively.In order to develop type 120 emergency valverubber diaphragms with long-life and high-performance,low-temperatureresistant CR and NR were processed.Design/methodology/approach–The physical properties of the low-temperature-resistant CR and NRwere tested by low-temperature stretching,dynamic mechanical analysis,differential scanning calorimetryand thermogravimetric analysis.Single-valve and single-vehicle tests of type 120 emergency valves werecarried out for emergency diaphragms consisting of NR and CR.Findings–The low-temperature-resistant CR and NR exhibited excellent physical properties.The elasticityand low-temperature resistance of NR were superior to those of CR,whereas the mechanical properties of thetwo rubbers were similar in the temperature range of 0℃–150℃.The NR and CR emergency diaphragms metthe requirements of the single-valve test.In the low-temperature single-vehicle test,only the low-temperaturesensitivity test of the NR emergency diaphragm met the requirements.Originality/value–The innovation of this study is that it provides valuable data and experience for futuredevelopment of type 120 valve rubber diaphragms.

Visualization Analysis of the Impact of Rubber Agroforestry Ecosystem on Soil Microbial Community

Rubber agroforestry systems positively impact soil microbial communities. This study employed a bibliometric approach to explore the research status, hotspots, and development trends related to these effects. Using CiteSpace software, we visually analyzed research literature from the Web of Science (WOS) core database, spanning 2004 to 2024. The focus was on the impact of rubber agroforestry ecosystems on soil microbial communities. The results indicate significant attention from Chinese researchers, who have published numerous influential papers in this field. Authors Liu Wenjie have contributed the most papers, although no stable core author group exists. The Chinese Academy of Sciences is the leading research institution in terms of publication volume. While there is close collaboration between different institutions and countries, the intensity of researcher cooperation is low. The most cited literature emphasizes soil nutrients and structure in rubber agroforestry, laying a foundation for soil microorganism studies. Most cited journals are from countries like Netherlands and the United Kingdom. Key research areas include the effects of rubber intercropping on soil microbial communities, agroforestry management, and soil health. Research development can be divided into three stages: the initial stage (2010-2015), the development stage (2015-2020), and the mature stage (2020-2024). Current studies show that rubber intercropping and rubber-based agroforestry systems enhance soil microbial communities, positively impacting soil health. This paper provides a theoretical basis for the sustainable development of rubber agroforestry systems and improved management plans. Future research could explore the effects of species composition on soil microbiological characteristics and develop methods for species interactions. An in-depth study of the soil microbial community’s structure and function, and its relationship with rubber trees, is crucial. Developing effective, rationally designed rubber agroforestry systems and underground soil microbiome technology will promote sustainability and improve plantation productivity.

Physical and Chemical Characterizations of Rubber Latex Cup Bottom Oil

Rubber latex is an important economic resource. However, the residues from its harvesting are thrown away, even though they contain lipids that can be recycled. This recovery of the residues from the bottom of the cup requires first and foremost their characterization. The aim of this study is therefore to determine the main physical and chemical characteristics of rubber latex cup bottom oil. Oil’s physical parameters determination shows that it has a density of 951 kg∙m−3, a kinematic viscosity of 48.57 cSt and a water content of 0.0845%. Chemical parameters, meanwhile, indicate that this cup bottom residue has a fat content of 95.96%, an acid number of 2.805 mg KOH/g and an iodine number of 92.42 g I2/100g. Therefore, rubber latex cup bottom oil can be used in the formulation of biofuels, biolubricants, paints, varnishes, alkyd resins, polishing oils, soaps, and insecticides.

Effect of graphene oxide with different oxidation degrees on mechanical properties of styrene-butadiene rubber: Experiment and molecular simulation

Graphene oxide(GO)has proven to be an effective reinfor-cing filler for rubber[1].GO has superior mechanical properties,barrier properties,large specific surface area and abundant oxygen-containing functional groups[2].However,the change in the oxidation degree of GO has a great effect on its chemical properties,the interaction between GO and the matrix,and the dispersion uniformity in the rubber matrix,which has a great effect on the reinforcement of rubber[3].

Transient NOE driven signal enhancement of INADEQUATE solid-state NMR spectroscopy for the structural analysis of rubbers

INADEQUATE(Incredible Natural Abundance DoublE QUAntum Transfer Experiment)is one of the most important techniques in revealing the carbon skeleton of organic solids in solid-state NMR spectroscopy.Nevertheless,its use for structural analysis is quite limited due to the low natural abundance of^(13)C-^(13)C connectivity(~0.01%)and thus low sensitivity.Particularly,in semi-solids like rubbers,the sensitivity will be further significantly reduced by the inefficient cross polarization from 1H to^(13)C due to molecular motions induced averaging of^(1)H-^(13)C dipolar couplings.Herein,in this study,we demonstrate that transient nuclear Overhauser effect(NOE)can be used to efficiently enhance^(13)C signals,and thus enable rapid acquisition of two-dimensional(2D)^(13)C INADEQUATE spectra of rubbers.Using chlorobutyl rubber as the model system,it is found that an overall signalto-noise ratio(SNR)enhancement about 22%can be achieved,leading to significant timesaving by about 33%as compared to the direct polarization-based INADEQUATE experiment.Further experimental results on natural rubber and ethylene propylene diene monomer(EPDM)rubber are also shown to demonstrate the robust performance of transient NOE enhanced INADEQUATE experiment.

Seismic evaluation of frequency influence and resonant behavior for lead rubber bearing isolated rigid rectangular liquid tanks

The seismic behavior of a partially filled rigid rectangular liquid tank is investigated under short-and longduration ground motions.A finite element model is developed to analyze the liquid domain by using four-noded quadrilateral elements.The competency of the model is verified with the available results.Parametric studies are conducted for the dynamic parameters of the base-isolated tank,using a lead rubber bearing to evaluate the optimum damping and time period of the isolator.The application of base isolation has reduced the total and impulsive hydrodynamic components of pressure by 80 to 90 percent,and base shear by 15 to 95 percent,depending upon the frequency content and duration of the considered earthquakes.The sloshing amplitude of the base-isolated tank is reduced by 18 to 94 percent for most of the short-duration earthquakes,while it is increased by 17 to 60 percent for the majority of the long-duration earthquakes.Furthermore,resonance studies are carried out through a long-duration harmonic excitation to obtain the dynamic behavior of non-isolated and isolated tanks,using a nonlinear sloshing model.The seismic responses of the base-isolated tank are obtained as higher when the excitation frequency matches the fundamental sloshing frequency rather than the isolator frequency.

Mechanical behavior of nanorubber reinforced epoxy over a wide strain rate loading

Nanorubber/epoxy composites containing 0,2,6 and 10 wt%nanorubber are subjected to uniaxial compression over a wide range of strain rate from 8×10^(-4) s^(-1) to~2×10^(4) s^(-1).Unexpectedly,their strain rate sensitivity and strain hardening index increase with increasing nanorubber content.Potential mechanisms are proposed based on numerical simulations using a unit cell model.An increase in the strain rate sensitivity with increasing nanorubber content results from the fact that the nanorubber becomes less incompressible at high strain,generating a higher hydro-static pressure.Adiabatic shear localization starts to occur in the epoxy under a strain rate of 22,000 s^(-1) when the strain exceeds 0.35.The presence of nanorubber in the epoxy reduces adiabatic shear localization by preventing it from propagating.

Hand Cooling Enhances the Proprioceptive Drift during Rubber Hand Illusion

Background: The neural representation of the body is easily altered by integrating multiple sensory signals in the brain. The “Rubber Hand Illusion” (RHI) is one of the most popular experimental paradigms to investigate this phenomenon. During this illusion, ownership of a rubber hand is temporarily induced. It was shown that external and continuous cooling of the palm enhanced the RHI, suggesting an association between altered the autonomic nervous system regulation and altered the sense of ownership of a specific limb. Purpose: To investigate whether artificially cooling the entire hand for a short period affects the magnitude of the illusion. Methods: Participants immersed their entire hand in cool, cold, or warm water for 1 min before the RHI procedure. Results: We found that cooling the entire hand enhanced the proprioceptive drift during the RHI but not the subjective feeling of ownership. In contrast, warming and intense cooling of the entire hand did not affect the RHI strength. Conclusion: Our results suggest that transient and moderate cooling of the entire hand was sufficient in enhancing the illusory disembodiment of one’s own hand.

Comparison of nonlinear modeling methods for the composite rubber clamp

The cubic stiffness force model(CSFM)and Bouc-Wen model(BWM)are introduced and compared innovatively.The unknown coefficients of the nonlinear models are identified by the genetic algorithm combined with experiments.By fitting the identified nonlinear coefficients under different excitation amplitudes,the nonlinear vibration responses of the system are predicted.The results show that the accuracy of the BWM is higher than that of the CSFM,especially in the non-resonant region.However,the optimization time of the BWM is longer than that of the CSFM.

Multi-omics-driven development of alternative crops for natural rubber production

Natural rubber(NR)is an irreplaceable biopolymer of economic and strategic importance owing to its unique physical and chemical properties.The Parárubber tree(Hevea brasiliensis(Willd.ex A.Juss.)Müll.Arg.)is currently the exclusive commercial source of NR,and it is primarily grown in plantations restricted to the tropical and subtropical areas of Southeast Asia.However,current Parárubber production barely meets the sharply increasing global industrial demand for rubber.Petroleum-based synthetic rubber(SR)has been used to supplement the shortage of NR but its industrial performance is not comparable to that of NR.Thus,there is an urgent need to develop new productive rubber crops with broader environmental adaptability.This review summarizes the current research progress on alternative rubberproducing plants,including horticultural plants(Taraxacum kok-saghyz Rodin and Lactuca L.species),woody plants(Parthenium argentatum A.Gray and Eucommia ulmoides Oliv.),and other plant species with potential for NR production.With an emphasis on the molecular basis of NR biosynthesis revealed by a multi-omics approach,we highlight new integrative strategies and biotechnologies for exploring the mechanism of NR biosynthesis with a broader scope,which may accelerate the breeding and improvement of new rubber crops.

The legacy effects of rubber defoliation period on the refoliation phenology,leaf disease,and latex yield

The leaf phenology of trees has received particular attention for its crucial role in the global water and carbon balances,ecosystem,and species distribution.However,current studies on leaf phenology have mainly focused on temperate trees,while few studies including tropical trees.Little attention has been paid to globally extensive industrial plantations.Rubber plantations are important to both the local and global economies.In this study,we investigated the legacy effects of defoliation phenology on the following year’s leaf flushing,leaf disease,and also latex yield of rubber trees,an economically important tree to local people and the world.Results show that extended duration of defoliation increased the subsequent duration of refoliation and rates of infection by powdery mildew disease,but led to reduced latex yield in March.This legacy effect of rubber defoliation may relate to the carbohydrate reserved in the trees.A longer duration of defoliation would consume more reserved carbohydrates,reducing available reserves for disease defense and latex production.Extended duration of defoliation period was associated with either a lower temperature before the cessation of latex tapping in October-November and/or a higher temperature after the cessation of latex tapping in December-January.Leaf falling signals the end of photosynthetic activities in deciduous trees.Thus,the leaf falling phenology will impact ecological processes involving rubber trees.Our findings indicated that the inclusion of defoliation periods in future rubber trees’ research,will be crucial to furthering our understanding of leaf flushing,powdery mildew disease,and latex yield.

Dispersion characteristics of clayey soils containing waste rubber particles

The rubber-containing waste materials have been widely used to improve the engineering properties of soils in recent years.Among others,granular rubbers are utilized in various ways to increase the bearing capacity and shear strength and to reduce the settlement and liquefaction potential of soils.The granular rubbers have many advantages such as temperature resistance,flexibility,tear-resistance,non-slip,and thermal and electrical insulation.This study presents the distribution characteristics of five different types of clayey soils with different engineering properties containing waste rubber particles(WRPs).On the other hand,determining and controlling the dispersion characteristics of clayey soils is two significant engineering problems.The study aims to solve these two remarkable and problematic issues in an eco-friendly and safe way.The role of WRP treatment in the investigation of soil dispersion behavior,which can cause dangerous problems such as piping,erosion,and dispersion,reflects the original and different perspectives of this study.Within this scope,geotechnical parameters of the clayey soils were determined.Subsequently,pinhole test,crumb test,double hydrometer test,and scanning electron microscopy(SEM)analysis were performed on the Na-activated bentonite,refined ball clay,Ukrainian kaolin,Avanos kaolin,and Afyon clay samples with different percentages of WRPs(0%,5%,10%,and 15%).Consequently,Avanos and Ukrainian kaolin clays gave the most limited response to the dispersion behavior with the addition of WRP.Also,WRP treatment on the ball clay and bentonite samples showed limited efficiency.Afyon clay,which was defined as dispersive by the three tests that determined its dispersion potential,showed 3 level changes in the pinhole tests and 2 level changes in the crumb tests,and gave the most effective results in terms of WRP efficiency.

Influence of Rubber Powder Movement on Properties of Asphalt Rubber from the Mesoscopic View

The research on asphalt performance mainly focused on the macro performance and micro mechanism.Mesoscopic analysis was introduced to study the effect of rubber powder movement on asphalt rubber properties.After the preparation parameters and the preparation process of asphalt rubber were determined,the modification mechanism and rheological properties were analyzed which revealed the compatible stability mechanism.Then,the analysis model of asphalt rubber was established to focus on simulating the effect of rubber powder and the spatial movement on its mechanical properties.The experimental results show that rubber powder can make the asphalt rubber bear more uniform stress distribution and enhance the ability to resist deformation.Meanwhile,the rotational motion and final distribution of rubber powder have an obvious impact on the mechanical properties of asphalt rubber.In the selected feature points,the average stress of rubber powder at 0°space angle is only 34.1%of that at90°space angle.When the rubber powders are all in parallel in the ideal state,it enhances the mechanical properties the most.This study supplements the“mesoscopic”scale between macro and micro research.The relationship between micro mechanism and macro properties of asphalt rubber will be established from the mesoscopic perspective.It is also an effort to realize the effective correlation from micro,mesoscopic to macro in asphalt.

Workability and Durability of Concrete Incorporating Waste Tire Rubber:A Review

Environmental problems caused by waste tires are becoming increasingly prominent.There is an urgent need to find a green way to dispose of waste tires,and scholars have made considerable efforts in this regard.In the construction industry,rubber extracted from waste tires can be added to concrete to alleviate environmental problems to a certain extent.As a new building material,rubber concrete has superior properties compared to ordinary concrete and has been widely used in many fields.Numerous studies have been conducted worldwide to investigate the effect of waste tire rubber on the performance of concrete.It has been reported that the addition of waste tire rubber has a significant influence on the performance of concrete.Workability influences the hardened performance of rubber concrete,especially the durability.Based on the current research results,the workability and durability of concrete manufactured with waste tire rubber,including water absorption and permeability,carbonation resistance,chloride ion permeability resistance,and freeze-thaw resistance,are summarized in this paper.It is concluded that the addition of waste tires has a negative effect on the workability of concrete.In terms of durability,concrete exhibits better chloride ion penetration resistance and frost resistance,with a higher water absorption rate,and lower anti-permeability and carbonation resistance owing to the addition of waste tire rubber.

Rheological and Morphological Characterization of Modified Bitumen with Cup Lump Rubber

Pure bitumen is not suitable for heavy traffic loads;hence modifiers are used to improve the bitumen performance.Recently,cup lump rubber(CLR)has become a preferred modifier due to its outstanding performance and less cost.However,little is known about the interactions between CLR and bitumen.Thus,this study investigates the behavior of bitumen with CLR.Four percentages of CLR(2.5%,5.0%,7.5%,and 10.0%by weight of bitumen)were used to modify conventional 60/70 penetration grade bitumen.The modified bitumen was evaluated through different laboratory testing such as dynamic shear rheometer,rotational viscosity,softening point,bending beam rheometer,ductility,and elastic recovery.The testing results show that the addition of CLR increased the bitumen’s rutting resistance by 3 PG grades at high temperatures.At low pavement temperatures,the cup lump rubber modified bitumen(CMB)can withstand up to−34℃.Fourier Transform Infrared(FTIR)analysis shows that the Aromaticity index at 1600 cm^(−1) rose as the CLR percentage increased,indicating the formation of a binder with a compact structure.This is expected to improve the elasticity of bitumen throughπ-πinteractions.Atomic Force Microscopy(AFM)results showed the Catana phase increased in size and quantity at 5.0%and 7.5%CLR content.While contact angle measurement revealed that the binders are hydrophobic and tend to repel the dropped water on the bitumen surface.

Mechanical Test and Meso-Model Numerical Study of Composite Rubber Concrete under Salt-Freezing Cycle

A composite rubber concrete(CRC)was designed by combining waste tire rubber particles with particle sizes of 3~5 mm,1~3 mm and 20 mesh.Taking the rubber content of different particle sizes as the influencing factors,the range and variance analysis of the mechanical and impermeability properties of CRC was carried out by orthogonal test.Through analysis,it is concluded that the optimal proportion of 3~5 mm,1~3 mm,and 20 mesh particle size composite rubber is 1:2.5:5.5 kinds of CRC and 3 kinds of ordinary single-mixed rubber concrete(RC)with a total content of 10%~20%were designed under this ratio,and the salt-freezing cycle test was carried out with a concentration of 5%Na 2 SO4 solution.The physical and mechanical damage laws during 120 salt-freezing cycles are obtained,and the corresponding damage prediction model is established according to the experimental data.The results show that:on the one hand,the composite rubber in CRC produces a more uniform“graded”structure,forms a retractable particle group,and reduces the loss of mechanical properties of CRC.On the other hand,colloidal particles with different particle sizes are used as air entraining agent to improve the pore structure of concrete and introduce evenly dispersed bubbles,which fundamentally improves the durability of concrete.Under the experimental conditions,the CRC performance is the best when the overall content of composite rubber is 15%.

Exploration and Practice of Rubber Based Agroforestry Complex Systems in China

Agroforestry ecosystems are constructed by simulating natural ecosystems, applying the principles of symbiosis in nature, and organizing multiple plant populations to coexist, while conducting targeted cultivation and structural control scientifically. Rubber agroforestry complex ecosystems aim for sustainable development in terms of industry, ecology, resource utilization, and the livelihoods of producers. Rubber agroforestry complex ecosystems create a complex production structure system that integrates biology, society, and the economy through species combinations. Rubber trees and associated biological components coordinate with each other, mutually promote growth, and yield a variety of products for producers. Cultivation techniques and patterns of rubber agroforestry are essential components of these ecosystems. This study analyzes the production practices of rubber agroforestry complex cultivation, with a focus on the development and characteristics (complexity, systematicity, intensity, and hierarchy) of rubber agroforestry systems using a literature analysis and a survey approach. It explores the types and scales of complex planting, specifications and forms, and major effects of complex cultivation. This study identifies successful rubber agroforestry cultivation patterns and practical techniques, as well as the potential benefits of developing rubber agroforestry cultivation. It also points out the shortcomings in the development of complex planting, including an emphasis on production practices but insufficient theoretical research, a focus on production but inadequate attention to the market, and an emphasis on yield while overlooking the improvement of standards, brands, and added value. There are various complex patterns for young rubber plantations, but relatively fewer for mature plantations. Based on this analysis, this study suggests that future efforts should focus on in-depth research on interspecies and environmental interactions in rubber agroforestry ecosystems, clearly define key roles, accelerate the innovation of development patterns, and strengthen the foundation for development. It recommends promoting and demonstrating successful rubber agroforestry complex patterns and providing technical training, developing product branding for rubber agroforestry patterns, enhancing product value, expanding the application functions of rubber-forest mixed crop products, and establishing a stable and sustainable industry chain. This study provide practical experience and theoretical insights in rubber agroforestry complex systems from China the potential to enrich the knowledge of rubber agroforestry composite systems, provide practical experience to improve the operating income of smallholders, and even promote the sustainable development of rubber plantations.

Mechanical Properties of Self-Compacting Rubberized Concrete with Different Rubber Types under Triaxial Compression

Different rubber aggregates lead to changes in the effect of stress conditions on the mechanical behavior of concrete,and studies on the triaxial properties of self-compacting rubber concrete(SCRC)are rare.In this study,35 cylindrical specimens taking lateral stress and rubber type as variables were prepared to study the fresh properties and mechanical behaviors of SCRC under triaxial compression,where the rubber contains two types,i.e.,380μm rubber powder and 1–4 mm rubber particles,and four contents,i.e.,10%,20%and 30%.The test results demonstrated that SCRC exhibited a typical oblique shear failure mode under triaxial compression and had a more moderate descending branch compared with self-compacting concrete(SCC).The presence of lateral stress can significantly improve the compression properties,including initial elastic modulus,peak stress and peak strain,with an improvement range of 3%–73%for peak stress.While rubber aggregates mainly targeted the deformation abilities and toughness for improvement,and the peak strain improvement ranges were 0.1–3.1 times and 0.1–1.0 times for SCRC containing rubber powder and SCRC containing rubber particles,respectively,relative to SCC.At a high lateral stress of at least 12 MPa,the loss of strength due to the addition of rubber can be controlled within 10%,in which case the content of rubber powder and rubber particles was recommended to be at most 20%and 30%,respectively.Based on the Mohr-Coulomb theory,the failure criteria of SCRC with different rubber types were established.For analysis and design purposes,an empirical model was proposed to predict the stressstrain behavior under triaxial compression,considering the influence of different rubber content and lateral stress.The results obtained in this study can provide a valuable reference for the design and application of self-compacting rubberized concrete in practical projects,especially those involving three-way compression states and requiring high-quality deformation and energy dissipation.

Preparation and application of carbon nanotubes/conductive carbon black/ethylene-propylene-diene rubber composite

Addition of conductive fillers such as conductive carbon black(CCB)and carbon nanotubes(CNTs)could significantly improve the electrical conductivity of rubber.However,that would result in the deterioration of processing properties for rubber compound and the rapid increase in hardness of vulcanizates,which affected seriously the preparation of conductive rubber composites and thus limits the application in the field of flexible conductive rubber materials.