Using Isotope Technology for Surface Water Environment Research in Southern Hanoi

The surface water in the southern of Hanoi capital is researched by identifying δ2H and δ18O stable isotopes together with EC, DO, BOD5, COD, TSS. Surface water samples for studying include the Red river, Nhue river and Kim Nguu river, Thanh Nhan lake, Yen So lake and Van Quan lake were collected in the dry season (April) and the rainy season (August) in 2015. The stable isotope analysis results showed that the δ18O values is a range from -42.53‰ to -64.05‰ and, the δ2H values is the range from -5.09‰ to -8.79‰ under global meteoric waterline (in the water vapor region). The δ2H results of the rivers and lakes in the dry season are more negative than the rainy season with a small difference. The δ18O results of lakes in the dry season are more negative than the rainy season, but the δ18O results of river in the dry season are more positive than the rainy season. The results of the EC, BOD, COD, DO, TSS analysis showed that surface water environment has changed clearly in the two seasons and the contamination level in the dry season is usually higher than the rainy season. The lakes and rivers strongly influenced by human activities led to seriously pollution are Van Quan lake and Yen So lake, Nhue river and Kim Nguu river.

Isotope implications of groundwater recharge,residence time and hydrogeochemical evolution of the Longdong Loess Basin,Northwest China

Groundwater plays a dominant role in the eco-environmental protection of arid and semi-arid regions.Understanding the sources and mechanisms of groundwater recharge,the interactions between groundwater and surface water and the hydrogeochemical evolution and transport processes of groundwater in the Longdong Loess Basin,Northwest China,is of importance for water resources management in this ecologically sensitive area.In this study,71 groundwater samples(mainly distributed at the Dongzhi Tableland and along the Malian River)and 8 surface water samples from the Malian River were collected,and analysis of the aquifer system and hydrological conditions,together with hydrogeochemical and isotopic techniques were used to investigate groundwater sources,residence time and their associated recharge processes.Results show that the middle and lower reaches of the Malian River receive water mainly from groundwater discharge on both sides of valley,while the source of the Malian River mainly comes from local precipitation.Groundwater of the Dongzhi Tableland is of a HCO3-Ca-Na type with low salinity.The reverse hydrogeochemical simulation suggests that the dissolution of carbonate minerals and cation exchange between Ca^(2+),Mg^(2+)and Na+are the main water-rock interactions in the groundwater system of the Dongzhi Tableland.Theδ^(18)O(from-11.70‰to-8.52‰)andδ2H(from-86.15‰to-65.75‰)values of groundwater are lower than the annual weighted average value of precipitation but closer to summer-autumn precipitation and soil water in the unsaturated zone,suggesting that possible recharge comes from the summer-autumn monsoonal heavy precipitation in the recent past(≤220 a).The corrected 14C ages of groundwater range from 3,000 to 25,000 a old,indicating that groundwater was mainly from precipitation during the humid and cold Late Pleistocene and Holocene periods.Groundwater flows deeper from the groundwater table and from the center to the east,south and west of the Dongzhi Tableland with estimated migration rate of 1.29-1.43 m/a.The oldest groundwater in the Quaternary Loess Aquifer in the Dongzhi Tableland is approximately 32,000 a old with poor renewability.Based on theδ^(18)O temperature indicator of groundwater,we speculate that temperature of the Last Glacial Maximum in the Longdong Loess Basin was 2.4℃-6.0℃ colder than the present.The results could provide us the valuable information on groundwater recharge and evolution under thick loess layer,which would be significative for the scientific water resources management in semi-arid regions.

Effects of long-term nitrogen addition on theδ^(15)N andδ^(13)C of Larix gmelinii and soil in a boreal forest

Background:Natural abundance of carbon(C)and nitrogen(N)stable isotope ratios(δ^(13)C andδ^(15)N)has been used to indicate the state and cycle of ecosystem C and N.However,it is still unclear how C and N cycle of boreal forests respond to the N deposition.Results:We conducted an 8-year continuous N addition field experiment in a Larix gmelinii forest in Greater Khingan Mountains,Northeast China.Four N treatments(0,25,50,75 kg N ha^(−1)year^(−1))were built.The effects of N addition on theδ^(13)C andδ^(15)N of needle,branch,bark,and fine root of Larix gmelinii and soil were studied.The result of the balance between the N input and output flux showed that N addition significantly increased theδ^(15)N in each organ of Larix gmelinii,but did not change theδ^(15)N of soil.We also found that the N absorption by needles of Larix gmelinii could increase the needle photosynthesis rate andδ^(13)C by increasing carboxylation,but N addition had no significant effect on theδ^(13)C of soil and other organs.In addition,both the soilδ^(15)N andδ^(13)C increased with the soil depth.Conclusions:Long-term N addition may lead to more open C and N cycles and further affect plant nutrient acquisition strategies in boreal forest ecosystems.