A block copolymer consisting of polyfluorene (PF) and polytriarylamine (PTAA) functionalized with green emitting phenoxazine moiety at the junction point of two blocks was designed and prepared for electroluminescent ...A block copolymer consisting of polyfluorene (PF) and polytriarylamine (PTAA) functionalized with green emitting phenoxazine moiety at the junction point of two blocks was designed and prepared for electroluminescent application. PF homopolymer was synthesized by Suzuki coupling polymerization, and was reacted with brominated phenoxazine. In the presence of the resulting PF functionalized with phenoxazine, C-N coupling polymerization of 4-(4’-bromophenyl)-4’’-butyldiphenylamine was carried out to afford a triblock copolymer, PTAA-phenoxazine-PF-phenoxazine-PTAA (PF-Ph-PTAA). Two types of random copolymers were also synthesized with fluorene and phenoxazine (PF2) by Suzuki coupling polymerization for comparison. All the polymers were soluble in common organic solvents and readily formed thin films by a solution processing. Prepared polymers exhibited similar UV absorption and PL emission in chloroform solutions. In a film state, the existence of phenoxazine unit drastically changed PL spectra. Although the content of phenoxazine unit in PF-Ph-PTAA was relatively high (13 mol%), it showed similar PL spectrum to that of PF2(phenoxazine content, 0.2 mol%) indicating that phenoxazine unit is isolated in single polymer chain nevertheless the high content. EL device based on PF-Ph-PTAA showed green-emission, suggesting that emission sites predominantly located in the vicinity of phenoxazine moiety because of its shallow HOMO level.展开更多
It is well known that temperature acts negatively on practically all the parameters of photovoltaic solar cells. Also, the solar cells which are subjected to particularly very high temperatures are the light concentra...It is well known that temperature acts negatively on practically all the parameters of photovoltaic solar cells. Also, the solar cells which are subjected to particularly very high temperatures are the light concentration solar cells and are used in light concentration photovoltaic systems (<i><span style="font-family:Verdana;">CPV</span></i><span style="font-family:Verdana;">). In fact, the significant heating of these solar cells is due to the concentration of the solar flux which arrives on them. Light concentration solar cells appear as solar cells under strong influences of heating and temperature. It is therefore necessary to take into account temperature effect on light concentration solar cells performances in order to obtain realistic results. </span><span style="font-family:""><span style="font-family:Verdana;">This one-dimensional study of a crystalline silicon solar cell under light concentration takes into account electrons concentration gradient electric field in the determination of the continuity equation of minority carriers in the base. To determine excess minority carrier’s density, the effects of temperature on the diffusion and mobility of electrons and holes, on the intrinsic concentration of electrons, on carrier’s generation rate as well as on width of band gap have also been taken into account. The results show that an increase of temperature improves diffusion parameters and leads to an increase of the short-circuit photocurrent density. However, an increase of temperature leads to a significant decrease in open-circuit photovoltage, maximum electric power and conversion efficiency. The results also show that the operating point and the maximum power point (</span><i><span style="font-family:Verdana;">MPP</span></i><span style="font-family:Verdana;">) moves to the open circuit when the cell temperature increases.</span></span>展开更多
Preliminary results of a study are reported here investigating mesoscopic tunnel junctions irradiated with coherent low-intensity (-50 to -10 dB) pulsed microwave RF fields at moderately low (LN2) temperatures. Quantu...Preliminary results of a study are reported here investigating mesoscopic tunnel junctions irradiated with coherent low-intensity (-50 to -10 dB) pulsed microwave RF fields at moderately low (LN2) temperatures. Quantum tunneling of electrons was observed through fabricated mesoscale gap junctions as a result of coherent irradiating fields at low temperatures around 77 - 100 K. The tunneling current was seen as a result of applied microwave fields across the junctions, distinguishable from shot noise and resistance effects. The form of tunneling behavior does not lead to any conductance quantization effects which could manifest the junction as a Quantum Point Contact (QPC), hence it is surmised that the phenomenon is purely low intensity RF field-induced tunneling of electrons across the mesoscale junctions at low temperatures.展开更多
For discrimination of the common W-junction and Y-junction in the labels of line drawing for a three-dimensional manifold plane surface with trihedral vertices, the existing algorithms are almost using angles between ...For discrimination of the common W-junction and Y-junction in the labels of line drawing for a three-dimensional manifold plane surface with trihedral vertices, the existing algorithms are almost using angles between two adjacent lines and W-junction and Y- junction＇s definitions, and other complex methods. This passage gives four methods with their detailed mathematical inference processes in order to use these algorithms implemented by computer. The algorithms listed are Angle Summation method and Points to the Line method, Triangle methods which are the Triangle Area method and the Cross method. When the computer programs discriminate junctions, by comparison, the Angle Summation method and Points to the Line method are less efficacious than the Triangle method, and Cross method is more efficacious than the Triangle Area method in the Triangle method.展开更多
Results of experimental investigation of detection (rectification) of high power X-band microwave signal in diodes of various design (semiconductor p-n-junction, point-contact, Schottky, Metal-Isolator-Metal—MIM) are...Results of experimental investigation of detection (rectification) of high power X-band microwave signal in diodes of various design (semiconductor p-n-junction, point-contact, Schottky, Metal-Isolator-Metal—MIM) are reported. The maximum of the detected direct voltage V vs. power P of microwave signal and subsequent polarity reversal, previously found in MIM diodes in the optical and microwave bands, have found to be characteristic of all investigated diodes as well. After the reversal of polarity, this dependence comes linear, and the sign of the voltage corresponds to thermoEMF. In some diodes, the hysteresis on V(P) was observed. All 5 types of V(P) of MIM diodes (have made from different pairs of metals), reported earlier, were reproduced on same p-n-junction diode by variable external DC bias. These results joined with abnormal frequency cutoff forced to suggest that there is an unknown mechanism for direct flow of charge carriers (and for generate direct current) in the high-frequency electrical field, which differs from the conventional rectification.展开更多
利用汊点水位预测-校正(junction-point water stage prediction and correction,JPWSPC)法处理缓流河网汊点处的回流效应,采用Preissmann格式离散Saint-Venant方程组,并采用Newton-Raphson方法求解非线性离散方程,构建了非恒定河网水...利用汊点水位预测-校正(junction-point water stage prediction and correction,JPWSPC)法处理缓流河网汊点处的回流效应,采用Preissmann格式离散Saint-Venant方程组,并采用Newton-Raphson方法求解非线性离散方程,构建了非恒定河网水动力模型。模型既无需特殊的河道编码,又避免了建立和求解总体矩阵。与常用的分级解法模型相比,保留了其既适用于树状又适用于环状河网的优点,同时克服了分级解法需要建立和求解河网总体矩阵的缺点,显著提高了稳定性和计算效率。展开更多
比较了汊点水位预测-校正法(junction-point water stage prediction and correction,JPWSPC)和经典的分级解法,在处理缓流河网汊点处回流效应时的不同,并对比了它们的计算效率。应用这2类方法时,Saint-Venant方程组都采用Preissmann格...比较了汊点水位预测-校正法(junction-point water stage prediction and correction,JPWSPC)和经典的分级解法,在处理缓流河网汊点处回流效应时的不同,并对比了它们的计算效率。应用这2类方法时,Saint-Venant方程组都采用Preissmann格式离散,生成的非线性离散方程用Newton-Raphson方法求解。比较表明:这2类方法都能处理普适河网,JPWSPC法无需求解整体连接矩阵,同时不会增加每一时间步的迭代次数,因而节约了系统内存,提高了计算效率;河网中河段数目越多,JPWSPC法的效率优势越明显。展开更多
目的探讨缝隙连接开放剂抗心律失常肽(AAP10)对低钾、低镁条件下伊布利特致尖端扭转性室性心动过速(TdP)及心肌电不稳定性的影响。方法 54只日本长耳大白兔随机制备成左室楔形心肌块模型,随机分为对照组、低钾低镁组、伊布利特组、低钾...目的探讨缝隙连接开放剂抗心律失常肽(AAP10)对低钾、低镁条件下伊布利特致尖端扭转性室性心动过速(TdP)及心肌电不稳定性的影响。方法 54只日本长耳大白兔随机制备成左室楔形心肌块模型,随机分为对照组、低钾低镁组、伊布利特组、低钾低镁伊布利特组和AAP10干预组。对照组灌流正常台氏液,低钾低镁组灌流低钾低镁台氏液,伊布利特组灌流浓度2mg/l的伊布利特,低钾低镁伊布利特组灌流溶有同浓度伊布利特的低钾低镁台氏液,AAP10组给予AAP10干预的条件后灌流溶有伊布利特的低钾低镁台氏液。比较各组早期后除极(EAD)、R on T室性早搏和TdP的发生情况,以及QT间期、T波顶点到终点距离(Tp-e)和Tp-e/QT的变化。结果与对照组比较,低钾低镁伊布利特组QT间期、Tp-e和Tp-e/QT延长,EAD、R on T室性早搏、TdP的发生率明显增多。AAP10干预组,TdP、QT间期、Tp-e和Tp-e/QT比低钾、低镁伊布利特组显著减少。结论 AAP10可能通过开放缝隙连接减少跨壁复极离散度,从而起到预防伊布利特在低钾、低镁条件下的致TdP的作用。展开更多
文摘A block copolymer consisting of polyfluorene (PF) and polytriarylamine (PTAA) functionalized with green emitting phenoxazine moiety at the junction point of two blocks was designed and prepared for electroluminescent application. PF homopolymer was synthesized by Suzuki coupling polymerization, and was reacted with brominated phenoxazine. In the presence of the resulting PF functionalized with phenoxazine, C-N coupling polymerization of 4-(4’-bromophenyl)-4’’-butyldiphenylamine was carried out to afford a triblock copolymer, PTAA-phenoxazine-PF-phenoxazine-PTAA (PF-Ph-PTAA). Two types of random copolymers were also synthesized with fluorene and phenoxazine (PF2) by Suzuki coupling polymerization for comparison. All the polymers were soluble in common organic solvents and readily formed thin films by a solution processing. Prepared polymers exhibited similar UV absorption and PL emission in chloroform solutions. In a film state, the existence of phenoxazine unit drastically changed PL spectra. Although the content of phenoxazine unit in PF-Ph-PTAA was relatively high (13 mol%), it showed similar PL spectrum to that of PF2(phenoxazine content, 0.2 mol%) indicating that phenoxazine unit is isolated in single polymer chain nevertheless the high content. EL device based on PF-Ph-PTAA showed green-emission, suggesting that emission sites predominantly located in the vicinity of phenoxazine moiety because of its shallow HOMO level.
文摘It is well known that temperature acts negatively on practically all the parameters of photovoltaic solar cells. Also, the solar cells which are subjected to particularly very high temperatures are the light concentration solar cells and are used in light concentration photovoltaic systems (<i><span style="font-family:Verdana;">CPV</span></i><span style="font-family:Verdana;">). In fact, the significant heating of these solar cells is due to the concentration of the solar flux which arrives on them. Light concentration solar cells appear as solar cells under strong influences of heating and temperature. It is therefore necessary to take into account temperature effect on light concentration solar cells performances in order to obtain realistic results. </span><span style="font-family:""><span style="font-family:Verdana;">This one-dimensional study of a crystalline silicon solar cell under light concentration takes into account electrons concentration gradient electric field in the determination of the continuity equation of minority carriers in the base. To determine excess minority carrier’s density, the effects of temperature on the diffusion and mobility of electrons and holes, on the intrinsic concentration of electrons, on carrier’s generation rate as well as on width of band gap have also been taken into account. The results show that an increase of temperature improves diffusion parameters and leads to an increase of the short-circuit photocurrent density. However, an increase of temperature leads to a significant decrease in open-circuit photovoltage, maximum electric power and conversion efficiency. The results also show that the operating point and the maximum power point (</span><i><span style="font-family:Verdana;">MPP</span></i><span style="font-family:Verdana;">) moves to the open circuit when the cell temperature increases.</span></span>
文摘Preliminary results of a study are reported here investigating mesoscopic tunnel junctions irradiated with coherent low-intensity (-50 to -10 dB) pulsed microwave RF fields at moderately low (LN2) temperatures. Quantum tunneling of electrons was observed through fabricated mesoscale gap junctions as a result of coherent irradiating fields at low temperatures around 77 - 100 K. The tunneling current was seen as a result of applied microwave fields across the junctions, distinguishable from shot noise and resistance effects. The form of tunneling behavior does not lead to any conductance quantization effects which could manifest the junction as a Quantum Point Contact (QPC), hence it is surmised that the phenomenon is purely low intensity RF field-induced tunneling of electrons across the mesoscale junctions at low temperatures.
文摘For discrimination of the common W-junction and Y-junction in the labels of line drawing for a three-dimensional manifold plane surface with trihedral vertices, the existing algorithms are almost using angles between two adjacent lines and W-junction and Y- junction＇s definitions, and other complex methods. This passage gives four methods with their detailed mathematical inference processes in order to use these algorithms implemented by computer. The algorithms listed are Angle Summation method and Points to the Line method, Triangle methods which are the Triangle Area method and the Cross method. When the computer programs discriminate junctions, by comparison, the Angle Summation method and Points to the Line method are less efficacious than the Triangle method, and Cross method is more efficacious than the Triangle Area method in the Triangle method.
文摘Results of experimental investigation of detection (rectification) of high power X-band microwave signal in diodes of various design (semiconductor p-n-junction, point-contact, Schottky, Metal-Isolator-Metal—MIM) are reported. The maximum of the detected direct voltage V vs. power P of microwave signal and subsequent polarity reversal, previously found in MIM diodes in the optical and microwave bands, have found to be characteristic of all investigated diodes as well. After the reversal of polarity, this dependence comes linear, and the sign of the voltage corresponds to thermoEMF. In some diodes, the hysteresis on V(P) was observed. All 5 types of V(P) of MIM diodes (have made from different pairs of metals), reported earlier, were reproduced on same p-n-junction diode by variable external DC bias. These results joined with abnormal frequency cutoff forced to suggest that there is an unknown mechanism for direct flow of charge carriers (and for generate direct current) in the high-frequency electrical field, which differs from the conventional rectification.
文摘利用汊点水位预测-校正(junction-point water stage prediction and correction,JPWSPC)法处理缓流河网汊点处的回流效应,采用Preissmann格式离散Saint-Venant方程组,并采用Newton-Raphson方法求解非线性离散方程,构建了非恒定河网水动力模型。模型既无需特殊的河道编码,又避免了建立和求解总体矩阵。与常用的分级解法模型相比,保留了其既适用于树状又适用于环状河网的优点,同时克服了分级解法需要建立和求解河网总体矩阵的缺点,显著提高了稳定性和计算效率。
文摘比较了汊点水位预测-校正法(junction-point water stage prediction and correction,JPWSPC)和经典的分级解法,在处理缓流河网汊点处回流效应时的不同,并对比了它们的计算效率。应用这2类方法时,Saint-Venant方程组都采用Preissmann格式离散,生成的非线性离散方程用Newton-Raphson方法求解。比较表明:这2类方法都能处理普适河网,JPWSPC法无需求解整体连接矩阵,同时不会增加每一时间步的迭代次数,因而节约了系统内存,提高了计算效率;河网中河段数目越多,JPWSPC法的效率优势越明显。
文摘目的探讨缝隙连接开放剂抗心律失常肽(AAP10)对低钾、低镁条件下伊布利特致尖端扭转性室性心动过速(TdP)及心肌电不稳定性的影响。方法 54只日本长耳大白兔随机制备成左室楔形心肌块模型,随机分为对照组、低钾低镁组、伊布利特组、低钾低镁伊布利特组和AAP10干预组。对照组灌流正常台氏液,低钾低镁组灌流低钾低镁台氏液,伊布利特组灌流浓度2mg/l的伊布利特,低钾低镁伊布利特组灌流溶有同浓度伊布利特的低钾低镁台氏液,AAP10组给予AAP10干预的条件后灌流溶有伊布利特的低钾低镁台氏液。比较各组早期后除极(EAD)、R on T室性早搏和TdP的发生情况,以及QT间期、T波顶点到终点距离(Tp-e)和Tp-e/QT的变化。结果与对照组比较,低钾低镁伊布利特组QT间期、Tp-e和Tp-e/QT延长,EAD、R on T室性早搏、TdP的发生率明显增多。AAP10干预组,TdP、QT间期、Tp-e和Tp-e/QT比低钾、低镁伊布利特组显著减少。结论 AAP10可能通过开放缝隙连接减少跨壁复极离散度,从而起到预防伊布利特在低钾、低镁条件下的致TdP的作用。
