Study on the characteristics and causes of carbon tetrachloride pollution of karst water in eastern suburbs of Jinan

By comparing the testing data of the hydrochemistry components and organic pollution of karst water sample in Jinan with large amount of historical data, the author finds the long-existing problem of carbon tetrachloride pollution and the great change of hydrochemical characteristics of karst water in eastern suburbs of Jinan. Since karst water is the main water-supply source in eastern suburbs of Jinan, these problems have greatly affected the safety of water supply. Based on the analysis of hydrogeological condition in eastern suburbs of Jinan, this thesis discusses the causes of carbon tetrachloride pollution and hydrochemical variation with hydrogeochemical theories so as to protect the precious karst groundwater and Jinan spring water. It is found that through research and analysis that there are mainly two causes of carbon tetrachloride pollution and hydrochemical variation: the vulnerability of karst water in this area; the other being the serious pollution in this area caused by remaining pollution sources of the last century.

Role of hydro-geochemical functions on karst critical zone hydrology for sustainability of water resources and ecology in Southwest China

Focusing on sustainability of water resources and ecology in the complex karst critical zone, we illustrated functions of the hydro-geochemical analysis on hydrology from the aspects of connection and interaction among hydrology–vegetation–soils/rock fractures along the karst subsurface profile. We reviewed isotopic and geochemical interpretations on tracing water sources for plant uptake, quantifying watershed outlet flow composition and residence times, and evaluating long-term evolution among climate–landscape–hydrology in the karst critical zone. In this paper, the application of the hydro-geochemical analysis on the above aspects in the karst areas of southwest China was summarized.

Problems for water resources development in typical small karst drainage basins and countermeasures

In karst area water deficit is one of the main factors constraining sustainable economic development. In 1979 the comprehensive karstic observational field station was set up in Houzhai drainage basin located,\ in Puding county of Guizhou Province, which can represent most of the small karst drainage basins on the dividing line of the Guizhou Plateau. Geomorphology, water resources and water chemistry were investigated and observed. Based on comparisons of water supply with water demand and analysis of the main problems in water exploitation and utilization. it is found out that the water deficiency was not directly caused by the scarcity of natural water resources. The true reason is the insufficient capacity of water supply caused by the dismatch of the water and soil water resources which can be dealt with by building more irrigation works. Some solutions such as to build scientific basis for water exploitation and utilization and sustainable economic development in karst drainage basins on dividing line of the Guizhou Plateau.

A review of water resources utilization and protection in Southwest China

Yunnan and Guizhou are two provinces in Southwest China where in recent years drought disasters have occurred due to natural and human factors. This paper reviewed literature and summarized the related achievements of water resources utilization and protection in Yunnan and Guizhou provinces. rivers, and karst ground water in the two provinces, and also This included characters and utilization of precipitation, the various explanations of drought （climate and human factors） and strategies for coping with droughts. Our concluding remarks highlight three lines of future studies： inequalities and equitable use of water distribution, better evaluation systems, and raising awareness through conservation practices.

Legislative Countermeasures for Preventing and Controlling Water Pollution in Water-deficient Regions

The shortage of water resources is severe in Beijing. The shortage of eco-environmental water and the sewage discharge over the environmental capacity are main bottlenecks that restrict the improvement of water environment. The reuse of wastewater could not only reduce the discharge of pollutants,but it could also increase the consumption of eco-environmental water. Therefore the reuse of wastewater is an important approach to improve the water environmental quality. Combined with the formulation process of Regulations of Beijing on Prevention and Control of Water Pollution,the current situations of prevention and control of water pollution in Beijing,the discharge of pollutant,water environmental quality,the population and economic development and water resources and so on were analyzed. And the bottlenecks that restricted the improvement of water environmental quality were found. And the necessity of solving the control of water pollution by reusing the wastewater and ensuring the consumption of eco-environmental water was analyzed from the perspective of the control of water pollution. And some legislative countermeasures were put forward,which provided new ideas for solving the problem of the prevention and control of water pollution and improving the water environmental quality. It was of important reference values for local governments（ especially water-deficient regions） to make relative polices or plans of water pollution control and water environmental protection.

WATER POLLUTION IN CHINA:CURRENT STATUS, FUTURE TRENDS AND COUNTERMEASURES

Based on the statistical data related to water pollution in recent years, this paper firstly describes in detail the current status of water pollution and water quality in rivers, lakes, reservoirs, groundwater and coastal waters in China, then makes a comprehensive analysis on future trends of water pollution in China. The authors hold that the economic power, technology level and management level have determinative influences on the current status and future trends of water pollution. At last, this paper discusses briefly the policies and measures for preventing and controlling water pollution in the light of the national conditions.

Instruments for Conservation and Sustainable Use of Water Resources in the Baikal Natural Area

The present paper contains the results of a review of economic instruments for water resources management in the Republic of Buryatia prepared under the OECD project “Improving the use of economic instruments for water management in the Republic of Buryatia (Lake Baikal basin)” and aimed at supporting the policy dialogue on water in Russia, in cooperation with the EU Water Initiative. Based on the analysis, some recommendations were developed for improving the use of instruments for water resources management in the Republic of Buryatia as a part of the Baikal Natural Area.

The Occurrence and Prevention of Filamentous Algae in Ecological Purification System of Micro-polluted Water

[ Objective ] The aim was to study the influence of filamentous algae on the process of water ecological purification. [ Method ] The occurrence mechanism of filamentous algae and its ecological system were summarized and analyzed. Considering the ecological purification in north- ern Jiangsu, the occurrence and prevention of filamentous algae in water, the method to prevent filamentous algae in polluted water was discussed. [ Result] The results showed that by measures of improving planting density, regular harvesting, and water flow state control before the filamentous algae blooming period, together with improving local pH value, light interference and ecological control during the blooming period, can effectively control the filamentous algae blooming. [ Condusion] The study of the happening mechanism of filamentous algae provided theoretical references and the technical basis in the work of filamentous algae prevention and control.

Groundwater resources in karst area in Southern China and sustainable utilization pattern

Occurrence conditions of groundwater in southern karst area are complicated. The water-bearing media in the karst have multiplicity, and the groundwater is hosted in holes, gaps, seams, pipes and caves. The karst water shows heterogeneity where fast and slow flow coexist, and the Darcy and non-Darcy flow coexist, and the liquid flow, the gas flow and solid flow coexist. The evaluation and investigation indicates that the mineable resource of karst groundwater is about 53.44 billion m^3/y, and the current exploitation quantity is merely 6.565 billion m^3/year. The exploitation and utilization potential is gigantic. In the region there are altogether 2 763 karst subterranean rivers with a total length of 12 687 km. The dry season runoff volume equals to 47 billion m^3/year. At present the exploitation is only 10%. Four effective utilization models of karst groundwater resources have been put forward.(1) The karst hills-depression zone formed the surface-underground united reservoir. By digging tunnels, water diversion irrigation and generating electricity, the ecological economy is developed.(2) In the deep-cut peak cluster depression area, by using the high-part Epikarst spring and constructing the regulation and storage water tank, the stereo ecological agriculture is developed.(3) In the karst peak forest plain and hilly-gully area, the pump-type underground regulating reservoir is constructed and the water-saving ecological agriculture is strengthened.(4) In the fault basin region with the surrounding groundwater runoff belting beam backwater, the water resources are jointly controlled to develop a fruit crop base within the basin.

Groundwater Systems and Eco-hydrological Features in the Main Karst Regions of China

Different karst water features and related water resources are present both in southern and northern China. There are over 3,358 well-developed karst ground river systems with total discharges in the dry season of about 420×10^8 m^3 in the main karst regions in the southern part of China. Exploitation rates are only 8-15%. Over 100 larger karst spring systems in the main karst regions of northern China cover a catchment area from 500 km^2 to over 4,000 km^2, of which the average discharge appears to be from about 1 m^3/s to 13 m^3/s and the exploitation rates are 70-80%. Six aspects of the eco- hydrological features of some typical karst regions in China comprising water environment, ecological features, materials and structures between parent rock and soil, bio-geological processes and palynological studies （spore-pollen） are discussed. Qualitative evaluation of eco-geology and rocky desertification in the karst regions should be based on the main karst ecological conditions as well as artificial, i.e., man-made impacts.

Emerging pollutants in the environment:A challenge for water resource management

A significant number of emerging pollutants(EPs)resulting from point and diffuse pollution is present in the aquatic environment.These are chemicals that are not commonly monitored but have the potential to enter the environment and cause adverse ecological and human health effects.According to the NORMAN network,at least 700 substances categorized into 20 classes,have been identified in the European aquatic environment.In light of their potential impact action is urgently required.In this study,we present a concept that shows the current state of art and challenges for monitoring programs,fate and risk assessment tools and requirements for policies with respect to emerging pollutants as a base for sustainable water resource management.Currently,methods for sampling and analysis are not harmonized,being typically focused on certain EP classes.For a number of known highly hazardous EPs detection limits are too high to allow proper risk assessment.For other EPs such as microplastics method development is in its infancy.Advanced ultra-sensitive instrumental techniques should be used for quantitative determination of prioritized EPs in water,suspended matter,soil and biota.Data on EPs'and their metabolites'properties that determine their fate in the environment are often not available.National surveys on water quality often use different parameters for water quality assessment and often do not include EPs.A harmonized monitoring of surface and groundwater is not yet achieved and urgently required.Specific component integrated into models assessing the fate of EPs in a multi compartment environmental approach are missing and must be developed.The main goal of risk assessment is the overall protection of ecological communities in the aquatic environment and human health.New methods for assessing the cumulative risks from combined exposures to several stressors,including mixtures of EPs in a multi-scale approach are required.A combination of regulations and management measures with respect to use/emissions of EPs into the environment,as well as to their occurrence in the environment are fundamental to reach an efficient water resource management.

Resourceful ecological treatment of wastewater in urban ecosystem

The treatment amount of wastewater is restricted to a small percentage in China. One of thereasons for that is the shortage of funds. Therefore , developing the technology of cost-effective , low energy-consuming and high efficiency is one of the important way to speed up the steps of wastewater treatment.This paper elucidated the principal and charactertics of the resourceful ecological treatment of wastewater. Asuccessful example of resourceful ecological land treatment of wastewater was given. The key points and therelative policies concerning the further development of resourceful ecological treatment of wastewater as asets of technologies have been suggested.

Concentrations,sources,and influential factors of water-soluble ions of atmospheric particles in Dunhuang Mogao Grottoes,a world heritage site in China

Atmospheric particle pollution is one of the major factors leading to degradation of ancient wall paintings,particularly heritage sites in arid and semi-arid regions.However,current systematic research on the changes,sources,and influential factors of atmospheric particulate matter and its water-soluble ion concentrations is not sufficient.Thus,the major water-soluble ion concentrations,sources,and influential factors of atmospheric particles PM_(2.5) and PM_(10)(particulate matter with an aerodynamic equivalent diameter≤2.5 and 10.0μm,respectively,in ambient air)were collected from Cave 16 and its ambient exterior environment in the Dunhuang Mogao Grottoes,China,between April 2015 and March 2016.Results showed that the concentrations of PM_(2.5) and PM_(10) inside and outside the cave were the highest in March 2016 and the lowest in December 2015.The higher particle concentration from March to May was related to the frequent occurrence of sand and dust events,and the lower particle concentration from June to September was associated with good diffusion conditions,increased precipitation,and an established cave shelterbelt.The concentration of particulate matter inside the cave was affected by the concentration of particles in the air outside the cave.Ca2+,NH+4,Na+,Cl-,and SO2-4were the main components of the total ions of PM_(2.5) and PM_(10) both inside and outside the cave.The total ions inside the cave were frequently affected by the disturbance of tourists'activities during the peak tourist season from May to August.Under the influence of dust,the total concentrations of Cl-,SO2-4,Na+,NH+4,and Ca2+in particles of different sizes inside and outside the cave increased,and the concentrations of Cl-,SO2-4,Na+,and Ca2+decreased during precipitation period.Backward air mass trajectory analysis suggested that the pollutants were mainly from Xinjiang,China.The pollutant sources of air particulates are straw burning,secondary pollution sources,soil dust,dry spring rivers,and tourist activities.

Spatial Availability of Nitrogen and Pesticides in the Surface Layers of Agricultural Soils of Tropical Hydrosystems in the Wet Season: Case of the BéréWatershed in Côte d’Ivoire (West Africa)

The objective of this study was to assess the contribution of the spatial organization of cropping systems and the physicochemical properties of surface layers of the agricultural zones soils in tropical hydrosystems to the spatial availability of nitrogen and pesticides during the wet season, such as the Béré watershed (BW) in C?te d’Ivoire. For this purpose, after mapping the spatial distribution of the BW cropping systems based on the likelihood classification methodology of satellite images of the study area, 27 samples from the 0 - 20 cm horizon of the soil surface layers of the agricultural areas were taken during the wet and agricultural season of the year 2016. The Kjeldahl method has been used to evaluate the total nitrogen concentration and high-performance liquid chromatography (HPLC) chain made it possible for the analysis of pesticide residues in the soil solutions. Geostatistical analysis and processing of spatial data and physicochemical and agrochemical soil parameters revealed that two major agricultural areas stand out in the BW, namely the Béré upstream watershed (BUW) dominated at 32.65% by annual croppings (maize, cotton, rainfed or lowland rice, market gardening, etc.) and the Béré downstream watershed (BDW) by large areas of perennial croppings (cashew nuts, cocoa, etc.), i.e. 21.47%. Agricultural soils in BW are usually of the moderately desaturated ferralitic type with a low acid pH and a quite strong temperature, such as those of tropical soils’ characteristics. However, agricultural soils in the BUW are characterized by higher proportions of sand and coarse sand. The parameters such as total porosity, cation exchange capacity, clay, organic matter, silt, fine silt, coarse silt, and potassium ions, are higher in the soils of the agricultural area of the BDW. Moreover, soils in the agricultural areas of the BUW are less rich in total nitrogen (0.84 g·kg-1) in contrast to those of the BDW (1.2 g·kg-1). On the other hand, the median concentrations of total pesticides remain very high in the BUW (193.80 μg·kg-1) in front of those of the BDW (94.81 μg·kg-1). In addition, the biological family of herbicides was the most notable in BW. The chemical families of triazines (100% detection;79.37 μg·kg-1) are the most important in the agricultural area of the BUW with the very significant presence of active molecules of pesticides such as simazine (92.86% detection;13.17 μg·kg-1). However, in the BDW, urea substitute (100% detection;44.02 μg·kg-1) dominate, including the active substance chlortoluron (84.62% detection;10.12 μg·kg-1). The presence and abundance of nitrogen and pesticides in the soils of the agricultural areas of BW are strongly linked to the intensive use of these agrochemicals in cropping systems in recent decades in West African countries, even though most of the active molecules found are forbidden in several countries, especially in European countries. These are applied to tropical agricultural soils with physicochemical characteristics favorable to their retention in wet weather, as confirmed by the case of BW’s agricultural soils. Therefore, the BW’s water resources present worrying risks of contamination during rainy events that deserve to be assessed and monitored. Hence the need to take mitigating measures to this effect in order to preserve the quality of the environment.

Mountain Water Tower and Ecological Risk Estimation of the Mesta-Nestos Transboundary River Basin (Bulgaria-Greece)

The Mesta-Nestos river basin in Bulgaria and Greece is a case study for transboundary decision-making support in south-eastern Europe and a show-case for the development of methodologies and information-gathering for the integrated regional planning of water resources. Land-use conflicts in this water-scarce region cover a wide spectrum of activities like agricultural irrigation, drinking water production, diversions for industrial water, and risk of pollution from mining, to name a few examples. Measurements of the water quality were carried out in the upper basin. Results will be illustrated by the example of the environmental situation in the alpine region of the Pirin National Park as well as in the Razlog Basin with a stronger anthropogenic impact and pollution around a former uranium mine near the village of Elesnica. The social and economic development of this transboundary region is a recently established priority for mean an increase in water usage the water resources if regional the future. It will and more stress for impacts of global climate change are verified. Problem-focused management of the catchment area as a whole on the basis of proved geo-data sets is needed for the future.

Eco-Toxicological Approach as a Contribution to Integrated Water Management on Okpara Dam at Kpassa in Benin: Evaluation of Contamination of Fish and Surface Water by Organochlorine Pesticides

The paper explores the degree of pollution of organochlorine pesticides in fish and water in the dam at Kpassa on a tributary of Okpara River that is pumped by Benin National Water agency (SONEB) in supplying drinking water to supply the city of Parakou. Doing so, fourteen parameters of organochlorine are analyzed. Most of obtain organoclorine concentration in water and fish below is indicated critical values. However, DDT and endrine concentration in water is slightly above legal tolerable values. Hexachlorobenen and dieldrine concentrations are three times higher than legal limit value while aldrine is ten times higher. However, heptachlore is double concentrated in fishery while aldrine (endrine, dieldrine aldrine, lindane, hexachloro-benzene, DDT) is found in the dam fish and surface water three times concentrated than tolerated value. These levels of concentrations result from the intensification of organoclorine pesticide used in agriculture especially in cotton production. These are caused by the chemical application accumulated in soil and through the food value chain system. Therefore, it is very important to extract sediment from the reservoir by dredging in oder to renew the ecosystem of the dam. To persistently manage the basin water resources, it is imperatively important to observe a significant behaviour changed from all stakeholders.