Hydrogeochemical and Isotopic Evidence for Flow Paths of Karst Waters Collected in the Heshang Cave,Central China

Understanding of hydrological processes in caves is important to help us interpret paleoclimate records from speleothems. In this study, we integrated hydrogeological and hydrogeochemical properties to characterize the hydraulic behavior of karst waters in the Heshang Cave, Central China. Using geological and topographical analyses, we identified regional watershed boundaries and hydrogeological connections that were controlled by anticlinal geometry and faults. Water samples were collected from the Heshang Cave and potential recharge sites. Geochemical data of c（Sr^2＋）/c（Ca^2＋） and c（Mg^2＋）/c（Ca^2＋） ratios suggest that the drainage system in Heshang Cave consists of two flow paths. For vadose waters, including drip water and rimstone pool water, c（Sr^2＋）/c（Ca^2＋） ratio ranges from 0.000 6 to 0.001 1, and c（Mg^2＋）/c（Ca^2＋） ratio ranges from 0.97 to 1.1, indicating that recharge was mainly from rainfall infiltration through the overlying Cambrian dolomite stratum. In contrast, slope current and underground river waters have higher c（Sr^2＋）/c（Ca^2＋） ratios （values from 0.002 2 to 0.002 8）, and lower c（Mg2＋）/c（Ca^2＋） ratios （values from 0.50 to 0.64）. These waters show homogeneous isotopic composition （δ^18O： -7.15‰- -6.95‰; δD： -52.73‰- -51.31‰）, implying recharge of allogeneic water from the Xiaocr River via karst conduits that pass through Ordovician limestone and Cambrian dolomite stratum.

Study on the characteristics and causes of carbon tetrachloride pollution of karst water in eastern suburbs of Jinan

By comparing the testing data of the hydrochemistry components and organic pollution of karst water sample in Jinan with large amount of historical data, the author finds the long-existing problem of carbon tetrachloride pollution and the great change of hydrochemical characteristics of karst water in eastern suburbs of Jinan. Since karst water is the main water-supply source in eastern suburbs of Jinan, these problems have greatly affected the safety of water supply. Based on the analysis of hydrogeological condition in eastern suburbs of Jinan, this thesis discusses the causes of carbon tetrachloride pollution and hydrochemical variation with hydrogeochemical theories so as to protect the precious karst groundwater and Jinan spring water. It is found that through research and analysis that there are mainly two causes of carbon tetrachloride pollution and hydrochemical variation: the vulnerability of karst water in this area; the other being the serious pollution in this area caused by remaining pollution sources of the last century.

Isotope Hydrogeological Study of Karst Water in the Lu' an Mining District and the Xin'ancun Spring Basin, Shanxi

Isotope hydrogeological study has shown that the water supply exploration area in the Lu' an coal mine may be divided into four zones of hydrodynamic conditions and the Xin'ancun Spring Basin where the mine is located may be divided into three Middle Ordovician karst water systems. This paper discusses the features of recharge, runoff and discharge of karst water in various zones, and hydrogeological parameters such as the age, flow rate and natural recharge of karst water have been estimated.

Exploration of Water Resource and Multiple Model for Water Resource Development in Karst Areas with the Preferred Plane Theory

According to the theory of preferred plane, preferred planes (faults) alwayscontrol the distribution of bedrock fissure water and hold abundant groundwater. Thus, theexploration of fissure or karst water can be converted into searching for the watery preferred plane(WPP). In the paper, the characteristic of watery preferred planes is analyzed and a series ofsuperior indices has been set up. It is introduced that WPPs are determined by the methods ofgeological analysis, superior index and complex geophysical analysis. Meanwhile, new multiple modelfor water resource development in the water-scarce areas of karst mountainous regions are advanced.

Effects of acid mine drainage on photochemical and biological degradation of dissolved organic matter in karst river water

Dissolved organic matter(DOM)can be removed or transformed by photochemical and biological processes,producing the negative effect of transforming organic carbon into inorganic carbon,which plays a vital role in the karst carbon cycle.However,acid mine drainage(AMD)will affect this process,so the degradation of DOM in karst river water(KRW)needs to be studied in this context.In this study,to reveal the evolution processes of DOM under photochemical and biological conditions in AMD-impacted KRW,AMD and KRW were mixed in different ratios under conditions of visible light irradiation(VL),biodegradation(BD),ultraviolet irradiation(UV)and ultraviolet irradiation+biodegradation(UV+BD).The average DOC concentrations in samples after mixing AMD and KRW in different proportions decreased significantly(by 23%)in UV+BD,which was 1.2–1.4 times higher than under the other conditions and would lead to a significant release of inorganic carbon.Further analysis of the fluorescence parameters via parallel factor analysis(PARAFAC)revealed that the DOM fluorescence components in AMD comprised mainly protein-like substances derived from autochthonous components,while the DOM fluorescence components in KRW were mainly humic-like substances with both autochthonous and allochthonous sources.Therefore,AMD could promote both the photochemical and biological degradation of DOM in karst receiving streams,resulting in the conversion of DOC to inorganic carbon.The results showed that the synergistic effects of UV+BD and AMD accelerated the degradation of DOM and the release of inorganic carbon in KRW,thus affecting the stability of the karst carbon cycle.

A review of water resources utilization and protection in Southwest China

Yunnan and Guizhou are two provinces in Southwest China where in recent years drought disasters have occurred due to natural and human factors. This paper reviewed literature and summarized the related achievements of water resources utilization and protection in Yunnan and Guizhou provinces. rivers, and karst ground water in the two provinces, and also This included characters and utilization of precipitation, the various explanations of drought （climate and human factors） and strategies for coping with droughts. Our concluding remarks highlight three lines of future studies： inequalities and equitable use of water distribution, better evaluation systems, and raising awareness through conservation practices.