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Diagnosis of the Kinetic Energy of the“21·7”Extreme Torrential Rainfall Event in Henan Province,China
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作者 Xiuping YAO Ruoying LI +1 位作者 Xiaohong BAO Qiaohua LIU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第1期73-83,共11页
An extreme torrential rain(ETR)event occurred in Henan Province,China,during 18-21 July 2021.Based on hourly rain-gauge observations and ERA5 reanalysis data,the ETR was studied from the perspective of kinetic energy(... An extreme torrential rain(ETR)event occurred in Henan Province,China,during 18-21 July 2021.Based on hourly rain-gauge observations and ERA5 reanalysis data,the ETR was studied from the perspective of kinetic energy(K),which can be divided into rotational wind(V_(R))kinetic energy(K_(R)),divergent wind kinetic energy(K_(D)),and the kinetic energy of the interaction between the divergent and rotational winds(K_(RD)).According to the hourly precipitation intensity variability,the ETR process was divided into an initial stage,a rapid increase stage,and maintenance stage.Results showed that the intensification and maintenance of ETR were closely related to the upper-level K,and most closely related to the upperlevel K_(R),with a correlation coefficient of up to 0.9.In particular,the peak value of hourly rainfall intensity lagged behind the K_(R) by 8 h.Furthermore,diagnosis showed that K transformation from unresolvable to resolvable scales made the ETR increase slowly.The meridional rotational wind(u_(R))and meridional gradient of the geopotential(φ)jointly determined the conversion of available potential energy(APE)to K_(R) through the barotropic process,which dominated the rapid enhancement of K_(R) and then caused the rapid increase in ETR.The transportation of K by rotational wind consumed K_(R),and basically offset the K_(R) produced by the barotropic process,which basically kept K_(R) stable at a high value,thus maintaining the ETR. 展开更多
关键词 extreme torrential rain rotational kinetic energy kinetic energy generation and transport barotropic process
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A Study on the Learning Progressions of Understanding the Core Concepts of Kinetic Energy in High School
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作者 Xuemei Cui Yue Zheng Yu Chen 《Journal of Contemporary Educational Research》 2024年第11期46-55,共10页
Learning progressions divide the logical system of a subject into ordered and continuously developing levels that are suitable for the cognitive development level of students,which plays an important role in understan... Learning progressions divide the logical system of a subject into ordered and continuously developing levels that are suitable for the cognitive development level of students,which plays an important role in understanding students’learning process.This paper focuses on the theme of“kinetic energy”in high school physics as the research object.Firstly,the concept map was used to represent the relationship between knowledge,and then five core concepts were selected based on the opinions of high school teachers.Secondly,the test tools were compiled and tested based on the relevant test questions.Finally,the paper analyzed the results based on the Rasch model,clarified students’cognitive development level of“kinetic energy”and constructed the learning progressions of“kinetic energy”based on the logical order of subject knowledge.The research provides theoretical and methodological support for the study of other subjects and learning progressions,and provides a valuable reference for high school teachers to effectively carry out the instruction of“kinetic energy.” 展开更多
关键词 Core concepts High school kinetic energy Learning progressions
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A nonlinear creep model for surrounding rocks of tunnels based on kinetic energy theorem 被引量:3
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作者 Wenbo Liu Hui Zhou +2 位作者 Shuguang Zhang Shuai Jiang Liu Yang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第2期363-374,共12页
The initiating condition for the accelerated creep of rocks has caused difficulty in analyzing the whole creep process.Moreover,the existing Nishihara model has evident shortcomings in describing the accelerated creep... The initiating condition for the accelerated creep of rocks has caused difficulty in analyzing the whole creep process.Moreover,the existing Nishihara model has evident shortcomings in describing the accelerated creep characteristics of the viscoplastic stage from the perspective of internal energy to analyze the mechanism of rock creep failure and determine the threshold of accelerated creep initiation.Based on the kinetic energy theorem,Perzyna viscoplastic theory,and the Nishihara model,a unified creep constitutive model that can describe the whole process of decaying creep,stable creep,and accelerated creep is established.Results reveal that the energy consumption and creep damage in the process of creep loading mainly come from the internal energy changes of geotechnical materials.The established creep model can not only describe the viscoelasticeplastic creep characteristics of rock,but also reflect the relationship between rock energy and creep deformation change.In addition,the research results provide a new method for determining the critical point of creep deformation and a new idea for studying the creep model and creep mechanical properties. 展开更多
关键词 Internal energy kinetic energy theorem Perzyna viscoplastic theory Nishihara model Accelerated creep Initiating threshold
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Description of martensitic transformation kinetics in Fe-C-X(X = Ni,Cr,Mn,Si) system by a modified model
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作者 Xiyuan Geng Hongcan Chen +3 位作者 Jingjing Wang Yu Zhang Qun Luo Qian Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期1026-1036,共11页
Controlling the content of athermal martensite and retained austenite is important to improving the mechanical properties of high-strength steels,but a mechanism for the accurate description of martensitic transformat... Controlling the content of athermal martensite and retained austenite is important to improving the mechanical properties of high-strength steels,but a mechanism for the accurate description of martensitic transformation during the cooling process must be addressed.At present,frequently used semi-empirical kinetics models suffer from huge errors at the beginning of transformation,and most of them fail to exhibit the sigmoidal shape characteristic of transformation curves.To describe the martensitic transformation process accurately,based on the Magee model,we introduced the changes in the nucleation activation energy of martensite with temperature,which led to the varying nucleation rates of this model during martensitic transformation.According to the calculation results,the relative error of the modified model for the martensitic transformation kinetics curves of Fe-C-X(X = Ni,Cr,Mn,Si) alloys reached 9.5% compared with those measured via the thermal expansion method.The relative error was approximately reduced by two-thirds compared with that of the Magee model.The incorporation of nucleation activation energy into the kinetics model contributes to the improvement of its precision. 展开更多
关键词 Fe-C-X system martensitic transformation kinetics curve semi-empirical model nucleation activation energy
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Dissolution mechanism and kinetics ofβ(Mg_(17)Al_(12))phases in AZ91 magnesium alloy
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作者 Sultan Alomairy 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1581-1592,共12页
In this study,the phase transformations,crystallization kinetics and dissolution mechanism ofβphase(Mg_(17)Al_(12))in magnesium alloy AZ91 were investigated by optical microscopy,X-ray diffraction,differential scanni... In this study,the phase transformations,crystallization kinetics and dissolution mechanism ofβphase(Mg_(17)Al_(12))in magnesium alloy AZ91 were investigated by optical microscopy,X-ray diffraction,differential scanning calorimetry and differential dilatometry.The results indicate that this AZ91 alloy undergoes a phase transformation during aging,a discontinuous precipitation of theβphase(Mg_(17)Al_(12))at 150℃at the grain boundaries and another continuous at 350℃within the grains.The activation energy of the dissolution reaction of theβphase(Mg_(17)Al_(12))under non-isothermal conditions is 116.781 kJ/mol,while it is 129.7383 kJ/mol under isothermal conditions.The Avrami coefficient,n,relevant for the dissolution kinetics of theβphase(Mg_(17)Al_(12))is 1.152 and 1.211 in the non-isothermal and isothermal conditions respectively.The numerical coefficients m and Avrami n are 0.993 and 1.152. 展开更多
关键词 AZ91 kineticS β(Mg_(17)Al_(12)) Activation energy Discontinuous precipitation Continuous precipitation DSC
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Turbulent Kinetic Energy of Flow during Inhale and Exhale to Characterize the Severity of Obstructive Sleep Apnea Patient
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作者 W.M.Faizal C.Y.Khor +4 位作者 Muhammad Nooramin Che Yaakob N.N.N.Ghazali M.Z.Zainon Norliza Binti Ibrahim Roziana Mohd Razi 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第7期43-61,共19页
This paper aims to investigate and present the numerical investigation of airflow characteristics using Turbulent Kinetic Energy(TKE)to characterize the upper airway with obstructive sleep apnea(OSA)under inhale and e... This paper aims to investigate and present the numerical investigation of airflow characteristics using Turbulent Kinetic Energy(TKE)to characterize the upper airway with obstructive sleep apnea(OSA)under inhale and exhale breathing conditions.The importance of TKE under both breathing conditions is that it showan accuratemethod in expressing the severity of flow in sleep disorder.Computational fluid dynamics simulate the upper airway’s airflow via steady-state Reynolds-averaged Navier-Stokes(RANS)with k–ωshear stress transport(SST)turbulencemodel.The three-dimensional(3D)airway model is created based on the CT scan images of an actual patient,meshed with 1.29 million elements using Materialise Interactive Medical Image Control System(MIMICS)and ANSYS software,respectively.High TKE were noticed around the region after the necking(smaller cross-sectional area)during the inhale and exhale breathing.The turbulent kinetic energy could be used as a valuablemeasure to identify the severity of OSA.This study is expected to provide a better understanding and clear visualization of the airflow characteristics during the inhale and exhale breathing in the upper airway of patients for medical practitioners in the OSA research field. 展开更多
关键词 Obstructive sleep apnea breathing disorders real patient CFD turbulent kinetic energy
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Kinetic Energy Budgets during the Rapid Intensification of Typhoon Rammasun (2014)
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作者 Xin QUAN Xiaofan LI 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2023年第1期78-94,共17页
In this study,Typhoon Rammasun(2014)was simulated using the Weather Research and Forecasting model to examine the kinetic energy during rapid intensification(RI).Budget analyses revealed that in the inner area of the ... In this study,Typhoon Rammasun(2014)was simulated using the Weather Research and Forecasting model to examine the kinetic energy during rapid intensification(RI).Budget analyses revealed that in the inner area of the typhoon,the conversion from symmetric divergent kinetic energy associated with the collocation of strong cyclonic circulation and inward flow led to an increase in the symmetric rotational kinetic energy in the lower troposphere.The increase in the symmetric rotational kinetic energy in the mid and upper troposphere resulted from the upward transport of symmetric rotational kinetic energy from the lower troposphere.In the outer area,both typhoon and Earth’s rotation played equally important roles in the conversion from symmetric divergent kinetic energy to symmetric rotational kinetic energy in the lower troposphere.The decrease in the symmetric rotational kinetic energy in the upper troposphere was caused by the conversion to asymmetric rotational kinetic energy through the collocation of symmetric tangential rotational winds and the radial advection of asymmetric tangential rotational winds by radial environmental winds. 展开更多
关键词 Typhoon Rammasun(2014) rapid intensification kinetic energy budget symmetric and asymmetric winds divergent and rotational circulations environmental flows
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Previously Unknown Formulas for the Relativistic Kinetic Energy of an Electron in a Hydrogen Atom
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作者 Koshun Suto 《Journal of Applied Mathematics and Physics》 2023年第4期972-987,共16页
Einstein’s energy-momentum relationship, which holds in an isolated system in free space, contains two formulas for relativistic kinetic energy. Einstein’s relationship is not applicable in a hydrogen atom, where po... Einstein’s energy-momentum relationship, which holds in an isolated system in free space, contains two formulas for relativistic kinetic energy. Einstein’s relationship is not applicable in a hydrogen atom, where potential energy is present. However, a relationship similar to that can be derived. That derived relationship also contains two formulas, for the relativistic kinetic energy of an electron in a hydrogen atom. Furthermore, it is possible to derive a third formula for the relativistic kinetic energy of an electron from that relationship. Next, the paper looks at the fact that the electron has a wave nature. Five more formulas can be derived based on considerations relating to the phase velocity and group velocity of the electron. This paper presents eight formulas for the relativistic kinetic energy of an electron in a hydrogen atom. 展开更多
关键词 Einstein’s energy-Momentum Relationship Relativistic kinetic energy Bohr’s Quantum Condition Potential energy Phase Velocity Group Velocity
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Quantization of the Kinetic Energy of Deterministic Chaos
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作者 Victor A. Miroshnikov 《American Journal of Computational Mathematics》 2023年第1期1-81,共81页
In previous works, the theoretical and experimental deterministic scalar kinematic structures, the theoretical and experimental deterministic vector kinematic structures, the theoretical and experimental deterministic... In previous works, the theoretical and experimental deterministic scalar kinematic structures, the theoretical and experimental deterministic vector kinematic structures, the theoretical and experimental deterministic scalar dynamic structures, and the theoretical and experimental deterministic vector dynamic structures have been developed to compute the exact solution for deterministic chaos of the exponential pulsons and oscillons that is governed by the nonstationary three-dimensional Navier-Stokes equations. To explore properties of the kinetic energy, rectangular, diagonal, and triangular summations of a matrix of the kinetic energy and general terms of various sums have been used in the current paper to develop quantization of the kinetic energy of deterministic chaos. Nested structures of a cumulative energy pulson, an energy pulson of propagation, an internal energy oscillon, a diagonal energy oscillon, and an external energy oscillon have been established. In turn, the energy pulsons and oscillons include group pulsons of propagation, internal group oscillons, diagonal group oscillons, and external group oscillons. Sequentially, the group pulsons and oscillons contain wave pulsons of propagation, internal wave oscillons, diagonal wave oscillons, and external wave oscillons. Consecutively, the wave pulsons and oscillons are composed of elementary pulsons of propagation, internal elementary oscillons, diagonal elementary oscillons, and external elementary oscillons. Topology, periodicity, and integral properties of the exponential pulsons and oscillons have been studied using the novel method of the inhomogeneous Fourier expansions via eigenfunctions in coordinates and time. Symbolic computations of the exact expansions have been performed using the experimental and theoretical programming in Maple. Results of the symbolic computations have been justified by probe visualizations. 展开更多
关键词 The Navier-Stokes Equations Quantization of kinetic energy Deterministic Chaos Elementary Pulson of Propagation Internal Elementary Oscillon Diagonal Elementary Oscillon External Elementary Oscillon Wave Pulson of Propagation Internal Wave Oscillon Diagonal Wave Oscillon External Wave Oscillon Group Pulson of Propagation Internal Group Oscillon Diagonal Group Oscillon External Group Oscillon energy Pulson of Propagation Internal energy Oscillon Diagonal energy Oscillon External energy Oscillon Cumulative energy Pulson
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Bus mass estimation algorithm based on kinetic energy theorem 被引量:1
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作者 张文娟 秦静 +2 位作者 谢辉 马红杰 黄登高 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2015年第2期103-110,共8页
Bus mass is an important factor that affects fuel consumption and one of the key input parameters associated with automatic shift and hybrid electric vehicle (HEV) energy management strategy. A city bus mass estimat... Bus mass is an important factor that affects fuel consumption and one of the key input parameters associated with automatic shift and hybrid electric vehicle (HEV) energy management strategy. A city bus mass estimation method based on kinetic energy theorem was proposed in this paper. The real-time data including vehicle speed and engine torque were collected by a remote data acquisition system. The samples in the process of being accelerated were selected to conduct vehicle mass estimation at the same bus stop with the same gear. The average estimation error is 2. 92% after the verification by actual data. Compared with the method based on recursive least squares, the algorithm based on kinetic energy theorem requires less sample length and the estimation error is smaller. Therefore, the method is more suitable for the bus mass estimation. The influences of gear, rolling resistance coefficient, wind resistance coefficient and road slope on mass estimation accuracy were analyzed. 展开更多
关键词 bus mass kinetic energy theorem recursive least squares
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Features of eddy kinetic energy and variations of upper circulation in the South China Sea 被引量:15
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作者 贺志刚 王东晓 胡建宇 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2002年第2期305-314,共10页
The features of eddy kinetic energy (EKE) and the variations of upper circulation in theSouth China Sea (SCS) are discussed in this paper using geostrophic currents estimated from Maps of Sea Level Anomalies of the TO... The features of eddy kinetic energy (EKE) and the variations of upper circulation in theSouth China Sea (SCS) are discussed in this paper using geostrophic currents estimated from Maps of Sea Level Anomalies of the TOPEX/Poseidon altimetry data. A high EKE center is identified in the southeast of Vietnam coast with the highest energy level 1 400 cm2 ·s^(-2) in both summer and autumn. This high EKE center is caused by the instability of the current axis leaving the coast of Vietnam in summer and the transition of seasonal circulation patterns in autumn. There exists another high EKE region in the northeastern SCS, southwest to Taiwan Island in winter. This high EKE region is generated from the eddy activities caused by the Kuroshio intrusion and accumulates more than one third of the annual EKE, which confirms that the eddies are most active in winter. The transition of upper circulation patterns is also evidenced by the directions of the major axises of velocity variance ellipses between 10?and 14.5°N, which supports the model results reported before. 展开更多
关键词 The South China Sea eddy kinetic energy TOPEX/POSEIDON upper circulation altimeter data
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Seasonal variation of eddy kinetic energy in the South China Sea 被引量:11
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作者 WANG Hui WANG Dakui +2 位作者 LIU Guimei WU Huiding LI Ming 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2012年第1期1-15,共15页
Mesoscale eddy activity and its modulation mechanism in the South China Sea (SCS) are inves- tigated with newly reprocessed satellite altimetry observations and hydrographic data. The eddy kinetic energy (EKE) lev... Mesoscale eddy activity and its modulation mechanism in the South China Sea (SCS) are inves- tigated with newly reprocessed satellite altimetry observations and hydrographic data. The eddy kinetic energy (EKE) level of basin-wide averages show a distinct seasonal cycle with the maximum in August-December and the minimum in February-May. Furthermore, the seasonal pattern of EKE in the basin is dominated by region offshore of central Vietnam (OCV), southwest of Taiwan Island (SWT), and southwest of Luzon (SWL), which are also the breeding grounds of mesoscale eddies in the SCS. Instability theory analysis suggests that the seasonal cycle of EKE is modulated by the baroclinic instability of the mean flow. High eddy growth rate (EGR) is found in the active eddy regions. Vertical velocity shear in the upper 50-500 m is crucial for the growth of baroclinic instability, leading to seasonal EKE evolution in the SCS. 展开更多
关键词 South China Sea eddy kinetic energy baroclinic instability vertical shear
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Solar energy conversion on g-C3N4 photocatalyst:Light harvesting,charge separation,and surface kinetics 被引量:11
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作者 Mu Xiao Bin Luo +1 位作者 Songcan Wang Lianzhou Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2018年第4期1111-1123,共13页
Photocatalysis. which utilizes solar energy to trigger chemical reactions, is one of the most desirable solar-energy-conversion approaches. Graphitic carbon nitride (g-C3N4). as an attractive metal-free photocatalys... Photocatalysis. which utilizes solar energy to trigger chemical reactions, is one of the most desirable solar-energy-conversion approaches. Graphitic carbon nitride (g-C3N4). as an attractive metal-free photocatalyst, has drawn worldwide research interest in the area of solar energy conversion due to its easy synthesis, earth-abundant nature, physicochemical stability and visible-light-responsive properties. Over the past ten years, g-C3N4 based photocatalysts have experienced intensive exploration, and great progress has been achieved. However, the solar conversion efficiency is still far from industrial applications due to the wide bandgap, severe charge recombination, and lack of surface active sites. Many strategies have been proposed to enhance the light absorption, reduce the recombination of charge carriers and accelerate the surface kinetics. This work makes a crucial review about the main contributions of various strategies to the light harvesting, charge separation and surface kinetics of g-C3N4 photocatalyst. Furthermore, the evaluation measurements for the enhanced light harvesting, reduced charge recombination and accelerated surface kinetics will be discussed. In addition, this review proposes future trends to enhance the photocatalytic performance of g-C3N4 photocatalyst for the solar energy conversion. 展开更多
关键词 PHOTOCATALYSIS g-C3N4 Light harvesting Charge separation Surface kinetics Solar energy conversion
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Improved Soft Abrasive Flow Finishing Method Based on Turbulent Kinetic Energy Enhancing 被引量:9
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作者 Jun LI Shiming JI Dapeng TAN 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第2期301-309,共9页
Soft abrasive flow(SAF) finishing can process the irregular geometric surfaces, but with the matter of low processing efficiency. To address the issue, an improved SAF finishing method based on turbulent kinetic ene... Soft abrasive flow(SAF) finishing can process the irregular geometric surfaces, but with the matter of low processing efficiency. To address the issue, an improved SAF finishing method based on turbulent kinetic energy enhancing is proposed. A constrained flow passage with serration cross-section is constructed to increase the turbulence intensity. Taking the constrained flow passage as the objective, a two-phase fluid dynamic model is set up by using particle trajectory model and standard k-ε turbulence model, and the flow field characteristics of the flow passage are acquired. The numerical results show that the serration flow passage can enhance the turbulence intensity, uniform the particles distribution, and increase the particle concentration near the bottom wall. The observation results by particle image velocimetry(PIV) show that the internal vortex structures are formed in flow passage, and the abrasive flow takes on turbulence concentrating phenomenon in near-wall region. The finishing experiments prove that the proposed method can obtain better surface uniformity, and the processing efficiency can be improved more 35%. This research provides an abrasive flow modeling method to reveal the particle motion regulars, and canoffer references to the technical optimization of fluid-based precision processing. 展开更多
关键词 Soft abrasive flow Serration flow passage ·kinetic energy enhancing Particle image velocimetry
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Turbulence Intensity and Turbulent Kinetic Energy Parameters over a Heterogeneous Terrain of Loess Plateau 被引量:5
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作者 YUE Ping ZHANG Qiang +2 位作者 WANG Runyuan LI Yaohui WANG Sheng 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2015年第9期1291-1302,共12页
A deep understanding of turbulence structure is important for investigating the characteristics of the atmospheric boundary layer,especially over heterogeneous terrain.In the present study,turbulence intensity and tur... A deep understanding of turbulence structure is important for investigating the characteristics of the atmospheric boundary layer,especially over heterogeneous terrain.In the present study,turbulence intensity and turbulent kinetic energy(TKE)parameters are analyzed for different conditions with respect to stability,wind direction and wind speed over a valley region of the Loess Plateau of China during December 2003 and January 2004.The purpose of the study is to examine whether the observed turbulence intensity and TKE parameters satisfy Monin–Obukhov similarity theory(MOST),and analyze the wind shear effect on,and thermal buoyancy function of,the TKE,despite the terrain heterogeneity.The results demonstrate that the normalized intensity of turbulence follows MOST for all stability in the horizontal and vertical directions,as well as the normalized TKE in the horizontal direction.The shear effect of the wind speed in the Loess Plateau region is strong in winter and could enhance turbulence for all stability conditions.During daytime,the buoyancy and shear effect together constitute the generation of TKE under unstable conditions.At night,the contribution of buoyancy to TKE is relatively small,and mechanical shearing is the main production form of turbulence. 展开更多
关键词 heterogeneous terrain turbulence intensity turbulent kinetic energy Monin–Obukhov similarity function
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Eddy Kinetic Energy Study of the Snowstorm over Southern China in January 2008 被引量:2
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作者 ZUO Qunjie GAO Shouting L Daren 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2014年第4期972-984,共13页
The energetics of the third stage of a snowstorm over China was analyzed using ECWMF data.The analysis of the energy budget for the Middle East trough and the western Pacific trough that developed toward China on 25-2... The energetics of the third stage of a snowstorm over China was analyzed using ECWMF data.The analysis of the energy budget for the Middle East trough and the western Pacific trough that developed toward China on 25-28 January 2008 showed the advection of the geopotential by the ageostrophic wind to be both a crucial source and the primary sink of the eddy kinetic energy centers associated with the troughs.The magnitudes of the energy conversion terms,interaction kinetic energy conversion and baroclinic conversion,were too small to explain the development of the energy centers and the jet streaks.The energy centers gained energy at their entrance regions via the convergence of the ageostrophic geopotential fluxes,and then lost energy at their exit regions by the same fluxes.At the entrance regions,the fluxes converged,increasing the geopotential gradient,which generated a stronger geostrophic wind and higher kinetic energy,resulting in an ascending motion in this area.When the troughs moved to China,the ascending motion caused by the convergence of the fluxes at entrance region intensified the snowstorms over central and southern China. 展开更多
关键词 eddy kinetic energy ageostrophic geopotential flux snowstorms jet streaks
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Effect of REs(Y,Nd)addition on high temperature oxidation kinetics,oxide layer characteristic and activation energy of AZ80 alloy 被引量:4
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作者 Chunlong Cheng Xiaoqiang Li +3 位作者 Qichi Le Ruizhen Guo Qing Lan Jianzhong Cui 《Journal of Magnesium and Alloys》 SCIE EI CAS 2020年第4期1281-1295,共15页
The oxidation behaviors of AZ80,AZ8O-0.32 Y and AZ8O-0.38 Nd(wt.%)alloys were researched at 413℃,420℃,427v and 433℃for up to 6 h in air environment via a high precision analytical balance,a laser confocal microscop... The oxidation behaviors of AZ80,AZ8O-0.32 Y and AZ8O-0.38 Nd(wt.%)alloys were researched at 413℃,420℃,427v and 433℃for up to 6 h in air environment via a high precision analytical balance,a laser confocal microscope,differential scanning calorimeter(DSC)analysis,X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and X-ray photoelectron spectroscopy(XPS)analysis.The results show that the weight gain and oxidation rate of AZ80 are reduced significantly,the initiation form and propagation of cracks in oxide layer are changed.Compact and protective oxide layer forms on alloy surface with Y or Nd addition.And the activation energies of AZ80,AZ80-0.32Y and AZ8O-0.38Nd alloys calculated via Arrhenius equation are 82.556 kJ/mol,177.148kJ/mol and 136.738 kJ/mol,respectively. 展开更多
关键词 MAGNESIUM RARE-EARTH Oxidation kinetics Activation energy
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Rapid and stable calcium-looping solar thermochemical energy storage via co-doping binary sulfate and Al–Mn–Fe oxides 被引量:1
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作者 Changjian Yuan Xianglei Liu +8 位作者 Xinrui Wang Chao Song Hangbin Zheng Cheng Tian Ke Gao Nan Sun Zhixing Jiang Yimin Xuan Yulong Ding 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第8期1290-1305,共16页
Solar thermochemical energy storage based on calcium looping(CaL)process is a promising technology for next-generation concentrated solar power(CSP)systems.However,conventional calcium carbonate(CaCO_(3))pellets suffe... Solar thermochemical energy storage based on calcium looping(CaL)process is a promising technology for next-generation concentrated solar power(CSP)systems.However,conventional calcium carbonate(CaCO_(3))pellets suffer from slow reaction kinetics,poor stability,and low solar absorptance.Here,we successfully realized high power density and highly stable solar thermochemical energy storage/release by synergistically accelerating energy storage/release via binary sulfate and promoting cycle stability,mechanical strength,and solar absorptance via Al–Mn–Fe oxides.The energy storage density of proposed CaCO_(3)pellets is still as high as 1455 kJ kg^(-1)with only a slight decay rate of 4.91%over 100 cycles,which is higher than that of state-of-the-art pellets in the literature,in stark contrast to 69.9%of pure CaCO_(3)pellets over 35 cycles.Compared with pure CaCO_(3),the energy storage power density or decomposition rate is improved by 120%due to lower activation energy and promotion of Ca^(2+)diffusion by binary sulfate.The energy release or carbonation rate rises by 10%because of high O^(2-)transport ability of molten binary sulfate.Benefiting from fast energy storage/release rate and high solar absorptance,thermochemical energy storage efficiency is enhanced by more than 50%under direct solar irradiation.This work paves the way for application of direct solar thermochemical energy storage techniques via achieving fast energy storage/release rate,high energy density,good cyclic stability,and high solar absorptance simultaneously. 展开更多
关键词 Calcium looping(CaL) Solar thermochemical energy storage Binary sulfate Fast reaction kinetics
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C haracteristics of turbulent kinetic energy dissipation rate and turbidity near the coast of East China Sea 被引量:1
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作者 张艳伟 许惠平 +2 位作者 覃如府 徐昌伟 范代读 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2016年第5期1134-1142,共9页
The East China Sea(ECS) has a high suspended-sediment concentration because of the influence of the Changjiang River,indicated by high turbidity in the water.Considering the islands off the coast and the complex topog... The East China Sea(ECS) has a high suspended-sediment concentration because of the influence of the Changjiang River,indicated by high turbidity in the water.Considering the islands off the coast and the complex topography,and the strong influence of tides and wind,the coast off the ECS is a typical region with strong oceanic mixing processes.The changes in the dynamic processes near the bottom play an important role in the control of water turbidity.The turbulent kinetic energy dissipation rate(ε) is a parameter that shows the strength of ocean mixing.This is estimated based on a structure method using current velocity that is measured by a high-frequency Acoustic Doppler Current Profiler(ADCP) from a seafloor observatory in the ECS.The results indicate strong ocean mixing processes with a mean e value of 5.7×10^(-5) W/kg and distinct tidal variations in the dissipation rate.Conversely,the variation of the water turbidity leads to changes in the water dynamical structure near the bottom.Comparing the dissipation rate with the turbidity near the bottom boundary layer,we find that the high turbidity mimics strong ocean mixing. 展开更多
关键词 turbulent kinetic energy DISSIPATION rate TURBIDITY TIDES NEAR BOTTOM boundary East China Sea
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Extend ethylene aromatization single-event kinetic modeling with physical and chemical descriptor based on ZSM-5 catalyst
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作者 Jia-Rong Xie Fang Jin 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3841-3853,共13页
The ethylene aromatization is critical for the methanol to aromatics and light alkane dehydroaromatization process.The single-event microkinetic(SEMK)model combining the linear free energy theory and solid acid distri... The ethylene aromatization is critical for the methanol to aromatics and light alkane dehydroaromatization process.The single-event microkinetic(SEMK)model combining the linear free energy theory and solid acid distribution concept were established and extend for the ethylene aromatization process,which can reduce the kinetic parameters and simplify the reaction network by comparison with the SEMK model including subtype elementary steps based on the type of carbenium ions.Further introducing deactivation parametersφinto the model and applying the linear free energy model to the deactivation experimental data,the obtained deactivation parametersφindicate that the carbon deposition precursors have the greatest impact on reducing the reaction rate of single-molecular reactions and the smallest impact on the hydrogen transfer reaction.Meanwhile,according to the change of reaction enthalpy,effect of carbenium ion structure on methylation,ethylation,cyclization and endo-βscission was investigated by introducing linear free energy concept into the SEMK model.The effect of different acid strengths on elementary steps was investigated based on the acid strength distribution model,it was found that the methylation and oligomerization reactions,the ali-βscission reaction,endo-βscission reaction and the cyclization reaction were more sensitive to strong acidity sites.The physisorption and chemisorption heat are separated from the protonation heat in the linear free energy kinetic model and the acid strength distribution kinetic model,and the absolute values of the obtained physisorption and chemisorption heat increase with the carbon number of carbenium ions.Furthermore,the parameters of the acid strength distribution kinetic model were applied to propane dehydroaromatization on H-ZSM-5 and the ethane dehydroaromatization on Zn/ZSM-5 to confirm the independence of parameters in the SEMK model with the similar reaction network. 展开更多
关键词 kinetic model Ethylene aromatization Acid strength distribution Linear free energy theory
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