基于ENTROPY-TOPSIS算法的电路实验课程综合成绩评定方法

针对高校实践教学成绩评定环节中存在的不足,该文将基于修正ENTROPY-TOPSIS算法应用到实验课程成绩评定当中,并推导了具体算法原理。同时将该算法与常用权值算法层次分析法以及CRITIC算法在电路实践成绩客观赋权过程中进行了横向对比。结果显示该方法可以为多源异构数据的科学赋权提供理论依据,有效消除因主观因素带来的不合理性,使教师在实验成绩的评定上更加趋向于客观化、科学化。

基于ISM-AHP-Entropy航空公司风险因素研究

针对航空公司风险因素研究,引入ISM-AHP-Entropy综合评价方法对风险因素进行评价。构建了风险因素指标体系,利用解析结构模型(ISM)将因素指标分为表层和深层致因,构建结构模型;根据问卷结果,用AHP-Entropy求出综合权重,结果表明人因和管理因素对风险影响最为显著;进一步运用AHP-Entropy综合法分别计算表层和深层致因权重并分析,结果表明表层致因中机组资源管理水平、签派员应急处置能力影响最为显著,深层致因中安全规章方针的制定情况、应急管理培训与实施情况影响最为显著;从多个现实角度出发,结合CBTA理念,为航空公司降低风险、提高安全意识与水平提出多条建议,可供航空公司参考采纳。

On the thermodynamics of plasticity during quasi-isentropic compression of metallic glass

Entropy production in quasi-isentropic compression (QIC) is critically important for understanding the properties of materials under extremeconditions. However, the origin and accurate quantification of entropy in this situation remain long-standing challenges. In this work, a framework is established for the quantification of entropy production and partition, and their relation to microstructural change in QIC. Cu50Zr50is taken as a model material, and its compression is simulated by molecular dynamics. On the basis of atomistic simulation-informed physicalproperties and free energy, the thermodynamic path is recovered, and the entropy production and its relation to microstructural change aresuccessfully quantified by the proposed framework. Contrary to intuition, entropy production during QIC of metallic glasses is relativelyinsensitive to the strain rate ˙γ when ˙γ ranges from 7.5 × 10^(8) to 2 × 10^(9)/s, which are values reachable in QIC experiments, with a magnitudeof the order of 10^(−2)kB/atom per GPa. However, when ˙γ is extremely high (>2 × 10^(9)/s), a notable increase in entropy production rate with˙γ is observed. The Taylor–Quinney factor is found to vary with strain but not with strain rate in the simulated regime. It is demonstrated thatentropy production is dominated by the configurational part, compared with the vibrational part. In the rate-insensitive regime, the increase inconfigurational entropy exhibits a linear relation to the Shannon-entropic quantification of microstructural change, and a stretched exponential relation to the Taylor–Quinney factor. The quantification of entropy is expected to provide thermodynamic insights into the fundamentalrelation between microstructure evolution and plastic dissipation.

Estimation of the anisotropy of hydraulic conductivity through 3D fracture networks using the directional geological entropy

With an extension of the geological entropy concept in porous media,the approach called directional entrogram is applied to link hydraulic behavior to the anisotropy of the 3D fracture networks.A metric called directional entropic scale is used to measure the anisotropy of spatial order in different directions.Compared with the traditional connectivity indexes based on the statistics of fracture geometry,the directional entropic scale is capable to quantify the anisotropy of connectivity and hydraulic conductivity in heterogeneous 3D fracture networks.According to the numerical analysis of directional entrogram and fluid flow in a number of the 3D fracture networks,the hydraulic conductivities and entropic scales in different directions both increase with spatial order(i.e.,trace length decreasing and spacing increasing)and are independent of the dip angle.As a result,the nonlinear correlation between the hydraulic conductivities and entropic scales from different directions can be unified as quadratic polynomial function,which can shed light on the anisotropic effect of spatial order and global entropy on the heterogeneous hydraulic behaviors.

Boron-doped high-entropy oxide toward high-rate and long-cycle layered cathodes for wide-temperature sodium-ion batteries

03-type layered metal oxides hold great promise for sodium-ion batteries cathodes owing to their energy density advantage.However,the severe irreversible phase transition and sluggish Na^(+)diffusion kinetics pose significant challenges to achieve high-performance layered cathodes.Herein,a boron-doped03-type high entropy oxide Na(Fe_(0.2)Co_(0.15)Cu_(0.05)Ni_(0.2)Mn_(0.2)Ti_(0.2))B_(0.02)O_(2)(NFCCNMT-B_(0.02))is designed and the covalent B-O bonds with high entropy configuration ensure a robust layered structure.The obtained cathode NFCCNMT-B_(0.02)exhibits impressive cycling performance(capacity retention of 95%and 82%after100 cycles and 300 cycles at 1 and 10 C,respectively)and outstanding rate capability(capacity of 83 mAh g^(-1)at 10 C).Furthermore,the NFCCNMT-B_(0.02)demonstrates a superior wide-temperature performance,maintaining the same capacity level(113,4 mAh g^(-1)@-20℃,121 mAh g^(-1)@25℃,and 119 mAh g^(-1)@60℃)and superior cycle stability(90%capacity retention after 100 cycles at 1 C at-20℃).The high-entropy configuration design with boron doping strategy contributes to the excellent sodium-ion storage performance.The high-entropy configuration design effectively suppresses irreversible phase transitions accompanied by small volume changes(ΔV=0.65 A3).B ions doping expands the Na layer distance and enlarges the P3 phase region,thereby enhancing Na^(+)diffusion kinetics.This work offers valuable insights into design of high-performance layered cathodes for sodium-ion batteries operating across a wide temperature.

Microstructure and Properties of AlCoCrFeNiTi High-Entropy Alloy Coatings Prepared by Laser Cladding

21-4N(5Cr21Mn9Ni4N)is extensively employed in the production of engine valves,operating under severe conditions.Apart from withstanding high-temperature gas corrosion,it must also endure the impact of cylinder explosion pressure.The predominant failure mode of 21-4N valves is abrasive wear.Surface coatings serve as an effective approach to prevent such failures.In this investigation,Laser cladding technology was utilized to fabricate AlCoCrFeNiTi high entropy alloy coatings onto the surfaces of 21-4N valves.According to the findings,the cladding zone has a normal dendritic microstructure,a good substrate-to-cladding layer interaction,and no obvious flaws.In terms of hardness,the cladding demonstrates an average hardness of 620 HV.The hardness has increased by 140%compared to the substrate.The average hardness of the cladding remains at approximately 520 HV even at elevated temperatures.Regarding frictional wear performance,between 400℃and 800℃,the cladding layer exhibits an average friction coefficient of 0.4,with the primary wear mechanisms being abrasive wear,adhesive wear,and a minor degree of plastic deformation.

Detection method of forward-scatter signal based on Rényi entropy

The application scope of the forward scatter radar(FSR)based on the Global Navigation Satellite System(GNSS)can be expanded by improving the detection capability.Firstly,the forward-scatter signal model when the target crosses the baseline is constructed.Then,the detection method of the for-ward-scatter signal based on the Rényi entropy of time-fre-quency distribution is proposed and the detection performance with different time-frequency distributions is compared.Simula-tion results show that the method based on the smooth pseudo Wigner-Ville distribution(SPWVD)can achieve the best perfor-mance.Next,combined with the geometry of FSR,the influence on detection performance of the relative distance between the target and the baseline is analyzed.Finally,the proposed method is validated by the anechoic chamber measurements and the results show that the detection ability has a 10 dB improvement compared with the common constant false alarm rate(CFAR)detection.

Recent progress and future prospects of high-entropy materials for battery applications

Due to the energy crisis caused by limited fossil fuel reserves,extensive use of the renewable energy sources such as wind or solar energy is deemed to replace the use of traditional fossil fuels in the future^([1−3]).However,most renewable energy sources face the same problem,which is the intermittency of energy.For example,solar energy cannot be utilized at night.That means the continuous energy demand required for large-scale power grids can’t be satisfied by a single solar panel model.

Energetic and Entropic Changes in Volume Work and Chemical Reactions

In the present study, energetic and entropic changes are investigated on a comparative basis, as they occur in the volume changes of an ideal gas in the Carnot cycle and in the course of the chemical reaction in a lead-acid battery. Differences between reversible and irreversible processes have been worked out, in particular between reversibly exchanged entropy (∆eS) and irreversibly produced entropy (∆iS). In the partially irreversible case, ∆eS and ∆iS add up to the sum ∆S for the volume changes of a gas, and only this function has an exact differential. In a chemical reaction, however, ∆eS is independent on reversibility. It arises from the different intramolecular energy contents between products and reactants. Entropy production in a partially irreversible Carnot cycle is brought about through work-free expansions, whereas in the irreversible battery reaction entropy is produced via activated complexes, whereby a certain, variable fraction of the available chemical energy becomes transformed into electrical energy and the remaining fraction dissipated into heat. The irreversible reaction process via activated complexes has been explained phenomenologically. For a sufficiently high power output of coupled reactions, it is essential that the input energy is not completely reversibly transformed, but rather partially dissipated, because this can increase the process velocity and consequently its power output. A reduction of the counter potential is necessary for this purpose. This is not only important for man-made machines, but also for the viability of cells.

基于Dematel-Entropy耦合赋权的煤层顶板富水性评价

矿井的安全问题一直是矿业领域关注的重点,而准确评估含水层的富水性是进行涌水或突水灾害风险分析的首要前提。以大南湖七号煤矿一、二分区3煤顶板为研究对象,首先,在分析采区的地质及水文地质条件的基础上,选取了含水层厚度、隔水指数、煤层倾角、岩心采取率、砂泥互层指数、岩性结构指数6个因素作为评价富水性的主要指标;然后,采用Dematel(决策实验室法)-Entropy(熵值法)确定主客观权重,利用信息熵原理协调2种评价方法之间既竞争又一致的关系,得到各影响因素组合权重;最后,结合GIS分析功能对含水层富水性进行评价分区。研究结果表明:一分区整体为弱富水性,二分区以中等-强富水性为主,评价结果准确率达80%以上,可为煤层顶板含水层的疏水方案提供参考。

IGED:Towards Intelligent DDoS Detection Model Using Improved Generalized Entropy and DNN

As the scale of the networks continually expands,the detection of distributed denial of service(DDoS)attacks has become increasingly vital.We propose an intelligent detection model named IGED by using improved generalized entropy and deep neural network(DNN).The initial detection is based on improved generalized entropy to filter out as much normal traffic as possible,thereby reducing data volume.Then the fine detection is based on DNN to perform precise DDoS detection on the filtered suspicious traffic,enhancing the neural network’s generalization capabilities.Experimental results show that the proposed method can efficiently distinguish normal traffic from DDoS traffic.Compared with the benchmark methods,our method reaches 99.9%on low-rate DDoS(LDDoS),flooded DDoS and CICDDoS2019 datasets in terms of both accuracy and efficiency in identifying attack flows while reducing the time by 17%,31%and 8%.

Entropy of deterministic trajectory via trajectories ensemble

We present a formulation of the single-trajectory entropy using the trajectories ensemble. The single-trajectory entropy is affected by its surrounding trajectories via the distribution function. The single-trajectory entropies are studied in two typical potentials, i.e., harmonic potential and double-well potential, and in viscous environment by interacting trajectory method. The results of the trajectory methods are in agreement well with the numerical methods(Monte Carlo simulation and difference equation). The single-trajectory entropies increasing(decreasing) could be caused by absorption(emission) heat from(to) the thermal environment. Also, some interesting trajectories, which correspond to the rare evens in the processes, are demonstrated.

Preparation of FeCoNi medium entropy alloy from Fe^(3+)-Co^(2+)-Ni^(2+)solution system

In recent years,medium entropy alloys have become a research hotspot due to their excellent physical and chemical performances.By controlling reasonable elemental composition and processing parameters,the medium entropy alloys can exhibit similar properties to high entropy alloys and have lower costs.In this paper,a FeCoNi medium entropy alloy precursor was prepared via sol-gel and coprecipitation methods,respectively,and FeCoNi medium entropy alloys were prepared by carbothermal and hydrogen reduction.The phases and magnetic properties of FeCoNi medium entropy alloy were investigated.Results showed that FeCoNi medium entropy alloy was produced by carbothermal and hydrogen reduction at 1500℃.Some carbon was detected in the FeCoNi medium entropy alloy prepared by carbothermal reduction.The alloy prepared by hydrogen reduction was uniform and showed a relatively high purity.Moreover,the hydrogen reduction product exhibited better saturation magnetization and lower coercivity.

ESTIMATION OF AVERAGE DIFFERENTIAL ENTROPY FOR A STATIONARY ERGODIC SPACE-TIME RANDOM FIELD ON A BOUNDED AREA

In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary random field in a small range,we give an entropy estimation and obtain the average entropy estimation formula in a certain bounded space region.It can be proven that the estimation of the average differential entropy converges to the theoretical value with a probability of 1.In addition,we also conducted numerical experiments for different parameters to verify the convergence result obtained in the theoretical proofs.

Numerical Simulation and Entropy Production Analysis of Centrifugal Pump with Various Viscosity

The fluid’s viscosity significantly affects the performance of a centrifugal pump.The entropy production method and leakage are employed to analyze the performance changes under various viscosities by numerical simulation and validated by experiments.The results showed that increasing viscosity reduces both the pump head and efficiency.In addition,the optimal operating point shifts to the left.Leakage is influenced by vortex distribution in the front chamber and boundary layer thickness in wear-ring clearance,leading to an initial increase and subsequent decrease in leakage with increasing viscosity.The total entropy production Spro,Total inside the pump rises with increasing viscosity.The different mechanisms dominate under varying conditions:Turbulent dissipation dominates at low viscosity.Under high-viscosity conditions,energy loss is primarily caused by direct dissipation Spro,D and wall entropy production Spro,W.This study provides a deeper and more objective understanding of the energy characteristics of centrifugal pumps handling fluids of various viscosity,potentially aiding in optimizing pump design and improving energy conversion efficiency.

Chemical Scissors Tailored Nano‑Tellurium with High‑Entropy Morphology for Efficient Foam‑Hydrogel‑Based Solar Photothermal Evaporators

The development of tellurium(Te)-based semiconductor nanomaterials for efficient light-to-heat conversion may offer an effective means of harvesting sunlight to address global energy concerns.However,the nanosized Te(nano-Te)materials reported to date suffer from a series of drawbacks,including limited light absorption and a lack of surface structures.Herein,we report the preparation of nano-Te by electrochemical exfoliation using an electrolyzable room-temperature ionic liquid.Anions,cations,and their corresponding electrolytic products acting as chemical scissors can precisely intercalate and functionalize bulk Te.The resulting nano-Te has high morphological entropy,rich surface functional groups,and broad light absorption.We also constructed foam hydrogels based on poly(vinyl alcohol)/nano-Te,which achieved an evaporation rate and energy efficiency of 4.11 kg m^(−2)h^(−1)and 128%,respectively,under 1 sun irradiation.Furthermore,the evaporation rate was maintained in the range 2.5-3.0 kg m^(−2)h^(−1)outdoors under 0.5-1.0 sun,providing highly efficient evaporation under low light conditions.

A Novel Derivation of Black Hole Entropy in all Dimensions from Truly Point Mass Sources

It is explicitly shown how the Schwarzschild Black Hole Entropy (in all dimensions) emerges from truly point mass sources at r=0due to a non-vanishing scalar curvature involving the Dirac delta distribution. In order to achieve this, one is required to extend the domain of r to negative values −∞≤r≤+∞. It is the density and anisotropic pressure components associated with the point mass delta function source at the origin r=0which furnish the Schwarzschild black hole entropy in all dimensions D≥4after evaluating the Euclidean Einstein-Hilbert action. Two of the most salient results are i) that the observed spacetime dimension D=4is precisely singled out from all the other dimensions when the strong and weak energy conditions are met, and ii) the point mass source described in this work is not the result of a spherically symmetric gravitational collapse of a star as described by the Oppenheimer-Snyder model because we are not neglecting the pressure. As usual, it is required to take the inverse Hawking temperature βHas the length of the circle Sβ1obtained from a compactification of the Euclidean time in thermal field theory which results after a Wick rotation, it=τ, to imaginary time. This approach can be generalized to the Reissner-Nordstrom and Kerr-Newman metrics. The physical implications of this finding warrant further investigation since it suggests a profound connection between the notion of gravitational entropy and spacetime singularities.

Composition optimization and performance prediction for ultra-stable water-based aerosol based on thermodynamic entropy theory

Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of the water-based aerosol is always unsatisfactory due to the rapid evaporation and sedimentation of the aerosol droplets.Great efforts have been devoted to improve the stability of water-based aerosol by using additives with different composition and proportion.However,the lack of the criterion and principle for screening the effective additives results in excessive experimental time consumption and cost.And the stabilization time of the aerosol is still only 30 min,which could not meet the requirements of the perdurable interference.Herein,to improve the stability of water-based aerosol and optimize the complex formulation efficiently,a theoretical calculation method based on thermodynamic entropy theory is proposed.All the factors that influence the shielding effect,including polyol,stabilizer,propellant,water and cosolvent,are considered within calculation.An ultra-stable water-based aerosol with long duration over 120 min is obtained with the optimal fogging agent composition,providing enough time for fighting the electro-optic weapon.Theoretical design guideline for choosing the additives with high phase transition temperature and low phase transition enthalpy is also proposed,which greatly improves the total entropy change and reduce the absolute entropy change of the aerosol cooling process,and gives rise to an enhanced stability of the water-based aerosol.The theoretical calculation methodology contributes to an abstemious time and space for sieving the water-based aerosol with desirable performance and stability,and provides the powerful guarantee to the homeland security.

Enhanced ferroelectric and improved leakage of BFO-based thin films through increasing entropy strategy

BiFeO_(3)(BFO)has received considerable attention as a lead-free ferroelectric film due to its large theoretical remnant polariza-tion.However,BFO suffers from a large leakage current,resulting in poor ferroelectric properties.Herein,the sol-gel method was used to deposit a series of BFO-based thin films on fluorine-doped tin oxide substrates,and the effects of the substitution of the elements Co,Cu,Mn(B-site)and Sm,Eu,La(A-site)on the crystal structure,ferroelectricity,and leakage current of the BFO-based thin films were invest-igated.Results confirmed that lattice distortion by X-ray diffraction can be attributed to the substitution of individual elements in the BFO-based films.Sm and Eu substitutions contribute to the lattice distortion in a pseudo-cubic structure,while La is biased toward pseudo-tet-ragonal.Piezoelectric force microscopy confirmed that reversible switching of ferroelectric domains by nearly 180°can be realized through the prepared films.The ferroelectric hysteresis loops showed that the order for the polarization contribution is as follows:Cu>Co>Mn(B-site),Sm>La>Eu(A-site).The current density voltage curves indicated that the order for leakage contribution is as follows:Mn<Cu<Co(B-site),La<Eu<Sm(A-site).Scanning electron microscopy showed that the introduction of Cu elements facilitates the formation of dense grains,and the grain size distribution statistics proved that La element promotes the reduction of grain size,leading to the increase of grain boundaries and the reduction of leakage.Finally,a Bi_(0.985)Sm_(0.045)La_(0.03)Fe_(0.96)Co_(0.02)Cu_(0.02)O_(3)(SmLa-CoCu)thin film with a qualitative leap in the remnant polarization from 25.5(Bi_(0.985)Sm_(0.075)FeO_(3))to 98.8µC/cm^(2)(SmLa-CoCu)was prepared through the syner-gistic action of Sm,La,Co,and Cu elements.The leakage current is also drastically reduced from 160 to 8.4 mA/cm^(2)at a field strength of 150 kV/cm.Thus,based on the increasing entropy strategy of chemical engineering,this study focuses on enhancing ferroelectricity and decreasing leakage current,providing a promising path for the advancement of ferroelectric devices.

Research Progress of High Entropy Carbides

High entropy carbides (HECds) are multi-component carbides consisting of transition metal carbides.HECds are generally composed of five or more metal cations of the equal or near-equal substances,obtaining a single crystal structure.HECds have great potentials for future applications due to excellent mechanical,antioxidant and thermal properties.Due to their complex crystal structures and lattice distortion,computer simulations are widely used to efficiently associate the properties of HECds with the corresponding microstructures.In response to the development of HECds,this article provides an overview of the basic design,preparation process and properties of HECds.