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三种典型熔铸载体及其悬浮液的流变特性
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作者 李卓恒 张向荣 +3 位作者 解寒飞 刘攀 吴欣欣 周霖 《火炸药学报》 EI CAS CSCD 北大核心 2023年第10期874-881,I0008,共9页
为了对比不同载体对熔铸炸药悬浮液流变特性的影响,使用Haake MarsⅢ流变仪对TNT、DNAN、DNP的HMX悬浮液的流变性能进行了测试,分析了载体种类、剪切速率、体系温度、固相颗粒含量、颗粒级配对悬浮液流变性能的影响。结果表明,3种载体... 为了对比不同载体对熔铸炸药悬浮液流变特性的影响,使用Haake MarsⅢ流变仪对TNT、DNAN、DNP的HMX悬浮液的流变性能进行了测试,分析了载体种类、剪切速率、体系温度、固相颗粒含量、颗粒级配对悬浮液流变性能的影响。结果表明,3种载体在熔融态时均为牛顿流体,而其悬浮液均表现出剪切变稀的性质;当温度在95~110℃时,熔融态载体单质的黏度变化均不超过12%;相同温度条件下,载体及其悬浮液表观黏度大小关系为:DNP>TNT>DNAN;当奥克托今(HMX)大小颗粒粒径比约为7、体积比为2时,3种载体悬浮液的表观黏度均为最低;将相对黏度和相对固含量的关系用Krieger-Dougherty函数进行拟合,结果表明3种载体均能较好地适用该模型,待拟合指数与熔铸载体的黏度和剪切速率均呈负相关。 展开更多
关键词 物理化学 熔铸炸药载体 表观黏度 流变特性 颗粒级配 krieger-dougherty模型
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HTPE推进剂药浆粘流性能及其影响因素研究 被引量:3
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作者 那青 姚维尚 +4 位作者 夏敏 郭涛 张铭浩 祁振宇 罗运军 《兵器装备工程学报》 CSCD 北大核心 2022年第6期1-6,共6页
为获得HTPE推进剂药浆中固体填料对粘流性能的影响,研究了固体填料的体积分数、粒径对药浆粘度的影响,利用Krieger-Dougherty粘度方程得到HTPE与填料体积分数的关系,分析了填料尺寸和粒度级配对药浆粘度与粘度方程的影响,并得到填料表... 为获得HTPE推进剂药浆中固体填料对粘流性能的影响,研究了固体填料的体积分数、粒径对药浆粘度的影响,利用Krieger-Dougherty粘度方程得到HTPE与填料体积分数的关系,分析了填料尺寸和粒度级配对药浆粘度与粘度方程的影响,并得到填料表面吸附层厚度的计算方法优化了粘度方程。结果表明,填料表面对HTPE的吸附和填料在HTPE中的分布,是填料粒径变化对HTPE推进剂药浆的粘度产生影响的原因,表面吸附造成粘度上升,颗粒分布对粘度η的影响取决于分散相在连续相内的最大体积分数Φ_(m)的大小,Φ_(m)越大药浆粘流性能越好;填料平均粒径较小或存在粒度级配时有利于提高HTPE中填料的填充上限,AP-Ⅲ/Al-3^(#)/HTPE体系的Φ_(m)=0.69,适合在固体推进剂中用于粒度级配。 展开更多
关键词 HTPE krieger-dougherty 粘度 表面吸附 固含量 颗粒级配
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Effect of Particle Phase Volume, Shape and Liquid Phase Concentrations on Rheological Properties of Large Particulate-Liquid Model Food Systems by Using Ball Measuring System
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作者 Chlharu Inoue Peter Versluis Pablo Coronel Johanna Maria Martina Elberse 《Journal of Chemistry and Chemical Engineering》 2013年第7期643-652,共10页
Rheological properties of large particulate-liquid model food systems were studied by using the BMS (ball measuring system). The model food systems were composed of alginate gel particles (-10mm) and a gelatinised... Rheological properties of large particulate-liquid model food systems were studied by using the BMS (ball measuring system). The model food systems were composed of alginate gel particles (-10mm) and a gelatinised starch solution with 1% w/w sodium chloride as a liquid phase. The effects of particle phase volume (Ф, 0-0.60), particle shapes (cube, sphere, rod and disc) and starch concentrations (3% and 5% w/w starch) were investigated. The power law model was successfully applied to characterize the flow properties of each system and the consistency K and power law index n were obtained. The K increased and n decreased with increasing # for samples at all particle shapes at 3% w/w starch in the liquid phase. The particle effect on the viscosity is further analysed by means of the Krieger-Dougherty model and the maximum packing fraction #,, and the intrinsic viscosity [η] were obtained in each system. The Фm, depended on the particle shape, as expected. The [7] value depended on particle shape and was largely in the order of 4.04 (cube), 3.28 (disc), 2.56 (sphere) and 2.32 (rod) at 3% w/w starch. The [η] also depended on starch concentration and was 1.1 at 5%,6 w/w starch in the liquid phase with spherical particles. The present results show successful application of BMS to study the rheological properties of large particulate liquid food systems at relatively small scale experiment (-0.5 L) and also that existing models for suspension rheology are applicable for such food systems to a great extend. 展开更多
关键词 Large particulate-liquid model food flow property ball measuring system power law model krieger-dougherty model.
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