The laminar combustion characteristics of CH_(4)/air premixed flames with CO_(2) addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed ...The laminar combustion characteristics of CH_(4)/air premixed flames with CO_(2) addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed in CH_(4)/CO_(2)/Air flames with various CO_(2) doping ratio under equivalence ratios of 1.0–1.4.GRI 3.0 mech and Aramco mech are employed for predicting LBV,adiabatic flame temperature(AFT),important intermediate radicals(CH_(3),H,OH,O)and NO_(x) emissions(NO,NO_(2),N2O),as well as the sensitivity analysis is also conducted.The detail analysis of experiment and simulation reveals that as the CO_(2) addition increases from 0%to 40%,the LBVs and AFTs decrease monotonously.Under the same CO_(2) doping ratio,the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio,and the maximum of LBV is reached at equivalence ratio of 1.05.The mole fraction tendency of important intermediates and NO_(x) with equivalence ratio and CO_(2) doping ratio are similar to the LBVs and AFTs.Reaction H+O_(2)⇔O+OH is found to be responsible for the promotion of the generation of important intermediates and NO_(x) under the equivalence ratios and CO_(2) addition through sensitivity analysis.The sensitivity coefficients of elementary reactions that the increasing of CO_(2) doping ratio promotes or inhibits formation of intermediate radicals and NO_(x) decreases.展开更多
A small cubic closed vessel with schlieren measurement technique combined with high-speed video camera were used to study limit flame properties under microgravity conditions at atmospheric pressure and room temperatu...A small cubic closed vessel with schlieren measurement technique combined with high-speed video camera were used to study limit flame properties under microgravity conditions at atmospheric pressure and room temperature.The rich flammability limit of C3H8/air was determined to be 9.2% C3H8.Stretched flame propagation speeds,stretched laminar burning velocities and unstretched laminar burning velocities near rich C3H8/air flammability limits were measured at different equivalence ratios.Outwardly propagating spherical flames were used to study the sensitivities of the flame propagation speeds and laminar burning velocities to flame stretch using Markstein lengths.Unstretched laminar burning velocity at rich flammability limit was determined to be 1.09cm/s.Lewis numbers were less than unity in rich C3H8/air and negative Markstein lengths were concluded.Absolute values of Markstein lengths were found to decrease linearly with equivalence ratios increase.展开更多
Ammonia utilisation in internal combustion engines has attracted wide interest due to the current trend toward decarbonisation,as ammonia is a zero-carbon fuel with different combustion properties to hydrocarbons.The ...Ammonia utilisation in internal combustion engines has attracted wide interest due to the current trend toward decarbonisation,as ammonia is a zero-carbon fuel with different combustion properties to hydrocarbons.The laminar burning velocity(LBV)is a fundamental property of fuels with a significant effect on the combustion processes and accurate calculations and measurements of the LBV over a wide range of fuel blends,pressures and flow conditions is a time-consuming,complicated procedure.The main goal of the current study is to predict the LBV of NH_(3)/H_(2)/air mixtures using a hybrid machine learning(ML)approach based on a training dataset consisting of both the experimental LBV values and additional data obtained from numerical simulations with a detailed kinetic model.Initial ML model training data is collected from existing experimental LBV in the literature for NH_(3)/H_(2)/air mixtures.Then,synthetic data is generated using one-dimensional(1D)simulations to reduce data inhomogeneity and increase accuracy of the ML model.In total,24 different ML algorithms are tested to find the best model both for the experimental and the hybrid dataset.The results suggest that both Gaussian Process Regression(GPR)and Neural Networks(NNs)can be utilised to predict LBV of NH_(3)/H_(2)/air mixtures with reasonable accuracy.The hybrid ML model achieved a coefficient of determination of R^(2)=0.998.Finally,hybrid ML model hyperparameters are optimised to achieve a coefficient of determination of R^(2)=0.999.It was also found that ML can speed up LBV computation from 9500 to 27000 times compared to 1D simulations with a reduced mechanism.展开更多
The laminar burning velocity belongs to the fundamental combustion properties of fuels being a measure for their heat release,flame length,as well as reactivity and combustion stability,and thus,may impact the design ...The laminar burning velocity belongs to the fundamental combustion properties of fuels being a measure for their heat release,flame length,as well as reactivity and combustion stability,and thus,may impact the design of burners and combustion chambers.Also,these experimental data are needed for the validation and optimization within the construction and development of detailed chemical kinetic reaction mechanisms.Within this study,an overview of the different applications of fuel characterization regarding the specific area of interest(road transport,aviation,and aerospace)will be given.Depending on the application,effects of different molecular characteristics on the laminar burning velocity are evaluated:the presence of oxygen atoms and the grade of branching in a specific fuel molecule as well as the difference in the type of a chemical bond,here,single and double bonds.Examples of alternative fuels being discussed in the present study are:(Ⅰ)oxymethylene ether(OMEn)in the field of road transport;(Ⅱ)a paraffinic Alcohol-to-Jet fuel as sustainable aviation fuel;and(Ⅲ)mixtures of ethane or ethene with nitrous oxide as green propellants for rocket propulsion applications.展开更多
The combustion of ammonia(NH3)has attracted wide interest in fuel vehicle engines,marine engines,and power generators to mitigate carbon dioxide emissions.Unfortunately,the relatively low laminar flame speed presents ...The combustion of ammonia(NH3)has attracted wide interest in fuel vehicle engines,marine engines,and power generators to mitigate carbon dioxide emissions.Unfortunately,the relatively low laminar flame speed presents a technical barrier for this renewable fuel to be used in practice.This work is concerned with numerical examining the effects of elevating inlet temperature on the laminar burning velocity of NH3/air flames with various contents of dimethyl ether(DME)using ID freely propagating flame calculations,and to shed light on the flame enhancement mechanism.For this,the mechanism is first validated by comparing the numerical predictions with experimental data.Results show that increasing the inlet temperature has a positive effect on the laminar burning velocity of pure NH3/DME/air flames.It is revealed that elevating inlet temperature contributes to a higher adiabatic flame temperature,which is beneficial to the overall chemical reaction rate.Furthermore,the thermal diffusivity of the binary mixture is observed to increase substantially as well.Further kinetic and sensitivities analyses reveal that the inlet temperature has a minimal effect on the reaction pathway,leading to the relative importance of the dominant chain branching over terminating reaction steps to be varied negligibly.The present work confirms that the flame speed enhancement with increasing inlet temperature is primarily the synergetic result of the thermal and diffusion effects,rather than the chemical effect.展开更多
基金The authors would like to thank the National Natural Science Foundation of China(52176095)Anhui Provincial Natural Science Foundation(2008085J25)the Project of support program for outstanding young people in Colleges and Universities(gxyqZD201830)for their financial support of this study.
文摘The laminar combustion characteristics of CH_(4)/air premixed flames with CO_(2) addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed in CH_(4)/CO_(2)/Air flames with various CO_(2) doping ratio under equivalence ratios of 1.0–1.4.GRI 3.0 mech and Aramco mech are employed for predicting LBV,adiabatic flame temperature(AFT),important intermediate radicals(CH_(3),H,OH,O)and NO_(x) emissions(NO,NO_(2),N2O),as well as the sensitivity analysis is also conducted.The detail analysis of experiment and simulation reveals that as the CO_(2) addition increases from 0%to 40%,the LBVs and AFTs decrease monotonously.Under the same CO_(2) doping ratio,the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio,and the maximum of LBV is reached at equivalence ratio of 1.05.The mole fraction tendency of important intermediates and NO_(x) with equivalence ratio and CO_(2) doping ratio are similar to the LBVs and AFTs.Reaction H+O_(2)⇔O+OH is found to be responsible for the promotion of the generation of important intermediates and NO_(x) under the equivalence ratios and CO_(2) addition through sensitivity analysis.The sensitivity coefficients of elementary reactions that the increasing of CO_(2) doping ratio promotes or inhibits formation of intermediate radicals and NO_(x) decreases.
基金Supported by the Research Foundation of Beijing Institute of Technology(20070242004)
文摘A small cubic closed vessel with schlieren measurement technique combined with high-speed video camera were used to study limit flame properties under microgravity conditions at atmospheric pressure and room temperature.The rich flammability limit of C3H8/air was determined to be 9.2% C3H8.Stretched flame propagation speeds,stretched laminar burning velocities and unstretched laminar burning velocities near rich C3H8/air flammability limits were measured at different equivalence ratios.Outwardly propagating spherical flames were used to study the sensitivities of the flame propagation speeds and laminar burning velocities to flame stretch using Markstein lengths.Unstretched laminar burning velocity at rich flammability limit was determined to be 1.09cm/s.Lewis numbers were less than unity in rich C3H8/air and negative Markstein lengths were concluded.Absolute values of Markstein lengths were found to decrease linearly with equivalence ratios increase.
文摘Ammonia utilisation in internal combustion engines has attracted wide interest due to the current trend toward decarbonisation,as ammonia is a zero-carbon fuel with different combustion properties to hydrocarbons.The laminar burning velocity(LBV)is a fundamental property of fuels with a significant effect on the combustion processes and accurate calculations and measurements of the LBV over a wide range of fuel blends,pressures and flow conditions is a time-consuming,complicated procedure.The main goal of the current study is to predict the LBV of NH_(3)/H_(2)/air mixtures using a hybrid machine learning(ML)approach based on a training dataset consisting of both the experimental LBV values and additional data obtained from numerical simulations with a detailed kinetic model.Initial ML model training data is collected from existing experimental LBV in the literature for NH_(3)/H_(2)/air mixtures.Then,synthetic data is generated using one-dimensional(1D)simulations to reduce data inhomogeneity and increase accuracy of the ML model.In total,24 different ML algorithms are tested to find the best model both for the experimental and the hybrid dataset.The results suggest that both Gaussian Process Regression(GPR)and Neural Networks(NNs)can be utilised to predict LBV of NH_(3)/H_(2)/air mixtures with reasonable accuracy.The hybrid ML model achieved a coefficient of determination of R^(2)=0.998.Finally,hybrid ML model hyperparameters are optimised to achieve a coefficient of determination of R^(2)=0.999.It was also found that ML can speed up LBV computation from 9500 to 27000 times compared to 1D simulations with a reduced mechanism.
文摘The laminar burning velocity belongs to the fundamental combustion properties of fuels being a measure for their heat release,flame length,as well as reactivity and combustion stability,and thus,may impact the design of burners and combustion chambers.Also,these experimental data are needed for the validation and optimization within the construction and development of detailed chemical kinetic reaction mechanisms.Within this study,an overview of the different applications of fuel characterization regarding the specific area of interest(road transport,aviation,and aerospace)will be given.Depending on the application,effects of different molecular characteristics on the laminar burning velocity are evaluated:the presence of oxygen atoms and the grade of branching in a specific fuel molecule as well as the difference in the type of a chemical bond,here,single and double bonds.Examples of alternative fuels being discussed in the present study are:(Ⅰ)oxymethylene ether(OMEn)in the field of road transport;(Ⅱ)a paraffinic Alcohol-to-Jet fuel as sustainable aviation fuel;and(Ⅲ)mixtures of ethane or ethene with nitrous oxide as green propellants for rocket propulsion applications.
基金We gratefully acknowledge the financial support provided by the University of Canterbury,New Zealand(grant no.CPS20-03-002,grant no.452DISDZ)National Research Foundation Singapore(grant no.NRF2016 NRF-NSFC001-102)Tao Cai would like to thank College of Engineering,University of Canterbury for providing PhD studentship.
文摘The combustion of ammonia(NH3)has attracted wide interest in fuel vehicle engines,marine engines,and power generators to mitigate carbon dioxide emissions.Unfortunately,the relatively low laminar flame speed presents a technical barrier for this renewable fuel to be used in practice.This work is concerned with numerical examining the effects of elevating inlet temperature on the laminar burning velocity of NH3/air flames with various contents of dimethyl ether(DME)using ID freely propagating flame calculations,and to shed light on the flame enhancement mechanism.For this,the mechanism is first validated by comparing the numerical predictions with experimental data.Results show that increasing the inlet temperature has a positive effect on the laminar burning velocity of pure NH3/DME/air flames.It is revealed that elevating inlet temperature contributes to a higher adiabatic flame temperature,which is beneficial to the overall chemical reaction rate.Furthermore,the thermal diffusivity of the binary mixture is observed to increase substantially as well.Further kinetic and sensitivities analyses reveal that the inlet temperature has a minimal effect on the reaction pathway,leading to the relative importance of the dominant chain branching over terminating reaction steps to be varied negligibly.The present work confirms that the flame speed enhancement with increasing inlet temperature is primarily the synergetic result of the thermal and diffusion effects,rather than the chemical effect.
