Thin polymer electrolyte with MXene functional layer for uniform Li^(+) deposition in all-solid-state lithium battery

Solid polymer electrolyte(SPE) shows great potential for all-solid-state batteries because of the inherent safety and flexibility;however, the unfavourable Li+deposition and large thickness hamper its development and application. Herein, a laminar MXene functional layer-thin SPE layer-cathode integration(MXene-PEO-LFP) is designed and fabricated. The MXene functional layer formed by stacking rigid MXene nanosheets imparts higher compressive strength relative to PEO electrolyte layer. And the abundant negatively-charged groups on MXene functional layer effectively repel anions and attract cations to adjust the charge distribution behavior at electrolyte–anode interface. Furthermore,the functional layer with rich lithiophilic groups and outstanding electronic conductivity results in low Li nucleation overpotential and nucleation energy barrier. In consequence, the cell assembled with MXene-PEO-LFP, where the PEO electrolyte layer is only 12 μm, much thinner than most solid electrolytes, exhibits uniform, dendrite-free Li+deposition and excellent cycling stability. High capacity(142.8 mAh g-1), stable operation of 140 cycles(capacity decay per cycle, 0.065%), and low polarization potential(0.5 C) are obtained in this Li|MXene-PEO-LFP cell,which is superior to most PEO-based electrolytes under identical condition. This integrated design may provide a strategy for the large-scale application of thin polymer electrolytes in all-solid-state battery.

Study of hybrid nanofluid flow in a stationary cone-disk system with temperature-dependent fluid properties

Cone-disk systems find frequent use such as conical diffusers,medical devices,various rheometric,and viscosimetry applications.In this study,we investigate the three-dimensional flow of a water-based Ag-Mg O hybrid nanofluid in a static cone-disk system while considering temperature-dependent fluid properties.How the variable fluid properties affect the dynamics and heat transfer features is studied by Reynolds's linearized model for variable viscosity and Chiam's model for variable thermal conductivity.The single-phase nanofluid model is utilized to describe convective heat transfer in hybrid nanofluids,incorporating the experimental data.This model is developed as a coupled system of convective-diffusion equations,encompassing the conservation of momentum and the conservation of thermal energy,in conjunction with an incompressibility condition.A self-similar model is developed by the Lie-group scaling transformations,and the subsequent self-similar equations are then solved numerically.The influence of variable fluid parameters on both swirling and non-swirling flow cases is analyzed.Additionally,the Nusselt number for the disk surface is calculated.It is found that an increase in the temperature-dependent viscosity parameter enhances heat transfer characteristics in the static cone-disk system,while the thermal conductivity parameter has the opposite effect.

Discovery of nano organo-clay complex pore-fractures in shale and its scientific significance:A case study of Cretaceous Qingshankou Formation shale,Songliao Basin,NE China

A new pore type,nano-scale organo-clay complex pore-fracture was first discovered based on argon ion polishing-field emission scanning electron microscopy,energy dispersive spectroscopy and three-dimensional reconstruction by focused ion-scanning electron in combination with analysis of TOC,R_(o)values,X-ray diffraction etc.in the Cretaceous Qingshankou Formation shale in the Songliao Basin,NE China.Such pore characteristics and evolution study show that:(1)Organo-clay complex pore-fractures are developed in the shale matrix and in the form of spongy and reticular aggregates.Different from circular or oval organic pores discovered in other shales,a single organo-clay complex pore is square,rectangular,rhombic or slaty,with the pore diameter generally less than 200 nm.(2)With thermal maturity increasing,the elements(C,Si,Al,O,Mg,Fe,etc.)in organo-clay complex change accordingly,showing that organic matter shrinkage due to hydrocarbon generation and clay mineral transformation both affect organo-clay complex pore-fracture formation.(3)At high thermal maturity,the Qingshankou Formation shale is dominated by nano-scale organo-clay complex pore-fractures with the percentage reaching more than 70%of total pore space.The spatial connectivity of organo-clay complex pore-fractures is significantly better than that of organic pores.It is suggested that organo-complex pore-fractures are the main pore space of laminar shale at high thermal maturity and are the main oil and gas accumulation space in the core area of continental shale oil.The discovery of nano-scale organo-clay complex pore-fractures changes the conventional view that inorganic pores are the main reservoir space and has scientific significance for the study of shale oil formation and accumulation laws.

Hardening mechanism and thermal-solid coupling model of laminar plasma surface hardening of 65 Mn steel

In the present work,the laminar plasma surface hardening method is employed to enhance the service life of metal components fabricated from 65 Mn steel.The mechanical and wear behaviors of the laminar plasma surface hardened 65 Mn steel were analyzed.The martensite transition transformation of the temperature of the laminar plasma-hardened 65 ferrite Mn steel was determined by a thermal-solid coupling model.Based on the orthogonal experimental results,the optimal hardening parameters were confirmed.The scanning velocity,quenching distance and arc current are 130 mm/min,50 mm and 120 A,respectively.The pearlites and ferrites are transformed into martensites in the hardened zone,while the ratio of martensite in the heataffected zone decreases with the increase in the hardening depth.Compared to the untreated 65Mn steel,the average hardness increases from 220 HV_(0.2)to 920 HV_(0.2)in the hardened zone and the corresponding absorbed power increases from 118.7 J to 175.5 J.At the same time,the average coefficient of friction(COF)decreases from 0.763 to 0.546,and the wear rate decreases from 5.39×10^(-6)mm^(3)/(N·m)to 2.95×10^(-6)mm^(3)/(N·m),indicating that the wear resistance of 65Mn steel could be significantly improved by using laminar surface hardening.With the same hardening parameters,the depth and width of the hardened zone predicted by the thermal-solid coupling model are 1.85 mm and 11.20 mm,respectively,which are in accordance with the experimental results;depth is 1.83 mm and width is 11.15 mm.In addition,the predicted hardness distributions of the simulation model are in accordance with the experimental results.These results indicate that the simulation model could effectively predict the microstructure characteristics of 65 Mn steel.

Flow Control with Intermittent Disturbance for the Laminar Separation Bubble on a NACA633-421 Airfoil

This study investigates the aerodynamic performance of the NACA 633-421 airfoil and the effectiveness and feasibility of intermittent disturbance flow control methods on laminar separation bubbles(LSBs).It is found that the average velocity and influence range of the synthetic jet actuator increase with the increasing of driving frequency and driving amplitude.LSB occurs at Re=1.0×10^(5),and ruptures atα=6°.But with intermittent disturbance control,the stall angle of attack(AoA)increases while significantly reducing drag.Research shows that although certain disturbance cannot fully recover from LSB stall,decreasing driving amplitude partially restores wing aerodynamic performance,more effectively than increasing driving amplitude.

Numerical Analysis of Explosion Characteristics of Vent Gas From 18650 LiFePO_(4) Batteries With Different States of Charge

The combustion and explosion characteristics of lithium-ion battery vent gas is a key factor in determining the fire hazard of lithium-ion batteries.Investigating the combustion and explosion hazards of lithium-ion batteries vent gas can provide guidance for rescue and protection in explosion accidents in energy storage stations and new energy vehicles,thereby promoting the application and development of lithium-ion batteries.Based on this understanding and combined with previous research on gas production from lithium-ion batteries,this article conducted a study on the combustion and explosion risks of vent gas from thermal runaway of 18650 LFP batteries with different states of charge(SOCs).The explosion limit of mixed gases affected by carbon dioxide inert gas is calculated through the“elimination”method,and the Chemkin-Pro software is used to numerically simulate the laminar flame speed and adiabatic flame temperature of the battery vent gas.And the concentration of free radicals and sensitivity coefficients of major elementary reactions in the system are analyzed to comprehensively evaluate the combustion explosion hazard of battery vent gas.The study found that the 100%SOC battery has the lowest explosion limit of the vent gas.The inhibitory elementary reaction sensitivity coefficient in the reaction system is lower and the concentration of free radicals is higher.Therefore,it has the maximum laminar flame speed and adiabatic flame temperature.The combustion and explosion hazard of battery vent gas increases with the increase of SOC,and the risk of explosion is the greatest and most harmful when SOC reaches 100%.However,the related hazards decrease to varying degrees with overcharging of the battery.This article provides a feasible method for analyzing the combustion mechanism of vent gas from lithium-ion batteries,revealing the impact of SOC on the hazardousness of battery vent gas.It provides references for the safety of storage and transportation of lithium-ion batteries,safety protection of energy storage stations,and the selection of related fire extinguishing agents.

Numerical Predictions of Laminar Forced Convection Heat Transfer with and without Buoyancy Effects from an Isothermal Horizontal Flat Plate to Supercritical Nitrogen

Numerical predictions are made for Laminar Forced convection heat transfer with and without buoyancy effects for Supercritical Nitrogen flowing over an isothermal horizontal flat plate with a heated surface facing downwards.Computations are performed by varying the value ofΔT from5 to 30 K and P_(∞)/P_(cr)ratio from1.1 to 1.5.Variation of all the thermophysical properties of supercritical Nitrogen is considered.The wall temperatures are chosen in such a way that two values of Tw are less than T∗(T*is the temperature at which the fluid has a maximum value of Cp for the given pressure),one value equal to T∗and two values greater than T∗.Three different values of U∞are used to obtain Re∞range of 3.6×10_(4)to 4.74×10^(5)for forced convection without buoyancy effects and Gr_(∞)/Re^(2)_(∞)range of 0.011 to 3.107 for the case where buoyancy effects are predominant.Six different forms of correlations are proposed based on numerical predictions and are compared with actual numerical predictions.It has been found that in all six forms of correlations,the maximum deviations are found to occur in those cases where the pseudocritical temperature TT∗lies between the wall temperature and bulk fluid temperature.

Phase-field simulations of forced flow effect on dendritic growth perpendicular to flow

The effect of supercooled melt forced laminar flow at low Reynolds Number on dendritic growth perpendicular to melt flow direction was investigated with the phase-field method by incorporating melt convection and thermal noise under non-isothermal condition. By taking the dendritic growth of high pure succinonitrile （SCN） supercooled melt as an example, side-branching shape difference of melts with flow and without flow was analyzed. Relationships among supercooled melt inflow velocity, deflexion angle of dendritic arm and dendritic tip growth velocity were studied. Results show that the melt inflow velocity has few effects on the dendritic tip growth velocity. A formula of relationship between the velocity of the melt in front of primary dendritic tip and the dendritic growth time was deduced, and the calculated result was in quantitative agreement with the simulation result.

Kinetics of cerium(Ⅳ) and fluoride extraction from sulfuric solutions using bifunctional ionic liquid extractant(Bif-ILE)[A336][P204]

The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.

同步辐射Laminar光栅的研制

采用全息离子束刻蚀和反应离子刻蚀相结合的新工艺 ,在熔石英基片上成功地刻蚀出 2 0 0l/mm、线空比 4:6、槽深 70nm、刻划面积 60× 2 0mm2 的浅槽矩形Laminar光栅。对改进光栅线条粗糙度和线空比的方法进行了系统的研究。这一新工艺相对简单 。

Rod-pinch二极管理论及数值模拟

介绍了Rod-pinch二极管的基本结构和工作原理,采用Laminar模型分析了Rod-pinch二极管中的粒子运动过程及其阻抗特性。考虑背景空间离子电荷的影响,用1维Laminar方程分析Rod-pinch二极管中电子的自箍缩过程,并且利用Magic程序对其中的粒子运动进行数值模拟,求解二极管中的电压和电流,最终得出二极管的阻抗特性,在较低电压下,负极性RPD的性能明显不如正极性RPD。根据临界电流经验公式,初步验证Laminar理论模型的可行性。

Fabrication of superaligned carbon nanotubes reinforced copper matrix laminar composite by electrodeposition

A new kind of laminar metal matrix nanocomposite（MMC） was fabricated by an electrodeposition process with copper and superaligned carbon nanotubes film（SACNT film）.The SACNT film was put on a titanium plate and then a layer of copper was electrodeposited on it.By repeating the above process,the laminar Cu/SACNT composite which contains dozens or hundreds of layers of copper and SACNT films was obtained.The thickness of a single copper layer was controlled by adjusting the process parameter easily and the thinnest layer is less than 2 μm.The microscopic observation shows that the directional alignment structure of SACNT is retained in the composite perfectly.The mechanical and electrical properties testing results show that the tensile and yield strengths of composites are improved obviously compared with those of pure copper,and the high conductivity is retained.This technology is a potential method to make applicable MMC which characterizes high volume fraction and directional alignment of carbon nanotubes.

Phase-field simulation of forced flow effect on random preferred growth direction of multiple grains

The random distribution problem of dendrite preferred growth direction was settled by random grid method.This method was used to study the influence of forced laminar flow effect on multiple grains during solidification.Taking high pure succinonitrile （SCN） undercooled melt as an example,the forced laminar flow effect on multiple grains was studied by phase-field model of single grain which coupled with flow equations at non-isothermal condition.The simulation results show that the random grid method can reasonably settle the problem of random distribution and is more effective.When the solid fraction is relatively low,melt particles flow around the downstream side of dendrite,and the flow velocity between two dendrite arms becomes high.At the stage of solidification time less than 1800Δt,every dendrite grows freely;the upstream dendrites are stronger than the downstream ones.The higher the melt flow rate,the higher the solid fraction.However,when the solid fraction is relatively high,the dendrite arm intertwins and only a little residual melt which is not encapsulated can flow;the solid fraction will gradually tend to equal to solid fraction of melt without flow.

Analytical Solution for Laminar Viscous Flow inthe Gap Between Two Parallel Rotary Disks

Aim To get the analytical for laminar viscous flow in the gap of two parallel rotating disks. Methods By estimating the order of magnitude of each term in the Navier-Stokes equations to drop small terms and achieve the required simplified differential equations, and by integrating the equations to obtain the solution for theflow between two rotary disks. Results Parameters related to the laminar viscous flow in the gap between two parallel rotary disks, such as the velocity, the pressure, the flowrate, the force, the shearing stress, the torque and the power derived. Conclusion The result provides a theoretical basis and an effective method for the designs of the devices connected with the laminar viscous flow in the gap between two parallel rotary disks.

用于高压无气喷涂原子灰的扇形喷嘴内部流场的数值仿真

利用计算流体软件ANSYS Fluent构建固瑞克645扇形喷嘴三维有限元模型,然后用Laminar层流模型对高压无气喷涂原子灰扇形喷嘴内的压力、速度流场以及入口压力对压力、速度流场和出口流量的影响进行数值模拟.结果表明:压力和速度场云图呈层状分布、梯度变化;在喷嘴的锥形前段和圆柱部分,压力和速度随距离的变化平缓;在圆锥向圆柱过渡段和出口段压力和速度变化剧烈;总体来看,入口压力越大,出口速度和流量越大;在出口段,入口压力对压力流场和速度流场影响尤为明显.根据结果综合分析,入口压力在15~20 MPa比较合理.

Experimental Research and Mathematical Model of Drag Torque in Single-plate Wet Clutch

Reduction of drag torque is one of important potentials to improve transmission efficiency.Existing mathematical model of drag torque was not accurate to predict the decrease after oil film shrinking because of the difficulty in modeling the flow pattern between two plates.Flow pattern was considered as laminar flow and full oil film in the gap between two plates in traditional model.Subsequent equivalent circumferential degree model presented an improvement in oil film shrinking due to centrifugal force,but was also based on full oil film in the gap,which resulted difference between model prediction and experimental data.The objective of this paper is to develop an accurate mathematical model for the above problem by using experimental verification.An experimental apparatus was set up to test drag torque of disengaged wet clutch consisting of single friction and separate plate.A high speed camera was used to record the flow pattern through transparent quartz disk plate.The visualization of flow pattern in the clearance was investigated to evaluate the characteristics of oil film shrinking.Visual test results reveal that the oil film begins to shrink from outer radius to inner radius at the stationary plate and only flows along the rotating plate after shrinking.Meanwhile,drag torque decreases sharply due to little contact area between the stationary plate and the oil.A three-dimensional Navier-Stokes （N-S） equation based on laminar flow is presented to model the drag torque.Pressure distributions in radial and circumferential directions as well as speed distributions are deduced.The model analysis reveals that the acceleration of flow in radial direction caused by centrifugal force is the key reason for the shrinking at the constant feeding flow rate.An approach to descript flow pattern was presented on the basis of visual observation.The drag torque predicted by the model agrees well with test data for non-grooved wet clutch.The proposed model enhances the precision for predicting drag torque,and lays down a framework on which some subsequent models are developed.

Opti mization and Model of Laminar Cooling Control Systemfor Hot Strip Mills

The structure of laminar cooling control system for hot rolling was introduced and the control mode, cooling strategy, segment tracking and model recalculation were analyzed. The parameters of air/water cooling models were optimized by regressing the data gathering in situ, and satisfactory effect was obtained. The coiling temperature can be controlled within ±15℃.

Self-Learning and Its Application to Laminar Cooling Model of Hot Rolled Strip

The mathematical model for online controlling hot rolled steel cooling on run-out table （ROT for abbreviation） was analyzed, and water cooling is found to be the main cooling mode for hot rolled steel. The calculation of the drop in strip temperature by both water cooling and air cooling is summed up to obtain the change of heat transfer coefficient. It is found that the learning coefficient of heat transfer coefficient is the kernel coefficient of coiler temperature control （CTC） model tuning. To decrease the deviation between the calculated steel temperature and the measured one at coiler entrance, a laminar cooling control self-learning strategy is used. Using the data acquired in the field, the results of the self-learning model used in the field were analyzed. The analyzed results show that the self-learning function is effective.

Simulation of Rolling Billet in Oval Pass by Explicit Dynamics Elastic-Plastic FEM

Considering the strip speed during controlled laminar cooling on Baosteel 1580 hot strip mill in China, the influence of strip speed fluctuation on coiling temperature control for the tail and “neck” of the strip was analyzed. The optimization strategies were put forward and proved effective in operation.

Physics-informed deep learning for incompressible laminar flows

Physics-informed deep learning has drawn tremendous interest in recent years to solve computational physics problems,whose basic concept is to embed physical laws to constrain/inform neural networks,with the need of less data for training a reliable model.This can be achieved by incorporating the residual of physics equations into the loss function.Through minimizing the loss function,the network could approximate the solution.In this paper,we propose a mixed-variable scheme of physics-informed neural network(PINN)for fluid dynamics and apply it to simulate steady and transient laminar flows at low Reynolds numbers.A parametric study indicates that the mixed-variable scheme can improve the PINN trainability and the solution accuracy.The predicted velocity and pressure fields by the proposed PINN approach are also compared with the reference numerical solutions.Simulation results demonstrate great potential of the proposed PINN for fluid flow simulation with a high accuracy.