The collection of different cations in the A and B sites of ABO3 was explored for the regularity of perovskites phase formability.Here,Sr2？,La3？,and Ce4？are selected as the cations of site A.The site B is considere...The collection of different cations in the A and B sites of ABO3 was explored for the regularity of perovskites phase formability.Here,Sr2？,La3？,and Ce4？are selected as the cations of site A.The site B is considered to be Mn or Co cations.XRD analysis and Fourier transform infrared spectroscopy results confirm the formation of perovskite structure for catalysts in which La3？and Sr2？are considered as the cations of site A.Ceria is detected as the main crystalline phase when Ce4？is selected to be cation of site A.It is found that the octahedral factor（rB/rO） takes the same important role as the tolerance factor to form cubic perovskite.Average crystallite size of the products was calculated by data of the XRD and measured by the TEM analysis.Results of the XRD and TEM studies were supported by the study of the particles size distribution,which was carried out in a particle size analyzer.The perovskite samples were also used for stoichiometric oxidation of carbon monoxide with air.展开更多
The ilmenite welding electrode has advantages of low cost and excellent welding technological properties.However, the welding quality is affected adversely by its poor crack resistance.To solve this problem, 12 kinds ...The ilmenite welding electrode has advantages of low cost and excellent welding technological properties.However, the welding quality is affected adversely by its poor crack resistance.To solve this problem, 12 kinds of rare earths coating formulas were optimized by means of orthogonal test design and curve fitting.Then the powders containing La/Ce O2 were extruded into ilmenite welding electrode through screw-type pressing–scribbling machine.After that, a series of mechanical properties tests were conducted according to national standards.Next, the mechanical properties data were analyzed comprehensively by analyzing variance, boxplot as well as Minitab 3D surface chart.The results show that compared with the formula without rare earth, the deposited metal’s impact toughness,the lower yield strength, the tensile strength, and the hardness are increased by 54.44 %, 9.25 %, 6.37 %, and4.27 %, respectively.In other words, Electrode 6 with the La/Ce O2 amount of 0.5 %/0.1 % in coating has better mechanical properties.展开更多
文摘The collection of different cations in the A and B sites of ABO3 was explored for the regularity of perovskites phase formability.Here,Sr2？,La3？,and Ce4？are selected as the cations of site A.The site B is considered to be Mn or Co cations.XRD analysis and Fourier transform infrared spectroscopy results confirm the formation of perovskite structure for catalysts in which La3？and Sr2？are considered as the cations of site A.Ceria is detected as the main crystalline phase when Ce4？is selected to be cation of site A.It is found that the octahedral factor（rB/rO） takes the same important role as the tolerance factor to form cubic perovskite.Average crystallite size of the products was calculated by data of the XRD and measured by the TEM analysis.Results of the XRD and TEM studies were supported by the study of the particles size distribution,which was carried out in a particle size analyzer.The perovskite samples were also used for stoichiometric oxidation of carbon monoxide with air.
基金financially supported by the National Natural Science Foundation of China (No.51305178)Xuzhou City Science and Technology Plan Project (No.XC12A013)
文摘The ilmenite welding electrode has advantages of low cost and excellent welding technological properties.However, the welding quality is affected adversely by its poor crack resistance.To solve this problem, 12 kinds of rare earths coating formulas were optimized by means of orthogonal test design and curve fitting.Then the powders containing La/Ce O2 were extruded into ilmenite welding electrode through screw-type pressing–scribbling machine.After that, a series of mechanical properties tests were conducted according to national standards.Next, the mechanical properties data were analyzed comprehensively by analyzing variance, boxplot as well as Minitab 3D surface chart.The results show that compared with the formula without rare earth, the deposited metal’s impact toughness,the lower yield strength, the tensile strength, and the hardness are increased by 54.44 %, 9.25 %, 6.37 %, and4.27 %, respectively.In other words, Electrode 6 with the La/Ce O2 amount of 0.5 %/0.1 % in coating has better mechanical properties.
