Phase transition of LaCrO3 and doped-LaCrO3 was studied by DSC, TG and XRD, and thermal expansion during the transition was analyzed. It is found that phase transition of LaCrO3 begins at about 240℃ and ends at about...Phase transition of LaCrO3 and doped-LaCrO3 was studied by DSC, TG and XRD, and thermal expansion during the transition was analyzed. It is found that phase transition of LaCrO3 begins at about 240℃ and ends at about 265 ℃. Temperatures of phase transition rise obviously with increasing Ca^2＋ content. The transition of LaCrO3 and Ca-doped LaCrO3 from orthorhombic to rhombohedral is accompanied with endothermic reaction. No obvious change occurs in mass, but remarkable shrinkage occurs during phase transition.展开更多
The interconnect materials La0.7Ca0.3Cr1-xZnxO3-δ(x=0,0.01,0.03,0.05,0.07) were prepared by a microwave assisted sol-gel auto-ignition process.The crystalline structures of the samples were characterized by X-ray dif...The interconnect materials La0.7Ca0.3Cr1-xZnxO3-δ(x=0,0.01,0.03,0.05,0.07) were prepared by a microwave assisted sol-gel auto-ignition process.The crystalline structures of the samples were characterized by X-ray diffraction(XRD) and the lattice parameters were evaluated with Rietveld method.For Ca-Zn co-doped LaCrO3 with x=0.03,the sintering activity was improved,and the relative density came up to 96.5% for the sample sintered at 1300 oC for 10 h.The electrical conductivity of the samples was increased fr...展开更多
基金Project supported bythe National Natural Science Foundation of China (50362001)
文摘Phase transition of LaCrO3 and doped-LaCrO3 was studied by DSC, TG and XRD, and thermal expansion during the transition was analyzed. It is found that phase transition of LaCrO3 begins at about 240℃ and ends at about 265 ℃. Temperatures of phase transition rise obviously with increasing Ca^2＋ content. The transition of LaCrO3 and Ca-doped LaCrO3 from orthorhombic to rhombohedral is accompanied with endothermic reaction. No obvious change occurs in mass, but remarkable shrinkage occurs during phase transition.
基金supported by the Key Fund of Natural Science for Education Department of Anhui Province,China (KJ2008A150)
文摘The interconnect materials La0.7Ca0.3Cr1-xZnxO3-δ(x=0,0.01,0.03,0.05,0.07) were prepared by a microwave assisted sol-gel auto-ignition process.The crystalline structures of the samples were characterized by X-ray diffraction(XRD) and the lattice parameters were evaluated with Rietveld method.For Ca-Zn co-doped LaCrO3 with x=0.03,the sintering activity was improved,and the relative density came up to 96.5% for the sample sintered at 1300 oC for 10 h.The electrical conductivity of the samples was increased fr...
