Modified Augmented Lagrange Multiplier Methods for Large-Scale Chemical Process Optimization

Chemical process optimization can be described as large-scale nonlinear constrained minimization. The modified augmented Lagrange multiplier methods (MALMM) for large-scale nonlinear constrained minimization are studied in this paper. The Lagrange function contains the penalty terms on equality and inequality constraints and the methods can be applied to solve a series of bound constrained sub-problems instead of a series of unconstrained sub-problems. The steps of the methods are examined in full detail. Numerical experiments are made for a variety of problems, from small to very large-scale, which show the stability and effectiveness of the methods in large-scale problems.

Preparation of Large-Scale Double-Side BDD Electrodes and Their Electrochemical Performances

Boron doped diamond(BDD)performs well in electrochemical oxidation for organic pollutants thanks to its wide electrochemical window and superior chemical stability.We presented a method to obtain well-adherent large-scale BDD/Nb electrode by the modified hot filament chemical vapor deposition system(HFCVD).SiC particles were sand blasted to enhance the adhesion of BDD coating.The BDD coating was then deposited on both sides of Nb which was placed vertically and closely with filament grids on both sides.The BDD/Nb electrodes had no deformation because the thermal deformations of the BDD films on both sides of the Nb substrate conteracted each other during cooling process after deposition.The surface morphology and purity of the BDD/Nb electrode were analyzed by Raman and scanning elestron microscope(SEM)techniques.Scratch test was used to investigate the adhesion of BDD films.The electrochemical performances were measured by cyclic voltammetry test.The BDD electrode at the B/C ratio of 2 000×10^(-6) held a higher oxygen evolution potential thanks to its high sp3 carbon content.Accelerated life test illustrated that the sandblasting pretreatment obviously enhanced the adhesion of BDD coating which resulted in a longer service duration than the un-sandblasted one.

Study on Preparation of Rice Husk Ash with High Specific Surface Area and Its Chemical Reactivity

Preparation of rice husk ash with high specific surface area and chemical reactivity of the product are reported in this paper. The amorphous rice husk ash with high specific surface area of 311 m2·g-1 was produced by heating acid treated rice husk at 700℃ for 4 h. The isotherms of rice husk ash are similar in shape to type Ⅱof Brunaner's classification with mesopores being predominant. The rice husk ash has a high chemical reactivity,especially that pretreated with acid. This chemical reactivity depends on ashing temperature and pretreatment conditions. There is an exponential relation between the specific surface area of rice husk ash and the change in the conductivity of saturated Ca(OH)2 solution with rice husk ash, from which the specific surface area can be known according to the conductivity change.

Evaluating Groundwater Pollution Using Hydrochemical Data: Case Study (Al Wahat Area East of Libya)

Water is one of the most challenging current and future natural resources, which will directly affect the environment and development by the changes in its quantity, quality and regional distribution. However, Water quality is the critical factor that influences human health and irrigation proposer. This work aims to investigate hydrochemical analysis and geochemical processes influencing the groundwater of Al Wahat area (Jalou, Awjla and Jukherra), which is located in central east Libya. Thirty four water samples collected from domestic and agricultural water wells were analyzed and used for conventional classification techniques which were Piper, Durov and Stiff diagrams to evaluate geochemical processes. Cluster analysis was used to identify the water type and ions concentration and distribution. Results show significant increase of dissolved salts, especially Nitrates. Elevated nitrates concentration can be attributed to either the disposal of untreated sewage water from disposal ponds and septic tanks or the infiltration of irrigation water saturated with fertilizing chemicals. Therefore, irrigation wells revealed that suffering from nitrate contamination caused an increase of the chance of nitrate pollution. In addition, contour maps present a sudden increase in the total dissolved salts (TDS) in the northeastern part?coincident with the highest of secondary ions of NO3 content, indicating the infiltration of irrigation water which is responsible partially for the groundwater degradation. Hydrogeochemical facie is NaCl type and enrichment of Na+ and Cl- can be attributed to urban untreated wastewaters and high rate of evapotranspiration. The concentrations of heavy elements such as Zn, Pb, Cu, Cd, Ni and Cr were low and within the WHO ranges.

Chemical characteristics of rainwater in karst rural areas,Guizhou Province, Southwest China

The chemical composition of rainwater has been studied in a karst rural area from September 2012 to August 2013 in Guizhou Province,Southwest China.The results indicated that the VWM value of p H was 5.4,varied from 4.6 to 6.9.Ca^(2+)and NH_4^+were the major cations,and SO_4^(2-)was the dominant anion.Neutralization factors show that the acid was mainly neutralized by Ca^(2+),NH_4^+and Mg^(2+).Investigations of correlation coefficients and enrichment factors revealed that Ca^(2+)and Mg^(2+)were mainly crust origins,and NH_4^+was from agriculture and livestock manure.SO_4^(2-)and NO_3^-were mainly from anthropogenic sources.

Chemical Forms of Selenium in Corn and Rice Grown in a High Selenium Area of China

The chemical forms of selenium were determined in maize grown near Yutangba Village and in rice grown near Haubei village, Exi Prefecture, Enshi county of Hubei Province, China. The maize sample contained 18 ppm and the rice samples an average of 3.6 ppm selenium. After they were ground to obtain a fine flour, this was acid hydrolyzed with hydrochloric acid in an inert atmosphere and the hydrolyzates chromatographed on columns of Dionex DC6A resin. The results indicate that the majority of the selenium is present as selenomethionine in both rice and corn.

Selective Area Growth and Characterization of GaN Nanorods Fabricated by Adjusting the Hydrogen Flow Rate and Growth Temperature with Metal Organic Chemical Vapor Deposition

CaN nanorods are successfully fabricated by adjusting the flow rate ratio of hydrogen （H2）/nitrogen （N2） and growth temperature of the selective area growth （SAG） method with metal organic chemical vapor deposition （MOCVD）. The SAG template is obtained by nanospherical-lens photolithography. It is found that increasing the flow rate of 1-12 will change the CaN crystal shape from pyramid to vertical rod, while increasing the growth temperature will reduce the diameters of GaN rods to nanometer scale. Finally the CaN nanorods with smooth lateral surface and relatively good quality are obtained under the condition that the H2：N2 ratio is 1：1 and the growth temperature is 1030℃. The good crystal quality and orientation of GaN nanorods are confirmed by high resolution transmission electron microscopy. The cathodoluminescence spectrum suggests that the crystal and optical quality is also improved with increasing the temperature.

Urban Chemical Industrial Cluster Area Restructuring and Determinants: A Case Study of a Typical Old Chemical Industry Area Along the Yangtze River, China

China is in a transitional period between urban renewal and industrial change.In this period,the focus has been on the suburbanization of enterprises and land transformation in old industrial areas,particularly areas with chemical industries.A life cycle theoretical framework was established to develop chemical industrial zones in the context of urban expansion and land function conversion.The long-term historical processes and mechanisms that transformed a typical old chemical industry area along the Yangtze River,Yanziji Area of Nanjing City were unveiled and comparatively analyzed.The study found that the entire life cycle of the case study area was formed through the combined action of different influencing factors.Traditional industrial location factors played important roles during the rise and continuity of the chemical industry zone,while unconventional environmental regulations and government policies drove its decline and transformation.In the transformation of the old chemical zone,the renewal and redevelopment of industrial land into higher-value residential land is a key link determining the feasibility of government fund compensation and the circulation of capital.These findings demonstrate that regional control and environmental regulation play crucial roles in determining the location of polluting industries and the renewal of urban industrial areas.This research enhances the understanding of the development history and reconstruction of chemical industry clusters and plots within megacities at a finer geographic scale.

Industrial Arrangement of Large-scale,Non-grid-connected Wind Power Industrial Zones in Coastal Areas of China

Constructing an industrial system for a large-scale,non-grid-connected wind power industry is a key step towards the diverse utilization of wind power.However,wind power exploitation is not only a technical challenge but an industrial problem as well.The objective of this study is to introduce a concept of large-scale,non-grid-connected wind power(LSNGCWP) industrial zones and establish an evaluation model to assess their industrial arrangement.The data of wind energy,industry,nature resources and socio-economy were collected in this study.Using spatial overlay analysis of geographic information system,this study proposes a spatial arrangement of the LSNGCWP indus-trial zones in the coastal areas of China,which could be summarized as the 'one line and three circles' structure,which will contribute to the optimization of the industrial structure,advance the wind power technology,coordinate the multi-industrial cooperation,and upgrade the industrial transformation of China's coastal areas.

Recommendations for Large-scale Farmland Operation in Hilly Areas Based on Long Tail Theory

At the background of urban and rural integration,this paper analyzed and discussed factors restricting large-scale farmland operation in China's hilly areas from the qualitative perspective. It recognized large-scale farmland operation on the basis of the long tail theory. Finally,it came up with recommendations for developing large-scale farmland operation in hilly areas.

Chemical Composition of Sphyraena barracuda with Different Area, Size and Season, in Sudanese Red Sea Coast

This study aims to determine the effect of area, size and season on chemical composition of Sphyraena barracuda from Sudanese Red Sea Coast. A total of 180 fish samples were collected from Port Sudan and Sawakin fishing sites during the winter and summer of 2020-2021. The fishes sample ranged between (30 - 50) cm in total length and (250 - 1000) gm in body weight of small size, and ranged between (60 - 90) cm in total length and (1250 - 250) gm in body weight for large size. Fish flesh was subject to gross chemical analysis. Moisture, protein, fat, ash, acidity and pH were determined. The results indicated a significant effect by area, season and size. The different areas had a significant effect on crude protein and ash;higher parameter value is found in Sawakin. Higher chemical parameters were showed in winter than in summer. Also, size had a significant effect in all parameters (except moisture), fat and ash were high in large size. The study has concluded that the large size fishes of S. barracuda with high nutritional value when caught in winter from the southern region of Sawakin.

Characteristics and chemical reactivity of biogenic volatile organic compounds from dominant forest species in the Jing-Jin-Ji area,China

Background:Biogenic volatile organic compounds(BVOCs)play an essential role in tropospheric atmospheric chemical reactions.There are few studies conducted on BVOCs emission of dominant forest species in the Jing-Jin-Ji area of China.Based on the field survey,forest resources data and the measured standard emission factors,the Guenther model developed in 1993(G93)was applied in this paper to estimate the emission of BVOCs from several dominant forest species(Platycladus orientalis,Quercus variabilis,Betula platyphylla,Populus tomentosa,Pinus tabuliformis,Robinia pseudoacacia,Ulmus pumila,Salix babylonica and Larix gmelinii)in the Jing-Jin-Ji area in 2017.Then the spatiotemporal emission characteristics and atmospheric chemical reactivity of these species were extensively evaluated.Results:The results showed that the total annual BVOCs emission was estimated to be 70.8 Gg C·year^(−1),consisting 40.5%(28.7 Gg C·year^(−1))of isoprene,36.0%(25.5 Gg C·year^(−1))of monoterpenes and 23.4%(16.6 Gg C·year^(−1))of other VOCs.The emissions from Platycladus orientalis,Quercus variabilis,Populus tomentosa and Pinus tabulaeformis contributed 56.1%,41.2%,36.0% and 31.1%,respectively.The total BVOCs emission from the Jing-Jin-Ji area accounted for 61.9% and 1.8%in summer and winter,respectively.Up to 28.8% of emission was detected from Chengde followed by Beijing with 24.9%,that mainly distributed in the Taihang Mountains and the Yanshan Mountains.Additionally,the Robinia pseudoacacia,Populus tomentosa,Quercus variabilis,and Pinus tabulaeformis contributed mainly to BVOCs reaction activity.Conclusions:The BVOCs emission peaked in summer(June,July,and August)and bottomed out in winter(December,January,and February).Chengde contributed the most,followed by Beijing.Platycladus orientalis,Quercus variabilis,Populus tomentosa,Pinus tabulaeformis and Robinia pseudoacacia represent the primary contributors to BVOCs emission and atmospheric reactivity,hence the planting of these species should be reduced.

Solving Multi-Area Environmental/Economic Dispatch by Pareto-Based Chemical-Reaction Optimization Algorithm

In this study, we present a Pareto-based chemicalreaction optimization(PCRO) algorithm for solving the multiarea environmental/economic dispatch optimization problems.Two objectives are minimized simultaneously, i.e., total fuel cost and emission. In the proposed algorithm, each solution is represented by a chemical molecule. A novel encoding mechanism for solving the multi-area environmental/economic dispatch optimization problems is designed to dynamically enhance the performance of the proposed algorithm. Then, an ensemble of effective neighborhood approaches is developed, and a selfadaptive neighborhood structure selection mechanism is also embedded in PCRO to increase the search ability while maintaining population diversity. In addition, a grid-based crowding distance strategy is introduced, which can obviously enable the algorithm to easily converge near the Pareto front. Furthermore,a kinetic-energy-based search procedure is developed to enhance the global search ability. Finally, the proposed algorithm is tested on sets of the instances that are generated based on realistic production. Through the analysis of experimental results, the highly effective performance of the proposed PCRO algorithm is favorably compared with several algorithms, with regards to both solution quality and diversity.

Surface Chemical Properties of Colloids in Main Soils of China

Surface chemical properties of soil colloids are the important factor affecting soil fertility and genesis. To provide scientific basis for soil genetic classification, promotion of soil fertility and reasonable fertilization, the specific surface area and electric charge of soil colloids in relation to clay minerals and organic matter are further discussed on the basis of the results obtained from the studies on surface chemical properties of soil colloids in five main soils of China. Results from the studies show that the effect of clay minerals and organic matter on the surface chemical properties of soil colloids is very complicated because the siloxane surface, hydrated oxide surface and organic matter surface do not exist separately, but they are always mixed together and influenced each other. The understanding of the relationship among clay minerals, organic matter and surface chemical properties of soil colloids depends upon further study of the relevant disciplines of soil science, especially the study on the mechanisms of organo-mineral complexes.

Formation conditions of Neogene large-scale high-abundance lithologic reservoir in the Laibei low uplift,Bohai Sea,East China

By using drilling,high-precision 3 D seismic data,data of geochemistry,logging and testing,the reservoir characteristics and accumulation conditions of the KL6-1 lithologic oilfield in the Laibei Low Uplift in the Bohai Sea are examined comprehensively.The study shows that:KL6-1 oilfield is a monolithic,high-quality,large-scale Neogene lithologic oilfield featuring shallow reservoir depth,high productivity,concentrated oil-bearing intervals,large oil-bearing area,and high reserve abundance;hydrocarbon source supply from two directions provides a sufficient material basis for the formation of large oil field;two types of"inherited structural ridge"developed under the effect of block rotation,late active faults formed by Neotectonic movement,and widely distributed contiguous sand bodies provide an efficient oil and gas transportation system for the large-scale accumulation of oil and gas;contiguous channel and lacustrine lowstand system sand bodies developed in low accommodation condition provide the basic condition for the formation of large-scale lithologic traps;deep formations structural ridge,faults(dominant migration pathways)and large-scale superimposed contiguous sand bodies constitute a"vine type"oil and gas migration and accumulation system in the Laibei Low Uplift,which is conducive to the formation of large-scale and high-abundance lithologic reservoir in this area.The successful discovery of KL6-1,100 million ton reserve order lithologic oil field,has revealed the exploration potential of Neogene large lithologic reservoirs in Bohai Sea,expanded the exploration field,and also has certain reference significance for the exploration of large lithologic reservoirs in similar areas.

Thermodynamic Analysis of Chemical Vapor Deposition of BCl_3-NH_3-SiCl_4-H_2-Ar System

The thermodynamic phase stability area diagrams of BCl3-NH3-Si Cl4-H2-Ar system were plotted via Factsage software to predict the kinetic experimental results. The effects of parameters(i e, partial pressure of reactants, deposition temperature and total pressure) on the distribution regions of solid phase products were analyzed based on the diagrams. The results show that:(a) Solid phase products are mainly affected by deposition temperature. The area of BN+Si3N4 phase increases with the temperature rising from 650 to 900 ℃, and decreases with the temperature rising from 900 to 1 200 ℃;(b) When temperature and total pressure are constants, BN+Si3N4 phase exists at a high partial pressure of NH3;(c) The effect of total system pressure is correlated to deposition temperature. The temperature ranging from 700 to 900 ℃ under low total pressure is the optimum condition for the deposition.(d) Appropriate kinetic parameters can be determined based on the results of thermodynamic calculation. Si–B–N coating is obtained via low pressure chemical vapor deposition. The analysis by X-ray photoelectron spectroscopy indicates that B–N and Si–N are the main chemical bonds of the coating.

Characteristics of Chemical Modified Activated Carbons from Bamboo Scaffolding

In this study, bamboo scaffolding was used to produce activated carbon by carbonization at 600 ℃ and 900 ℃with the purge of nitrogen. The 600 ℃ char was then further modified chemically by acids and alkalis by reflux for 6 hours. The produced chars were then characterized by nitrogen adsorption isotherm, He pyncometry, pH, elemental analysis and Boehm titration. For most of the chemically modified carbons, the micropore surface areas and volumes have increased compared with the 600 ~C char, while the mesopore surface areas and volumes slightly decreased, which may have been due to the dissolving of some of the permeated inorganic matter and oxidizing deposited carbon that blocks the pore openings. For the acidic modified carbons, larger amounts of acidic groups were present in the carbons after being activated by phosphoric acid, phosphoric acid furth, er treated with 2 mol-L-1nitric-acid, and calcium hydroxide. Although carbon treated with 2 mol.L-1 and 5 mol·L-1 nitric acid also produced high acidity, the surface areas and pore volumes were relatively low, due to the destruction of pores by nitric acid oxidation. The reduction of porosity may impair the adsorption capacity.

Analysis of the Engineering Restoration Effect of Abandoned Yongledian Quarry in Beijing City Based on Soil Physical and Chemical Properties

The improvement of the soil physical and chemical properties is the most important foundation for mine ecological restoration.The experiment is aimed at undisturbed area,restored area,and damaged area of abandoned Yongledian Quarry in Beijing.Through determination and analysis of soil physical and chemical properties,it shows that there are significant differences in the composite effects of soil physical and chemical properties between restored area,and undisturbed area,damaged area,and engineering restoration effectively improves the composite effects of soil physical and chemical properties in the restored area.The single factor hypothesis test shows that soil pH value,organic matter,alkali-hydrolyzable nitrogen,and total nitrogen traits are the key targets to be restored in this mining area.

Organic Phosphorus in Shallow Lake Sediments in Middle and Lower Reaches of the Yangtze River Area in China

Thirteen sediment core samples(0-10 cm) were taken from the seven lakes in the middle and lower reaches of the Yangtze River to determine the contents and distributions of organic phosphorus(P) fractions in the sediments of the shallow lakes in the area.The organic P fractions in the sediments were in the order of moderately labile organic P(MLOP) > moderately resistant organic P(MROP) > highly resistant organic P(HROP) > labile organic P(LOP),with average proportional ratios of 13.2:2.8:1.3:1.0.LOP,MLOP,and MROP were significantly related to the contents of total organic carbon(TOC),water-soluble P(WSP),algal-available P(AAP),NaHCO3-extractable P(Olsen-P),total P(TP),organic P(OP),and inorganic P(IP).However,HROP was significantly related to OP and weakly correlated with TOC,WSP,AAP,Olsen-P,TP or IP.This suggested that organic P,especially LOP and MLOP in sediments,deserved even greater attention than IP in regards to lake eutrophication.In terms of organic P,sediments were more hazardous than soils in lake eutrophication.Although OP concentrations were higher in moderately polluted sediment than those in heavily polluted sediment,LOP and MLOP were higher in the heavily polluted sediment,which indicated that heavily polluted sediment was more hazardous than moderately polluted sediment in lake eutrophication.