Narrowband photodetectors as specific spectral sensing pixels have drawn intense attention in multispectral detection due to their distinct characteristic of filter-free spectrum discrimination,in which the emerging h...Narrowband photodetectors as specific spectral sensing pixels have drawn intense attention in multispectral detection due to their distinct characteristic of filter-free spectrum discrimination,in which the emerging halide lead perovskites witness a booming development in their performance and wavelength-selectivity from blue to near-infrared light.However,the challenge in integrating perovskite narrowband photodetectors on one chip imposes an impediment on practical application.In this work,the combination of laser-direct-writing and ion exchange is proposed as an efficient way to fabricate high-definition colorful sensing array with perovskite narrowband photodetector unit as pixel.Under laser irradiation,the photolysis of halocarbon solvent(CHCl_(3),CH_(3)CH_(2)I,etc)releases the halide ions,which brings the ion exchange and gives rise to slow-varying bandgap in single perovskite photoactive film.This ion exchange can be controlled via laser irradiation time and focus point,thus enabling precisely engineerable bandgap.By optimizing the process,it is successfully applied to develop patterned perovskite narrow blue and green photodetectors array with a high-definition of~53 ppi.We believe this result will make a great step forward to integrate multifunctional perovskite devices on one chip,which will pave the way for perovskite optoelectronic device to the commercial application.展开更多
基金supported by the National Natural Science Foundation of China(No.52172146)Natural Science Foundation of Jiangsu Province(Nos.BK20190443 and BK20200071)+7 种基金Shuangchuang Talent of Jiangsu Province(No.JSSCRC2021506)Young Elite Scientists Sponsorship Program by Jiangsu CAST(No.JS19TJGC132574)2019 Overseas Students'Science and Technology Innovation Project Selection Funding of Nanjing,Fundamental Research Funds for the Central Universities(Nos.30919011298,30919011299 and 30919012107)National Key R&D Program of China(No.2017YFA0305500)the National Natural Science Foundation of China(Nos.61725402,11604152,and 51672132)the National“ten thousand talents plan”leading talents(No.W03020394)the Six top talent innovation teams of Jiangsu Province(No.TD-XCL-004)Y.D.and Z.H.conducted all the experiments.Y.D.and X.X.wrote the manuscript.Y.Z.and H.Z.supervised this project.
文摘Narrowband photodetectors as specific spectral sensing pixels have drawn intense attention in multispectral detection due to their distinct characteristic of filter-free spectrum discrimination,in which the emerging halide lead perovskites witness a booming development in their performance and wavelength-selectivity from blue to near-infrared light.However,the challenge in integrating perovskite narrowband photodetectors on one chip imposes an impediment on practical application.In this work,the combination of laser-direct-writing and ion exchange is proposed as an efficient way to fabricate high-definition colorful sensing array with perovskite narrowband photodetector unit as pixel.Under laser irradiation,the photolysis of halocarbon solvent(CHCl_(3),CH_(3)CH_(2)I,etc)releases the halide ions,which brings the ion exchange and gives rise to slow-varying bandgap in single perovskite photoactive film.This ion exchange can be controlled via laser irradiation time and focus point,thus enabling precisely engineerable bandgap.By optimizing the process,it is successfully applied to develop patterned perovskite narrow blue and green photodetectors array with a high-definition of~53 ppi.We believe this result will make a great step forward to integrate multifunctional perovskite devices on one chip,which will pave the way for perovskite optoelectronic device to the commercial application.
