Benzene is a major industrial air pollutant and can cause serious human health disorders. In this paper an investigation on benzene destruction, in an atmospheric-pressure fast-flow pulsed DC-discharge by means of las...Benzene is a major industrial air pollutant and can cause serious human health disorders. In this paper an investigation on benzene destruction, in an atmospheric-pressure fast-flow pulsed DC-discharge by means of laser ionization combined with time-of-flight （TOF） mass spectrometry, is reported. Most by-products including transient reactive species from the benzene discharge were characterized by molecular beam sampling combined with TOF mass spectrometry. It is showed that, with a gas mixture of 0.5% C6H6 in Ar, benzene can be effectively destroyed by discharge plasma. The intermediate species consisted of small fragments of CnHm （n=3-5, m = 1-11）, cycle-chain species of CnHm （n =6-9, m = 7-10） and polycyclic species CnHm （n ≥9, m = 8-12）. The alternation of mass peaks （intensity） with even/odd electrons was observed in the measured mass spectra. The results indicated that the alternation is mainly due to the different ionization potentials of the open shell and close shell species. Based on the examination of the features of the species＇ composition, the primary reaction pathways are proposed and discussed.展开更多
The laser-ion acceleration from the ultra-short and ultra-intense laser-matter interactions attracts more and more interest nowadays. When a laser pulse interacts with a target, relativistic electrons are generated in...The laser-ion acceleration from the ultra-short and ultra-intense laser-matter interactions attracts more and more interest nowadays. When a laser pulse interacts with a target, relativistic electrons are generated in a period of few femtoseconds and driven away by the ponderomotive force, then a huge charge-separation field forms. In general cases, the ion acceleration is determined by this charge-separation field and the scale length of the plasma density. A general time-dependent solution is obtained to describe laser-plasma isothermal expansions into a vacuum, which is the fundamental theory of the laser-ion acceleration. It is adequate for non-quasi-neutral plasmas and different types of the scale length of the density gradient. The previous solutions are some special cases of our general solution. It is found that there exist both a compression layer of the ion velocity distribution and a potential well for sorue initial conditions. However, many unaccounted idiographic solutions, which may be used to reveal new mechanisms of ion acceleration, may be deduced from our general solutions.展开更多
基金supported by National Natural Science Foundation of China (No. 10875023)Scientific and Technical Key Project of Educational Ministry of China (No. 108034)
文摘Benzene is a major industrial air pollutant and can cause serious human health disorders. In this paper an investigation on benzene destruction, in an atmospheric-pressure fast-flow pulsed DC-discharge by means of laser ionization combined with time-of-flight （TOF） mass spectrometry, is reported. Most by-products including transient reactive species from the benzene discharge were characterized by molecular beam sampling combined with TOF mass spectrometry. It is showed that, with a gas mixture of 0.5% C6H6 in Ar, benzene can be effectively destroyed by discharge plasma. The intermediate species consisted of small fragments of CnHm （n=3-5, m = 1-11）, cycle-chain species of CnHm （n =6-9, m = 7-10） and polycyclic species CnHm （n ≥9, m = 8-12）. The alternation of mass peaks （intensity） with even/odd electrons was observed in the measured mass spectra. The results indicated that the alternation is mainly due to the different ionization potentials of the open shell and close shell species. Based on the examination of the features of the species＇ composition, the primary reaction pathways are proposed and discussed.
基金supported by the Key Project of Chinese National Programs for Fundamental Research (973 Program) (No.2006CB806004)National Natural Science Foundation of China (No.10834008)
文摘The laser-ion acceleration from the ultra-short and ultra-intense laser-matter interactions attracts more and more interest nowadays. When a laser pulse interacts with a target, relativistic electrons are generated in a period of few femtoseconds and driven away by the ponderomotive force, then a huge charge-separation field forms. In general cases, the ion acceleration is determined by this charge-separation field and the scale length of the plasma density. A general time-dependent solution is obtained to describe laser-plasma isothermal expansions into a vacuum, which is the fundamental theory of the laser-ion acceleration. It is adequate for non-quasi-neutral plasmas and different types of the scale length of the density gradient. The previous solutions are some special cases of our general solution. It is found that there exist both a compression layer of the ion velocity distribution and a potential well for sorue initial conditions. However, many unaccounted idiographic solutions, which may be used to reveal new mechanisms of ion acceleration, may be deduced from our general solutions.
