Comparative Study between Dielectric Properties and Compaction Parameters: Case Study on Three Laterite Quarries

This work studies the variability of the relationship between relative permittivity and compaction parameters as a function of certain geotechnical properties for different laterite types. This study allows to purpose the dielectric permittivity as a third compaction parameter allowing to obtain a non destructive control méthod. Preliminary studies on Diack laterite had shown a good correlation. Additional investigations are carried out to verify the possibility of generalizing this correlation to three new laterite careers: Ngoudiane, Yéba and Fandene. To proceed, particle size analysis, Atterberg limits, specific weight tests and compaction according to the modified Proctor test were performed on laterite samples. Using the radar method, experimental permittivities are determined for laterite samples by the point method of propagation times and confirmed by the diffraction hyperbole method. The geotechnical and radar data obtained allowed correlations between permittivity and water content on the one hand and between permittivity and dry density on the other. The results show that the maximum dry density as a function of permittivity corresponds with the optimum Proctor, which confirms the results previously obtained on Diack laterite.

Performance evaluation of laterite soil embankment stabilized with bottom ash,coir fiber,and lime

In tropical regions,heavy rainfall induces erosion and shallow landslides on road embankments.Cement-based stabilization methods,common in these regions,contribute to climate change due to their high carbon footprint.This study explored the potential application of coir fiber-reinforced laterite soil-bottom ash mixtures as embankment materials in the tropics.The objective is to enhance engineered embankment slopes'erosion resistance and stability while offering reuse options for industrial byproducts.This study examined various mix designs for unconfined compressive strength(UCS)and permeability,utilizing 30%bottom ash(BA)and 1%coir fiber(CF)with varying sizes ranging from 10 to 40 mm,6%lime,and laterite soil(LS),followed by microstructural analyses.The results demonstrate that the compressive strength increases as the CF length increases to 25 mm.In contrast,permeability increases continuously with increasing CF length.Lime-treated mixtures exhibit superior short-and long-term strength and reduce permeability owing to the formation of cementitious materials,as confirmed by microstructural analyses.A lab-scale slope box was constructed to evaluate the surface erosion of the stabilized laterite soil embankment.Based on the rainfall simulation results,the LS-BA-CF mixtures show better resistance to erosion and deformation compared to untreated LS,especially when lime is added to the top layer.This study provides insights into a sustainable and cost-effective approach for slope stabilization using BA and CF,offering a promising solution for tropical regions susceptible to surface erosion and landslides.

Influence of the Granular Class of Crushed Granites on the Litho-Stabilization of Samo Laterites (South-East of Côte d’Ivoire)

Most of the laterites found in Ivory Coast do not meet the technical conditions to be used in their natural state for the design of road foundations. Also, to meet the growing needs for road materials, various amendments are made to them, including litho-stabilization. Thus, this study proposes to understand the influence of the granular class of natural aggregates on the performance of laterites. To achieve this objective, different proportions of crushed granites of class 0/5, 0/15 and 5/15 have been incorporated into the soils of southern Côte d’Ivoire, especially in Samo. This modified soil has been subjected to mechanical tests such as the modified Proctor and CBR test. The results obtained show that the dry densities of the incorporated laterites containing crushed granites increase with the content of natural aggregates and decrease with the increase in the water content. Likewise, the CBR bearing indices at 95% of the Modified Optimum Proctor of the different compositions (laterites + crushed granites) increase with the proportion of aggregates. The addition of coarse aggregates to the laterites therefore promotes the establishment of a framework which improves its bearing capacity. From 20% to 30% crushed granites respectively of class 0/15;0/5 and 5/15, the values of the CBR obtained are greater than those of 30% therefore these modified soils can be used as a foundation layer for traffic of T1, T2 and T3 type. Likewise, the laterites’ mixtures with at least 40% crushed granites of class 0/15 and 0/5 can also be used for the foundation and base layers.

Relative Dielectric Permittivity Variations during Compaction as a Mean of Compaction Quality Control: Case Study on Laterite Samples from Senegal

This study explores an alternative to the classical use of direct methods, as water content and dry density measurements, for compaction quality control. For this purpose, the dielectric properties of lateritic materials are determined by radar method and are compared with the permittivity determined from the Topp formula and from the CRIM model. This approach allowed to establish a relationship between the geotechnical properties determined during compaction such as dry density, water content or porosity with dielectric permittivity. The obtained results made it possible to determine an optimum dielectric permittivity corresponding to the optimum dry density and the optimum water content that could be used for non-destructive in situ compaction testing. Such an approach should improve the implementation and effectiveness of in situ compaction quality control of geotechnical infrastructures.

Effect of Polyethylene Terephthalate Plastic Waste on the Physico-Mechanical and Thermal Characteristics of Stabilized Laterite Bricks

The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm3 was observed.

Physical Characterization of Laterite for the Formulation of Structural Concrete

This study presents another approach to the use of laterite as a common construction material for the development of a new type of concrete. Laterites are found all over the world and are used in various ways in road construction as sub-base, base course or wear courses. Being a material consisting in the raw state of sand and gravel, the study addresses its use for the formulation of structural concrete. The physical characterization made it possible to identify three granular classes distributed as follows: 28.26% passing at 80 μm, 32.12% sand (0.08/4 mm) and 39.62% nodule (4/25) mm. The absolute density of the aggregates varies from 2.73 and 2.82 from the sand to the nodules. The absorption rate varies from 3.01% and 5.71% respectively for sand and nodules. The granular compactness of the different granular classes studied varies from 0.580 to 0.630. The formulation of the concrete was made by the method of absolute volumes by varying the W/C ratio from 0.4 to 0.7, N/S from 2.2 to 2.8 and that of the cement dosage from 350 to 450 kg/m3. The results obtained show that the density of the concrete formulated based on these aggregates of lateritic origin have a density which varies between 2000 and 2300 kg/m3. With a cement content of 400 kg/m3, a W/C ratio of 0.4 and N/S of 2.8, concrete based on lateritic aggregates offers better mechanical performance in compression of approximately 21.23 ± 1.24 MPa at 28 days. This strength class obtained allows laterite concrete to be used as structural concrete in the structure of civil engineering works.

Leaching behavior of metals from limonitic laterite ore by high pressure acid leaching

The leaching behavior of metals from a nickeliferous limonitic laterite ore was investigated by high pressure acid leaching process for the extraction of nickel and cobalt.The effects of sulfuric acid added,leaching temperature,leaching time and liquid/solid（L/S） ratio on metals extraction were examined.More than 97% Ni,96% Co,93% Mn,95% Mg and less than 1% Fe are extracted under optimum conditions.Analysis of the high pressure acid leaching residue by chemical and XRD analysis indicates that the residual iron and sulfur are mainly present in phases of hematite and alunite,respectively.The high pressure leaching process provides a simple and efficient way for the high recovery of nickel and cobalt from laterite ore,leaving residue as a suitable iron resource.

Mineralogy and crystal chemistry of a low grade nickel laterite ore

To acquire understanding of Ni enrichment from laterite ore,the mineralogy and crystal chemistry of a low grade limonite type nickel laterite ore sample assaying 0.97% Ni from Indonesia were studied using optical microscopy,X-ray diffraction（XRD）,scanning electron microscopy（SEM） and electron probe microanalysis（EPMA）.According to EPMA results,the mineral includes 80% goethite（（Fe,Ni,Al）O（OH）） with 0.87% Ni,15% silicate minerals with lizardite（（Mg,Fe,Ni）3Si2O5（OH）） and olivine（（Mg,Fe,Ni）2SiO4）,and 1.19% Ni,and other minor phases,such as hematite,maghemite,chromite and quartz,and no Ni was detected.The mineralogy of the laterite ore indicates that due to the complicated association of the various phases and the variable distribution of Ni,this refractory laterite ore can not be upgraded by traditional physical beneficiation processes.

Dechromization and dealumination kinetics in process of Na_2CO_3-roasting pretreatment of laterite ores

A novel process was proposed for the activation pretreatment of limonitic laterite ores by Na2CO3 roasting. Dechromization and dealumination kinetics of the laterite ores and the effect of particle size, Na2CO3-ore mass ratio, and roasting temperature on Cr and Al extraction were studied. Experimental results indicate that the extraction rates of Cr and Al are up to 99%and 82%, respectively, under the optimal particle size of 44–74μm, Na2CO3-to-ore mass ratio of 0.6：1, and temperature of 1000 ℃. Dechromization within the range of 600–800 oC is controlled by the diffusion through the product layer with an apparent activation energy of 3.9 kJ/mol, and that it is controlled by the chemical reaction at the surface within the range of 900–1100 ℃ with an apparent activation energy of 54.3 kJ/mol. Besides, the Avrami diffusion controlled model with on apparent activation energy of 16.4 kJ/mol is most applicable for dealumination. Furthermore, 96.8%Ni and 95.6%Co could be extracted from the alkali-roasting residues in the subsequent pressure acid leaching process.

Coal-based reduction mechanism of low-grade laterite ore

A low-grade nickel laterite ore was reduced at different reduction temperatures. The morphology of metallic particles was investigated by scanning electron microscopy （SEM） and energy dispersive spectroscopy （EDS）. Experimental results indicate that the metallic nickel and iron gradually assemble and grow into larger spherical particles with increasing temperature and prolonging time. After reduction, the nickel laterite ore obviously changes into two parts of Fe-Ni metallic particles and slag matrix. An obvious relationship is found between the reduction of iron magnesium olivine and its crystal chemical properties. The nickel and iron oxides are reduced to metallic by reductant, and the lattice of olivine is destroyed. The entire reduction process is comprised of oxide reduction and metallic phase growth.

Thermodynamic of selective reduction of laterite ore by reducing gases

As the sulfide ore deposits become less economical and environmental viable as a source of nickel,increasing attention is being paid to the laterite ores.But in the pyrometallurgical process of laterite,more efforts should be paid to control the reduction of iron oxide in order to get high nickel-content nickeliferous product.For these reasons,equilibrium condition of iron oxide when laterite ore was selectively reduced by CO2/CO,H2O/H2 and CO2/H2 was studied from the perspective of iron activity with an assumption that the activities of Fe O and Fe3O4 equal 1 in this work,and it well accounts for the inescapability of Fe metallization.Activity coefficient of iron in Ni-Fe binary solid alloy was calculated by Miedema model based on the known thermodynamics datum filed.According to Raoult＇s law,the relationship among the Fe/Ni ratio,reduction temperature and reduction gas composition was calculated when laterite ore was selectively reduced by the three different reduction systems.The calculation result was discussed and also compared with the experimental result.The trend of metal iron content in the reduction product of laterite ore varying with temperature and gas composition was well predicted by the calculation result.

Efficient enrichment of nickel and iron in laterite nickel ore by deep reduction and magnetic separation

The process of deep reduction and magnetic separation was proposed to enrich nickel and iron from laterite nickel ores.Results show that nickel-iron concentrates with nickel grade of 6.96%,nickel recovery of 94.06%,iron grade of 34.74%,and iron recovery of 80.44% could be obtained after magnetic separation under the conditions of reduction temperature of 1275℃,reduction time of 50 min,slag basicity of 1.0,carbon-containing coefficient of 2.5,and magnetic field strength of 72 kA/m.Reduction temperature and time affected the possibility of deep reduction and reaction progress.Slag basicity affected the composition of slag in burden and the spilling and enriching rate of nickel-iron from a matrix to form nickel-iron particles.Nickel-iron particles were generated,aggregated,and grew gradually in the reduction process.Nickel-iron particles can be effectively separated from gangue minerals by magnetic separation.

Study on the creep permeability of mining-cracked N2 laterite as the key aquifuge for preserving water resources in Northwestern China

This research focused on the impact of mining on the permeability of key aquifuge （N2 laterite） that is widespread in the arid and semi-arid areas of northwestern China and is critical for preserving water resources. The impact of mining stress recovery on the permeability of cracked N2 laterite was assessed for parts of northwestern China that included the Jingle laterite and Baode laterite. The mineral compositions and swelling properties of the laterite at both locations were examined, and analytical results showed that the laterite contained abundant clay minerals. The Baode laterite exhibited higher expansibility than Jingle laterite. The triaxial creep permeability performance of laterite specimens with a prefabricated crack width of 1.0, 1.5, and 2.5 mm were tested. The results indicated that strain of cracked laterite all exhibited transient creep following each level of loading, and then unstable creep and stable creep. With the increase of loading, the transient creep deformation corresponding to each level of loading decreased, the unstable creep deformation produced by identical loading gradually and incrementally increased. The nonlinear power function equation was selected to fit creep grading curves which have high precision. The cracks within the laterite gradually closed with the stress recovery, and permeability gradually recovered. During the stress recovery, the narrower cracks exhibited a smaller change in permeability. However, for narrow cracks in mining soil, permeability recovered after mining stress when permeability was closer to initial permeability, and the Baode laterite showed greater recovery than that of the Jingle laterite.

Extraction of valuable metals from low-grade nickeliferous laterite ore by reduction roasting-ammonia leaching method

Nickel and cobalt were extracted from low-grade nickeliferous laterite ore using a reduction roasting-ammonia leaching method.The reduction roasting-ammonia leaching experimental tests were chiefly introduced,by which fine coal was used as a reductant.The results show that the optimum process conditions are confirmed as follows:in reduction roasting process,the mass fraction of reductant in the ore is 10%,roasting time is 120 min,roasting temperature is 1 023-1 073 K;in ammonia leaching process,the liquid-to-solid ratio is 4:1(mL/g),leaching temperature is 313 K,leaching time is 120 min,and concentration ratio of NH3 to CO2 is 90 g/L:60 g/L.Under the optimum conditions,leaching efficiencies of nickel and cobalt are 86.25% and 60.84%,respectively.Therefore,nickel and cobalt can be effectively reclaimed,and the leaching agent can be also recycled at room temperature and normal pressure.

Transformation and leaching kinetics of silicon from low-grade nickel laterite ore by pre-roasting and alkaline leaching process

The mineralogical phase transformation of a low-grade nickel laterite ore during pre-roasting process and the extraction of silicon during alkaline leaching process were investigated.The results indicate that the reaction activity of nickel ores is effectively improved by pre-roasting at650°C for2h,because of the transformation of lizardite into magnesium olivine and protoenstatite.When finely ground ore samples(44-61μm)pre-roasted firstly react with sodium hydroxide solution(60g/L)with a solid/liquid ratio of1:5at140°C for120min,the extraction of silicon can reach89.89%,and the other valuable elements of magnesium,iron and nickel are accumulated in the solid residues.The leaching kinetics of nickel laterite ore can be described successfully by the diffusion through the product layer control model.The activation energy is calculated to be11.63kJ/mol and the kinetics equation can be expressed as1-3(1-x)2/3+2(1-x)=13.53×10-2exp[-11.63/(RT)]t.

Rare Earth Elements Geochemistry of Sheikh-Marut Laterite Deposit,NW Mahabad,West-Azarbaidjan Province,Iran

Laterite deposit at Sheikh-Marut （NW occurred within middle-upper Permian carbonate Mahabad, West-Azarbaidjan province, Iran） rocks. It consists of seven stratiform and/or discontinuous lenticular layers extending over 4.2 km in length and having thicknesses ranging from 3 to 14 m. Mineralogical data show that the ores contain kaolinite and hematite as major and boehmite, diaspore, halloysite, amesite, anatase, and muscovite-illite as minor mineral phases. The computed Ce anomaly values in the ores range from 0.05 to 20.84. Conservative index （e.g., Eu/Eu＊） suggests that this deposit is a product of alteration and weathering of basaltic rocks. Rhythmic increment of EREE values of the ores with approaching to the carbonate bedrocks shows an in-situ occurrence of lateritization processes. Mass change calculations of elements indicate that two competing processes namely leaching and fixation were the major regulating factors in concentration variation of REEs （La-Lu） in this deposit. The obtained results show that pH increase of weathering solutions by carbonate bedrocks, existence of organic matters, and the degree of comlexation with organic ligands played remarkable role in distribution of REEs during lateritization. Further geochemical considerations revealed that secondary phosphates, Mn-oxides and -hydroxides, diaspore, and anatase were the potential hosts for REEs in this deposit.

Adsorption of mercury on laterite from Guizhou Province,China

The adsorption behaviors of Hg(Ⅱ) on laterite from Guizhou Province,China,were studied and the adsorption mechanism was discussed.The results showed that different mineral compositons in the laterite will cause differences in the adsorption capacity of laterite to Hg(Ⅱ).Illite and non-crystalloids are the main contributors to enhancing the adsorption capacity of laterite to Hg(Ⅱ).The pH of the solution is an important factor affecting the adsorption of Hg(Ⅱ) on laterite.The alkalescent environment (pH 7-9) ...

Properties of Bentonite Enhanced Loess and Laterite

Loess and laterite distributed widely in the northern and southern China cannot be directly used as the natural barrier to isolate the solid waste because of their high hydraulic conductivity. In this paper, they are enhanced by bentonite to improve their hydraulic performance. The impact of bentonite content and water content on compressive strength of the compacted soil was investigated. The effects of bentonite content, water content, dry density and hydraulic gradient on the hydraulic conductivity were studied in detail. For the laterite and the laterite with 8% of bentonite, the experimental results of hydraulic conductivity can be applied in the engineering design. However, for the loess and the bentonite enhanced loess, those of hydraulic conductivity can not be directly applied in the engineering design because their hydraulic performance does not comply with the Darcy's law. These experimental results have to be carefully modified before application.

Microwave assisted atmospheric acid leaching of nickel from laterite ore

The recovery of nickel from laterite ore with sulphuric acid under the effect of microwave irradiation was studied.The experimental results indicated that the extraction rate of nickel was influenced by reaction time,sulphuric acid concentration,and temperature,especially by microwave power.The results obtained from the experiments of orthogonal arrays showed that the optimum conditions of sulphuric acid concentration,reaction time,microwave power,and temperature were 25 vol.%,1.5 h,600 W,and 90°C,respectively.Under the optimal conditions,the nickel recovery could reach approximately 90.8%,which was higher than that obtained by conventional water bath heating.Kinetic experiments showed that the leaching of nickel in a sulphuric acid medium was controlled by chemical reaction occurring on the surface of laterite ore.The apparent activation energy was 38.9 kJ/mol.Microwave heating technology is efficient,clean,and easy to control and facilitate continuous processing of materials.

Desiliconization kinetics of nickeliferous laterite ores in molten sodium hydroxide system

A novel process was proposed for treating nickeliferous laterite ores with molten sodium hydroxide.The effect on silicon extraction caused by the factors,such as stirring speed,reaction temperature,particle size and NaOH-to-ore mass ratio,was investigated.The results show that increasing stirring speed,reaction temperature and NaOH-to-ore mass ratio while decreasing particle size increases silicon extraction rate.The desiliconization kinetics of nickeliferous laterite ores in molten sodium hydroxide system was described successfully by chemical reaction control model.The activation energy of the desiliconization process was found to be 44.01 kJ/mol,and the reaction rate based on a chemical reaction-controlled process can be expressed as:1-(1-α) 1/3 = 27.67exp[-44 010/(RT)]t.