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Band structures of strained kagome lattices
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作者 徐露婷 杨帆 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期456-463,共8页
Materials with kagome lattices have attracted significant research attention due to their nontrivial features in energy bands.We theoretically investigate the evolution of electronic band structures of kagome lattices... Materials with kagome lattices have attracted significant research attention due to their nontrivial features in energy bands.We theoretically investigate the evolution of electronic band structures of kagome lattices in response to uniaxial strain using both a tight-binding model and an antidot model based on a periodic muffin-tin potential.It is found that the Dirac points move with applied strain.Furthermore,the flat band of unstrained kagome lattices is found to develop into a highly anisotropic shape under a stretching strain along y direction,forming a partially flat band with a region dispersionless along ky direction while dispersive along kx direction.Our results shed light on the possibility of engineering the electronic band structures of kagome materials by mechanical strain. 展开更多
关键词 kagome lattice STRAIN band structure engineering
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Rule acquisition of three-way semi-concept lattices in formal decision context
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作者 Jie Zhao Renxia Wan +1 位作者 Duoqian Miao Boyang Zhang 《CAAI Transactions on Intelligence Technology》 SCIE EI 2024年第2期333-347,共15页
Three-way concept analysis is an important tool for information processing,and rule acquisition is one of the research hotspots of three-way concept analysis.However,compared with three-way concept lattices,three-way ... Three-way concept analysis is an important tool for information processing,and rule acquisition is one of the research hotspots of three-way concept analysis.However,compared with three-way concept lattices,three-way semi-concept lattices have three-way operators with weaker constraints,which can generate more concepts.In this article,the problem of rule acquisition for three-way semi-concept lattices is discussed in general.The authors construct the finer relation of three-way semi-concept lattices,and propose a method of rule acquisition for three-way semi-concept lattices.The authors also discuss the set of decision rules and the relationships of decision rules among object-induced three-way semi-concept lattices,object-induced three-way concept lattices,classical concept lattices and semi-concept lattices.Finally,examples are provided to illustrate the validity of our conclusions. 展开更多
关键词 finer relation rule acquisition three-way concept analysis three-way semi-concept lattices
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Design and optimization of diffraction-limited storage ring lattices based on many-objective evolutionary algorithms 被引量:1
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作者 He-Xing Yin Jia-Bao Guan +1 位作者 Shun-Qiang Tian Ji-Ke Wang 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第10期20-35,共16页
Multi-objective evolutionary algorithms(MOEAs) are typically used to optimize two or three objectives in the accelerator field and perform well. However, the performance of these algorithms may severely deteriorate wh... Multi-objective evolutionary algorithms(MOEAs) are typically used to optimize two or three objectives in the accelerator field and perform well. However, the performance of these algorithms may severely deteriorate when the optimization objectives for an accelerator are equal to or greater than four. Recently, many-objective evolutionary algorithms(MaOEAs)that can solve problems with four or more optimization objectives have received extensive attention. In this study, two diffraction-limited storage ring(DLSR) lattices of the Extremely Brilliant Source(ESRF-EBS) type with different energies were designed and optimized using three MaOEAs and a widely used MOEA. The initial population was found to have a significant impact on the performance of the algorithms and was carefully studied. The performances of the four algorithms were compared, and the results demonstrated that the grid-based evolutionary algorithm(GrEA) had the best performance.Ma OEAs were applied in many-objective optimization of DLSR lattices for the first time, and lattices with natural emittances of 116 and 23 pm·rad were obtained at energies of 2 and 6 GeV, respectively, both with reasonable dynamic aperture and local momentum aperture(LMA). This work provides a valuable reference for future many-objective optimization of DLSRs. 展开更多
关键词 Storage ring lattices Many-objective evolutionary algorithms GrEA algorithm NSGA
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Design and comparison of hybrid multi-bend achromat lattices for HALF storage ring
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作者 Peng-Hui Yang Gang-Wen Liu +3 位作者 Jian-Hao Xu Wei-Wei Li Tian-Long He Zheng-He Bai 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第7期189-197,共9页
The Hefei Advanced Light Facility(HALF)proposed by the National Synchrotron Radiation Laboratory is a green-field vacuum ultraviolet and soft X-ray diffraction-limited storage ring light source with a beam energy of 2... The Hefei Advanced Light Facility(HALF)proposed by the National Synchrotron Radiation Laboratory is a green-field vacuum ultraviolet and soft X-ray diffraction-limited storage ring light source with a beam energy of 2.2 GeV and emittance goal of less than 100 pm rad.Inspired by the ESRF-EBS hybrid multi-bend achromat(HMBA),SLS-2,and Diamond-II lattices,we have proposed and designed a modified H6BA lattice as the baseline lattice of the HALF storage ring with 20 identical cells and a natural emittance of approximately 86 pm rad.In this paper,three other types of HMBA lattices including two H7BA lattices and a H6BA lattice are designed for HALF with the same number of cells.The main storage ring proper-ties of these four HMBA lattices are compared.Because the intra-beam scattering(IBS)effect is significant in the HALF storage ring,we calculate and compare the equilibrium emittances of the four lattices with IBS included.These comparisons show that the present modified H6BA lattice,which has a relatively low equilibrium emittance and more straight sections,is preferred for the HALF storage ring after a comprehensive consideration. 展开更多
关键词 Hefei advanced light facility lattice design Hybrid MBA lattice Intra-beam scattering
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基于ALBERT、Lattice IndyLSTM和Attention融合的用户意图分类
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作者 吕海峰 冀肖榆 +2 位作者 庞光垚 涂井先 黄芳香 《计算机与数字工程》 2024年第3期834-840,共7页
旨在对话式智能系统中的用户意图识别任务,论文提出了一种新型的用户意图分类模型。该模型结合了ALBERT预训练模型、格形式的独立循环长短期记忆网络(Lattice IndyLSTM)以及词注意力融合机制。通过构造一个由字嵌入和词嵌入组成的Latti... 旨在对话式智能系统中的用户意图识别任务,论文提出了一种新型的用户意图分类模型。该模型结合了ALBERT预训练模型、格形式的独立循环长短期记忆网络(Lattice IndyLSTM)以及词注意力融合机制。通过构造一个由字嵌入和词嵌入组成的Lattice,输入至IndyLSTM网络实现对用户输入语句编码,能够处理传统意图分类任务中无法同时利用字词信息、RNN中存在梯度爆炸或者消失,LSTM模型过拟合等问题。此外,利用能够提高对用户输入语句中领域特定词汇的编码贡献度的词注意力机制,大大提升了意图识别准确性。通过实验得出,论文提出的用户意图分类模型能够有效提升精确率、召回率和F1值等指标。 展开更多
关键词 注意力机制 循环神经网络 意图分类 ALBERT lattice IndyLSTM
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Modulational instability of a resonantly polariton condensate in discrete lattices
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作者 漆伟 郭晓刚 +1 位作者 董亮伟 张晓斐 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第3期143-146,共4页
We study modulational instability of a resonantly polariton condensate in a discrete lattice.Employing a discrete gain-saturation model,we derive the dispersion relation for the modulational instability by means of th... We study modulational instability of a resonantly polariton condensate in a discrete lattice.Employing a discrete gain-saturation model,we derive the dispersion relation for the modulational instability by means of the linear-stability analysis.Effects of the pumping strength,the nonlinearity,the strength of the detuning,and the coupling strength on the modulation instability are investigated.It is found that the interplay between these parameters will dramatically change the modulational instability condition.We believe that the predicted results in this work can be useful for future possible experiment of exciton-polariton condensate in lattices. 展开更多
关键词 modulational instability polariton condensate discrete lattices
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An inverse analysis of fluid flow through granular media using differentiable lattice Boltzmann method 被引量:1
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作者 Qiuyu Wang Krishna Kumar 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第6期2077-2090,共14页
This study presents a method for the inverse analysis of fluid flow problems.The focus is put on accurately determining boundary conditions and characterizing the physical properties of granular media,such as permeabi... This study presents a method for the inverse analysis of fluid flow problems.The focus is put on accurately determining boundary conditions and characterizing the physical properties of granular media,such as permeability,and fluid components,like viscosity.The primary aim is to deduce either constant pressure head or pressure profiles,given the known velocity field at a steady-state flow through a conduit containing obstacles,including walls,spheres,and grains.The lattice Boltzmann method(LBM)combined with automatic differentiation(AD)(AD-LBM)is employed,with the help of the GPU-capable Taichi programming language.A lightweight tape is used to generate gradients for the entire LBM simulation,enabling end-to-end backpropagation.Our AD-LBM approach accurately estimates the boundary conditions for complex flow paths in porous media,leading to observed steady-state velocity fields and deriving macro-scale permeability and fluid viscosity.The method demonstrates significant advantages in terms of prediction accuracy and computational efficiency,making it a powerful tool for solving inverse fluid flow problems in various applications. 展开更多
关键词 Inverse problem Fluid flow Granular media Automatic differentiation(AD) lattice Boltzmann method(LBM)
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Evaluation of Codebook Design Using SCMA Scheme Based on A_(n) and D_(n) Lattices
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作者 G.Rajamanickam G.Ravi 《Intelligent Automation & Soft Computing》 SCIE 2023年第3期3037-3048,共12页
The sparse code multiple access(SCMA)scheme is a Non-Orthogonal Multiple Access(NOMA)type of scheme that is used to handle the uplink com-ponent of mobile communication in the current generation.A need of the 5G mobil... The sparse code multiple access(SCMA)scheme is a Non-Orthogonal Multiple Access(NOMA)type of scheme that is used to handle the uplink com-ponent of mobile communication in the current generation.A need of the 5G mobile network is the ability to handle more users.To accommodate this,the SCMA allows each user to deploy a variety of sub-carrier broadcasts,and several consumers may contribute to the same frequency using superposition coding.The SCMA approach,together with codebook design for each user,is used to improve channel efficiency through better management of the available spectrum.How-ever,developing a codebook with a greater number of value sets is still another challenge.With enhanced techniques of encoding and decoding for 5G networks,mapping the multidimensional constellations in the SCMA system plays a signif-icant role in improving the system performance and enhancing the overall system performance.The creation of a codebook utilizing the SCMA approach in con-junction with the lattice theory is suggested in this study.The prototype is shaped using a popular lattice,such as A n and D n,as the basis.Afterward,from the primary lattice constellation,the multidimensional complex mother constellation with the most noticeable variance in power is discovered.The lattice-based cod-ing is generated by combining the codebooks with the mother constellation,and the codes in the matrices are mapped by rotating the constellations in this context.The suggested technique,in conjunction with the investigation of novel SCMA codebook sets,provides improved performance in terms of Bit Error Rate(BER)and complexity with regard to Signal to Noise Ratio(SNR).Finally,the bit error rate is reduced for various SNRs during transmission in the channel. 展开更多
关键词 5G NOMA SCMA lattice coding codebook design bit error rate
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Volumetric lattice Boltzmann method for pore-scale mass diffusionadvection process in geopolymer porous structures 被引量:1
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作者 Xiaoyu Zhang Zirui Mao +6 位作者 Floyd W.Hilty Yulan Li Agnes Grandjean Robert Montgomery Hans-Conrad zur Loye Huidan Yu Shenyang Hu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第6期2126-2136,共11页
Porous materials present significant advantages for absorbing radioactive isotopes in nuclear waste streams.To improve absorption efficiency in nuclear waste treatment,a thorough understanding of the diffusion-advecti... Porous materials present significant advantages for absorbing radioactive isotopes in nuclear waste streams.To improve absorption efficiency in nuclear waste treatment,a thorough understanding of the diffusion-advection process within porous structures is essential for material design.In this study,we present advancements in the volumetric lattice Boltzmann method(VLBM)for modeling and simulating pore-scale diffusion-advection of radioactive isotopes within geopolymer porous structures.These structures are created using the phase field method(PFM)to precisely control pore architectures.In our VLBM approach,we introduce a concentration field of an isotope seamlessly coupled with the velocity field and solve it by the time evolution of its particle population function.To address the computational intensity inherent in the coupled lattice Boltzmann equations for velocity and concentration fields,we implement graphics processing unit(GPU)parallelization.Validation of the developed model involves examining the flow and diffusion fields in porous structures.Remarkably,good agreement is observed for both the velocity field from VLBM and multiphysics object-oriented simulation environment(MOOSE),and the concentration field from VLBM and the finite difference method(FDM).Furthermore,we investigate the effects of background flow,species diffusivity,and porosity on the diffusion-advection behavior by varying the background flow velocity,diffusion coefficient,and pore volume fraction,respectively.Notably,all three parameters exert an influence on the diffusion-advection process.Increased background flow and diffusivity markedly accelerate the process due to increased advection intensity and enhanced diffusion capability,respectively.Conversely,increasing the porosity has a less significant effect,causing a slight slowdown of the diffusion-advection process due to the expanded pore volume.This comprehensive parametric study provides valuable insights into the kinetics of isotope uptake in porous structures,facilitating the development of porous materials for nuclear waste treatment applications. 展开更多
关键词 Volumetric lattice Boltzmann method(VLBM) Phase field method(PFM) Pore-scale diffusion-advection Nuclear waste treatment Porous media flow Graphics processing unit(GPU) parallelization
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Observation of flat-band localized state in a one-dimensional diamond momentum lattice of ultracold atoms
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作者 曾超 石悦然 +5 位作者 毛一屹 武菲菲 谢岩骏 苑涛 戴汉宁 陈宇翱 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期212-217,共6页
We investigated the one-dimensional diamond ladder in the momentum lattice platform. By inducing multiple twoand four-photon Bragg scatterings among specific momentum states, we achieved a flat band system based on th... We investigated the one-dimensional diamond ladder in the momentum lattice platform. By inducing multiple twoand four-photon Bragg scatterings among specific momentum states, we achieved a flat band system based on the diamond model, precisely controlling the coupling strength and phase between individual lattice sites. Utilizing two lattice sites couplings, we generated a compact localized state associated with the flat band, which remained localized throughout the entire time evolution. We successfully realized the continuous shift of flat bands by adjusting the corresponding nearest neighbor hopping strength, enabling us to observe the complete localization process. This opens avenues for further exploration of more complex properties within flat-band systems, including investigating the robustness of flat-band localized states in disordered flat-band systems and exploring many-body localization in interacting flat-band systems. 展开更多
关键词 diamond lattice flat band momentum lattice localized state
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An Unbounded Fully Homomorphic Encryption Scheme Based on Ideal Lattices and Chinese Remainder Theorem
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作者 Zhiyong Zheng Fengxia Liu Kun Tian 《Journal of Information Security》 2023年第4期366-395,共30页
We propose an unbounded fully homomorphic encryption scheme, i.e. a scheme that allows one to compute on encrypted data for any desired functions without needing to decrypt the data or knowing the decryption keys. Thi... We propose an unbounded fully homomorphic encryption scheme, i.e. a scheme that allows one to compute on encrypted data for any desired functions without needing to decrypt the data or knowing the decryption keys. This is a rational solution to an old problem proposed by Rivest, Adleman, and Dertouzos [1] in 1978, and to some new problems that appeared in Peikert [2] as open questions 10 and open questions 11 a few years ago. Our scheme is completely different from the breakthrough work [3] of Gentry in 2009. Gentry’s bootstrapping technique constructs a fully homomorphic encryption (FHE) scheme from a somewhat homomorphic one that is powerful enough to evaluate its own decryption function. To date, it remains the only known way of obtaining unbounded FHE. Our construction of an unbounded FHE scheme is straightforward and can handle unbounded homomorphic computation on any refreshed ciphertexts without bootstrapping transformation technique. 展开更多
关键词 Fully Homomorphic Encryption Ideal lattices Chinese Remainder Theorem General Compact Knapsacks Problem
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A novel triple periodic minimal surface-like plate lattice and its data-driven optimization method for superior mechanical properties
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作者 Yanda WANG Yanping LIAN +2 位作者 Zhidong WANG Chunpeng WANG Daining FANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第2期217-238,共22页
Lattice structures can be designed to achieve unique mechanical properties and have attracted increasing attention for applications in high-end industrial equipment,along with the advances in additive manufacturing(AM... Lattice structures can be designed to achieve unique mechanical properties and have attracted increasing attention for applications in high-end industrial equipment,along with the advances in additive manufacturing(AM)technologies.In this work,a novel design of plate lattice structures described by a parametric model is proposed to enrich the design space of plate lattice structures with high connectivity suitable for AM processes.The parametric model takes the basic unit of the triple periodic minimal surface(TPMS)lattice as a skeleton and adopts a set of generation parameters to determine the plate lattice structure with different topologies,which takes the advantages of both plate lattices for superior specific mechanical properties and TPMS lattices for high connectivity,and therefore is referred to as a TPMS-like plate lattice(TLPL).Furthermore,a data-driven shape optimization method is proposed to optimize the TLPL structure for maximum mechanical properties with or without the isotropic constraints.In this method,the genetic algorithm for the optimization is utilized for global search capability,and an artificial neural network(ANN)model for individual fitness estimation is integrated for high efficiency.A set of optimized TLPLs at different relative densities are experimentally validated by the selective laser melting(SLM)fabricated samples.It is confirmed that the optimized TLPLs could achieve elastic isotropy and have superior stiffness over other isotropic lattice structures. 展开更多
关键词 lattice structure triple periodic minimal surface(TPMS) plate lattice structural optimization machine learning
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On the spreading behavior of a droplet on a circular cylinder using the lattice Boltzmann method
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作者 杨帆 金虎 戴梦瑶 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期434-443,共10页
The study of a droplet spreading on a circular cylinder under gravity was carried out using the pseudo-potential lattice Boltzmann high-density ratios multiphase model with a non-ideal Peng–Robinson equation of state... The study of a droplet spreading on a circular cylinder under gravity was carried out using the pseudo-potential lattice Boltzmann high-density ratios multiphase model with a non-ideal Peng–Robinson equation of state. The calculation results indicate that the motion of the droplet on the cylinder can be divided into three stages: spreading, sliding, and aggregating.The contact length and contact time of a droplet on a cylindrical surface can be affected by factors such as the wettability gradient of the cylindrical wall, the Bond number, and droplet size. Furthermore, phase diagrams showing the relationship between Bond number, cylinder wall wettability gradient, and contact time as well as maximum contact length for three different droplet sizes are given. A theoretical foundation for additional research into the heat and mass transfer process between the droplet and the cylinder can be established by comprehending the variable rules of maximum contact length and contact time. 展开更多
关键词 lattice Boltzmann methods DROPLET circular cylinder wettability gradient
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Speed limit effect during lane change in a two-lane lattice model under V2X environment
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作者 金灿 彭光含 聂方彦 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期718-722,共5页
Speed limit measures are ubiquitous due to the complexity of the road environment,which can be supplied with the help of vehicle to everything(V2X)communication technology.Therefore,the influence of speed limit on tra... Speed limit measures are ubiquitous due to the complexity of the road environment,which can be supplied with the help of vehicle to everything(V2X)communication technology.Therefore,the influence of speed limit on traffic system will be investigated to construct a two-lane lattice model accounting for the speed limit effect during the lane change process under V2X environment.Accordingly,the stability condition and the mKdV equation are closely associated with the speed limit effect through theory analysis.Moreover,the evolution of density and hysteresis loop is simulated to demonstrate the positive role of the speed limit effect on traffic stability in the cases of strong reaction intensity and high limited speed. 展开更多
关键词 traffic flow lattice model speed limit
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{1012}twin–twin intersection-induced lattice rotation and dynamic recrystallization in Mg–6Al–3Sn–2Zn alloy
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作者 Bin-Jiang Lv Sen Wang +4 位作者 Fu-Hao Gao Ning Cui Yi-Nan Li Tie-Wei Xu Feng Guo 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1529-1539,共11页
This study investigated the formation mechanism of new grains due to twin–twin intersections in a coarse-grained Mg–6Al–3Sn–2Zn alloy during different strain rates of an isothermal compression.The results of elect... This study investigated the formation mechanism of new grains due to twin–twin intersections in a coarse-grained Mg–6Al–3Sn–2Zn alloy during different strain rates of an isothermal compression.The results of electron backscattered diffraction investigations showed that the activated twins were primarily{1012}tension twins,and 60°<1010>boundaries formed due to twin–twin intersections under different strain rates.Isolated twin variants with 60°<1010>boundaries transformed into new grains through lattice rotations at a low strain rate(0.01 s^(−1)).At a high strain rate(10 s^(−1)),the regions surrounded by subgrain boundaries through high-density dislocation arrangement and the 60°<1010>boundaries transformed into new grains via dynamic recrystallization. 展开更多
关键词 Mg alloy Twin-twin intersection lattice rotation Dynamic recrystallization
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基于LATTICE的文言文自动断句研究
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作者 庄百川 于文年 邱秀连 《计算机与数字工程》 2024年第4期1137-1141,1158,共6页
随着社会主义文化强国的建设,利用自然语言处理技术实现对古汉语典籍的处理与挖掘越发受到关注。针对文言文自动化断句任务,论文提出一种基于BERT-LATTICE-LAN网络的深度学习模型,通过集成预训练模型和融入词向量的长短时记忆网络,实现... 随着社会主义文化强国的建设,利用自然语言处理技术实现对古汉语典籍的处理与挖掘越发受到关注。针对文言文自动化断句任务,论文提出一种基于BERT-LATTICE-LAN网络的深度学习模型,通过集成预训练模型和融入词向量的长短时记忆网络,实现对文言文语句的自动化断句处理。相比于传统的BiLSTM-CRF网络,其准确率和F值分别提高了8.03%和7.88%。 展开更多
关键词 深度学习 BERT latticE 序列标注 自动断句
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Operando measurement of lattice deformation profiles of synchrotron radiation monochromator
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作者 Yue Zhang Zhong-Liang Li +4 位作者 Shang-Yu Si Lian Xue Hong-Xin Luo Xiao-Wei Zhang Jun Hu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第7期8-19,共12页
This study presents a new method for characterizing the thermal lattice deformation of a monochromator with high precision under service conditions and first reports the operando measurements of nanoscale thermal latt... This study presents a new method for characterizing the thermal lattice deformation of a monochromator with high precision under service conditions and first reports the operando measurements of nanoscale thermal lattice deformation on a double-crystal monochromator at different incident powers.The nanoscale thermal lattice deformation of the monochromator first crystal was obtained by analyzing the intensity of the distorted DuMond diagrams.DuMond diagrams of the 333 diffraction index,sensitive to lattice deformation,were obtained directly using a 2D detector and an analyzer crystal orthogonal to the monochromator.With increasing incident power and power density,the maximum height of the lattice deformation increased from 3.2 to 18.5 nm,and the deformation coefficient of the maximum height increased from 1.1 to 3.2 nm/W.The maximum relative standard deviation was 4.2%,and the maximum standard deviation was 0.1 nm.Based on the measured thermal deformations,the flux saturation phenomenon and critical point for the linear operation of the monochromator were predicted with increasing incident power.This study provides a simple solution to the problem of the lower precision of synchrotron radiation monochromator characterizations compared to simulations. 展开更多
关键词 Synchrotron radiation MONOCHROMATOR lattice deformation X-ray dynamic diffraction
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Synergism of preintercalated manganese ions and lattice water in vanadium oxide cathodes for high-capacity and long-life Zn-ion batteries
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作者 Mengjing Wu Rongrong Li +3 位作者 Kai Yang Lijiang Yin Weikang Hu Xiong Pu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期709-717,共9页
Aqueous Zn-ion batteries(AZIBs)are recognized as a promising energy storage system with intrinsic safety and low cost,but its applications still rely on the design of high-capacity and stable-cycling cathode materials... Aqueous Zn-ion batteries(AZIBs)are recognized as a promising energy storage system with intrinsic safety and low cost,but its applications still rely on the design of high-capacity and stable-cycling cathode materials.In this work,we present an intercalation mechanism-based cathode materials for AZIB,i.e.the vanadium oxide with pre-intercalated manganese ions and lattice water(noted as MVOH).The synergistic effect between Mn^(2+)and lattice H_(2)O not only expands the interlayer spacing,but also significantly enhances the structural stability.Systematic in-situ and ex-situ characterizations clarify the Zn^(2+)/H^(+)co–(de)intercalation mechanism of MVOH in aqueous electrolyte.The demonstrated remarkable structure stability,excellent kinetic behaviors and ion-storage mechanism together enable the MVOH to demonstrate satisfactory specific capacity of 450 mA h g^(−1)at 0.2 A g^(−1),excellent rate performance of 288.8 mA h g^(−1)at 10 A g^(−1)and long cycle life over 20,000 cycles at 5 A g^(−1).This work provides a practical cathode material,and contributes to the understanding of the ion-intercalation mechanism and structural evolution of the vanadium-based cathode for AZIBs. 展开更多
关键词 Zn-ion batteries Vanadium oxide Pre-intercalation lattice water Manganese ion
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Asymmetric configuration activating lattice oxygen via weakening d-p orbital hybridization for efficient C/N separation in urea overall electrolysis
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作者 Chongchong Liu Peifang Wang +3 位作者 Bin Hu Xiaoli Liu Rong Huang Gang Zhou 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期233-239,共7页
Urea oxidation reaction(UOR)is proposed as an exemplary half-reaction in renewable energy applications because of its low thermodynamical potential.However,challenges persist due to sluggish reaction kinetics and comp... Urea oxidation reaction(UOR)is proposed as an exemplary half-reaction in renewable energy applications because of its low thermodynamical potential.However,challenges persist due to sluggish reaction kinetics and complex by-products separation.To this end,we introduce the lattice oxygen oxidation mechanism(LOM),propelling a novel UOR route using a modified CoFe layered double hydroxide(LDH)catalyst termed CFRO-7.Theoretical calculations and in-situ characterizations highlight the activated lattice oxygen(O_(L))within CFRO-7 as pivotal sites for UOR,optimizing the reaction pathway and accelerating the kinetics.For the urea overall electrolysis application,the LOM route only requires a low voltage of 1.54 V to offer a high current of 100 mA cm^(-2) for long-term utilization(>48 h).Importantly,the by-product NCO^(-)−is significantly suppressed,while the CO_(2)2/N_(2) separation is efficiently achieved.This work proposed a pioneering paradigm,invoking the LOM pathway in urea electrolysis to expedite reaction dynamics and enhance product selectivity. 展开更多
关键词 lattice oxygen Urea oxidation reaction Overall electrolysis Products selectivity
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A Yb optical clock with a lattice power enhancement cavity
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作者 王春云 姚远 +3 位作者 师浩森 于洪浮 马龙生 蒋燕义 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期70-74,共5页
We construct a power enhancement cavity to form an optical lattice in an ytterbium optical clock.It is demonstrated that the intra-cavity lattice power can be increased by about 45 times,and the trap depth can be as l... We construct a power enhancement cavity to form an optical lattice in an ytterbium optical clock.It is demonstrated that the intra-cavity lattice power can be increased by about 45 times,and the trap depth can be as large as 1400Er when laser light with a power of only 0.6 W incident to the lattice cavity.Such high trap depths are the key to accurate evaluation of the lattice-induced light shift with an uncertainty down to~1×10-18.By probing the ytterbium atoms trapped in the power-enhanced optical lattice,we obtain a 4.3 Hz-linewidth Rabi spectrum,which is then used to feedback to the clock laser for the close loop operation of the optical lattice clock.We evaluate the density shift of the Yb optical lattice clock based on interleaving measurements,which is-0.46(62)mHz.This result is smaller compared to the density shift of our first Yb optical clock without lattice power enhancement cavity mainly due to a larger lattice diameter of 344μm. 展开更多
关键词 optical atomic clock optical lattice optical cavity Stark shift
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