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Recent progress in Ni-rich layered oxides and related cathode materials for Li-ion cells
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作者 Boyang Fu Maciej Moździerz +1 位作者 Andrzej Kulka Konrad Świerczek 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第11期2345-2367,共23页
Undoubtedly,the enormous progress observed in recent years in the Ni-rich layered cathode materials has been crucial in terms of pushing boundaries of the Li-ion battery(LIB)technology.The achieved improvements in the... Undoubtedly,the enormous progress observed in recent years in the Ni-rich layered cathode materials has been crucial in terms of pushing boundaries of the Li-ion battery(LIB)technology.The achieved improvements in the energy density,cyclability,charging speed,reduced costs,as well as safety and stability,already contribute to the wider adoption of LIBs,which extends nowadays beyond mobile electronics,power tools,and electric vehicles,to the new range of applications,including grid storage solutions.With numerous published papers and broad reviews already available on the subject of Ni-rich oxides,this review focuses more on the most recent progress and new ideas presented in the literature references.The covered topics include doping and composition optimization,advanced coating,concentration gradient and single crystal materials,as well as innovations concerning new electrolytes and their modification,with the application of Ni-rich cathodes in solid-state batteries also discussed.Related cathode materials are briefly mentioned,with the high-entropy approach and zero-strain concept presented as well.A critical overview of the still unresolved issues is given,with perspectives on the further directions of studies and the expected gains provided. 展开更多
关键词 lithium-ion batteries cathode materials nickel-rich layered oxides recent progress critical issues improvement strategies
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Designing ultrastable P2/O3-type layered oxides for sodium ion batteries by regulating Na distribution and oxygen redox chemistry
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作者 Jieyou Huang Weiliang Li +3 位作者 Debin Ye Lin Xu Wenwei Wu Xuehang Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期466-476,共11页
P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phas... P2/O3-type Ni/Mn-based layered oxides are promising cathode materials for sodium-ion batteries(SIBs)owing to their high energy density.However,exploring effective ways to enhance the synergy between the P2 and 03 phases remains a necessity.Herein,we design a P2/O3-type Na_(0.76)Ni_(0.31)Zn_(0.07)Mn_(0.50)Ti_(0.12)0_(2)(NNZMT)with high chemical/electrochemical stability by enhancing the coupling between the two phases.For the first time,a unique Na*extraction is observed from a Na-rich O3 phase by a Na-poor P2 phase and systematically investigated.This process is facilitated by Zn^(2+)/Ti^(4+)dual doping and calcination condition regulation,allowing a higher Na*content in the P2 phase with larger Na^(+)transport channels and enhancing Na transport kinetics.Because of reduced Na^(+)in the O3 phase,which increases the difficulty of H^(+)/Na^(+) exchange,the hydrostability of the O3 phase in NNZMT is considerably improved.Furthermore,Zn^(2+)/Ti^(4+)presence in NNZMT synergistically regulates oxygen redox chemistry,which effectively suppresses O_(2)/CO_(2) gas release and electrolyte decomposition,and completely inhibits phase transitions above 4.0 V.As a result,NNZMT achieves a high discharge capacity of 144.8 mA h g^(-1) with a median voltage of 3.42 V at 20 mA g^(-1) and exhibits excellent cycling performance with a capacity retention of 77.3% for 1000 cycles at 2000 mA g^(-1).This study provides an effective strategy and new insights into the design of high-performance layered-oxide cathode materials with enhanced structure/interface stability forSIBs. 展开更多
关键词 Sodium-ion batteries P2/O3-type layered oxides Na distribution Oxygen redox chemistry Hydrostability
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The superhydrophobic sponge decorated with Ni-Co double layered oxides with thiol modification for continuous oil/water separation
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作者 Xiaodong Yang Na Yang +4 位作者 Ziqiang Gong Feifei Peng Bin Jiang Yongli Sun Luhong Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期296-305,共10页
In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modific... In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modification with n-dodecyl mercaptan(DDT). This method provides a new strategy to fabricate superhydrophobic PU sponge with a water contact angle of 157° for absorbing oil with low cost and in large scale. It exhibits the strong absorption capacity and highly selective characteristic for various kinds of oils which can be recycled by simple squeezing. Besides, the as-prepared sponge can deal with the floating and underwater oils, indicating its application value in handling oil spills and domestic oily wastewater. The good self-cleaning ability shows the potential to clear the pollutants due to the ultralow adhesion to water. Especially, the most important point is that the superhydrophobic sponge can continuously and effectively separate the oil/water mixture against the condition of turbulent disturbance by using our designed device system, which exhibit its good superhydrophobicity, strong stability.Furthermore, the SS-PU still maintained stable absorption performance after 150 cycle tests without losing capacity obviously, showing excellent durability in long-term operation and significant potential as an efficient absorbent in large-scale dispose of oily water. 展开更多
关键词 Superhydrophobic sponge Ni-Co double layered oxides Thiol modification Oil absorption Oil/water separation
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Facet-dependent Thermal and Electrochemical Degradation of Lithium-rich Layered Oxides
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作者 Guohua Li Zhimin Ren +12 位作者 Haoxiang Zhuo Changhong Wang Biwei Xiao Jianwen Liang Ruizhi Yu Ting Lin Alin Li Tianwei Yu Wei Huang Anbang Zhang Qinghua Zhang Jiantao Wang Xueliang Sun 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第6期345-355,共11页
Lithium-rich layered oxides(LLOs)are promising candidate cathode materials for safe and inexpensive high-energy-density Li-ion batteries.However,oxygen dimers are formed from the cathode material through oxygen redox ... Lithium-rich layered oxides(LLOs)are promising candidate cathode materials for safe and inexpensive high-energy-density Li-ion batteries.However,oxygen dimers are formed from the cathode material through oxygen redox activity,which can result in morphological changes and structural transitions that cause performance deterioration and safety concerns.Herein,a flake-like LLO is prepared and aberration-corrected scanning transmission electron microscopy(STEM),in situ high-temperature X-ray diffraction(HT-XRD),and soft X-ray absorption spectrum(sXAS)are used to explore its crystal facet degradation behavior in terms of both thermal and electrochemical processes.Void-induced degradation behavior of LLO in different facet reveals significant anisotropy at high voltage.Particle degradation originates from side facets,such as the(010)facet,while the close(003)facet is stable.These results are further understood through ab initio molecular dynamics calculations,which show that oxygen atoms are lost from the{010}facets.Therefore,the facet degradation process is that oxygen molecular formed in the interlayer and accumulated in the ab plane during heating,which result in crevice-voids in the ab plane facets.The study reveals important aspects of the mechanism responsible for oxygen-anionic activity-based degradation of LLO cathode materials used in lithium-ion batteries.In particular,this study provides insight that enables precise and efficient measures to be taken to improve the thermal and electrochemical stability of an LLO. 展开更多
关键词 electrochemical degradation facet degradation lithium-rich layered oxides thermal degradation
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Oxygen-defects evolution to stimulate continuous capacity increase in Co-free Li-rich layered oxides 被引量:2
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作者 Yibin Zhang Xiaohui Wen +3 位作者 Zhepu Shi Bao Qiu Guoxin Chen Zhaoping Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第7期259-267,I0006,共10页
Though oxygen defects are associated with deteriorated structures and aggravated cycling performance in traditional layered cathodes,the role of oxygen defects is still ambiguous in Li-rich layered oxides due to the i... Though oxygen defects are associated with deteriorated structures and aggravated cycling performance in traditional layered cathodes,the role of oxygen defects is still ambiguous in Li-rich layered oxides due to the involvement of oxygen redox.Herein,a Co-free Li-rich layered oxide Li_(1.286)Ni_(0.071)Mn_(0.643)O_(2)has been prepared by a co-precipitation method to systematically investigate the undefined effects of the oxygen defects.A significant O_(2)release and the propagation of oxygen vacancies were detected by operando differential electrochemical mass spectroscopy(DEMS)and electron energy loss spectroscopy(EELS),respectively.Scanning transmission electron microscopy-high angle annular dark field(STEMHAADF)reveals the oxygen vacancies fusing to nanovoids and monitors a stepwise electrochemical activation process of the large Li_(2)MnO_(3)domain upon cycling.Combined with the quantitative analysis conducted by the energy dispersive spectrometer(EDS),existed nano-scale oxygen defects actually expose more surface to the electrolyte for facilitating the electrochemical activation and subsequently increasing available capacity.Overall,this work persuasively elucidates the function of oxygen defects on oxygen redox in Co-free Li-rich layered oxides. 展开更多
关键词 Li-rich layered oxide Irreversible oxygen loss Nano-scale oxygen defect Li_(2)MnO_(3)-domain activation
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Cationic potential:An effective descriptor for rational design of layered oxides for sodium-ion batteries
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作者 Xudong Zhao Li-Zhen Fan Zhen Zhou 《Green Energy & Environment》 SCIE CSCD 2021年第4期455-457,共3页
Sodium-ion batteries are very promising in large-scale energy storage.The exploration of Na layered oxides as cathode materials for Na ion batteries usually consumes much resource,while the performances of Na layered ... Sodium-ion batteries are very promising in large-scale energy storage.The exploration of Na layered oxides as cathode materials for Na ion batteries usually consumes much resource,while the performances of Na layered oxides are dominated by their crystal structures.Therefore,it is highly desired to predict the stacking mode of the target oxides in advance:whether O3-type with higher ordered structure and stability,or P2-type with more Na content.For this purpose density functional theory computations do not work.Very recently,Hu's group and international collaborators have proposed a cationic potential to provide a very timely,effective,and accurate criterion to predict the stacking mode of Na layered oxides(Science,370(2020)708-711).Under the guidance of the cationic potential phase map,Na layered oxides could be rationally designed.Here we would like to highlight the progress that novel Na layered oxides could be obtained with the combination of large specific capacity,high power density and good cycling stability. 展开更多
关键词 Na ion batteries layered oxides Materials design
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Ultralow-strain Ti substituted Mn-vacancy layered oxides with enhanced stability for sodium-ion batteries
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作者 Yanchen Liu Chenchen Wang +3 位作者 Meng Ren Hengyi Fang Zhuoliang Jiang Fujun Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第12期351-357,I0008,共8页
Anionic redox reaction(ARR) in layered manganese-based oxide cathodes has been considered as an effective strategy to improve the energy density of sodium-ion batteries.Mn-vacancy layered oxides deliver a high ARR-rel... Anionic redox reaction(ARR) in layered manganese-based oxide cathodes has been considered as an effective strategy to improve the energy density of sodium-ion batteries.Mn-vacancy layered oxides deliver a high ARR-related capacity with small voltage hysteresis,however,they are limited by rapid capacity degradation and poor rate capability,which arise from inferior structure changes due to repeated redox of lattice oxygen.Herein,redox-inactive Ti^(4+)is introduced to substitute partial Mn^(4+)to form Na_(2) Ti_(0.5)Mn_(2.5)O_7(Na_(4/7)[□_(1/7)Ti_(1/7)Mn_(5/7)]O_(2),□ for Mn vacancies),which can effectively restrain unfavorable interlayer gliding of Na2 Mn307 at high charge voltages,as reflected by an ultralow-strain volume variation of 0.11%.There is no irreversible O_(2) evolution observed in Na_(2) Ti_(0.5)Mn_(2.5)O_7 upon charging,which stabilizes the lattice oxygen and ensures the overall structural stability.It exhibits increased capacity retention of 79.1% after 60 cycles in Na_(2) Ti_(0.5)Mn_(2.5)O_7(17.1% in Na_(2) Mn_(3) O_7) and good rate capability(92.1 mAh g^(-1) at 0.5 A g^(-1)).This investigation provides new insights into designing high-performance cathode materials with reversible ARR and structural stability for SIBs. 展开更多
关键词 Mn vacancy layered oxide cathode Anionic redox reaction Sodium-ion batteries
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Characterization of Li-rich layered oxides by using transmission electron microscope
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作者 Hu Zhao Bao Qiu +3 位作者 Haocheng Guo Kai Jia Zhaoping Liu Yonggao Xia 《Green Energy & Environment》 SCIE 2017年第3期174-185,共12页
Lithium-rich layered oxides(LrLOs) deliver extremely high specific capacities and are considered to be promising candidates for electric vehicle and smart grid applications. However, the application of LrLOs needs fur... Lithium-rich layered oxides(LrLOs) deliver extremely high specific capacities and are considered to be promising candidates for electric vehicle and smart grid applications. However, the application of LrLOs needs further understanding of the structural complexity and dynamic evolution of monoclinic and rhombohedral phases, in order to overcome the issues including voltage decay, poor rate capability, initial irreversible capacity loss and etc. The development of aberration correction for the transmission electron microscope and concurrent progress in electron spectroscopy, have fueled rapid progress in the understanding of the mechanism of such issues. New techniques based on the transmission electron microscope are first surveyed, and the applications of these techniques for the study of the structure, migration of transition metal, and the activation of oxygen of LrLOs are then explored in detail, with a particular focus on the mechanism of voltage decay. 展开更多
关键词 Lithium-ion battery Transmission electron microscope Lithium-rich layered oxide Cathode material
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Entropy-modulated and interlayer-doped transition metal layered oxides enable high-energy-density sodium-ion capacitors
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作者 Tiansheng Wang Yadong Li +8 位作者 Zhengyuan Chen Qingshan Liu Jian Lang Langyuan Wu Wendi Dong Zhengyu Ju Hongsen Li Xiaogang Zhang Guihua Yu 《Nano Research》 SCIE EI CSCD 2024年第10期8785-8793,共9页
In recent years,sodium-ion capacitors have attracted attention due to their cost-effectiveness,high power density and similar manufacturing process to lithium-ion capacitors.However,the utilization of oxide electrodes... In recent years,sodium-ion capacitors have attracted attention due to their cost-effectiveness,high power density and similar manufacturing process to lithium-ion capacitors.However,the utilization of oxide electrodes in traditional sodium-ion capacitors restricts their further advancement due to the inherent low operating voltage and electrolyte consumption based on their energy storage mechanism.To address these challenges,we incorporated Zn,Cu,Ti,and other elements into Na_(0.67)Ni_(0.33)Mn_(0.67)O_(2) to synthesize P2-type Na_(0.7)Ni_(0.28)Mn_(0.6)Zn_(0.05)Cu_(0.02)Ti_(0.05)O_(2) with a modulated entropy and pillaring Zn.Through the synergistic interplay between the interlayer pillar and the entropy modulation within the layers,the material exhibits exceptional toughness,effectively shielding it from detrimental phase transitions at elevated voltage regimes.As a result,the material showcases outstanding kinetic properties and long-term cycling stability across the voltage range.By integrating these materials with hierarchical porous carbon nanospheres to form a"rocking chair"sodium-ion capacitor,the hybrid full device delivers a high energy density(171 Wh·kg^(-1))and high power density(5245 W·kg^(-1)),as well as outstanding cycling stability(77% capacity retention after 3000 cycles).This work provides an effective material development route to realize simultaneously high energy and power for next-generation sodium-ion capacitors. 展开更多
关键词 sodium-ion capacitors entropy modulation high power density long-term cycling layered oxide
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Challenges and strategies of lithium-rich layered oxides for Li-ion batteries 被引量:2
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作者 Lu Nie Shaojie Chen Wei Liu 《Nano Research》 SCIE EI CSCD 2023年第1期391-402,共12页
Lithium-ion batteries are considered a promising energy storage technology in portable electronics and electric vehicles due to their high energy density,competitive cost,and environmental friendliness.Improving catho... Lithium-ion batteries are considered a promising energy storage technology in portable electronics and electric vehicles due to their high energy density,competitive cost,and environmental friendliness.Improving cathode materials is an effective way to meet the demand for better batteries,of which the utilization of high-voltage cathode materials is an important development trend.In recent years,lithium-rich layered oxides have gained great attention due to their desirable energy density.This review presents the relationships between lattice structure and electrochemical properties,the underlying degradation mechanisms,and corresponding modification strategies.The recent progress and strategies are then highlighted,including element doping,surface coating,morphology design,size control,etc.Finally,a concise perspective for future developments and practical applications of lithium-rich layered oxides has been provided. 展开更多
关键词 lithium-ion batteries lithium-rich layered oxides lattice structure degradation mechanism element doping
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Electrodes for Li-ion batteries: From high-voltage LiCoO_(2) to Coreduced /Co-free layered oxides with potential anodes
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作者 Luting Song Weiguo Chu 《Nano Research》 SCIE EI CSCD 2023年第12期12983-13007,共25页
Li-ion batteries(LIBs)are one type of more and more widely used devices for energy storage and power supply in which cathode materials are playing a relatively more decisive role at current stage.In this review,we sta... Li-ion batteries(LIBs)are one type of more and more widely used devices for energy storage and power supply in which cathode materials are playing a relatively more decisive role at current stage.In this review,we start with pioneeringly commercialized R¯3mLiCoO_(2)(LCO)with a layered rhombohedral structure(space group)to discuss novel sequentially emerging LCO-derived layered oxides from the perspectives of both cobalt content reduction and performance improvement.Emphasis is placed on the improvement of high-voltage performance of LCO and Co-reduced/free layered oxides,including Co-reduced high-nickel layered oxides,Co-free Li-rich layered oxides,and Ni-based layered oxides cathodes,and their underlying mechanisms via different strategies.Also,possibly matched carbon and silicon-based anode materials are briefly discussed.The common issues and prospects of the layered oxides cathodes and their potential anodes are summarized and commented on.This review can help understand the emergence logics of novel layered oxides with gradually vanishing cobalt involved,provide insights about the underlying mechanisms of performance enhancement pertaining to particular strategies,and even inspire the discovery of novel cathode materials with high performance and low cost. 展开更多
关键词 Li-ion batteries cathodic materials anode materials high-voltage LiCoO_(2) Co-reduced/free layered oxides
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High-entropy layered oxides nanosheets for highly efficient photoelectrocatalytic reduction of CO_(2)and application research
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作者 Xuefei Liu Xiaoyan Wang +2 位作者 Beibei Yang Junzheng Zhang Jun Lu 《Nano Research》 SCIE EI CSCD 2023年第4期4775-4785,共11页
High-entropy oxides receive significant attention owing to their“four effects”.However,they still suffer from harsh construction conditions such as high temperature and high pressure and present a block-like structu... High-entropy oxides receive significant attention owing to their“four effects”.However,they still suffer from harsh construction conditions such as high temperature and high pressure and present a block-like structure.Herein,in this work,Ni-Mn-Cu-Co-Fe-Al high-entropy layered oxides(HELOs)with a layered nanosheet structure were constructed by a simple pathway of topological transformation under relatively low temperature(300℃)with six-membered Ni-Mn-Cu-Co-Fe-Al layered double hydroxides(LDHs)precursors,which exhibited an outstanding activity and excellent selectivity for CO_(2)photoelectroreduction(obtaining the highest carbon monoxide yield of 909.55μmol·g^(−1)·h^(−1)under−0.8 V vs.reversible hydrogen electrode(RHE),which is almost twice that of pure electrocatalysis).In addition,the charging voltage of a photo-assisted Zn-CO_(2)battery with HELOs as electrode was reduced from 2.62 to 2.40 V;the discharging voltage of the battery was increased from 0.51 to 0.59 V with the assistance of illumination.The improvement of round-trip efficiency of the battery indicates that light played a positive role in both the charging and discharging processes.This study not only lays an important foundation for the development of high-entropy oxides but also expands their application in the field of photoelectrochemistry. 展开更多
关键词 high-entropy layered oxides(HELOs) CO_(2)reduction layered double hydroxides(LDHs) PHOTOELECTROCATALYTIC
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Alkali and alkaline ions co-substitution of P2 sodium layered oxides for sodium ion batteries
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作者 Yuncai Chen Maolin Yang +8 位作者 Liangtao Yang Ziwei Chen Huiyun Li Haw Jiunn Woo Shang-Sen Chi Yinguo Xiao Jun Wang Chaoyang Wang Yonghong Deng 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2023年第5期13-21,共9页
Alkali and alkaline ion substitutions enhance the electrochemical properties of P2 sodium layered oxide,while the effect on electrochemical property enhancement of alkali and alkaline ions co-substitution is still unc... Alkali and alkaline ion substitutions enhance the electrochemical properties of P2 sodium layered oxide,while the effect on electrochemical property enhancement of alkali and alkaline ions co-substitution is still unclear.In this work,the structural and electrochemical properties of the Li alkali and Mg alkaline ions co-substituted P2 layered oxide Na_(0.67)(Li_(0.5)Mg_(0.5))_(0.1)(Ni_(0.33)Mn_(0.67))_(0.9)O_(2)are investigated in detail.Compared to the pristine and single-ion substituted materials,the co-substituted material shows an enhanced cycling performance with a reversible ca-pacity of 127 mAh/g and a capacity retention of 75%over 100 cycles at 0.5C.Galvanostatic intermittent titration technique(GITT)and cyclic voltammetry(CV)results show that the Li and Mg synergistically improve the ion diffusion.Moreover,the structure stability is also improved by the Li and Mg co-substitution that is clarified by operando X-ray diffraction(XRD)measurements.These results explain the origin of the enhanced electrochemical properties of the Li/Mg co-substituted P2 layered oxides for sodium ion batteries. 展开更多
关键词 Sodium ions batteries Sodium layered oxides Alkali and alkaline elements co-substitution Neutron diffraction Structural evolution
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Approaching Ultimate Synthesis Reaction Rate of Ni-Rich Layered Cathodes for Lithium-Ion Batteries
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作者 Zhedong Liu Jingchao Zhang +9 位作者 Jiawei Luo Zhaoxin Guo Haoran Jiang Zekun Li Yuhang Liu Zijing Song Rui Liu Wei-Di Liu Wenbin Hu Yanan Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期392-402,共11页
Nickel-rich layered oxide LiNi_(x)Co_(y)MnzO_(2)(NCM,x+y+z=1)is the most promising cathode material for high-energy lithium-ion batteries.However,conventional synthesis methods are limited by the slow heating rate,slu... Nickel-rich layered oxide LiNi_(x)Co_(y)MnzO_(2)(NCM,x+y+z=1)is the most promising cathode material for high-energy lithium-ion batteries.However,conventional synthesis methods are limited by the slow heating rate,sluggish reaction dynamics,high energy consumption,and long reaction time.To overcome these chal-lenges,we first employed a high-temperature shock(HTS)strategy for fast synthesis of the NCM,and the approaching ultimate reaction rate of solid phase transition is deeply investigated for the first time.In the HTS process,ultrafast average reaction rate of phase transition from Ni_(0.6)Co_(0.2)Mn_(0.2)(OH)_(2) to Li-containing oxides is 66.7(%s^(-1)),that is,taking only 1.5 s.An ultrahigh heating rate leads to fast reaction kinetics,which induces the rapid phase transition of NCM cathodes.The HTS-synthesized nickel-rich layered oxides perform good cycling performances(94%for NCM523,94%for NCM622,and 80%for NCM811 after 200 cycles at 4.3 V).These findings might also assist to pave the way for preparing effectively Ni-rich layered oxides for lithium-ion batteries. 展开更多
关键词 Nickel-rich layered oxides High-temperature shock Solid reaction kinetics Phase transition Reaction rate
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Surface encapsulation of layered oxide cathode material with NiTiO_(3) for enhanced cycling stability of Na-ion batteries
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作者 胡紫霖 唐彬 +8 位作者 林挺 张楚 牛耀申 刘渊 高立克 谢飞 容晓晖 陆雅翔 胡勇胜 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期551-558,共8页
In Na-ion batteries,O3-type layered oxide cathode materials encounter challenges such as particle cracking,oxygen loss,electrolyte side reactions,and multi-phase transitions during the charge/discharge process.This st... In Na-ion batteries,O3-type layered oxide cathode materials encounter challenges such as particle cracking,oxygen loss,electrolyte side reactions,and multi-phase transitions during the charge/discharge process.This study focuses on surface coating with NiTiO_(3) achieved via secondary heat treatment using a coating precursor and the surface material.Through in-situ x-ray diffraction(XRD)and differential electrochemical mass spectrometry(DEMS),along with crystal structure characterizations of post-cycling materials,it was determined that the NiTiO_(3) coating layer facilitates the formation of a stable lattice structure,effectively inhibiting lattice oxygen loss and reducing side reaction with the electrolyte.This enhancement in cycling stability was evidenced by a capacity retention of approximately 74%over 300 cycles at 1 C,marking a significant 30%improvement over the initial sample.Furthermore,notable advancements in rate performance were observed.Experimental results indicate that a stable and robust surface structure substantially enhances the overall stability of the bulk phase,presenting a novel approach for designing layered oxide cathodes with higher energy density. 展开更多
关键词 Na-ion battery layered oxides high voltage surface coating
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Achieving structurally stable O3-type layered oxide cathodes through site-specific cation-anion co-substitution for sodium-ion batteries
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作者 Yihao Shen Chen Cheng +5 位作者 Xiao Xia Lei Wang Xi Zhou Pan Zeng Jianrong Zeng Liang Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期411-418,I0011,共9页
O3-type layered oxides have garnered great attention as cathode materials for sodium-ion batteries because of their abundant reserves and high theoretical capacity.However,challenges persist in the form of uncontrolla... O3-type layered oxides have garnered great attention as cathode materials for sodium-ion batteries because of their abundant reserves and high theoretical capacity.However,challenges persist in the form of uncontrollable phase transitions and intricate Na^(+)diffusion pathways during cycling,resulting in compromised structural stability and reduced capacity over cycles.This study introduces a special approach employing site-specific Ca/F co-substitution within the layered structure of O_(3)-NaNi_(0.5)Mn_(0.5)O_(2) to effectively address these issues.Herein,the strategically site-specific doping of Ca into Na sites and F into O sites not only expands the Na^(+)diffusion pathways but also orchestrates a mild phase transition by suppressing the Na^(+)/vacancy ordering and providing strong metal-oxygen bonding strength,respectively.The as-synthesized Na_(0.95)Ca_(0.05)Ni_(0.5)Mn_(0.5)O_(1.95)F_(0.05)(NNMO-CaF)exhibits a mild O3→O3+O'3→P3 phase transition with minimized interlayer distance variation,leading to enhanced structural integrity and stability over extended cycles.As a result,NNMO-CaF delivers a high specific capacity of 119.5 mA h g^(-1)at a current density of 120 mA g^(-1)with a capacity retention of 87.1%after 100 cycles.This study presents a promising strategy to mitigate the challenges posed by multiple phase transitions and augment Na^(+)diffusion kinetics,thus paving the way for high-performance layered cathode materials in sodium-ion batteries. 展开更多
关键词 Sodium-ion batteries O3-type layered oxides Site-specific co-doping Phase transition
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A Facile Li_(2)TiO_(3) Surface Modification to Improve the Structure Stability and Electrochemical Performance of Full Concentration Gradient Li-Rich Oxides
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作者 Naifang Hu Yuan Yang +5 位作者 Lin Li Yuhan Zhang Zhiwei Hu Lan Zhang Jun Ma Guanglei Cui 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期41-48,共8页
Full concentration gradient lithium-rich layered oxides are catching lots of interest as the next generation cathode for lithium-ion batteries due to their high discharge voltage,reduced voltage decay and enhanced rat... Full concentration gradient lithium-rich layered oxides are catching lots of interest as the next generation cathode for lithium-ion batteries due to their high discharge voltage,reduced voltage decay and enhanced rate performance,whereas the high lithium residues on its surface impairs the structure stability and long-term cycle performance.Herein,a facile multifunctional surface modification method is implemented to eliminate surface lithium residues of full concentration gradient lithium-rich layered oxides by a wet chemistry reaction with tetrabutyl titanate and the post-annealing process.It realizes not only a stable Li_(2)TiO_(3)coating layer with 3D diffusion channels for fast Li^(+)ions transfer,but also dopes partial Ti^(4+)ions into the sub-surface region of full concentration gradient lithium-rich layered oxides to further strengthen its crystal structure.Consequently,the modified full concentration gradient lithium-rich layered oxides exhibit improved structure stability,elevated thermal stability with decomposition temperature from 289.57℃to 321.72℃,and enhanced cycle performance(205.1 mAh g^(-1)after 150 cycles)with slowed voltage drop(1.67 mV per cycle).This work proposes a facile and integrated modification method to enhance the comprehensive performance of full concentration gradient lithium-rich layered oxides,which can facilitate its practical application for developing higher energy density lithium-ion batteries. 展开更多
关键词 full concentration gradient lithium-rich layered oxides structure stability surface modification
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Tuning exsolution of nanoparticles in defect engineered layered perovskite oxides for efficient CO_(2) electrolysis 被引量:1
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作者 Zhengrong Liu Jun Zhou +7 位作者 Yueyue Sun Xiangling Yue Jiaming Yang Lei Fu Qinyuan Deng Hongfei Zhao Chaofan Yin Kai Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期219-227,共9页
Solid oxide electrolysis cell(SOEC) could be a potential technology to afford chemical storage of renewable electricity by converting water and carbon dioxide.In this work,we present the Ni-doped layered perovskite ox... Solid oxide electrolysis cell(SOEC) could be a potential technology to afford chemical storage of renewable electricity by converting water and carbon dioxide.In this work,we present the Ni-doped layered perovskite oxides,(La_(4)Sr_(n-4))_(0.9)Ti_(0.9n)Ni_(0.1n)O_(3n+2) with n=5,8,and 12(LSTNn) for application as catalysts of CO_(2) electrolysis with the exsolution of Ni nanoparticles through a simple in-situ growth method.It is found that the density,size,and distribution of exsolved Ni nanoparticles are determined by the number of n in LSTNn due to the different stack structures of TiO_6 octahedra along the c axis.The Ni doping in LSTNn significantly improved the electrochemical activity by increasing oxygen vacancies,and the Ni metallic nanoparticles afford much more active sites.The results show that LSTNn cathodes can successfully be manipulated the activity by controlling both the n number and Ni exsolution.Among these LSTNn(n=5,8,and 12),LSTN8 renders a higher activity for electrolysis of CO_(2) with a current density of 1.50A cm^(-2)@2.0 V at 800℃ It is clear from these results that the number of n in(La_(4)Sr_(n-4))_(0.9)Ti_(0.9n)Ni_(0.1n)O_(3n+2)with Ni-doping is a key factor in controlling the electrochemical performance and catalytic activity in SOEC. 展开更多
关键词 layered perovskite oxides In-situ growth SOEC TITANATE
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High‑Entropy Layered Oxide Cathode Enabling High‑Rate for Solid‑State Sodium‑Ion Batteries 被引量:3
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作者 Tianxun Cai Mingzhi Cai +5 位作者 Jinxiao Mu Siwei Zhao Hui Bi Wei Zhao Wujie Dong Fuqiang Huang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期160-171,共12页
Na-ion O3-type layered oxides are prospective cathodes for Na-ion batteries due to high energy density and low-cost.Nevertheless,such cathodes usually suffer from phase transitions,sluggish kinetics and air instabilit... Na-ion O3-type layered oxides are prospective cathodes for Na-ion batteries due to high energy density and low-cost.Nevertheless,such cathodes usually suffer from phase transitions,sluggish kinetics and air instability,making it difficult to achieve high performance solid-state sodium-ion batteries.Herein,the high-entropy design and Li doping strategy alleviate lattice stress and enhance ionic conductivity,achieving high-rate performance,air stability and electrochemically thermal stability for Na_(0.95)Li_(0.06)Ni_(0.25)Cu_(0.05)Fe_(0.15)Mn_(0.49)O_(2).This cathode delivers a high reversible capacity(141 mAh g^(−1)at 0.2C),excellent rate capability(111 mAh g^(−1)at 8C,85 mAh g^(−1)even at 20C),and long-term stability(over 85%capacity retention after 1000 cycles),which is attributed to a rapid and reversible O3–P3 phase transition in regions of low voltage and suppresses phase transition.Moreover,the compound remains unchanged over seven days and keeps thermal stability until 279℃.Remarkably,the polymer solid-state sodium battery assembled by this cathode provides a capacity of 92 mAh g^(−1)at 5C and keeps retention of 96%after 400 cycles.This strategy inspires more rational designs and could be applied to a series of O3 cathodes to improve the performance of solid-state Na-ion batteries. 展开更多
关键词 High-entropy High-rate performance Li-TM interaction Air stability O3 layered oxide cathode
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Cycling performance of layered oxide cathode materials for sodium-ion batteries
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作者 Jinpin Wu Junhang Tian +1 位作者 Xueyi Sun Weidong Zhuang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第7期1720-1744,共25页
Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the applicat... Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity,high operating voltage,and simple synthesis.Cycling performance is an important criterion for evaluating the application prospects of batteries.However,facing challenges,including phase transitions,ambient stability,side reactions,and irreversible anionic oxygen activity,the cycling performance of layered oxide cathode materials still cannot meet the application requirements.Therefore,this review proposes several strategies to address these challenges.First,bulk doping is introduced from three aspects:cationic single doping,anionic single doping,and multi-ion doping.Second,homogeneous surface coating and concentration gradient modification are reviewed.In addition,methods such as mixed structure design,particle engineering,high-entropy material construction,and integrated modification are proposed.Finally,a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials. 展开更多
关键词 sodium-ion battery layered oxide materials cycling performance bulking doping surface coating concentration gradient mixed structure high-entropy
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