Lamellar water induced quantized interlayer spacing of nanochannels walls

The nanoscale confinement is of great important for the industrial applications of molecular sieve,desalination,and also essential in bio-logical transport systems.Massive efforts have been devoted to the influence of restricted spaces on the properties of confined fluids.However,the situation of channel-wall is crucial but attracts less attention and remains unknown.To fundamentally understand the mechanism of channel-walls in nanoconfinement,we investigated the interaction between the counter-force of the liquid and interlamellar spacing of nanochannel walls by considering the effect of both spatial confinement and surface wettability.The results reveal that the nanochannel stables at only a few discrete spacing states when its confinement is within 1.4 nm.The quantized interlayer spacing is attributed to water molecules becoming laminated structures,and the stable states are corresponding to the monolayer,bilayer and trilayer water configurations,respectively.The results can potentially help to understand the characterized interlayers spacing of graphene oxide membrane in water.Our findings are hold great promise in design of ion filtration membrane and artificial water/ion channels.

Layer regrouping for water-flooded commingled reservoirs at a high water-cut stage

Layer regrouping is to divide all the layers into several sets of production series according to the physical properties and recovery percent of layers at high water-cut stage, which is an important technique to improve oil recovery for high water-cut multilayered reservoirs. Dif- ferent regroup scenarios may lead to different production performances. Based on unstable oil-water flow theory, a multilayer commingled reservoir simulator is established by modifying the production split method. Taking into account the differences of layer properties, including per- meability, oil viscosity, and remaining oil saturation, the pseudo flow resistance contrast is proposed to serve as a characteristic index of layer regrouping for high water-cut multilayered reservoirs. The production indices of multi- layered reservoirs with different pseudo flow resistances are predicted with the established model in which the data are taken from the Shengtuo Oilfield. Simulation results show that the pseudo flow resistance contrast should be less than 4 when the layer regrouping is implemented. The K-means clustering method, which is based on the objec- tive function, is used to automatically carry out the layer regrouping process according to pseudo flow resistances. The research result is applied to the IV-VI sand groups of the second member of the Shahejie Formation in the Shengtuo Oilfield, a favorable development performance is obtained, and the oil recovery is enhanced by 6.08 %.

Water masses classification of the upper layer in the Equatorial Western Pacific using ISODATA of fuzzy cluster

-In this paper,by using ISODATA of fuzzy cluster,the water masses classification of the upper layer in the E-quatorial Western Pacific is carried out. On the basis of the degree of the membership in the obtained optima) classification matrix, the solid distribution of the detailed structure of water masses is made. The water of the upper layer,consisting of six water masses,may be divided into three layers,i, e. ,the surface,subsurface and intermediate layer. Besides analyzing the features of various water masses,a discussion on their distribution structure and formation mechanism is also made.

Enhancement of water self-diffusion at super-hydrophilic surface with ordered water

It has been well acknowledged that molecular water structures at the interface play an important role in the surface properties, such as wetting behavior or surface frictions. Using molecular dynamics simulation, we show that the water self-diffusion on the top of the first ordered water layer can be enhanced near a super-hydrophilic solid surface. This is attributed to the fewer number of hydrogen bonds between the first ordered water layer and water molecules above this layer, where the ordered water structures induce much slower relaxation behavior of water dipole and longer lifetime of hydrogen bonds formed within the first layer.

Rogoznica Lake(Croatia),a Unique Euxinic Seawater System on the Adriatic Coast

1 Introduction Rogoznica Lake is a typical example of euxinic saline lake,situated on the eastern Adriatic coast(43o32’N15o58’E).It is a karstic depression filled with seawater,

THE CAUCHY PROBLEM FOR THE TWO LAYER VISCOUS SHALLOW WATER EQUATIONS

In this paper,the Cauchy problem for the two layer viscous shallow water equations is investigated with third-order surface-tension terms and a low regularity assumption on the initial data.The global existence and uniqueness of the strong solution in a hybrid Besov space are proved by using the Littlewood-Paley decomposition and Friedrichs'regularization method.

Water-Excluding Underwater Glue Induced by Marangoni Effect

Marangoni effect at the two-phase interface with different surface tension as a unique mass transfer phenomenon has been widely used in daily life and industrialmanufacture.However,their marvelous liquid-driving capability between miscible liquids has long been ignored,especially in water environments.Here,we first reveal a distinct underwater Marangoni effect between the solvent of glues and the water layer on solid surfaces.Driven by the Marangoni effect,organic solvents with water solubility,high dielectric constant,and low diffusivity could effectively exclude the interfacial water layer,enabling direct and effective contact between glues and solid surfaces.Our experimental results and theoretical simulation proved that a relatively large ratio of the Marangoni number in the horizontal direction and to the vertical direction ensured an effective underwater adhesion of the water-excluding glue.This surface engineering approach provides an alternative to the traditional methods of molecular engineering for realizing underwater adhesion.

The Top of the Biomimetic Triangle

There is increasing observational evidence indicating that crystalline interfacial water layers play a central role in evolution and biology. For instance in cellular recognition processes, in particular during first contact events, where cells decide upon survival or entering apoptosis. Understanding water layers is thus crucial in biomedical engineering, specifically in the design of biomaterials inspired by biomimetic principles. Whereas there is ample experimental evidence for crystalline interfacial water layers on surfaces in air, their subaquatic presence could not be verified directly, so far. Analysing a polarity dependent asym- metry in the surface conductivity on hydrogenated nanocrystalline diamond, we show that crystalline interfacial water layers persist subaquatically. Nanoscopic interfacial water layers with an order different from that of bulk water have been identified at room temperature on both hydrophilic and hydrophobic model surfaces - in air and subaquatically. Their generalization and systematic inclusion into the catalogue of physical and chemical determinants of biocompatibility complete the biomimetic triangle.

Nature Inspired Hay Fever Therapy

The survival oriented adaptation of evolved biosystems to variations in their environment is a selective optimization process. Recognizing the optimised end product and its functionality is the classical arena of bionic engineering. In a primordial world, however, the molecular organization and functions of prebiotic systems were solely defined by formative processes in their physical and chemical environment, for instance, the interplay between interfacial water layers on surfaces and solar light. The formative potential of the interplay between light （laser light） and interfacial water layers on surfaces was recently exploited in the formation of supercubane carbon nanocrystals. In evolved biosystems the formative potential of interracial water layers can still be activated by light. Here we report a case of hay fever, which was successfully treated in the course of a facial rejuvenation program starting in November 2007. Targeting primarily interfacial water layers on elastin fibres in the wrinkled areas, we presumably also activated mast cells in the nasal mucosa, reported to progressively decrease in the nasal mucosa of the rabbit, when frequently irradiated. Hay fever is induced by the release of mediators, especially histamine, a process associated with the degranulation of mast cells. Decrease in mast cells numbers implies a decrease in the release of histamine. To the best of our knowledge this is the first report on the treatment of hay fever with visible light. This approach was inspired by bionic thinking, and could help ameliorating the condition of millions of people suffering from hay fever world wide.

Optimization of the wash process and wash water recycling in the preparation of MgZnAl-CO_3 layered double hydroxides

An MgZnAI-CO3 layered double hydroxide （LDH） slurry with Na2 S04 as the by-product has been prepared by a co-precipitation method. The filtrates in the LDH washing process were collected according to their different levels of salinity. Filtrates with lower salinity can be used to wash a LDH slurry with higher salinity in the next cycle. Only in the final stages is pure water used. Recycling of the wash water in this way has been employed in a commercial production process, resulting in a water-saving of over 80%. The resulting MgZnAI-CO3-LDH product has a well-formed crystalline layered structure with a low content of impurities.

Pan Gnammas (Weathering Pits) across Australia: Morphology in Response to Formative Processes

Pan gnammas occur across Australia, mainly in granites and sandstones. Their morphology and origins on Eyre Peninsula, South Australia are known, but this Twidale model is not applicable everywhere. I investigated their morphology and theorized on their origins at eight sites across the continent, noting particularly their edge profiles, floors and depths in relation to their geological placement. The steep sides, flat floors, depths up to about 25 cm in laminated granites apply only in the hot climates of Western Australia and South Australia. Laminations are rare in Victorian granites, so their pan gnammas have sloped edges and are not as deep (ca. 10 cm) and in the granitic uplands of southeast Queensland, corrosion at the edge is concentrated to a narrow zone and most gnammas are only ca. 5 cm deep. Gnammas in horizontal sandstones in New South Wales and Queensland have steep or sloping edges and reach ca 10 cm deep but in dipping sandstones of the Grampians, Victoria horizontality of corrosion has produced visors at pan edges. The vertically bedded Uluru sandstones have enabled deeper corrosion and pans of different morphology. Regional depth variation has biological consequences.

Ionic liquids in electrocatalysis

The performance of an electrocatalyst, which is needed e.g. for key energy conversion reactions such as hydrogen evolution, oxygen reduction or CO2 reduction, is determined not only by the inherent structure of active sites but also by the properties of the interfacial structures at catalytic surfaces. Ionic liquids（ILs）, as a unique class of metal salts with melting point below 100 ℃, present themselves as ideal modulators for manipulations of the interfacial structures. Due to their excellent properties such as good chemical stability, high ionic conductivity, wide electrochemical windows and tunable solvent properties the performance of electrocatalysts can be substantially improved through ILs. In the current minireview, we highlight the critical role of the IL phase at the microenvironments created by the IL, the liquid electrolyte, catalytic nanoparticles and/or support materials, by detailing the promotional effect of IL in electrocatalysis as reaction media, binders, and surface modifiers. Updated exemplary applications of IL in electrocatalysis are given and moreover, the latest developments of IL modified electrocatalysts following the ＂Solid Catalyst with Ionic Liquid Layer（SCILL）＂ concept are presented.

NirS-type denitrifying bacteria in aerobic water layers of two drinking water reservoirs: Insights into the abundance, community diversity and co-existence model

The nirS-type denitrifying bacterial community is the main drivers of the nitrogen loss process in drinking water reservoir ecosystems.The temporal patterns in nirS gene abundance and nirS-type denitrifying bacterial community harbored in aerobic water layers of drinking water reservoirs have not been studied well.In this study,quantitative polymerase chain reaction(qPCR)and Illumina Miseq sequencing were employed to explore the nirS gene abundance and denitrifying bacterial community structure in two drinking water reservoirs.The overall results showed that the water quality parameters in two reservoirs had obvious differences.The qPCR results suggested that nirS gene abundance ranged from(2.61±0.12)×10^(5) to(3.68±0.16)×10^(5) copies/mL and(3.01±0.12)×10^(5) to(5.36±0.31)×10^(5) copies/mL in Jinpen and Lijiahe reservoirs,respectively.The sequencing results revealed that Paracoccus sp.,Azoarcus sp.,Dechloromonas sp.and Thauera sp.were the dominant genera observed.At species level,Cupriavidus necator,Dechloromonas sp.R-28400,Paracoccus denitrificans and Pseudomonas stutzeri accounted for more proportions in two reservoirs.More importantly,the co-occurrence network analysis demonstrated that Paracoccus sp.R-24615 and Staphylococcus sp.N23 were the keystone species observed in Jinpen and Lijiahe reservoirs,respectively.Redundancy analysis indicated that water quality(particularly turbidity,water temperature,pH and Chlorophyll a)and sampling time had significant influence on the nirS-type denitrifying bacterial community in both reservoirs.These results will shed new lights on exploring the dynamics of nirS-type denitrifying bacteria in aerobic water layers of drinking water reservoirs.

Transformation optics for efficient calculation of transmembrane voltage induced on cells

We present a novel efficient approach in calculating induced transmembrane voltage（ITV） on cells based on transformation optics. As cell membrane is much thinner than the dimension of a typical cell, discretizing the membrane needs numerous meshes. Using an anisotropic medium based on transformation optics, the thickness of the membrane can be exaggerated by at least one order, which eliminates rigorous mesh refinement and reduces unknowns greatly. The accuracy and efficiency of the proposed method are verified by a cylindrical cell model. Moreover, the influence on ITV with bound water（BW） layers is also studied. The results show that when cells are exposed to nanosecond electric field, BW layers should be rigorously considered in calculating ITV.

Construction Technology and Quality Control of Double Layer Continuous Paving of Cement Stabilized Macadam Base

The construction method of continuous paving of the upper and lower base of the water stable macadam base can improve the construction efficiency,overcome the quality problems of the traditional layered paving of the upper and lower base,such as untimely curing,slow construction,poor interlayer bonding,contraction joint and interlayer,so as to ensure the construction quality of the water stable macadam.It is also the promotion and application of new technology.

Properties of a water layer on hydrophilic and hydrophobic self-assembled monolayer surfaces: A molecular dynamics study

The microscopic behaviors of a water layer on different monolayers （SAMs） are studied by molecular dynamics hydrophilic and hydrophobic surfaces of well ordered self-assembled simulations. The SAMs consist of 18-carbon alkyl chains bound to a silicon（111） substrate, and the characteristic of its surface is tuned from hydrophobic to hydrophilic by using different terminal functional groups （-CH3, -COOH）. In the simulation, the properties of water membranes adjacent to the surfaces of SAMs were reported by comparing pure water in mobility, structure, and orientational ordering of water molecules. The results sug- gest that the mobility of water molecules adjacent to hydrophilic surface becomes weaker and the molecules have a better or- dering. The distribution of hydrogen bonds indicates that the number of water-water hydrogen bonds per water molecule tends to be lower. However, the mobility of water molecules and distribution of hydrogen bonds of a water membrane in hydropho- bic system are nearly the same as those in pure water system. In addition, hydrogen bonds are mainly formed between the hy- droxyl of the COOH group and water molecules in a hydrophilic system, which is helpful in understanding the structure of in- terfacial water.

Water storage variations of the Yangtze,Yellow,and Zhujiang river basins derived from the DEOS Mass Transport (DMT-1) model

In general, China is short of water resources and some regions even experience a shortage of daily water supply. This could threaten the stability and economic development of the nation. A study on the water storage variations is especially important for the water management and storage prediction in three largest river basins of China, namely, Yangtze, Yellow, and Zhujiang, where the most dense population and leading economic regions are located. The satellite gravity mission GRACE （Gravity Recovery and Climate Experiment） provides an opportunity to macroseopically identify water （or mass） variations in the Earth＇s system with a spatial resolution of 300-400 km and a temporal resolution of about one month. We use the first release of the DEOS （Delft Institute of Earth Observation and Space Systems） Mass Transport （DMT-1） model based on GRACE data to analyze water storage changes in the three river basins. The DMT-1 model consists of monthly solutions, which are computed using an innovative methodology. The methodology includes, in particular, the application of a statistically optimal Wiener-type filter based on full varianee-covariance matrices of noise and signal. This results in particularly sharp mass variation maps. Taking one monthly solution as an example, we compare the results derived from the DMT-1 model with ones produced with the standard post-processing scheme based on a combination of the de-striping and Gaussian filtering. The comparison shows that the DMT-1 model outperforms the other models and is suitable for the analysis of the mass changes in river basins. A subset of the DMT-1 solutions in the interval between February 2003 and May 2008 is used to estimate the secular trends and seasonal variations for the three river basins. The estimated trends show that the water storage of the Yellow River basin does not have significant changes, while the Zhujiang and Yangtze river basins have a large and statistically significant water storage increase. The estimation of seasonal variations demonstrates that the water storage variations in Yangtze and Zhujiang river basins are almost in the same phase. The amplitude of variations in the Zhujiang River basin is larger than that in Yangtze. No clear annual variations are observed in the Yellow River basin. The observed water storage variations generally coincide with the observations and conclusions presented in the hydrological reports of the Chinese Ministry of Water Resources

Experimental Study of Turbulent Wake Behind a Sine Shaped Island in a Shallow-Water Layer

A series of experiments is conducted to study shallow-water flow in the wake of a sine shaped island. Digital particle imaging velocimetry (DPIV) is used to measure velocities in the turbulent wake behind a sine shaped island for different characteristic coefficients S. Flow streamlines are given for the wake flows. The measured results show that the characteristic coefficient S is uniquely related to the flow pattern around a sine shaped island in a shallow water layer. An S value of approximately 0.20 is the critical value for transition from a vortex street to unsteady flow and a value of approximately 0.40 is the critical value for transition from unsteady flow to steady flow.

Pyrolysis preparation of WO_3 thin films using ammonium metatungstate DMF/water solution for efficient compact layers in planar perovskite solar cells

The tungsten trioxide（WO3） thin films were firstly prepared by spin-coating-pyrolysis methods using the ammonium metatungstate（（NH4）6H2W12O40）DMF/water solution, and successfully applied as the efficient compact layers for the planar perovskite solar cells. The influence of the WO3 film thickness and the rinsing treatment of CH_3NH_3 PbI_3 thin film with isopropanol on the photovoltaic performance of the corresponding perovskite solar cells was systematically investigated. The results revealed that the perovskite solar cell with a 62 nm thick WO3 compact layer achieved a photoelectric conversion efficiency of 5.72%, with a short circuit photocurrent density of 17.39 mA/cm^2, an open circuit voltage of 0.58 V and a fill factor of 0.57. The photoelectric conversion efficiency was improved from 5.72% to 7.04% by the isopropanol rinsing treatment.

ON THE ICE NUCLEATION BY CONTACT ON THE INNER AND OUTER LAYER OF A WATER DROP

Nucleation of ice by contact takes place when an aerosol particle collides with asurface of supercooled water drop.Aerosol particle may either bounce off the watersurface or be captured on it.McCully et al.(1956) and Rosinski et al.(1963) have shownthat capture of hydrophilic particles was four times larger than of hydrophobic ones.Hydrophobic aerosol particles will nucleate ice preferentially during the brief time ofcontact when they bounce off the surface.Patricles that become captured on the surfacewill float and produce clusters that may nucleate ice at some later time (delayed on surface