基于YOLOv5_4layers的PCB小目标缺陷识别方法

针对PCB表面缺陷分辨率低、小目标性以及多样性等问题,提出了一种基于YOLOv5_4layers的PCB小目标缺陷识别方法。该方法在YOLOv5架构的基础上,通过新增采样层的方式添加小目标检测层,优化特征金字塔模型,提升小目标特征提取性能,实现小目标缺陷识别。在调整合适的锚框规格后,改进后的模型在输入640像素×640像素图像时,相较原模型识别精确率提升了7.5%。在输入736像素×736像素图像时,识别精确率提升了1.3%,有效地提升了对PCB小目标缺陷的识别能力,对提高PCB制造过程的质量控制和产品可靠性具有实际意义。

Quantum dynamics within curved thin layers with deviation

Combining the deviation between thin layers' adjacent surfaces with the confining potential method applied to the quantum curved systems,we derive the effective Schr?dinger equation describing the particle constrained within a curved layer,accompanied by a general geometric potential V_(gq) composed of a compression-corrected geometric potential V_(gq)~*and a novel potential V_(gq)~(**) brought by the deviation.Applying this analysis to the cylindrical layer emerges two types of deviation-induced geometric potential,resulting from the the cases of slant deviation and tangent deviation,respectively,which strongly renormalizes the purely geometric potential and contribute to the energy spectrum based on a very substantial deepening of bound states they offer.

Indispensable gutter layers in thin-film composite membranes for carbon capture

Industrial thin-film composite(TFC)membranes achieve superior gas separation properties from high-performance selective layer materials,while the success of membrane technology relies on high-performance gutter layers to achieve production scalability and low-cost manufacturing.However,the current literature predominantly focuses on the design of polymer architectures to obtain high permeability and selectivity,while the art of fabricating gutter layers is usually safeguarded by industrial manufacturers and appears lackluster to academic researchers.This is the first report aiming to provide a comprehensive and critical review of state-of-the-art gutter layer materials and their design and modification to enable TFC membranes with superior separation performance.We first elucidate the importance of the gutter layer on membrane performance through modeling and experimental results.Then various gutter layer materials used to obtain high-performance composite membranes are critically reviewed,and the strategies to improve their compatibility with the selective layer are highlighted,such as oxygen plasma treatment,polydopamine deposition,and surface grafting.Finally,we present the opportunities of the gutter layer design for practical applications.

FlowBreakdown of Hybrid Nanofluid on a Rigid Surface with Power Law Fluid as Lubricated Layers

Thiswork investigates an oblique stagnation point flowof hybrid nanofluid over a rigid surface with power lawfluidas lubricated layers. Copper (Cu) and Silver (Ag) solid particles are used as hybrid particles acting in water H2O asa base fluid. The mathematical formulation of flow configuration is presented in terms of differential systemthat isnonlinear in nature. The thermal aspects of the flow field are also investigated by assuming the surface is a heatedsurface with a constant temperature T. Numerical solutions to the governing mathematical model are calculatedby the RK45 algorithm. The results based on the numerical solution against various flow and thermal controllingparameters are presented in terms of line graphs. The specific results depict that the heat flux increases over thelubricated-indexed parameter.

Coated boron layers by boronization and a real-time boron coating using an impurity powder dropper in the LHD

In the Large Helical Device(LHD),diborane(B2H6)is used as a standard boron source for boronization,which is assisted by helium glow discharges.In 2019,a new Impurity Powder Dropper(IPD)system was installed and is under evaluation as a real-time wall conditioning technique.In the LHD,which is a large-sized heliotron device,an additional helium(He)glow discharge cleaning(GDC)after boronization was operated for a reduction in hydrogen recycling from the coated boron layers.This operational time of 3 h was determined by spectroscopic data during glow discharges.A flat hydrogen profile is obtained on the top surface of the coated boron on the specimen exposed to boronization.The results suggest a reduction in hydrogen at the top surface by He-GDC.Trapped oxygen in coated boron was obtained by boronization,and the coated boron,which has boron-oxide,on the first wall by B-IPD was also shown.Considering the difference in coating areas between B2H6 boronization and B-IPD operation,it would be most effective to use the IPD and B2H6 boronization coating together for optimized wall conditioning.

Graphene effectively activating "dead" water molecules between manganese dioxide layers in potassium-ion battery

Aqueous potassium-ion batteries(APIBs),recognized as safe and reliable new energy devices,are considered as one of the alternatives to traditional batteries.Layered MnO_(2),serving as the main cathode,exhibits a lower specific capacity in aqueous electrolytes compared to organic systems and operates through a different reaction mechanism.The application of highly conductive graphene may effectively enhance the capacity of APIBs but could complicate the potassium storage environment.In this study,a MnO_(2) cathode pre-intercalated with K~+ions and grown on graphene(KMO@rGO) was developed using the microwave hydrothermal method for APIBs.KMO@rGO achieved a specific capacity of 90 mA h g^(-1) at a current density of 0.1 A g^(-1),maintaining a capacity retention rate of>90% after 5000 cycles at 5 A g^(-1).In-situ and exsitu characterization techniques revealed the energy-storage mechanism of KMO@rGO:layered MnO_(2)traps a large amount of "dead" water molecules during K~+ions removal.However,the introduction of graphene enables these water molecules to escape during K~+ ions insertion at the cathode.The galvanostatic intermittent titration technique and density functional theory confirmed that KMO@rGO has a higher K~+ions migration rate than MnO_(2).Therefore,the capacity of this cathode depends on the interaction between dead water and K~+ions during the energy-storage reaction.The optimal structural alignment between layered MnO_(2) and graphene allows electrons to easily flow into the external circuit.Rapid charge compensation forces numerous low-solvent K~+ions to displace interlayer dead water,enhancing the capacity.This unique reaction mechanism is unprecedented in other aqueous battery studies.

Effect of carbon material and surfactant on ink property and resulting surface cracks of fuel-cell microporous layers

Ensuring the consistency of electrode structure in proton-exchange-membrane fuel cells is highly desired yet challenging because of wide-existing and unguided cracks in the microporous layer(MPL). The first thing is to evaluate the homogeneity of MPL with cracks quantitatively. This paper proposes the homogeneity index of a full-scale MPL with an area of 50 cm~2, which is yet to be reported in the literature to our knowledge. Besides, the effects of the carbon material and surfactant on the ink and resulting MPL structure have been studied. The ink with a high network development degree produces an MPL with low crack density, but the ink with high PDI produces an MPL with low crack homogeneity. The polarity of the surfactant and the non-polarity of polytetrafluoroethylene(PTFE) are not mutually soluble,resulting in the heterogeneous PTFE distribution. The findings of this study provide guidelines for MPL fabrication.

Boosting the cycling stability of all-solid-state lithium metal batteries through MOF-based polymeric protective layers

Solid-state electrolytes(SSEs)play a pivotal role in advancing next-generation lithium metal battery technology.However,they commonly encounter substantial interfacial resistance and poor stability when interfacing with lithium metal,hindering practical applications.Herein,we introduce a flexible metal-organic framework(MOF:NUS-6)-incorporated polymeric layer,denoted as NP,designed to protect the sodium superionic conductor(NASICON)-type Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)electrolyte from Li metal anodes.The NP matrix establishes a soft interface with the LATP surface,effectively reducing voids and gaps that may arise between the LATP electrolyte and Li metal.Moreover,the MOF component in NP enhances ionic conductivity,offers abundant Li^(+)transport sites,and provides hierarchical ion channels,ensuring a homogeneous Li^(+)flow and thus effectively inhibiting Li dendrite formation.Utilizing NP,we fabricate Li symmetrical cells cycled for over 1600 h at 0.2 mA cm^(-2)and all-solid-state LiINP-LATPI LiFePO_(4)batteries,achieving a remarkable 99.3%capacity retention after 200 cycles at 0.2 C.This work outlines a general strategy for designing long-lasting and stable solid-state Li metal batteries.

Engineering hydrophobic protective layers on zinc anodes for enhanced performance in aqueous zinc-ion batteries

Aqueous zinc-ion batteries possess substantial potential for energy storage applications;however,they are hampered by challenges such as dendrite formation and uncontrolled side reactions occurring at the zinc anode.In our investigation,we sought to mitigate these issues through the utilization of in situ zinc complex formation reactions to engineer hydrophobic protective layers on the zinc anode surface.These robust interfacial layers serve as effective barriers,isolating the zinc anode from the electrolyte and active water molecules and thereby preventing hydrogen evolution and the generation of undesirable byproducts.Additionally,the presence of numerous zincophilic sites within these protective layers facilitates uniform zinc deposition while concurrently inhibiting dendrite growth.Through comprehensive evaluation of functional anodes featuring diverse functional groups and alkyl chain lengths,we meticulously scrutinized the underlying mechanisms influencing performance variations.This analysis involved precise modulation of interfacial hydrophobicity,rapid Zn^(2+)ion transport,and ordered deposition of Zn^(2+)ions.Notably,the optimized anode,fabricated with octadecylphosphate(OPA),demonstrated exceptional performance characteristics.The Zn//Zn symmetric cell exhibited remarkable longevity,exceeding 4000 h under a current density of 2 mA cm^(-2)and a capacity density of 2 mA h cm^(-2),Furthermore,when integrated with a VOH cathode,the complete cell exhibited superior capacity retention compared to anodes modified with alternative organic molecules.

Preserving the Ozone Layers: Battling Illegal Trade in Ozone-Depleting Substances

The depletion of the ozone layer, a vital shield protecting the Earth from harmful ultraviolet (UV) radiation, is now a worldwide environmental concern. Human activities, particularly the release of ozone depleting substances (ODS), have led to the thinning of this protective layer over recent decades. Simultaneously, illegal trade has emerged as a global challenge, giving rise to economic issues, losses of tax revenue, heightened criminal activities, health risks, and environmental hazards. The depletion of the ozone layer, a critical shield protecting the Earth from harmful ultraviolet (UV) radiation, has become a global environmental concern. This paper delves into the legal dimensions surrounding ozone-depleting substances (ODS), their impact on the ozone layer, and the subsequent risk of skin cancer. As countries navigate international agreements, domestic regulations, and enforcement mechanisms, the intricate interplay between legal frameworks and the health implications of ozone layer depletion comes to the forefront. The paper highlights particular instances of illegal trade in ozone depleting substances, drawing from data reported by the parties to the Montreal Protocol. Notably, China stands out as a significant source of contraband ODS, with other countries such as Bulgaria, Lithuania, Poland, and France reporting numerous cases. Analyzing these case instances offers insights into the efficacy of legal frameworks and enforcement measures. The paper offers a comprehensive set of recommendations to strengthen global control and enforcement against the illegal trade of ozone depleting substances. These recommendations span diverse aspects such as production monitoring, customs collaboration, mutual verification, cross-border agreements, public-private partnerships, international cooperation, detection equipment, global regulatory standards, resource allocation, public awareness campaigns, alternative substance development, and controlling the trade at its source. By applying these recommendations and enhancing enforcement measures, we aim to protect the ozone layer and create a healthier and safer world for future generations and achieve sustainable development goals.

Dynamic and electrical responses of a curved sandwich beam with glass reinforced laminate layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact

The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are investigated.The current study aims to carry out a dynamic analysis on the sandwich beam when the impactor hits the top face sheet with an initial velocity.For the layer analysis,the high-order shear deformation theory(HSDT)and Frostig's second model for the displacement fields of the core layer are used.The classical non-adhesive elastic contact theory and Hunter's principle are used to calculate the dynamic responses in terms of time.In order to validate the analytical method,the outcomes of the current investigation are compared with those gained by the experimental tests carried out by other researchers for a rectangular composite plate subject to the LVI.Finite element(FE)simulations are conducted by means of the ABAQUS software.The effects of the parameters such as foam modulus,layer material,fiber angle,impactor mass,and its velocity on the generated voltage are reviewed.

Fabrication of Graphene/Cu Composite by Chemical Vapor Deposition and Effects of Graphene Layers on Resultant Electrical Conductivity

Graphene(Gr)has unique properties including high electrical conductivity;Thus,graphene/copper(Gr/Cu)composites have attracted increasing attention to replace traditional Cu for electrical applications. However,the problem of how to control graphene to form desired Gr/Cu composite is not well solved. This paper aims at exploring the best parameters for preparing graphene with different layers on Cu foil by chemical vapor deposition(CVD)method and studying the effects of different layers graphene on Gr/Cu composite’s electrical conductivity. Graphene grown on single-sided and double-sided copper was prepared for Gr/Cu and Gr/Cu/Gr composites. The resultant electrical conductivity of Gr/Cu composites increased with decreasing graphene layers and increasing graphene volume fraction. The Gr/Cu/Gr composite with monolayer graphene owns volume fraction of less than 0.002%,producing the best electrical conductivity up to59.8 ×10^(6)S/m,equivalent to 104.5% IACS and 105.3% pure Cu foil.

短时数据下利用双HTLS参数估计的异步电机转子断条故障诊断

传统基于傅里叶分析的算法,其频谱分辨率受限于数据长度,对此,提出一种在短时数据下利用双HTLS算法进行异步电机转子断条故障诊断的方法。利用HTLS算法中的Hankel矩阵左奇异子矩阵的平移不变性质,准确估算出基波幅值、频率、相位参数;然后利用基波参数构造基波表达式,将其从定子电流原始信号中剔除,从而得到残余电流;对残余电流再次进行HTLS参数估计,辨识出故障成分的参数,并有效抑制噪声的影响。对不同数量的转子断条故障进行实验验证,结果表明双HTLS算法具有高鲁棒性的优点,且适用于噪声背景及短时数据下的转子断条故障检测。

考虑高斯有色噪声的FOMC-HTLS-Adaline算法在低频振荡模式辨识中的研究

针对广域测量系统的实测信号受高斯色噪声的影响,提出一种利用FOMC-HTLSAdaline进行低频振荡在线辨识的新方法。首先,为抑制高斯色噪声的影响,利用四阶混合累积量的盲高斯性,将四阶混合累积量(FOMC)序列代替实测序列进行低频振荡的辨识。然后,利用HTLS和自适应神经网络算法(Adaline ANN)相结合,估计出低频振荡的频率、衰减因子、幅值和相位。Adaline神经网络的引入解决了四阶混合累积处理后,模式幅值和相位不易确定的难点,同时减少矩阵处理引入的误差累积,提高检测精度。四机两区域系统仿真算例和实测相量测量单元(PMU)算例共同表明,FOMC-HTLS-Adaline算法可以在高斯色噪声环境下,精确地在线辨识系统振荡模式。

In-situ investigation of atmospheric corrosion behavior of bronze under thin electrolyte layers using electrochemical technique

The atmospheric corrosion behavior of bronze under thin electrolyte layer （TEL） with different thicknesses was monitored using cathodic polarization curves, open circuit potential （OCP） and electrochemical impedance spectroscopy （EIS）. Cathodic polarization result indicates that the cathodic limiting current density increases with decreasing the TEL thickness. EIS result shows that the corrosion rate increases with decreasing the TEL thickness at the initial stage because the corrosion is dominated by the cathodic process, whereas after long immersion time, the corrosion degree with the TEL thickness is in the sequence of 150 μm 〉 310 μm〉 10μm ≈ bulk solution 〉 57 μm. The measurements of OCP and EIS present in-situ electrochemical corrosion information and their results are in good agreement with that of physical characterizations.

A study of perfectly matched layers for joint multicomponent reverse-time migration

Reverse-time migration in finite space requires effective boundary processing technology to eliminate the artificial truncation boundary effect in the migration result.On the basis of the elastic velocity-stress equations in vertical transversely isotropic media and the idea of the conventional split perfectly matched layer（PML）,the PML wave equations in reverse-time migration are derived in this paper and then the high order staggered grid discrete schemes are subsequently given.Aiming at the＂reflections＂from the boundary to the computational domain,as well as the effect of seismic event＇s abrupt changes at the two ends of the seismic array,the PML arrangement in reverse-time migration is given.The synthetic and real elastic,prestack,multi-component,reverse-time depth migration results demonstrate that this method has much better absorbing effects than other methods and the joint migration produces good imaging results.

基于CCF-HTLS算法的异步电动机转子故障检测

定子电流经低通滤波器处理后产生高斯有色噪声,限制了异步电机转子故障检测算法的辨识精度。针对该问题,提出一种抑制高斯有色噪声的异步电机故障检测技术。首先对采集到的定子电流进行预处理,利用逆同步旋转变换剔除基波,避免了直接检测时基波对故障辨识精度的影响。然后利用互相关函数(CCF)处理技术对高斯有色噪声的抑制作用,提出基于CCF-HTLS算法的电机转子故障诊断技术。针对异步电机转子断条和偏心故障的识别进行试验,结果表明CCF-HTLS算法可以有效抑制高斯有色噪声,并保留故障有用信息,显著地提高了故障检测的分辨率。

Ice thickness,internal layers,and surface and subglacial topography in the vicinity of Chinese Antarctic Taishan station in Princess Elizabeth Land,East Antarctica

We present the results of two ground-based radio-echo-sounding（RES） and GPS surveys performed in the vicinity of new Chinese Taishan station,Princess Elizabeth Land,East Antarctica,obtained in two austral summers during CHINARE 21（2004/2005） and CHINARE 29（2012/2013）.The radar surveys measured ice thickness and internal layers using 60- and 150-MHz radar systems,and GPS measurements showed smooth surface slopes around the station with altitudes of 2607-2636 m above sea level（a.s.l.）.Radar profiles indicate an average ice thickness of 1900 m,with a maximum of 1949 m and a minimum of 1856 m,within a square area measuring approximately 2 km × 2 km in the vicinity of the station.The ice thickness beneath the station site is 1870 m.The subglacial landscape beneath the station is quiet sharp and ranges from 662 to 770 m a.s.l.,revealing part of a mountainous topography.The ice volume in the grid is estimated to be 7.6 km^3.Along a 60-MHz radar profile with a length of 17.6 km at the region covering the station site,some disturbed internal layers are identified and traced;the geometry of internal layers within the englacial stratigraphy may imply a complex depositional process in the area.

Reconstruction of Highly-efficient Smash-ridging Ecological Cultivation Method for Sustainable Yield-increasing of Soil Plough Layers

With consideration of highly-efficient use of natural resources, reducing production cost and construction of high-standard agricultural fields, rice production of good seed＋fertilizer investment is reformed on basis of research of smash-ridging technology, and rice smash-ridging ecological and highly-efficient cultivation was pro- posed, namely, smash-ridging based deeply poughing and rotary tillage technology was used to loosen soils deeply, with the depth from 13-15 cm to 26-28 cm. Fur- thermore, after soils softening, seedling slinging or direct seeding was adopted, which is dominated by natural rainfall and supplemented by artificial irrigation. The test proved that the technology help increasing yield and profits over 20%, with chemical fertilizer reduced by more than 10%, and labor cost reduced by 10%. What＇s more, if the technology applied once, no-tillage or slight tillage is recom- mended in the field, which would maintain original eco-conditions of soils and reach high yield, with energy, water, labor costs reduced in an environment-friendly way.

Preliminary Analysis on Abnormal Granularity Layers of Soil Profile and the Response of Relative Factors in Loess Plateau

[Objective] The paper was to analyze organic carbon content （SOC）, granularity, total nitrogen content （TN）, carbon-nitrogen ratio （C/N）, calcium carbonate content （CaCO3） of 1cm soil profiles in returning forest in Zhifanggou watershed of Ansai County in Loess Plateau, so as to study the changes of physical and chemical properties in abnormal layer of soil reflected with granularity, as well as the physical and chemical responses of soil. [Method] Three quadrats with the size of 10 m×10 m were randomly selected in three sampling plots in Loess Plateau, three profiles in upper, middle and lower slope were excavated, and the samples were collected with interval of 10 cm; the surface layer with the depth of 0-10 cm was divided into two layers of 0-5 and 5-10 cm for sampling, respectively. Eleven samples were collected in each profile with a total of 99 samples. Its organic carbon content, granularity, total nitrogen content, carbon-nitrogen ratio and CaCO3 content were analyzed. [Result] The soil profiles in three sampling sites contained five characteristic layers, including a1, b1, b2, c1 and c2, the content of soil granule with particle size less than 0.02 mm decreased, and those with particle size 0.02 mm increased, the organic carbon content and C/N value （a1, b1, b2, c2） increased, but the increase trend of CaCO3 content was not obvious. [Conclusion] The study shows that the characteristic soil layer is commonly existed in loess region, especially the eroded loess region, which should be paid attention in the research fields of modern soil science and ecology.