Nitrogen recovery and nitrate leaching of controlled release nitrogen fertilizer in irrigated paddy soil

Ordinary high nitrogen fertilizer often results in nitrate (NO3--N) leaching and low recovery. Microplot and field plot experiments were conducted to determine the effect of controlled release nitrogen fertilizer (CRNF) on reco very and nitrate leaching on paddy soils. During two early rice cropping seasons (2002 and 2003), a single basal application of CRNF at 90 kg N ha-1 increased grain yields by 7.7%to 11.6%compared with two applications of urea. Estimated by the difference method fertilizer N recovery of CRNF (mean 76.3%) was 38.9 pe rcentage point higher than that of urea (mean 37.4%); estimated by 15N isotope method (mean 49.6%) CRNF (mean 67.1%) was 35.9 percentage point higher than ur ea (mean 31.2%). NO3--N leaching losses were 9.19 and 6.70 kg ha-1 for urea and CRNF, respectively. NO3--N leaching during the early rice cropping season was 27.1 %lower from CRNF than from two applications of urea. These losses repr esent 10.2%and 7.4%of applied urea-N and CRNF-N. Results from this study ind icate that CRNF improves N recovery and reduces NO3--N leaching and increases rice yield.

Nitrate Leaching in an Irrigated Wheat-Maize Rotation Field in the North China Plain

Soil water deep drainage and nitrate (NO-3) leaching losses below the root zone were investigated in a 1 ha wheat-maize rotation field under traditional agricultural management that local farmers generally follow in the North China Plain, using the soil water balance method and NO3-N concentration in suction samples. Water drainage, and NO3-N distribution and leaching losses exhibited pronounced spatial and temporal variability. Soil water deep drainage and NO3-N leaching loss mostly occurred during the sum…

Influences of nitrification inhibitor 3,4-dimethyl pyrazole phosphate on nitrogen and soil salt-ion leaching

An undisturbed heavy clay soil column experiment was conducted to examine the influence of the new nitrification inhibitor, 3,4- dimethylpyrazole phosphate （DMPP）, on nitrogen and soil salt-ion leaching. Regular urea was selected as the nitrogen source in the soil. The results showed that the cumulative leaching losses of soil nitrate-N under the treatment of urea with DMPP were from 57.5% to 63.3% lower than those of the treatment of urea without DMPP. The use of nitrification inhibitors as nitrate leaching retardants may be a proposal in regulations to prevent groundwater contaminant. However, there were no great difference between urea and urea with DMPP treatments on ammonium-N leaching. Moreover, the soil salt-ion leaching losses of Ca^2＋, Mg^2＋, K^＋, and Na^＋ were reduced from 26.6% to 28.8%, 21.3% to 27.8%, 33.3% to 35.5%, and 21.7% to 32.1%, respectively. So, the leaching losses of soil salt-ion were declined for nitrification inhibitor DMPP addition, being beneficial to shallow groundwater protection and growth of crop. These results indicated the possibility of ammonium or ammonium producing compounds using nitrification inhibitor DMPP to control the nitrate and nutrient cation leaching losses, minimizing the risk of nitrate pollution in shallow groundwater.

Effect of long-term fertilization on soil nitrate distribution

A thirteen years long-term field fertilizer experiment was conducted to monitor the effect of different fertilization on soil nitrate distribution. The results showed: (1) Applying relative excessive N fertilizer could result large quantities of NO3- residue and NO3- movement downward in soil profiles; amending phosphate fertilizer or organic manure with nitrogen fertilizer together could significantly improve the status of NO3- leaching downward due to the balanced uptake of nutrients by crops. ( 2) Appropriate amounts of nitrogen fertilizer which was equal or smaller than the optimal fertilization rate could not result in more NO3- leaching in Northern China. (3) Precipitation influenced the amounts and depth of soil NO3- leaching: NO3- could move to 80 cm depth or below at autumn or at the next spring when rainfall was higher during the rainy season through July to September in North China.

The characterization of soil profile distribution for nitrate leached in the paddy soil

Experiment was conducted for five successiveyears under large undisturbed monolith lysime-ters(2m×2m in square,l m in depth).Thesoil was silty clay loam texture and had a con-tent of total N 1.55 g/kg.The soil was flood-ed with penetration rate controlled at approxi-mate 3 mm per day in duration of double-riceseason and laid fallow and natural in winterand spring.Results showed that nitrate was the mainform of nitrogen in percolates.The change of

Evaluation of Pathway of Nitrogen Loss in Winter Wheat and Summer Maize Rotation System

The nitrogen loss pathway in winter wheat and summer maize rotation system was studied based on field experimental data. The results showed that nitrogen recovery rate was significantly decreased with nitrogen fertilization rate increased, while residual rate and losses rate had an increasing trend. Accumulated ammonia volatilization loss in winter wheat and summer maize rotation was 12. 8(N0), 22.0(N120), 33. 0(N240) and 64. 5 kg N ha-1 (N360) respectively and rate of ammonia volatilization loss was 3.8, 4.2 and 7.2% respectively while urea was mixed with 0 -10 cm soil or spread before irrigation. Denitrification loss with acetylene-soil core incubation method in winter wheat was lower than 1 kg N ha-1 and rate of denitrification loss was 0. 21 - 0. 26% or trace. Denitrification loss in summer maize was 1 - 14 kg N ha-1 and rate of denitrification loss was 1-5%. The total gaseous loss in winter wheat and summer maize rotation system was less than 10%, and the main nitrogen fertilizer loss way was leaching below 0 - 100 cm soil profile and accumulated in deeper soil.

Use of the Nitrogen Index to assess nitrate leaching and water drainage from plastic-mulched horticultural cropping systems of Florida

Water quality in Florida is significantly impacted by nitrate(NO_(3)-N)leaching losses from agriculture in a large part of the state.Horticultural crops are planted across large areas of Florida on coarse sandy soils with low soil water retention and soil organic matter,increasing the potential for NO_(3)-N leaching.Nitrate leaching losses from the root zone of vegetable cropping systems can negatively impact groundwater.New tools such as the Nitrogen Index(N-Index)are able to quickly assess N use efficiency and losses via NO_(3)-N leaching from agricultural systems.Furthermore,the N-Index provides technical information about N losses pathways tied to agricultural management practices with a great level of confidence;this information has been used by researchers,growers and policymakers as a decision support system.However,the current version of the NIndex that has been used for different field crops has not been calibrated to be used in plastic-mulched horticultural cropping systems.The aim of this work was to calibrate and validate the N-Index for plasticmulched horticultural cropping systems of Florida.This study found that the N-Index tool accurately identified and ranked the risk of N losses in the evaluated horticultural systems.The N-Index was calibrated for Florida's plastic-mulched horticultural cropping systems using a sensitivity analysis.The adjusted N-Index was validated using compiled data of vegetables grown under plastic mulching systems during three consecutive seasons.Results from these studies suggest that the N-Index can be an easy-to-use tool capable of assessing nitrogen management practices for vegetable systems.The tool can be used to guide nutrient managers in the implementation of best nitrogen management practices that could contribute to reduced NO_(3)-N leaching losses from vegetable systems in Florida,contributing to a smaller environmental footprint and conservation of water quality.

Process optimization of rare earth and aluminum leaching from weathered crust elution-deposited rare earth ore with compound ammonium salts

In order to intensify the leaching process of rare earth（RE） and reduce the impurities in the leachate, ammonium chloride（NH4Cl） and ammonium nitrate（NH4NO3） were mixed as a compound leaching agent to treat the weathered crust elution-deposited RE ore. Effects of molar ratio of NH~＋_4Cl and NH_4NO_3, ammonium（NH_4） concentration, leaching agent pH and flow rate on the leaching process of RE were studied and evaluated by the chromatographic plate theory. Leaching process of the main impurity aluminium（Al） was also discussed in detail. Results showed that a higher initial ammonium concentration in a certain range could enhance the mass transfer process of RE and Al by providing a driving force to overcome the resistance of diffusion. pH almost had no effects on the mass transfer efficiency of RE and Al in the range of 4 to 8. The relationship between the flow rate and height equivalent to a theoretical plate（HETP） could fit well with the Van Deemter equation, and the flow rate at the lowest HETP was determined. The optimum conditions of column leaching for RE and Al were 1：1（molar ratio） of NH_4Cl and NH_4NO_3, 0.2 mol/L of ammonium concentration, pH 4–8 of leaching agent and 0.5 mL /min of flow rate. Under this condition, the mass transfer efficiency of RE was improved, but no change was observed for Al compared with the most widely used ammonium sulfate. Moreover, the significant difference value（around 20 mL） of retention volume at the peak concentration between RE and Al provided a possibility for their separation. It suggested the potential application of the novel compound leaching agent（NH_4Cl/NH_4NO_3）. It was found that the relative concentration of RE in the leachate could be easily obtained by monitoring the pH of leachate.

Biochar for Sustainable Soil Health:A Review of Prospects and Concerns

Biochar as a soil amendment is confronted with the challenge that it must benefit soil health as it can be by no means separated from soils once it is added. The available literature even though sparse and mostly based on short-term studies has been encouraging and the trend obtained so far has raised many hopes. Biochar has been reported to positively impact an array of soil processes ranging from benefiting soil biology, controlling soil-borne pathogens, enhancing nitrogen fixation, improving soil physical and chemical properties,decreasing nitrate(NO-3) leaching and nitrous oxide(N2O) emission to remediation of contaminated soils. However, very little biochar is still utilized as soil amendment mainly because these benefits are yet to be quantified, and also the mechanisms by which the soil health is improved are poorly understood. Due to the infancy of research regarding this subject, there are still more questions than answers. The future research efforts must focus on carrying out long-term experiments and uncover the mechanisms underlying these processes so that key concerns surrounding the use of biochar are addressed before its large scale application is recommended.

Optimizing Nitrogen Use Efficiency for No-Till Corn Production by Improving Root Growth and Capturing NO_(3)-N in Subsoil

Subsoil acidity restricts root growth and reduces crop yields in many parts of the world. More than half of the fertilizer nitrogen(N) applied in crop production is currently lost to the environment. This study aimed to investigate the effect of gypsum application on the efficiency of N fertilizer in no-till corn(Zea mays L.) production in southern Brazil. A field experiment examined the effects of surface-applied gypsum(0, 5, 10, and 15 Mg ha^(-1)) and top-dressed ammonium nitrate(NH_4NO_3)(60, 120, and 180 kg N ha^(-1)) on corn root length, N uptake, and grain yield. A greenhouse experiment was conducted using undisturbed soil columns collected from the field experiment site to evaluate NO_3-N leaching, N uptake, and root length with surface-applied gypsum(0 and 10 Mg ha^(-1)) and top-dressed NH_4NO_3(0 and 180 kg N ha^(-1)). Amelioration of subsoil acidity due to gypsum application increased corn root growth,N uptake, grain yield, and N use efficiency. Applying gypsum to the soil surface increased corn grain yield by 19%–38% and partial factor productivity of N(PFPN) by 27%–38%, depending on the N application rate. Results of the undisturbed soil column greenhouse experiment showed that improvement of N use efficiency by gypsum application was due to the higher N uptake from NO_3-N in the subsoil as a result of increased corn root length. Our results suggest that ameliorating subsoil acidity with gypsum in a no-till corn system could increase N use efficiency, improve grain yield, and reduce environmental risks due to NO_3-N leaching.

A nitrogen index for improving nutrient management within commercial Mexican dairy operations

Some intensive dairy operations in Mexico are contributing to large,negative environmental impacts,especially in regions dominated by high concentrations of animals.Excessive manure inputs plus additional nitrogen(N)fertilizer has,in some cases,resulted in background nitrate–nitrogen(NO3–N)levels in irrigation water that are so high,it is not safe for human consumption.One reason is that commercial farmers in this region are currently not using any method to rapidly calculate N budgets based on their practices,N inputs and/or crop N uptake.The Nitrogen Index,a quick tool that can be used to conduct an assessment within a few minutes,was developed for Mexico,but needed further testing under commercial field operations.We conducted studies in 2010 and 2011 and collected soil and crop information from several commercial farming operations to test the tool.The index accurately assessed(Po0.0001)residual soil nitrate after harvesting corn(Zea mays L.)and oats(Avena sativa L.);and also accurately assessed the N uptake of these crops(Po0.01).The Mexico N Index is a tool that can be used to quickly conduct N balances,show when N is being over-applied,and help reduce over-application,thus reducing N losses to the environment and improving management of dairy forage systems in Mexico.