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Analysis of Oxygen Consumption in Lead and Zinc Metallurgy
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作者 Lun Sheng Pengpeng Zhang 《Frontiers of Metallurgical Industry》 2024年第2期5-9,共5页
This article analyzes the role of oxygen in lead zinc metallurgy,including shortening the metallurgical process,promoting energy conservation and environmental protection,improving metallurgical strength,enhancing raw... This article analyzes the role of oxygen in lead zinc metallurgy,including shortening the metallurgical process,promoting energy conservation and environmental protection,improving metallurgical strength,enhancing raw material adaptability,and enhancing comprehensive recovery efficiency.This article introduces different lead zinc metallurgical processes and their oxygen consumption characteristics,including oxygen enriched side blowing lead smelting,oxygen bottom blowing lead smelting,oxygen enriched top blowing lead smelting,flash smelting lead,oxygen pressure leaching zinc smelting,and atmospheric pressure oxygen leaching zinc smelting.It is pointed out that oxygen enhanced metallurgy is the direction for the transformation and upgrading of lead zinc metallurgy. 展开更多
关键词 lead zinc metallurgy oxygen rich smelting oxygen pressure leaching energy conservation and emission reduction
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典型铅锌矿区周边土壤-稻米重金属污染特征及健康风险评价
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作者 符露 秦俊虎 +1 位作者 贾亚琪 高庚申 《地球与环境》 CAS CSCD 北大核心 2024年第1期112-121,共10页
为了掌握黔西北典型铅锌矿区周边稻田土壤重金属污染状况,分别采集98个土壤样品和稻米样品,运用单因子污染指数法、内梅罗综合污染指数法和潜在生态危害指数法对研究区稻田土壤中八种重金属(Cr、Ni、Cu、Zn、Cd、Pb、Hg、As)进行污染特... 为了掌握黔西北典型铅锌矿区周边稻田土壤重金属污染状况,分别采集98个土壤样品和稻米样品,运用单因子污染指数法、内梅罗综合污染指数法和潜在生态危害指数法对研究区稻田土壤中八种重金属(Cr、Ni、Cu、Zn、Cd、Pb、Hg、As)进行污染特征分析和风险评价,并采用健康风险评估模型对研究区稻米进行健康风险评价。结果表明:研究区稻田土壤受到重金属不同程度污染,整体处于中度污染水平(P_(N)=2.61),但Cu为重度污染(P_(Cu)=3.13);土壤生态风险总体处于中等水平(RI=279),最主要生态风险因子为Hg,其生态风险危害程度为很强(E_(Hg)=179);研究区稻米中重金属平均含量未超标,但有部分点位样品重金属含量超标;食用研究区种植的稻米不会对成人和儿童引起单一重金属健康风险,但长期食用,多种重金属复合污染会对成人和儿童健康产生负面影响(THQ_(成人)=2.41,THQ_(儿童)=2.48)。 展开更多
关键词 铅锌矿区 土壤 稻米 重金属污染 生态风险 健康风险
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Heavy metal concentrations in soils and plants in the vicinity of Arufu lead-zinc mine, Middle Benue Trough, Nigeria 被引量:3
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作者 Nganje T.N. Adamu C.I. Ukpong E.E. 《Chinese Journal Of Geochemistry》 EI CAS 2010年第2期167-174,共8页
This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from c... This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cul-tivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farm-lands have neutral pH values (6.5-7.5), and low organic matter contents (<10%). Levels of Zn, Pb and Cd in culti-vated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leaves>cassava tubers>peelings. In the same plant species, metal levels decreased in the order of Zn>Fe>Mn>Cu>Pb>Cr>Cd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake. 展开更多
关键词 土壤重金属含量 土壤样品 植物样本 铅锌矿 尼日利亚 原子吸收光谱法 线性回归分析 amp
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Z-200体系下Pb^(2+),Zn^(2+)对黄铜矿可浮性的影响及其机理
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作者 鱼博 何廷树 +2 位作者 王鑫 贺寒冰 王宇斌 《矿产综合利用》 CAS 2024年第1期155-159,166,共6页
这是一篇矿物加工工程领域的论文。黄铜矿、方铅矿和闪锌矿通常会相互伴(共)生,为了探究Pb^(2+)和Zn^(2+)对黄铜矿浮选行为和表面性质的影响,本研究对黄铜矿进行了单矿物浮选实验,并利用溶液化学计算、Zeta电位和XPS检测等方法,对比研究... 这是一篇矿物加工工程领域的论文。黄铜矿、方铅矿和闪锌矿通常会相互伴(共)生,为了探究Pb^(2+)和Zn^(2+)对黄铜矿浮选行为和表面性质的影响,本研究对黄铜矿进行了单矿物浮选实验,并利用溶液化学计算、Zeta电位和XPS检测等方法,对比研究了Pb^(2+)和Zn^(2+)对黄铜矿浮选行为和表面性质的影响。黄铜上的Zn^(2+)。矿石可浮性影响的差异。测试结果表明,Pb^(2+)和Zn^(2+)都会吸附在黄铜矿表面,改变黄铜矿表面的Zeta电位,抑制黄铜矿的可浮性,并且随着pH值的升高,抑制作用增强;结合浮选实验结果可知,浮选所处的矿浆pH值范围内,锌主要以Zn(OH)2沉淀的形式吸附在黄铜矿表面从而对黄铜矿的浮选产生抑制效果,所以Zn^(2+)对黄铜矿浮选的抑制效果要比Pb^(2+)显著;且XPS分析结果表明,Pb^(2+)和Zn^(2+)都能在黄铜矿表面形成沉淀物,并以化学吸附的形式出现在黄铜矿表面,从而抑制黄铜矿的可浮性。 展开更多
关键词 矿物加工工程 黄铜矿 铅锌离子 可浮性 抑制作用
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Sulphidization flotation for recovery of lead and zinc from oxide-sulfide ores 被引量:11
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作者 FA Keqing Jan D.Miller +1 位作者 姜涛 李光辉 《中国有色金属学会会刊:英文版》 EI CSCD 2005年第5期1138-1144,共7页
A new flowsheet was developed to recover the valuable minerals from oxide or oxide-sulfide ores of lead and zinc. The flowsheet consisted of flotation of sulfide minerals, desliming and sulphidization-flotation of oxi... A new flowsheet was developed to recover the valuable minerals from oxide or oxide-sulfide ores of lead and zinc. The flowsheet consisted of flotation of sulfide minerals, desliming and sulphidization-flotation of oxide minerals. The corresponding reagent system and techniques to the flowsheet were investigated. Batch and continuous tests show that the dosage of sodium sulfide, temperature, and collector type are main affecting factors on the recovery of smithsonite and cerussite. For the flotation of cerussite, there is an appropriate dosage of sodium sulfide at which the recovery reaches its maximum value. The required sodium sulfide for smithsonite flotation is higher than that for cerussite and the recovery of smithsonite flotation increases with the dosage of sodium sulfide at low level and becomes insensitive at high dosage. The appropriate temperature for smithsonite and cerussite flotation is found to be 2540℃. Amines are found to be the effective collectors for the flotation of smithsonite after sulphidization. Investigation also shows that desliming prior to sulphidization-flotation is essential to the effective recovery of smithsonite and cerussite, and the desliming process of two-stage hydrocyclon is well feasible and effective for the treatment of lead-zinc oxide ores. A further treatment on the cerussite flotation concentrate by shaking table is proposed to obtain higher lead grade. 展开更多
关键词 氧化物 硫化物 矿石 浮选工艺
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Separation of sulfide lead-zinc-silver ore under low alkalinity condition 被引量:7
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作者 孙伟 苏建芳 +1 位作者 张刚 胡岳华 《Journal of Central South University》 SCIE EI CAS 2012年第8期2307-2315,共9页
A complex lead-zinc-silver sulfide ore containing 2.98% Pb, 6.49% Zn and 116.32×10-4% Ag (mass fraction) from Yunnan Province, China, was subjected to this work. Research on mineral processing was conducted accor... A complex lead-zinc-silver sulfide ore containing 2.98% Pb, 6.49% Zn and 116.32×10-4% Ag (mass fraction) from Yunnan Province, China, was subjected to this work. Research on mineral processing was conducted according to the properties of the lead-zinc-silver ore. Under low alkalinity condition, the lead minerals are successfully separated from the zinc minerals with new reagent YZN as zinc depressant, new reagent BPB as lead collector, CuSO4 as zinc activator and ethyl xanthate as zinc collector. The associated silver is mostly concentrated to the lead concentrate. With the process utilized in this work, a lead concentrate of 51.90% Pb with a recovery of 82.34% and a zinc concentrate of 56.96% Zn with a recovery of 81.98% are produced. The silver recovery in the lead concentrate is 80.61%. Interactions of flotation reagents with minerals were investigated, of which the results indicate that the presence of proper amount of Na2S can precipitate Pb2+ and has a sulfidation on oxidized lead minerals. The results also show that Na2CO3 and YZN used together as combined depressants for sphalerite can signally improve the depressing effect of new reagent YZN on sphalerite. 展开更多
关键词 锌矿物 矿石分离 硫化铅 银矿石 度条件 低碱 多金属硫化矿 矿物加工
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Effect of Lead-Zinc Interaction on Size of Microbial Biomass in Red Soil 被引量:8
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作者 K. S. KHAN and HUANG CHANGYONG College of Natural Resources and Environmental Sciences, Zhejiang Agricultural University, Hangzhou 310029 (China) 《Pedosphere》 SCIE CAS CSCD 1998年第2期143-148,共6页
Leadandzincarethemetalswelrecognizedfortheirwidespreaddistributionandpotentialrisktotheenvironment.Outofthes... Leadandzincarethemetalswelrecognizedfortheirwidespreaddistributionandpotentialrisktotheenvironment.Outofthesetwo,zincisanesen... 展开更多
关键词 微生物 数量 红壤 相互作用
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Analysis and Evaluation of Bioavailable Heavy Metals in Surface Soil of the Abandoned Lead-zinc Mine in Changhua,Hainan Province 被引量:1
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作者 Jianping YUAN Fangfang ZHENG +2 位作者 Dan WU Tianhong YU Qianqian JIANG 《Agricultural Biotechnology》 CAS 2018年第4期165-171,共7页
[Objectives] The research was conducted to study characteristics of bioavailable levels pollution of heavy metals in the surface soil of the lead-zinc mine in Changhua.[Methods] A total of 56 surface samples were coll... [Objectives] The research was conducted to study characteristics of bioavailable levels pollution of heavy metals in the surface soil of the lead-zinc mine in Changhua.[Methods] A total of 56 surface samples were collected from the 3 study zones (peripheral zone, reclamation zone and tailing zone) located at the lead-zine mine in Changhua. Based on total and bioavailable heavy metals (Pb, Zn, Cu and Cd) in soils, the correlation of total content with bioavailable content was analyzed, and their pollution characteristics were assessed by methods of single factor pollution index, Nemerow pollution index, geological accumulation index and potential ecological risk index.[Results] (i) The surface soils were polluted by Pb, Zn, Cu, Cd in different degrees, and the overall trend of the contents of the 4 heavy metals was in order of Cd 〉 Pb 〉 Zn 〉 Cu. The average excess multiple of heavy metals of total and bioavailable content in soils were in the order of peripheral zone 〉 tailing zone 〉 reclaimed zone, and their pollution degrees were tailing zone 〉 peripheral zone 〉 reclaimed zone. (ii) In general, the total and bioavailable contents of Pb, Zn, Cu, Cd showed a significant correlation, but were not correlated in each study zone. (iii) Pollution degrees of the study zones were in the order of tailing zone 〉 peripheral zone 〉 reclamation zone. The pollutions of heavy metals Pb and Cd were more serious, especially Cd reached high levels of pollution degree, and the pollution degrees of Zn, Cu were lighter. Contributors of ecological risk were mainly Cd, Pb and Cu, and the contribution of Cd achieved more than 90 %, making it the main source of pollution.[Conclusions] The results not only revealed the pollution status of heavy metals in the surface soil of the abandoned coal mine, but also could provide scientific guidance for reasonable utilization and ecological recovery of the land. 展开更多
关键词 lead-zinc mine Heavy metal Bioavailable form Analysis and assessment
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An experimental study on metal precipitation driven by fluid mixing: implications for genesis of carbonate-hosted lead–zinc ore deposits 被引量:3
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作者 Yan Zhang Runsheng Han +2 位作者 Xing Ding Junjie He Yurong Wang 《Acta Geochimica》 EI CAS CSCD 2019年第2期202-215,共14页
A type of carbonate-hosted lead–zinc(Pb–Zn)ore deposits, known as Mississippi Valley Type(MVT)deposits, constitutes an important category of lead–zinc ore deposits. Previous studies proposed a fluid-mixing model to... A type of carbonate-hosted lead–zinc(Pb–Zn)ore deposits, known as Mississippi Valley Type(MVT)deposits, constitutes an important category of lead–zinc ore deposits. Previous studies proposed a fluid-mixing model to account for metal precipitation mechanism of the MVT ore deposits, in which fluids with metal-chloride complexes happen to mix with fluids with reduced sulfur, producing metal sulfide deposition. In this hypothesis, however, the detailed chemical kinetic process of mixing reactions, and especially the controlling factors on the metal precipitation are not yet clearly stated. In this paper, a series of mixing experiments under ambient temperature and pressure conditions were conducted to simulate the fluid mixing process, by titrating the metal-chloride solutions, doping withor without dolomite, and using NaHS solution. Experimental results, combined with the thermodynamic calculations, suggest that H_2S, rather than HS^-or S^(2-),dominated the reactions of Pb and/or Zn precipitation during the fluid mixing process, in which metal precipitation was influenced by the stability of metal complexes and the pH. Given the constant concentrations of metal and total S in fluids, the pH was a primary factor controlling the Pb and/or Zn metal precipitation. This is because neutralizing or neutralized processes for the ore-forming fluids can cause instabilities of Pb and/or Zn chloride complexes and re-distribution of sulfur species, and thus can facilitate the hydrolysis of Pb and Zn ions and precipitation of sulfides. Therefore, a weakly acidic to neutral fluid environment is most favorable for the precipitation of Pb and Zn sulfides associated with the carbonate-hosted Pb–Zn deposits. 展开更多
关键词 METAL PRECIPITATION Fluid mixing Sulfur species MVT lead-zinc ORE DEPOSITS Carbonate-hosted lead-zinc DEPOSITS
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Investigation on the deactivation cause of lead-zinc double oxide for the synthesis of diphenyl carbonate by transesterification 被引量:3
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作者 Zhihui Li Yanji Wang +1 位作者 Xiaoshu Ding Xinqiang Zhao 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2009年第1期104-109,共6页
The deactivation cause of lead-zinc double oxide for synthesis of diphenyl carbonate (DPC) by transesterification of dimethyl carbonate (DMC) with phenol has been investigated. X-ray diffraction (XRD), X-ray pho... The deactivation cause of lead-zinc double oxide for synthesis of diphenyl carbonate (DPC) by transesterification of dimethyl carbonate (DMC) with phenol has been investigated. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), infrared spectroscopy (IR), thermogravimetry analysis (TG), atomic absorption spectroscopy and elementary analysis are employed for the catalyst characterization. The results show that, the formation of Pb4O(OC6H5)6 through the reaction of phenol and lead species in the catalyst leads to the crystal phase change of active component and serious leaching of lead, which is the cause of the catalyst deactivation. In addition, the composition of the leached lead is ascertained to be a mixture of Pb4O(OC6H5)6 and PbO with the weight percentage of 62.7% and 37.3%, respectively. 展开更多
关键词 lead-zinc double oxide DEACTIVATION dimethyl carbonate TRANSESTERIFICATION diphenyl carbonate organic lead
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Improvement of flotation behavior of Mengzi lead-silver-zinc ore by pulp potential control flotation 被引量:12
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作者 覃文庆 何名飞 陈玉平 《中国有色金属学会会刊:英文版》 EI CSCD 2008年第4期949-954,共6页
The electrochemical behavior of Mengzi lead-silver-zinc ore flotation system was studied. Based on the electrochemical characteristics of sulfide mineral flotation system, a stage potential control flotation was devel... The electrochemical behavior of Mengzi lead-silver-zinc ore flotation system was studied. Based on the electrochemical characteristics of sulfide mineral flotation system, a stage potential control flotation was developed with the main parameters of pulp potential(φp), pH value and collector dosage. Using N,N’ diphenylamino-dithiolphosphoric acid(NNDDC) as a collector, which has good selectivity for galena flotation at pH 8.8 and pulp potential 330 mV, DDTC is used as secondary collector to improve both the grade and recovery of Pb and Ag. The pulp potential values significantly influence the floatability of practical minerals and single minerals when using NNDDC as the collector. The flotation recovery of galena reaches 85% at about 0.3 V and pH8.8. With the usage of pulp potential control during grinding and flotation, the new pulp electrochemical technology for Mengzi lead-silver-zinc ore flotation was developed. The results show that the grades of Pb and Ag of galena concentrate are 55% and 1 800 g/t, respectively, while the recoveries of Pb and Ag are 86.5% and 65%, respectively, the grade of Zn of marmatite concentrate is 42.5%, and the recovery of Zn is 91.25%. 展开更多
关键词 铅银锌矿石 矿浆电压控制浮选 浮选技术 浮选行为
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Isotopic Compositions of Sulfur in the Jinshachang Lead–Zinc Deposit, Yunnan, China, and its Implication on the Formation of Sulfur-Bearing Minerals 被引量:9
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作者 BAI Junhao HUANG Zhilong +2 位作者 ZHU Dan YAN Zaifei ZHOU Jiaxi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2013年第5期1355-1369,共15页
The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China... The Jinshachang lead-zinc deposit is mainly hosted in the Upper Neoproterozoic carbonate rocks of the Dengying Group and located in the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn-Ag multi- metal mineralization area in China. Sulfides minerals including sphalerite, galena and pyrite postdate or coprecipitate with gangue mainly consisting of fluorite, quartz, and barite, making this deposit distinct from most lead-zinc deposits in the SYG. This deposit is controlled by tectonic structures, and most mineralization is located along or near faults zones. Emeishan basalts near the ore district might have contributed to the formation of orebodies. The j34S values of sphalerite, galena, pyrite and barite were estimated to be 3.6‰-13.4‰, 3.7‰-9.0‰, -6.4‰ to 29.2‰ and 32.1‰34.7‰, respectively. In view of the similar δ34S values of barite and sulfates being from the Cambrian strata, the sulfur of barite was likely derived from the Cambrian strata. The homogenization temperatures (T ≈ 134--383℃) of fluid inclusions were not suitable for reducing bacteria, therefore, the bacterial sulfate reduction could not have been an efficient path to generate reduced sulfur in this district. Although thermochemical sulfate reduction process had contributed to the production of reduced sulfur, it was not the main mechanism. Considering other aspects, it can be suggested that sulfur of sulfides should have been derived from magmatic activities. The δ34S values of sphalerite were found to be higher than those of coexisting galena. The equilibrium temperatures calculated by using the sulfur isotopic composition of mineral pairs matched well with the homogenization temperature of fluid inclusions, suggesting that the sulfur isotopic composition in ore-forming fluids had reached a partial equilibrium. 展开更多
关键词 sulfur isotopic composition thermochemical sulfate reduction homogenization temperature equilibrium temperature Jinshachang lead-zinc deposit
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Feasibility of Simultaneous Application of Fuzzy Neural Network and TOPSIS Integrated Method in Potential Mapping of Lead and Zinc Mineralization in Isfahan-Khomein Metallogeny Zone 被引量:1
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作者 Bahareh Hedayat Mohammad Ehsan Ahmadi +2 位作者 Hamed Nazerian Aref Shirazi Adel Shirazy 《Open Journal of Geology》 2022年第3期215-233,共19页
Iran is located on a silver, lead, and zinc belt and according to the latest studies holds 11 million tons of lead, zinc, and silver stones which constitute 4 percent of global resources. Considering that mineral mate... Iran is located on a silver, lead, and zinc belt and according to the latest studies holds 11 million tons of lead, zinc, and silver stones which constitute 4 percent of global resources. Considering that mineral materials are explored in an uncertain space, exploration investment risk is an inseparable part of these activities. The important fact is to minimize the effect of this undesired factor in exploration. To achieve this, it is required that exploration activities and withdrawals are performed in a certain framework in which risk minimization is considered. Using mineral potential modelling for determining promising zones which should be taken into consideration in more detailed stages could make achieving the purpose possibly. This work is aimed at applying fuzzy neural network and TOPSIS methods simultaneously in order to explore zinc and lead resources. In this article, geological, telemetry, geophysics, and geochemistry data is integrated using fuzzy-neural network (neuro fuzzy) and using TOPSIS method rating for lead and zinc ore deposit potential mapping in Isfahan-Khomein strip which has been introduced as one of zinc and leads mineral scopes in Iran. This area which is composed of several zinc and lead ore deposits has been considered as the target area. Fuzzy integration results of zinc and lead mineralization witness layers confirm the relatively high potential of lead and zinc mineralization in this region having a northwest-southeast trend and involving more than 90 percent of the known indices and ore deposits of the region. In this research, it was shown that the results of TOPSIS-Neuro-Fuzzy integrated model (a combination of neural network and fuzzy logic) have increased the resolution of talented areas from the areas with no mineralization potential in comparison with the fuzzy method individually. 展开更多
关键词 Potential Mapping TOPSIS NEURAL-FUZZY zinc and lead Isfahan-Khomein
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REE Geochemistry of the Lead-Zinc Ores from the Jinding Lead-Zinc Deposit, Lanping, Yunnan 被引量:3
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作者 牟传龙 余谦 张立生 《Chinese Journal Of Geochemistry》 EI CAS 2002年第1期57-64,共8页
Nineteen volcanic and magmatic rock samples were collected from the Jinding lead-zinc deposit and its surrounding areas in Yunnan. The ICP and AES analyses, referred to the previous results, show that the metal minera... Nineteen volcanic and magmatic rock samples were collected from the Jinding lead-zinc deposit and its surrounding areas in Yunnan. The ICP and AES analyses, referred to the previous results, show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ΣREE from the early to late stages of mineralization, and similarities in REE distribution patterns, indicating that the ore fluids are characterized by high LREE enrichment, markedly negative δCe anomaly and slight δEu anomaly. These REE distribution patterns exhibit striking similarities to those of the Pliocene trachyte in the study area, both of which are similar in ΣREE, LREE/HREE ratio, δEu and δCe. The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas. 展开更多
关键词 稀土元素地球化学 云南 锌矿石 磁性 锌矿床
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广西佛子冲铅锌矿田闪锌矿LA-ICP-MS微量元素特征及指示意义
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作者 常晋阳 吴小雷 +6 位作者 王加昇 曾南石 姜海 范春宝 黄长帅 李敏 赵毅 《矿物学报》 CAS CSCD 北大核心 2024年第3期335-349,共15页
广西佛子冲铅锌矿田所在的钦杭成矿带西段是广西重要的多金属矿集区,矿田范围内发现的铅锌矿有条带状、浸染状、热液脉状3种类型矿石。3种类型矿石中的闪锌矿均具有Fe元素最为富集,Cd元素富集,Co元素较富集,In元素亏损,Ge、As、Mo、Tl... 广西佛子冲铅锌矿田所在的钦杭成矿带西段是广西重要的多金属矿集区,矿田范围内发现的铅锌矿有条带状、浸染状、热液脉状3种类型矿石。3种类型矿石中的闪锌矿均具有Fe元素最为富集,Cd元素富集,Co元素较富集,In元素亏损,Ge、As、Mo、Tl元素含量低且含量变化不大的特征,但三者Fe元素含量存在一定差异,条带状闪锌矿w(Fe)<浸染状闪锌矿w(Fe)<热液脉状闪锌矿w(Fe)。3种闪锌矿的Mn、Fe、Co、Cd、In元素以类质同象的形式赋存于闪锌矿的晶格中,Cu、Pb、Bi元素则以独立矿物(黄铜矿、方铅矿、辉铋矿)或显微包裹体的形式赋存于闪锌矿中,但3种闪锌矿的Ag元素的赋存形式却存在一定差异。其中,条带状与热液脉状闪锌矿的Ag元素主要以独立矿物(自然银)或显微包裹体的形式赋存于闪锌矿之中,而浸染状闪锌矿的Ag元素则可能以类质同象的形式赋存于闪锌矿的晶格中。3种闪锌矿中Fe对Cd(或Mn、Co、In)与Zn的替代所起到的作用存在一定差异,其中条带状闪锌矿中Fe对Cd(或Mn)与Zn的替代可能起一定促进作用,对Co(或In)与Zn的替代机制所起作用不明。浸染状闪锌矿中Fe对Cd(或Mn、Co、In)与Zn的替代均起促进作用。而热液脉状闪锌矿中Fe对Mn与Zn的替代起促进作用,对Cd(或In)与Zn的替代可能也起到一定促进作用,但却对Co与Zn的替代起到了抑制进作用。3种闪锌矿的形成与岩浆活动密切相关,但沉积改造作用在条带状闪锌矿的形成过程中也发挥了重要作用。条带状闪锌矿可能形成于中-低温环境,浸染状和热液脉状闪锌矿则可能形成于中-高温环境,但热液脉状闪锌矿形成温度可能高于浸染状闪锌矿。结合Ga/Ge-Zn/Cd和Zn/Cd-Mn投影及前人的研究成果综合分析认为佛子冲铅锌矿田存在喷流沉积型、矽卡岩型、岩浆热液型3种矿床成因类型。 展开更多
关键词 闪锌矿 微量元素 佛子冲铅锌矿田 LA-ICP-MS 成因类型
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Study on the multi-sources of ore-forming materials and ore-forming fluids in the Huize lead-zinc ore deposit 被引量:4
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作者 张振亮 黄智龙 +2 位作者 管涛 严再飞 高德荣 《Chinese Journal Of Geochemistry》 EI CAS 2005年第3期243-252,共10页
The Huize large-sized Pb-Zn deposit in Yunnan Province, China, is characterized by favorable metallogenic background and particular geological settings. This suggested that the ore-forming mechanism is relatively uniq... The Huize large-sized Pb-Zn deposit in Yunnan Province, China, is characterized by favorable metallogenic background and particular geological settings. This suggested that the ore-forming mechanism is relatively unique. On the basis of geological features such as the contents of mineralization elements, the REE concentrations of gangue calcites, the REE concentrations of calcite veins in the NE-trending tectonic zone and the Pb, Sr, C, H and O isotopic compositions of different minerals, this paper presents that the ore-forming materials and ore-forming fluids of the deposit were derived from various types of strata or rocks. This is a very significant conclusion for us to further discuss the mineralization mechanism of the deposit at depth and establish an available genetic model. 展开更多
关键词 矿石 流动性 沉积作用
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A Preliminary Study on Fluid Inclusions and Mineralization of Xitieshan Sedimentary-Exhalative (SEDEX) Lead-Zinc Deposit 被引量:4
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作者 WANG Lijuan ZHU Xinyou +3 位作者 WANG Jingbin DENG Jiniu WANG Yuwang ZHU Heping 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第4期838-844,共7页
The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming f... The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming fluids shows that fluid inclusions in quartz from altered stockwork rocks that represent the pipe facies have a wide range of temperature and salinity. The intense fluid activities are characteristics of the pipe facies of the exhalative system. Fluid inclusions in carbonates near the unstratified ore bodies hosted in the thick-bedded marble which represents vent-proximal facies are large in size and have moderate to high temperatures. They represent unerupted sub-seafloor fluid activity. Fluids in altered stockwork rocks and carbonates have similar H20-NaCI-CO2 system, both belonging to the sedimentary-exhalative system. The fluids migrate from the pipe facies to the unstratified ore bodies. Boiling of the fluids causes the separation of CO2 vapor and liquid H2O. When the fluids migrate into the unconsolidated thick-bedded marble, the escape of CO2, decreasing temperature and pressure as well as some involvement of seawater into the fluids result in the unmixing of fluids with high and low salinity and deposition of ore-forming materials. The two unmixed fluids were trapped in unconsolidated carbonates and the ore-forming materials were deposited in the unconsolidated carbonates to form the sedimentary-exhalative type unstratified ore bodies. The oreforming temperature of unstratified ore bodies is up to high temperature indicating that there is a huge ore-forming potential in its deep. 展开更多
关键词 sedimentary-exhalative system pipe facies unstratified ore bodies fluid inclusions the Xitieshan lead-zinc deposit
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Recycle of Wastewater from Lead-Zinc Sulfide Ore Flo-tation Process by Ozone/BAC Technology 被引量:3
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作者 Xingyu Liu Bowei Chen +3 位作者 Wenjuan Li Yongsheng Song Jiankang Wen Dianzuo Wang 《Journal of Environmental Protection》 2013年第1期5-9,共5页
Lead-zinc sulphide ore contains lead sulphide (galena), and zinc sulphide (sphalerite). In the first flotation stage, galena is rendered hydrophobic with an organic collector such as xanthate, while sphalerite is kept... Lead-zinc sulphide ore contains lead sulphide (galena), and zinc sulphide (sphalerite). In the first flotation stage, galena is rendered hydrophobic with an organic collector such as xanthate, while sphalerite is kept from floating by depressants, and in the second flotation stage, activator was used to activated zinc flotation. Since the organic regent used are different in the two flotation stage, wastewater from the second zinc flotation stage can’t be directly recycled to the first lead flotation stage. Wastewater from flotation process for concentrating lead-zinc sulphide ore often containing organic compounds such as diethyldithiocarbamate(DDTC), xanthate, terpenic oil(2# oil) and thionocarbamate esters (Z-200), are environmentally hazardous. Their removal from contaminated water and the reuse of the water is one of the main challenges facing lead-zinc sulphide ore processing plants. In this study, synthetic wastewater containing DDTC, xanthate, 2# oil and Z-200 at concentrations ranging from 21 to 42 mg/L was fed into an Ozone/Biological activated carbon (BAC) reactor. Analyses of the effluent indicated a chemical oxygen demand (COD) removal over 86.21% and Total organic carbon (TOC) removal over 90.00% were achieved under Hydraulic retention time (HRT) of 4h and O3 feeding concentration of 33.3mg/L. The effluent was further recycled to the lab scale lead concentrating process and no significant difference was found in compare with fresh water. Furthermore, lead-zinc sulphide mineral concentrating process was carried out at lab scale. The produced wastewater was treated by Ozone/BAC reactor at O3 feeding concentration of 16.7mg/L and HRT of 4h. The effluent analysis showed that TOC removal was 74.58%. This effluent was recycled to the lab scale lead-zinc sulphide mineral concentrating process and the recovery of lead was not affected. The results showed that by using Ozone/BAC technology, the lead-zinc sulphide mineral processing wastewater could be recycled. 展开更多
关键词 lead-zinc SULPHIDE ore Ozone/BAC FLOTATION WASTEWATER RECYCLE
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Organic Geochemistry of Lead-Zinc Polymetallic Deposits, Northern Guangdong 被引量:1
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作者 李兆麟 郭洪中 雷丽宏 《Chinese Journal Of Geochemistry》 EI CAS 1997年第4期330-335,共6页
The characters of organic matter in rocks and ores in the Fankou and Dabaoshan deposits are systematically studied with regard to their implications for mineralization. The results show that kerogens in this area fall... The characters of organic matter in rocks and ores in the Fankou and Dabaoshan deposits are systematically studied with regard to their implications for mineralization. The results show that kerogens in this area fall mainly into the plutonism field in Van Krevelen’s diagram.Reflectivity of the organic substance was measured to be 3. 06% (Fankou) and 1. 67% (Dabaoshan) , corresponding to the paleo-geotemperatures of 232℃ and 184℃ respectively.The same types of porphyrins and hydrocarbons were recognized in the rocks and ores and hydrocarbon-bearing inclusions are widespread in quartz and calcite, particularly in Dabaoshan. It is thought that the organic matter must have played a critical role in diagenesis and metallization in these deposits and that the hydrothermal solution was most 1ikely to be the type of water-oil hot brine. 展开更多
关键词 有机地球化学 锌矿床 成矿作用 昆仑山 广东
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Metallogeny of the Baiyangping Lead-Zinc Polymetallic Ore Concentration Area, Northern Lanping Basin of Yunnan Province, China 被引量:5
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作者 WANG Xiaohu SONG Yucai +3 位作者 ZHANG Hongrui LIU Yingchao PAN Xiaofei GUO Tao 《Acta Geologica Sinica(English Edition)》 CAS CSCD 2018年第4期1486-1507,共22页
The Lanping Basin in the Nujiang-Lancangjiang-Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of l... The Lanping Basin in the Nujiang-Lancangjiang-Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment-hosted Pb-Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India-Asia continental coUisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the oreforming elements in the east ore belt are mainly Pb-Zn -Sr-Ag, while Pb-Zn-Ag-Cu-Co elements are dominant in the west ore belt. Comparative analysis of the C-O-Sr-S-Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore- forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb-Zn mineralization age of both ore belts was contemporary and formed in the same metaliogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship. 展开更多
关键词 eastern Tethyan metallogenic domain Lanping Basin Baiyangping ore concentration area lead-zinc polymetallic ore deposit genesis of deposit
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