Lead extraction from spent lead–acid battery paste in a molten Na2CO3 salt containing Zn O as a sulfur-fixing agent was studied. Some influencing factors, including smelting temperature, reaction time, Zn O and salt ...Lead extraction from spent lead–acid battery paste in a molten Na2CO3 salt containing Zn O as a sulfur-fixing agent was studied. Some influencing factors, including smelting temperature, reaction time, Zn O and salt dosages, were investigated in detail using single-factor experiments. The optimum conditions were determined as follows: T = 880°C; t = 60 min; Na2CO3/paste mass ratio = 2.8:1; and the Zn O dosage is equal to the stoichiometric requirement. Under the optimum conditions, the direct recovery rate of lead reached 98.14%. The results suggested that increases in temperature and salt dosage improved the direct recovery rate of lead. XRD results and thermodynamic calculations indicated that the reaction approaches of lead and sulfur were Pb SO4→Pb and Pb SO4→Zn S, respectively. Sulfur was fixed in the form of Zn S, whereas the molten salt did not react with other components, serving only as a reaction medium.展开更多
The tectono-stratigraphic sequences of the Kuqa foreland fold-thrust belt in the northern Tarim basin, northwest China, can be divided into the Mesozoic sub-salt sequence, the Paleocene-Eocene salt sequence and the Ol...The tectono-stratigraphic sequences of the Kuqa foreland fold-thrust belt in the northern Tarim basin, northwest China, can be divided into the Mesozoic sub-salt sequence, the Paleocene-Eocene salt sequence and the Oligocene-Quaternary supra-salt sequence. The salt sequence is composed mainly of light grey halite, gypsum, marl and brown elastics. A variety of salt-related structures have developed in the Kuqa foreland fold belt, in which the most fascinating structures are salt nappe complex. Based on field observation, seismic interpretation and drilling data, a large-scale salt nappe complex has been identified. It trends approximately east-west for over 200 km and occurs along the west Qiulitag Mountains. Its thrusting displacement is over 30 km. The salt nappe complex appears as an arcuate zone projecting southwestwards along the leading edge of the Kuqa foreland fold belt. The major thrust fault is developed along the Paleocene-Eocene salt beds. The allochthonous nappes comprise large north-dipping faulting monoclines which are made up of Paleocene-Pliocene sediments. Geological analysis and cross-section restoration revealed that the salt nappes were mainly formed at the late Himalayan stage (c.a. 1.64 Ma BP) and have been active until the present day. Because of inhomogeneous thrusting, a great difference may exist in thrust displacement, thrust occurrence, superimposition of allochthonous and autochthonous sequences and the development of the salt-related structures, which indicates the segmentation along the salt nappes. Regional compression, gravitational gliding and spreading controlled the formation and evolution of the salt nappe complex in the Kuqa foreland fold belt.展开更多
The main purpose of this presented article was to explain the need to study the amount of heavy metal salts in the environment where animals live, in the water, in air, and in the food and fodder consumed. This articl...The main purpose of this presented article was to explain the need to study the amount of heavy metal salts in the environment where animals live, in the water, in air, and in the food and fodder consumed. This article presents materials from the literature on the effects of heavy metal salts on the body of animals and the environment in which they live. The cited analytical data showed that the general information on the negative effects of heavy metal salts on the body is sufficient, but their effects on the digestive tract and morpho-functional properties of rabbits should be studied in depth. Therefore, we planned to focus our scientific work on this topic. The article mainly refers to salts of heavy metals cadmium, lead, and mercury (Cd, Pb, Hg). It is noted in the literature that heavy metal salts have a negative effect on the body of animals. We focused mainly on data on the effects of heavy metals on farm animals, including rabbits. But it is clear that the authors referred to were referring to experimental animals. These negative effects are manifested in the form of disorders of digestive functions, disorders of neurovegetative processes, increasing incidence of cardiovascular disease, rapid heart failure, deterioration of calcium metabolism, as well as impaired haemoglobin metabolism. Disorders of protein metabolism manifest themselves in the form of cases of hyperproteinaemia and dysproteinaemia. The results of the evaluation of the organism of healthy animals in chemically and radioactively contaminated areas showed the accumulation of significant levels of chemical elements in their organism. We mainly looked at the effects of heavy metal salts on farm animals. The cited analytical data showed that the general information on the negative effects of heavy metal salts on the body is sufficient, but the effects on the activity of organ systems in the body (respiration, blood and blood circulation, digestion, reproduction, productivity and immunological systems) have not been comprehensively studied.展开更多
The results of recent mineral exploration in the Yuele lead-zinc mining area of Daguan County, northeastern Yunnan province, showed that there are much early Paleozoic strata under thick late Paleozoic strata in north...The results of recent mineral exploration in the Yuele lead-zinc mining area of Daguan County, northeastern Yunnan province, showed that there are much early Paleozoic strata under thick late Paleozoic strata in northeastern Yunnan province, where developed some hidden salt structures (SSs), often with lead-zinc polymetallic mineralization varying degrees along the tension torsional fault (belts) or fracture (joint). The ore-bodies belong to the epigenetic hydrothermal filling vein-type deposit, and the prospecting potential is great. In this area, the superficial mineralization information displayed clear, but the deep mineralization is unknown, so the exploration work is restricted. The audio-megnetotelluric (AMT) surveying is an advantageous method to characterize the size, resistivity and skin depth of the polarizable mineral deposit concealed beneath thick overburden. This paper presents the surveying results using AMT method to evaluate the concealed lead-zinc mineralization in Yuele lead-zinc ore field, Daguancounty, NE Yunnan province, China. After comparing the interpretation result of AMT surveying data with the geological data and the drilling data, it is found that there is some distinct difference in resistivity and polarizable between ore-bodies hosted strata, upper strata and gypsum strata. The results show that AMT method is helpful to identify lead-zinc mineralization under this geological condition.展开更多
基金financially supported by the National Nature Science Foundation of China (Nos. 51234009 and 51104182)the Natural Science Foundation of Hunan Province, China (No. 13JJ5035)the Scientific Research Fund of Hunan Provincial Education Department, China (No. 14C0349)
文摘Lead extraction from spent lead–acid battery paste in a molten Na2CO3 salt containing Zn O as a sulfur-fixing agent was studied. Some influencing factors, including smelting temperature, reaction time, Zn O and salt dosages, were investigated in detail using single-factor experiments. The optimum conditions were determined as follows: T = 880°C; t = 60 min; Na2CO3/paste mass ratio = 2.8:1; and the Zn O dosage is equal to the stoichiometric requirement. Under the optimum conditions, the direct recovery rate of lead reached 98.14%. The results suggested that increases in temperature and salt dosage improved the direct recovery rate of lead. XRD results and thermodynamic calculations indicated that the reaction approaches of lead and sulfur were Pb SO4→Pb and Pb SO4→Zn S, respectively. Sulfur was fixed in the form of Zn S, whereas the molten salt did not react with other components, serving only as a reaction medium.
基金This research received financial supports from the National Natural Science Foundation of China(grant 40172076)the National Major Fundamental Research and Development Project(grant G1999043305)the National Key Project of the Ninth Five—Year Plan(grant 99—1111)
文摘The tectono-stratigraphic sequences of the Kuqa foreland fold-thrust belt in the northern Tarim basin, northwest China, can be divided into the Mesozoic sub-salt sequence, the Paleocene-Eocene salt sequence and the Oligocene-Quaternary supra-salt sequence. The salt sequence is composed mainly of light grey halite, gypsum, marl and brown elastics. A variety of salt-related structures have developed in the Kuqa foreland fold belt, in which the most fascinating structures are salt nappe complex. Based on field observation, seismic interpretation and drilling data, a large-scale salt nappe complex has been identified. It trends approximately east-west for over 200 km and occurs along the west Qiulitag Mountains. Its thrusting displacement is over 30 km. The salt nappe complex appears as an arcuate zone projecting southwestwards along the leading edge of the Kuqa foreland fold belt. The major thrust fault is developed along the Paleocene-Eocene salt beds. The allochthonous nappes comprise large north-dipping faulting monoclines which are made up of Paleocene-Pliocene sediments. Geological analysis and cross-section restoration revealed that the salt nappes were mainly formed at the late Himalayan stage (c.a. 1.64 Ma BP) and have been active until the present day. Because of inhomogeneous thrusting, a great difference may exist in thrust displacement, thrust occurrence, superimposition of allochthonous and autochthonous sequences and the development of the salt-related structures, which indicates the segmentation along the salt nappes. Regional compression, gravitational gliding and spreading controlled the formation and evolution of the salt nappe complex in the Kuqa foreland fold belt.
文摘The main purpose of this presented article was to explain the need to study the amount of heavy metal salts in the environment where animals live, in the water, in air, and in the food and fodder consumed. This article presents materials from the literature on the effects of heavy metal salts on the body of animals and the environment in which they live. The cited analytical data showed that the general information on the negative effects of heavy metal salts on the body is sufficient, but their effects on the digestive tract and morpho-functional properties of rabbits should be studied in depth. Therefore, we planned to focus our scientific work on this topic. The article mainly refers to salts of heavy metals cadmium, lead, and mercury (Cd, Pb, Hg). It is noted in the literature that heavy metal salts have a negative effect on the body of animals. We focused mainly on data on the effects of heavy metals on farm animals, including rabbits. But it is clear that the authors referred to were referring to experimental animals. These negative effects are manifested in the form of disorders of digestive functions, disorders of neurovegetative processes, increasing incidence of cardiovascular disease, rapid heart failure, deterioration of calcium metabolism, as well as impaired haemoglobin metabolism. Disorders of protein metabolism manifest themselves in the form of cases of hyperproteinaemia and dysproteinaemia. The results of the evaluation of the organism of healthy animals in chemically and radioactively contaminated areas showed the accumulation of significant levels of chemical elements in their organism. We mainly looked at the effects of heavy metal salts on farm animals. The cited analytical data showed that the general information on the negative effects of heavy metal salts on the body is sufficient, but the effects on the activity of organ systems in the body (respiration, blood and blood circulation, digestion, reproduction, productivity and immunological systems) have not been comprehensively studied.
文摘The results of recent mineral exploration in the Yuele lead-zinc mining area of Daguan County, northeastern Yunnan province, showed that there are much early Paleozoic strata under thick late Paleozoic strata in northeastern Yunnan province, where developed some hidden salt structures (SSs), often with lead-zinc polymetallic mineralization varying degrees along the tension torsional fault (belts) or fracture (joint). The ore-bodies belong to the epigenetic hydrothermal filling vein-type deposit, and the prospecting potential is great. In this area, the superficial mineralization information displayed clear, but the deep mineralization is unknown, so the exploration work is restricted. The audio-megnetotelluric (AMT) surveying is an advantageous method to characterize the size, resistivity and skin depth of the polarizable mineral deposit concealed beneath thick overburden. This paper presents the surveying results using AMT method to evaluate the concealed lead-zinc mineralization in Yuele lead-zinc ore field, Daguancounty, NE Yunnan province, China. After comparing the interpretation result of AMT surveying data with the geological data and the drilling data, it is found that there is some distinct difference in resistivity and polarizable between ore-bodies hosted strata, upper strata and gypsum strata. The results show that AMT method is helpful to identify lead-zinc mineralization under this geological condition.
