Investigation of the thermodynamic processes of a floe-lead system in the central Arctic during later summer

Thermodynamic processes of a system involving a floe and a small lead in the central Arctic were investigated during the ice-camp period of the third Chinese National Arctic Research Expedition from 20 to 28 August, 2008. The measurements included surface air temperatures above the floe, spectral albedo of the lead, seawater temperatures in the lead and under the ice cover, and the lateral and bottom mass balance of the floe. The surface air temperature at 1.15 m remained below 0~Cthroughout the observation period and sea ice had commenced its annual cycle of growth in response to autumn cooling during the study. The surface of the lead was frozen by 23 August, after which the spectral albedo of the thin-ice-covered lead in the band of 320-950 nm was 0.46 -0.03, the seawater temperatures both in the lead and under the ice cover, as well as the vertical seawater-temperature gradient in the lead decreased gradually, and the oceanic heat under the ice was maintained at a low level approaching 0 W/m2. By the end of the measurement, the thickness of the investigated floe had reached its annual minimum, while the lateral of the floe was still in the melting phase, with a mean melting rate of 1.0±0.3 cm/d during the measurement, responding to an equivalent latent heat flux of 21 ±6 W/m2. The lateral melting of the floe had made a more significant contribution to the sea-ice mass balance than the surface and bottom melting in the end of August.

Vapor pressure measurement of lead and lead chlorides in FeO_T-CaO-SiO_2-Al_2O_3 system

Vapor pressure of lead and lead chlorides from FeOT？CaO？SiO2？Al2O3 slag system was measured by using Knudsen effusion method. The results suggest that the vapor pressures of lead and lead chlorides increase with increasing temperature. For the slag systems without chlorine, the logarithm of vapor pressure （lnp） shows highly linear dependency on the reciprocal of temperature （1/T）, and higher vapor pressure is observed in the condition where more metallic lead vapor is formed. In this case, the vapor pressure of lead increases with increasing slag basicity （w（CaO）/w（SiO2））, increasing FeO content andw（Fe2＋）/w（Fe3＋） ratio. For the case of slag system with chlorine addition, the total pressures of PbCl2 and PbCl increase with decreasing basicity and FeO content of slag.

Quantity-based shipment consolidation and stock replenishment policy with lead time in vendor-managed inventory system

In order to let the supplier make more reasonable supply decisions,an integrated continuous replenishment policy for the vendor-managed inventory system is presented,which considers the quantity-based shipment consolidation and stock replenishment with lead time.Then the system cost is analyzed and a mathematical model is built.Since the model is rather complex,the bounds of the optimal policy are first attained,then the problem is solved by a heuristic algorithm.Through experiments the relationship between the order lead time and the corresponding integrated policy is discussed,and the influence on the system cost is also analyzed.The results reveal that the lead time's influence on the system is more serious with the increase of the order lead time,the integrated policy with the order lead time is more reasonable and the optimal policy can minimize the total system cost.Finally,the parameter sensitivity of the model is analyzed.

Thermodynamic model of lead oxide activity in PbO-CaO-SiO_2-FeO-Fe_2O_3 slag system

According to the ion and molecule coexistence theory, a thermodynamic model of lead oxide activity in PbO-CaO-SiO2-FeO-Fe2O3 slag system was established at the temperature of 1273-1733 K. The activities of Pb O in slag were calculated, and their equal activity curves were plotted. The influences of slag basicity Q, iron oxide rate R and temperature T on activity NPb O and activity coefficient γPbO were also investigated. Results show that the calculated values of γPb O are in good agreement with the reported experimental data, showing that the model can wholly embody the slag structural characteristics. NPbO departures positively from Raoult values, and increases with increasing Pb O content in slag but changes little with T. γPbO increases with increasing Q, and goes through the maximum with increasing R for basic slag（Q0.3）. Results can be applied to the thermodynamic research and operational optimization of modern lead smelting technologies.

A suggestion for unification of present limb lead systems into a single“F”lead system

Abstract In this paper it is intended to unify the standard lead and the augmented unipolar limb lead (aV lead) system into a single lead system. Viewing from the angle of lead axes, the standard leads and the aV leads are not only reflecting the frontal plane vector, but are also actually complementary to each other. By now it has become quite obvious that they not only can, but also should be unified into a single system. Viewing these six leads (from standard lead and aV lead systems), starting from aVL, lead Ⅰ, reversed aVR, lead Ⅱ, aVF to lead Ⅲ, an arc including approximately 150° is formed. It is suggested that this unified system may be called “F” system with each of the above leads renamed as F1 F6 leads, respectively, since they are all reflecting the vectors of the frontal plane. In this F lead system each lead is approximately 30° apart. If such a system would be adopted it is only necessary to time the amplitude of the P, QRS and T of aV lead by 1.15 (a figure calculated by vector analysis). If this suggestion is widely adopted there will be only a F lead system for the frontal vectors and the present V system for the “horizontal” vectors in the electrocardiogram.

In-situ Leaching-immobilization of Lead in Soilvegetable System Based on Coupling of Remediation & Production

[Objective] The aim was to seek effective soil remediation technologies suitable for soils slightly or moderately polluted. [Method] In-situ leaching-immobi- lization was used to research remediation soil and vegetable contaminated by lead in vegetable bases in Chongqing. [Result] By tartaric acid-based leaching-sodium sulphide-based immobilization, vegetable Pb reduction rate was 46.4%, soil Pb reduction rate was 8.45% and Pb immobilization rate was 9.3% in deeper horizons. EDTA leaching did reduce lead content in vegetables, but reduced vegetable yield simultaneously. [Conclusion] The coupling remediation technology brought heavy metal contents down in vegetables without affecting productions. Therefore, it guarantees vegetable safety and reduces vegetable farmer＇s economic loss. It is a remediation technology suitable for soils slightly or moderately contaminated by heavy metals.

φ-pH diagram of As-N-Na-H_2O system for arsenic removal during alkaline pressure oxidation leaching of lead anode slime

In order to illustrate the thermodynamic characteristics of arsenic during alkaline pressure oxidation leaching process oflead anode slime(NaNO3as oxidant;NaOH as alkaline reagent),theφ-pH diagrams of As-Na-H2O,N-H2O,As-N-Na-H2Osystems at ionic mass concentration of0.1mol/kg and temperatures of298,373,423and473K were established according tothermodynamic calculation.The results show that the existence forms of arsenic are associated with pH value,which mainly exists inthe forms of H3AsO4,24H AsO-,24HAsO-,H2AsO2-and As2O3in lower pH region,while it mainly exists in the form of3AsO4-when pH>11.14.High alkali concentration and high temperature are advantageous to the arsenic leaching.The alkaline pressureoxidation leaching experiments display that the tendency of arsenic leaching rate confirms the thermodynamic analysis resultsobtained from theφ-pH diagrams of As-N-Na-H2O system,and the highest leaching rate of arsenic reaches95.85%at453K.

Vaporization behavior of lead from the FeO-CaO-SiO_2-Al_2O_3 slag system

Vaporization behavior （1163-1463 K） of lead in the slag system of FeO-CaO-SiO2-Al2O3 with CaC% was examined. A thermodynamic estimation with the principle of Gibbs free energy minimization showed that the major vapor species from the sample of the FeO-CaO-SiO2-Al2O3 system＋PbO＋CaCl2 were metallic Pb, PbCl, PbCl2, and FeCl2, at the experimental temperature range. The experimental results show that the mole ratio of vaporized Cl in lead chlorides to vaporized Pb, simply expressed as Cl/Pb decreases with increasing temperature. The larger Cl/Pb means a larger ratio of gaseous PbCl2, since metallic Pb and PbCl vapors are formed in a similar reduction atmosphere. The evaporation is initially rapid and becomes steady after holding for 10 min. Gaseous PbCl2 is mainly formed during the heating period, and at the holding stage, it reacts with FeO to produce gaseous FeCl2 With regard to slag composition, FeO content and basicity significantly affect the evaporation of lead. High FeO content and high basicity promotes the formation of metallic Pb and PbCI, whereas, it prohibits PbCl2 evaporation.

Removal of lead and cadmium ions by single and binary systems using phytogenic magnetic nanoparticles functionalized by 3-marcaptopropanic acid

The present research study is focused on green fabrication of superparamagnetic Phytogenic Magnetic Nanoparticles(PMNPs), and then its surface functionalization with 3-Mercaptopropionic acid(3-MPA). The resulting material(i.e. 3-MPA@PMNPs) characterized by FTIR, powder XRD, SEM, TEM, EDX, VSM, BET and TGA techniques and then further employed for the investigation of the adsorptive removal of lead(Pb^2+) and cadmium(Cd^2+) ions from aqueous solutions in single and binary systems. The material showed fastest adsorptive rate(98.23%) for Pb^2+ and(96.5%) Cd2+within the contact time of 60 min at pH 6.5 in the single system. The experimental data were fitted well to Langmuir isotherm, indicated monolayer adsorption of both metal ions onto 3-MPA@PMNPs and an estimated comparable adsorptive capacity of 68.41 mg·g^-1(Pb2+) and 79.8 mg·g^-1(Cd2+) at p H 6.5. However, kinetic data agreed well with pseudo-second-order model, and indicated that the removal mainly supported chemisorption and/or ion-exchange mechanism. Thermodynamic parameters such asΔGo,ΔHo, and ΔSo, were-3259.20, 119.35 and 20.73 for Pb^2+, and-1491.10, 45.441 and 7.87 for Cd^2+ at temperature 298.15 K, confirmed that adsorption was endothermic, spontaneous and favorable. The material demonstrated higher selectivity of Pb2+ and its removal efficiency was(98.20 ± 0.3)% in binary system experiments. The material persisted performance up-to seven(07) consecutive treatment cycles without losing their stability and offered comparable fastest magnetic separation(35 s) from aqueous solutions. Therefore, it is recommended that the prepared material can be employed to remove toxic heavy metal ions from water/wastewaters and this "green" method can easily be implemented at large scale in low economy countries.

A Systematic Assessment of Blood Lead Level in Children and Associated Risk Factors in China

In this study, we searched multiple databases for all relevant original articles (1996-2013). To investigate blood lead levels (BLL) and possible risk factors for lead exposure among children in China A total of 388 articles met our inclusion criteria. The overall geometric mean (GM) BLL was 71 μg/L, and the prevalence of elevated BLL (EBLL, defined as BLL ≥100 μg/L) was 18.48% among children. The prevalence of EBLL remained significantly higher among boys. In children less than 6 years of age, there were significantly increasing trends in both BLL and prevalence of EBLL in an age-dependent manner. The ban on leaded gasoline significantly reduced the BLL as well as EBLL prevalence; however, children whose parents had lower educational levels or were exposed to lead in the workplace had a higher EBLL prevalence. Despite its decline over time, the average BLL among children in China remains higher than the average level most recently reported in the United States. Childhood lead poisoning remains a public health problem in China.

Transition from the Southern Mode of the Mei-yu Front Cloud System to Other Leading Modes

Based on normalized six-hourly black body temperature （TBB） data of three geostationary meteorological satellites,the leading modes of the mei-yu cloud system between 1998 and 2008 were extracted by the Empirical Orthogonal Function （EOF） method,and the transition processes from the first typical leading mode to other leading modes were discussed and compared.The analysis shows that,when the southern mode （EOF1） transforms to the northeastern mode （EOF3）,in the mid-troposphere,a low trough develops and moves southeastward over central and eastern China.The circulation pattern is characterized by two highs and one low in the lower troposphere.A belt of low pressure is sandwiched between the weak high over central and western China and the strong western North Pacific subtropical high （WNPSH）.Cold air moves southward along the northerly flow behind the low,and meets the warm and moist air between the WNPSH and the forepart of the low trough,which leads to continuous convection.At the same time,the central extent of the WNPSH increases while its ridge extends westward.In addition,transitions from the southern mode to the dual centers mode and the tropical-low-influenced mode were found to be atypical,and so no common points could be concluded.Furthermore,the choice of threshold value can affect the number of samples discussed.

A pre-warning system of abnormal energy consumption in lead smelting based on LSSVR-RP-CI

The pre-warning of abnormal energy consumption is important for energy conservation of industrial engineering. However, related studies on the lead smelting industries which usually have a huge energy consumption are rarely reported. Therefore, a pre-warning system was established in this study based on the intelligent prediction of energy consumption and the identification of abnormal energy consumption. A least square support vector regression (LSSVR) model optimized by the adaptive genetic algorithm was developed to predict the energy consumption in the process of lead smelting. A recurrence plots (RP) analysis and a confidence intervals (CI) analysis were conducted to quantitatively confirm the stationary degree of energy consumption and the normal range of energy consumption, respectively, to realize the identification of abnormal energy consumption. It is found the prediction accuracy of LSSVR model can exceed 90% based on the comparison between the actual and predicted data. The energy consumption is considered to be non-stationary if the correlation coefficient between the time series of periodicity and energy consumption is larger than that between the time series of periodicity and Lorenz. Additionally, the lower limit and upper limit of normal energy consumption are obtained.

A Study on the Seismic Isolation Systems of Bridges with Lead Rubber Bearings

This study consists of the development and presentation of example of seismic isolation system analysis and design for a continuous, 3-span, cast-in-place concrete box girder bridge. It is expected that example is developed for all Lead-Rubber Bearing (LRB) seismic isolation system on piers and abutments which placed in between super-structure and sub-structure. Design forces, displacements, and drifts are given distinctive consideration in accordance with Caltrans Seismic Design Criteria (2004). Most of all, total displacement on design for all LRBs case is reduced comparing with combined lead-rubber and elastomeric bearing system . Therefore, this represents substantial reduction in cost because of reduction of expansion joint. This presents a summary of analysis and design of seismic isolation system by energy mitigation with LRB on bridges.

Thermodynamic analysis of separating lead and antimony in chloride system

In chloride system, thermodynamic analysis is a useful guide to separate lead and antimony as well as to understand the separation mechanism. An efficient and feasible way for separating lead and antimony was discussed. The relationships of [Pb2+][Cl-]2—lg[Cl]T and E—lg[Cl]T in Pb-Sb-Cl-H2O system were studied, and the solubilities of lead chloride at different antimony concentrations were calculated based on principle of simultaneous equilibrium. The results show that insoluble salt PbCl2 will only exist stably in a certain concentration range of chlorine ion. This concentration range of chlorine ion expands a little with increasing the concentration of antimony in the system while narrows as the system acidity increases. The solubility of Pb2+ in solution decreases with increasing the concentration of antimony in the system, whereas increases with increasing the concentration of total chlorine. The concentration range of total chlorine causing lead solubility less than 0.005 mol/L increases monotonically.

Electrical and Spectroscopic Studies of the CdO Substituted Lead Vanadate Glass System vs Crystalline Form

Results of the direct current (DC) Electrical Conductivity, thermoelectric power and Electron Spin Resonance (ESR) of CdO substituted PbO-V2O5 glass system are reported. Conduction in these glasses is found to be electronic and the hoping of polaron seems to be the dominant process in the transport mechanism. There is a remarkable decrease in the activation energy for conduction in the annealed and devitrified samples when compared to their amorphous counter parts. It is observed that there is remarkable improvement in the conductivity of the crystalline samples when compared to their amorphous counter parts. The thermoelectric power measurements indicates that the amorphous samples are n-type at room temperature where as the crystalline samples are p-type at room temperature. In crystalline samples the hyperfine structure is nearly smeared out and a relatively broad line with an isotropic g value characterizes the spectra.

Influence of Iron Supplementation on DMT1(IRE)-induced Transport of Lead by Brain Barrier Systems in vivo

Objective To investigate the potential involvement of DMT1（IRE） protein in the brain vascular system in vivo during Pb exposure. Methods Three groups of male Sprague-Dawley rats were exposed to Pb in drinking water, among which two groups were concurrently administered by oral gavage once every other day as the low and high Fe treatment group, respectively, for 6 weeks. At the same time, the group only supplied with high Fe was also set as a reference. The animals were decapitated, then brain capillary-rich fraction was isolate from cerebral cortex. Western blot method was used to identify protein expression, and RT-PCR to detect the change of the m RNA. Results Pb exposure significantly increased Pb concentrations in cerebral cortex. Low Fe dose significantly reduced the cortex Pb levels, However, high Fe dose increased the cortex Pb levels. Interestingly, changes of DMT1（IRE） protein in brain capillary-rich fraction were highly related to the Pb level, but those of DMT1（IRE） m RNA were not significantly different. Moreover, the consistent changes in the levels of p-ERK1/2 or IRP1 with the changes in the levels of DMT1（IRE）. Conclusion These results suggest that Pb is transported into the brain through DMT1（IRE）, and the ERK MAPK pathway is involved in DMT1（IRE）-mediated transport regulation in brain vascular system in vivo.

ANALYSIS AND IMPROVEMENT OF LEAD TIME FOR JOB SHOP UNDER MIXED PRODUCTION SYSTEM

Firstly an overview of the potential impact on work-in-process （WIP） and lead time is provided when transfer lot sizes are undifferentiated from processing lot sizes. Simple performance examples are compared to those from a shop with one-piece transfer lots. Next, a mathematical programming model for minimizing lead time in the mixed-model job shop is presented, in which one-piece transfer lots are used. Key factors affecting lead time are found by analyzing the sum of the longest setup time of individual items among the shared processes （SLST） and the longest processing time of individual items among processes （LPT）. And lead time can be minimized by cutting down the SLST and LPT. Reduction of the SLST is described as a traveling salesman problem （TSP）, and the minimum of the SLST is solved through job shop scheduling. Removing the bottleneck and leveling the production line optimize the LPT. If the number of items produced is small, the routings are relatively short, and items and facilities are changed infrequently, the optimal schedule will remain valid. Finally a brief example serves to illustrate the method.

Effect of cerium on microstructure and mechanical properties of Sn-Ag-Cu system lead-free solder alloys

The melting point, spreading property, mechanical properties and microstructures of Sn-3.0Ag-2.8Cu solder alloys added with micro-variable-Ce were studied by means of optical microscopy, scanning electron microscopy(SEM) and energy dispersive X-ray(EDX). The results indicate that the melting point of Sn-3.0Ag-2.8Cu solder is enhanced by Ce addition; a small amount of Ce will remarkably prolong the creep-rupture life of Sn-3.0Ag-2.8Cu solder joint at room temperature, especially when the content of Ce is 0.1%, the creep-rupture life will be 9 times or more than that of the solder joint without Ce addition; the elongation of Sn-3.0Ag-2.8Cu solder is also obviously improved even up to 15.7%. In sum, the optimum content of Ce is within 0.05%-0.1 %.

CATHODE ELECTRODEPOSITION OF LEAD IN Pb2+-OH--C4H4O62- SYSTEM

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Impact of Water Chemistry on Lead Carbonate Dissolution in Drinking Water Distribution Systems

Elemental lead is a known toxic metal that can pose threats to human health and can be found in a variety of sources including drinking water at very low level concentrations (i.e. μg/L range). Destabilization of the corrosion scale at the inner layer of pipeline is the major source of lead in drinking water. Chemical properties of the water passing through the distribution system such as pH, alkalinity, chlorine content, oxidation reduction potential (ORP) and natural organic matters will affect the formation and/or destabilization of the corrosion scale. This research examines the impact of pH values (7.0 - 9.5), temperatures (5°C vs 20°C) and alkalinity levels (moderate vs low), in the presence of chlorine, on dissolution of hydrocerussite and cerussite in drinking water by various sets of batch dissolution experiments. The results showed dissolution of cerussite and hydrocerussite was not impacted significantly by pH ranging 7.0 - 9.5. In addition, and somewhat surprisingly, cold temperature (5°C) and moderate alkalinity showed a great influence on decreasing the solubility of lead species.