Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research ob...Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.展开更多
The first-principles calculations are performed to examine structural,mechanical,and electronic properties at large strain for a monolayer C_(4)N_(4),which has been predicted as an anchoring promising material to atte...The first-principles calculations are performed to examine structural,mechanical,and electronic properties at large strain for a monolayer C_(4)N_(4),which has been predicted as an anchoring promising material to attenuate shuttle effect in Li–S batteries stemming from its large absorption energy and low diffusion energy barrier.Our results show that the ideal strengths of C_(4)N_(4)under tension and pure shear deformation conditions reach 13.9 GPa and 12.5 GPa when the strains are 0.07 and 0.28,respectively.The folded five-membered rings and diverse bonding modes between carbon and nitrogen atoms enhance the ability to resist plastic deformation of C_(4)N_(4).The orderly bond-rearranging behaviors under the weak tensile loading path along the[100]direction cause the impressive semiconductor–metal transition and inverse semiconductor–metal transition.The present results enrich the knowledge of the structure and electronic properties of C_(4)N_(4)under deformations and shed light on exploring other two-dimensional materials under diverse loading conditions.展开更多
Organic–inorganic lead halide perovskites(LHPs) have attracted great interest owing to their outstanding optoelectronic properties.Typically,the underlying electronic structure would determinate the physical properti...Organic–inorganic lead halide perovskites(LHPs) have attracted great interest owing to their outstanding optoelectronic properties.Typically,the underlying electronic structure would determinate the physical properties of materials.But as for now,limited studies have been done to reveal the underlying electronic structure of this material system,comparing to the huge amount of investigations on the material synthesis.The effective mass of the valance band is one of the most important physical parameters which plays a dominant role in charge transport and photovoltaic phenomena.In pristine CsPbBr_(3),the Fr?hlich polarons associated with the Pb–Br stretching modes are proposed to be responsible for the effective mass renormalization.In this regard,it would be very interesting to explore the electronic structure in doped LHPs.Here,we report high-resolution angle-resolved photoemission spectroscopy(ARPES) studies on both pristine and Cl-doped CsPbBr_(3).The experimental band dispersions are extracted from ARPES spectra along both ■ and ■ high symmetry directions.DFT calculations are performed and directly compared with the ARPES data.Our results have revealed the band structure of Cl-doped CsPbBr_(3) for the first time,which have also unveiled the effective mass renormalization in the Cl-doped CsPbBr_(3) compound.Doping dependent measurements indicate that the chlorine doping could moderately tune the renormalization strength.These results will help understand the physical properties of LHPs as a function of doping.展开更多
The size of pores or the grille spacing of water–sediment separation structures directly affects their regulation effect on the debris flow performance.A suitable pore size or grille spacing can effectively improve t...The size of pores or the grille spacing of water–sediment separation structures directly affects their regulation effect on the debris flow performance.A suitable pore size or grille spacing can effectively improve the water–sediment separation ability of the structure.The new funnel-type grating water–sediment separation structure(FGWSS)combines vertical and horizontal structures and provides a satisfactory water–sediment separation effect.However,the regulation effect of the grille spacing of the structure on the debris flow performance has not been studied.The regulation effect of the structure grille spacing on the debris flow performance is studied through a flume test,and the optimal structure grille spacing is obtained.An empirical equation of the relationship between the relative grille spacing of the structure and the sediment separation rate is established.Finally,the influence of the water–sediment separation structure on the regulation effect of debris flows is examined from two aspects:external factors(properties of debris flows)and internal factors(structural factors).The experimental results show that the gradation characteristics of solid particles in debris flows constitute a key factor affecting the regulation effect of the structure on the debris flow performance.The optimum grille spacing of the FGWSS matches the particle size corresponding to the material distribution curves d85~d90 of the debris flow.The total separation rate of debris flow particles is related to the grille spacing of the structure and the content of coarse and fine particles in the debris flow.展开更多
Objective:To explore the application effect of structured healthcare education in patients with brittle diabetes mellitus.Methods:188 brittle diabetic patients admitted to our hospital from May 2021 to December 2023 w...Objective:To explore the application effect of structured healthcare education in patients with brittle diabetes mellitus.Methods:188 brittle diabetic patients admitted to our hospital from May 2021 to December 2023 were selected as the study subjects,and were divided into the control group(n=94)and the observation group(n=94)according to the random number table method.The control group used conventional nursing intervention and the observation group used structured healthcare education.The general information,glycemic indexes,self-efficacy,compliance,and nursing satisfaction of patients in the two groups were observed.Results:There was no statistical significance in the basic information of the two groups of patients(P>0.05);after the intervention,the fasting plasma glucose,2-hour postprandial blood glucose,and HbA1c of the patients in the observation group were lower than those of the control group(P<0.001);after the intervention,the self-efficacy scores of the patients in the two groups increased,and the scores of the observation group were significantly higher than those of the control group(P<0.001);the total adherence rate of the patients in the observation group(90/95.75%)was significantly higher than that of the control group(80/90.10%)(χ^(2)=6.144,P<0.05);and the total satisfaction rate of patients in the observation group(92/97.87%)was significantly higher than that of the control group(78/82.98%)(χ^(2)=12.042,P<0.05).Conclusion:In patients with brittle diabetes mellitus,structured healthcare education can effectively control patients’blood glucose levels,improve patients’self-efficacy and adherence,and enhance patient satisfaction.展开更多
The clathrate hydrate memory effect is a fascinating phenomenon with potential applications in carbon capture,utilization and storage(CCUS),gas separation,and gas storage as it can accelerate the secondary formation o...The clathrate hydrate memory effect is a fascinating phenomenon with potential applications in carbon capture,utilization and storage(CCUS),gas separation,and gas storage as it can accelerate the secondary formation of clathrate hydrate.However,the underlying mechanism of this effect remains unclear.To gain a better understanding of the mechanism,we conducted molecular dynamic simulations to simulate the initial formation and reformation processes of methane hydrate.In this work,we showed the evolution process of hydrate residual structures into hydrate cages.The simulation results indicate that the residual structures are closely related to the existence of hydrate memory effect,and the higher the contribution of hydrate dissociated water to the hydrate nucleation process,the faster the hydrate nucleation.After hydrate dissociation,the locally ordered structures still exist after hydrate dissociation and can promote the formation of cluster structures,thus accelerating hydrate nucleation.Additionally,the nucleation process of hydrate and the formation process of clusters are inseparable.The size of clusters composed of cup-cage structures is critical for hydrate nucleation.The residence time at high temperature after hydrate decomposition will affect the strength of the hydrate memory effect.Our simulation results provide microscopic insights into the occurrence of the hydrate memory effect and shed light on the hydrate reformation process at the molecular scale.展开更多
Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materia...Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.展开更多
Aim: This paper aims to evaluate disparities of type 2 diabetes structured health education programmes that is utilised within the communities. Design: systematic review, (a type of secondary research design) aiming t...Aim: This paper aims to evaluate disparities of type 2 diabetes structured health education programmes that is utilised within the communities. Design: systematic review, (a type of secondary research design) aiming to summarize the results of prior primary research studies on available evidence Community type 2 diabetes structured education (CT2DSHE). Methods: Research question: Type 2 diabetic structured health education within a community how effective is it? Qualitative Systematic review, defined as a way to get reliable and objective picture of current available evidence on the specific topic—(CT2DSHE), (Denscombe, 2021) through reflexivity synthesis of available data as an example. This is valuable in time constraints such as project assignments that must be met within specific time and also to bring together available evidence together [1]. Results: This review has shown that CT2DSHE is effective with seven out of the eleven authors supporting, three authors against and one was neutral, further showed that knowledge and skills acquired can last longer with patient activation improved among T2DM patients ideal for sustaining their self-management of T2DM. Conclusion: This research provides suggestive answers to the research question: “Type 2 diabetic structured health education within a community how effective is it?”, This has demonstrated CT2DSHE effectiveness in knowledge acquisition and improving T2DM awareness among T2DM patients, whilst evidencing long effects beyond the study times of 3 - 9 months period in relation to patient activation. Also Identified diabetes education self-management on newly diagnosed (DESMOND) patient as CT2DSHE program for recommendation. Patient or Public Contribution: This work aspires to contribute to CT2DSHE in these areas;Influencing policy decision-making for community diabetes care within the UK and world at large., Contributing to already vast knowledge on diabetes self-management and reasons why?, Influencing educators on how CT2DSHEP are designed, delivered by putting the patient at the Centre and bringing different perspectives on CT2DSHEP in one place that is serving users time of having to consult several resources especially busy clinicians [2] [3].展开更多
Dielectric laser accelerators(DLAs)are considered promising candidates for on-chip particle accelerators that can achieve high acceleration gradients.This study explores various combinations of dielectric materials an...Dielectric laser accelerators(DLAs)are considered promising candidates for on-chip particle accelerators that can achieve high acceleration gradients.This study explores various combinations of dielectric materials and accelerated structures based on the inverse Cherenkov effect.The designs utilize conventional processing methods and laser parameters currently in use.We optimize the structural model to enhance the gradient of acceleration and the electron energy gain.To achieve higher acceleration gradients and energy gains,the selection of materials and structures should be based on the initial electron energy.Furthermore,we observed that the variation of the acceleration gradient of the material is different at different initial electron energies.These findings suggest that on-chip accelerators are feasible with the help of these structures and materials.展开更多
Molecular dynamics (MD) simulations of monocrystalline copper (100) surface during nanomachining process were performed based on a new 3D simulation model. The material removal mechanism and system temperature dis...Molecular dynamics (MD) simulations of monocrystalline copper (100) surface during nanomachining process were performed based on a new 3D simulation model. The material removal mechanism and system temperature distribution were discussed. The simulation results indicate that the system temperature distribution presents a roughly concentric shape, a steep temperature gradient is observed in diamond cutting tool, and the highest temperature is located in chip. Centrosymmetry parameter method was used to monitor defect structures. Dislocations and vacancies are the two principal types of defect structures. Residual defect structures impose a major change on the workpiece physical properties and machined surface quality. The defect structures in workpiece are temperature dependent. As the temperature increases, the dislocations are mainly mediated from the workpiece surface, while the others are dissociated into point defects. The relatively high cutting speed used in nanomachining results in less defect structures, beneficial to obtain highly machined surface quality.展开更多
The effects of tropical storm on the community structure of Sonneratia caseolaris-Sonneratia apetala(S.caseolaris-S.apetala) artificial mangroves and Ceriops tagal-Rhizophora stylosa(C.tagal-R.stylosa) natural mangrov...The effects of tropical storm on the community structure of Sonneratia caseolaris-Sonneratia apetala(S.caseolaris-S.apetala) artificial mangroves and Ceriops tagal-Rhizophora stylosa(C.tagal-R.stylosa) natural mangroves were analyzed in Dongzhai Harbor in Hainan Island,and the results showed that the average tree height,crown width(CW) in east-west direction(E-W) and north-south direction(N-S) of S.caseolaris-S.apetala artificial mangroves were decreased by 2.8%,14.3% and 12.1% respectively,but the average clear bole height was increased by 60.0% after tropical storm.For C.tagal-R.stylosa natural mangroves,the average tree height and clear bole height were increased by 8.3% and 20.0%,but there was no change in CW(E-W) and CW(N-S).Therefore,tropical storm had greater effects on artificial mangroves than natural mangroves.After tropical storm,tree heights of different species increased in the following sequence:C.tagal>R.stylosa>S.apetala>S.caseolaris,and the sequence of effect degree on CW was C.tagal>R.stylosa>S.caseolaris>S.apetala,while it was C.tagal < R.stylosa < S.caseolaris < S.apetala for clear bole height.Under the effect of tropical storm,the average biomass loss and dry biomass loss of S.caseolaris-S.apetala artificial mangroves were 0.22 and 0.13 t/hm2 respectively,while there was a minimal biomass loss in C.tagal-R.stylosa natural mangroves.On the whole,the wind resistance of natural mangroves was better than artificial mangroves,and that of C.tagal was stronger than R.stylosa,while S.caseolaris was better than S.apetala.展开更多
The structure difference between light and heavy liquid water has been systematically in- vestigated by high precision Raman spectroscopy over the temperature range of 5-85℃. Distinct difference between the Raman spe...The structure difference between light and heavy liquid water has been systematically in- vestigated by high precision Raman spectroscopy over the temperature range of 5-85℃. Distinct difference between the Raman spectral profiles of two different liquid waters is clearly observed. By analyzing the temperature-dependent Raman spectral contour using global fitting procedure, it is found that the micro-structure of heavy water is more ordered than that of light water at the same temperature, and the structure difference between the light and heavy water decreases with the increase of the temperature. The temperature off- set, an indicator for the structure difference, is determined to vary from 28 ℃ to 18 ℃ for the low-to-high temperature. It indicates that quantum effect is significantly not only at low temperature, but also at room temperature. The interaction energy among water molecules has also been estimated from van't Hoff's relationship. The detailed structural information should help to develop reliable force fields for molecular modeling of liquid water.展开更多
In this study,Tremella fuciformis residues as raw material,dietary fibers from tremella were prepared by multiple enzymes.The structure of dietary fibers from tremella was studied by Fourier transform infrared(FTIR),X...In this study,Tremella fuciformis residues as raw material,dietary fibers from tremella were prepared by multiple enzymes.The structure of dietary fibers from tremella was studied by Fourier transform infrared(FTIR),X-ray diffraction analysis(XRD)and scanning electron microscopy(SEM).We analyzed their lipidlowering properties in vitro(water holding,oil holding swelling cholesterol and sodium cholate binding capacitises)and the hypolipidemic effects in mice.The results showed that tremella dietary fibers presented the infrared absorption spectrum characteristics of polysaccharides and the characteristic diffraction peaks of cellulose type I.SEM results indicated that the surface of insoluble dietary fiber(IDF)was porous,while the soluble dietary fiber(SDF)was relatively compact and spongy.IDF exhibited significantly higher water holding,oil holding,and swelling binding capacities than the corresponding SDF.However,SDF exhibited significantly higher viscosity than IDF.The results showed tremella dietary fibers were significant in swelling,water holding and oil holding,cholesterol and bile acids.In vivo experiment results in mice indicated that SDF has the best effect on hyperlipidemia mice than IDF and total dietary fiber(TDF).SDF showed that the total cholesterol(TC),triglyceride(TG)and low density lipoprotein cholesterol(LDL-C)contents dropped by 28.33%,18.65%,and 48.97%,respectively,while high density lipoprotein cholesterol(HDL-C)content increased by 43.80%.Compared with the high-fat control(HCM)group,the arteriosclerosis index(AI)and liver index(LI)of the SDF group mice showed significant differences,indicating that SDF has a good auxiliary effect of lowering blood lipids.The administration of tremella fibers improved the lipid metabolism disorderly situation of hyperlipidemia mice.These results provide a reference for further research and rational development of T.fuciformis.展开更多
Because of the existence of gradient field of the urban center and the corridor effect. underthe drive of going merely after economic benefit, the city intrinsically has the trend of massive growth, and this will se...Because of the existence of gradient field of the urban center and the corridor effect. underthe drive of going merely after economic benefit, the city intrinsically has the trend of massive growth, and this will seriously destroy the urban reasonable landscape structure and the ecological equilibrium.By applying the theory of corridor effect. this paper studies the interactive process between artificialcorridors and natural corridors. At the same time, by studying the Beijing's spatial extension pattern in central urban area during different periods. this paper analyses the corridors extension volume.extension velocity and variant tendency of urban landscape on & directions. Moreover. this paperbrings forward the idea of incorporating the systen of natural corridors into the Beijing'smetropolitan planning, namely to form a star-shaped scattering-group pattern in which artificialcorridors and natural corridors are alternately distributed in order to effectively prevent built-up areafrom massive growth .展开更多
Based on the results of two dimension velo city structure, 1∶100 000 aeromagnetic anomaly, 1∶200 000 bouguer gravity anom aly and seismic anisotropy of Jiaodong and neighboring region in Shandong, China , the info...Based on the results of two dimension velo city structure, 1∶100 000 aeromagnetic anomaly, 1∶200 000 bouguer gravity anom aly and seismic anisotropy of Jiaodong and neighboring region in Shandong, China , the information of geophysical field was divided into two parts: deep and sh allow focus fields. And then, the information of two different fields was c ombined with that of deep seated geology and ore deposit features. The syntheti c result was adopted to analyze three dimension structure, to probe into crust mantle coupling effects of mineralization and dynamics of ore formation system .展开更多
Numerical method is popular in analysing the blast wave propagation and interaction with structures.However,because of the extremely short duration of blast wave and energy trans-mission between different grids,the nu...Numerical method is popular in analysing the blast wave propagation and interaction with structures.However,because of the extremely short duration of blast wave and energy trans-mission between different grids,the numerical results are sensitive to the finite element mesh size.Previous numerical simulations show that a mesh size acceptable to one blast scenario might not be proper for another case,even though the difference between the two scenarios is very small,indicating a simple numerical mesh size convergence test might not be enough to guarantee accu-rate numerical results.Therefore,both coarse mesh and fine mesh were used in different blast scenarios to investigate the mesh size effect on numerical results of blast wave propagation and interaction with structures.Based on the numerical results and their comparison with field test re-sults and the design charts in TM5-1300,a numerical modification method was proposed to correct the influence of the mesh size on the simulated results.It can be easily used to improve the accu-racy of the numerical results of blast wave propagation and blast loads on structures.展开更多
The data of 16o national meteorological observatory stations including the long-term monthly temperature data in China were analyzed to study the seasonal variation of the spatial temperature structures across China i...The data of 16o national meteorological observatory stations including the long-term monthly temperature data in China were analyzed to study the seasonal variation of the spatial temperature structures across China in the past half century. It is found that temperature structures differ between seasons: a latitude temperature pattern in winter and a landform temperature pattern in summer, which indicate that the effect of landform on temperature structure is much stronger in summer than that in winter and the effect of latitudinal temperature is much stronger in winter than that in summer. The mechanisms of the seasonal difference in temperature structures are also discussed in this paper.展开更多
In the present research, hierarchical structure observation and mechanical property characterization for a type of biomaterial are carried out. The investigated bioma- terial is Hyriopsis cumingii, a typical limnetic ...In the present research, hierarchical structure observation and mechanical property characterization for a type of biomaterial are carried out. The investigated bioma- terial is Hyriopsis cumingii, a typical limnetic shell, which consists of two different structural layers, a prismatic "pillar" structure and a nacreous "brick and mortar" structure. The prismatic layer looks like a "pillar forest" with variationsection pillars sized on the order of several tens of microns. The nacreous material looks like a "brick wall" with bricks sized on the order of several microns. Both pillars and bricks are composed of nanoparticles. The mechanical properties of the hierarchical biomaterial are measured by using the nanoindentation test. Hardness and modulus are measured for both the nacre layer and the prismatic layer, respectively. The nanoindentation size effects for the hierarchical structural materials are investigated experimentally. The results show that the prismatic nanostructured material has a higher stiffness and hardness than the nacre nanostructured material. In addition, the nanoindentation size effects for the hierarchical structural materials are described theoretically, by using the trans-scale mechanics theory considering both strain gradient effect and the surface/interface effect. The modeling results are consistent with experimental ones.展开更多
Digital structured light (SL) profilometry is increasingly used in three-dimensional (3D) measurement technology. However, the nonlinearity of the off-the-shelf projectors and cameras seriously reduces the measure...Digital structured light (SL) profilometry is increasingly used in three-dimensional (3D) measurement technology. However, the nonlinearity of the off-the-shelf projectors and cameras seriously reduces the measurement accuracy. In this paper, first, we review the nonlinear effects of the projector-camera system in the phase-shifting structured light depth measurement method. We show that high order harmonic wave components lead to phase error in the phase-shifting method. Then a practical method based on frequency domain filtering is proposed for nonlinear error reduction. By using this method, the nonlinear calibration of the SL system is not required. Moreover, both the nonlinear effects of the projector and the camera can be effectively reduced. The simulations and experiments have verified our nonlinear correction method.展开更多
Based on the analysis and comparison of soil temperature, thermal regime and permafrost table under the experimental embankment of crushed rock structures in Beiluhe, results show that crushed rock structures provide ...Based on the analysis and comparison of soil temperature, thermal regime and permafrost table under the experimental embankment of crushed rock structures in Beiluhe, results show that crushed rock structures provide an extensive cooling effect, which produces a rising permafrost table and decreasing soil temperatures. The rise of the permafrost table under the embankment ranges from an increase of 1.08 m to 1.67 m, with an average of 1.27 m from 2004 to 2007. Mean annual soil temperatures under the crushed rock layer embankment decreased significantly from 2005 to 2007, with average decreases of ?1.03 °C at the depth of 0.5 m, ?1.14 °C at the depth of 1.5 m, and ?0.5 °C at the depth of 5 m. During this period, mean annual soil temperatures under the crushed rock cover embankment showed a slight decrease at shallow depths, with an average decrease of ?0.2 °C at the depth of 0.5 m and 1.5 m, but a slight rise at the depth of 5 m. After the crushed rock structures were closed or crammed with sand, the cooling effect of the crushed rock layer embankment was greatly reduced and that of the crushed rock cover embankment was just slightly reduced.展开更多
基金Under the auspices of National Natural Science Foundation of China(No.42171230)。
文摘Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.
基金Project support by the National Natural Science Foundation of China(Grant Nos.11704044 and 12074140)。
文摘The first-principles calculations are performed to examine structural,mechanical,and electronic properties at large strain for a monolayer C_(4)N_(4),which has been predicted as an anchoring promising material to attenuate shuttle effect in Li–S batteries stemming from its large absorption energy and low diffusion energy barrier.Our results show that the ideal strengths of C_(4)N_(4)under tension and pure shear deformation conditions reach 13.9 GPa and 12.5 GPa when the strains are 0.07 and 0.28,respectively.The folded five-membered rings and diverse bonding modes between carbon and nitrogen atoms enhance the ability to resist plastic deformation of C_(4)N_(4).The orderly bond-rearranging behaviors under the weak tensile loading path along the[100]direction cause the impressive semiconductor–metal transition and inverse semiconductor–metal transition.The present results enrich the knowledge of the structure and electronic properties of C_(4)N_(4)under deformations and shed light on exploring other two-dimensional materials under diverse loading conditions.
基金Project supported by the International Partnership Program of the Chinese Academy of Sciences(Grant No.123GJHZ2022035MI)the Fundamental Research Funds for the Central Universities(Grant Nos.WK3510000015 and WK3510000012)。
文摘Organic–inorganic lead halide perovskites(LHPs) have attracted great interest owing to their outstanding optoelectronic properties.Typically,the underlying electronic structure would determinate the physical properties of materials.But as for now,limited studies have been done to reveal the underlying electronic structure of this material system,comparing to the huge amount of investigations on the material synthesis.The effective mass of the valance band is one of the most important physical parameters which plays a dominant role in charge transport and photovoltaic phenomena.In pristine CsPbBr_(3),the Fr?hlich polarons associated with the Pb–Br stretching modes are proposed to be responsible for the effective mass renormalization.In this regard,it would be very interesting to explore the electronic structure in doped LHPs.Here,we report high-resolution angle-resolved photoemission spectroscopy(ARPES) studies on both pristine and Cl-doped CsPbBr_(3).The experimental band dispersions are extracted from ARPES spectra along both ■ and ■ high symmetry directions.DFT calculations are performed and directly compared with the ARPES data.Our results have revealed the band structure of Cl-doped CsPbBr_(3) for the first time,which have also unveiled the effective mass renormalization in the Cl-doped CsPbBr_(3) compound.Doping dependent measurements indicate that the chlorine doping could moderately tune the renormalization strength.These results will help understand the physical properties of LHPs as a function of doping.
基金supported by the National Natural Science Foundation of China(Grant Nos.42027806 and 42041006)。
文摘The size of pores or the grille spacing of water–sediment separation structures directly affects their regulation effect on the debris flow performance.A suitable pore size or grille spacing can effectively improve the water–sediment separation ability of the structure.The new funnel-type grating water–sediment separation structure(FGWSS)combines vertical and horizontal structures and provides a satisfactory water–sediment separation effect.However,the regulation effect of the grille spacing of the structure on the debris flow performance has not been studied.The regulation effect of the structure grille spacing on the debris flow performance is studied through a flume test,and the optimal structure grille spacing is obtained.An empirical equation of the relationship between the relative grille spacing of the structure and the sediment separation rate is established.Finally,the influence of the water–sediment separation structure on the regulation effect of debris flows is examined from two aspects:external factors(properties of debris flows)and internal factors(structural factors).The experimental results show that the gradation characteristics of solid particles in debris flows constitute a key factor affecting the regulation effect of the structure on the debris flow performance.The optimum grille spacing of the FGWSS matches the particle size corresponding to the material distribution curves d85~d90 of the debris flow.The total separation rate of debris flow particles is related to the grille spacing of the structure and the content of coarse and fine particles in the debris flow.
文摘Objective:To explore the application effect of structured healthcare education in patients with brittle diabetes mellitus.Methods:188 brittle diabetic patients admitted to our hospital from May 2021 to December 2023 were selected as the study subjects,and were divided into the control group(n=94)and the observation group(n=94)according to the random number table method.The control group used conventional nursing intervention and the observation group used structured healthcare education.The general information,glycemic indexes,self-efficacy,compliance,and nursing satisfaction of patients in the two groups were observed.Results:There was no statistical significance in the basic information of the two groups of patients(P>0.05);after the intervention,the fasting plasma glucose,2-hour postprandial blood glucose,and HbA1c of the patients in the observation group were lower than those of the control group(P<0.001);after the intervention,the self-efficacy scores of the patients in the two groups increased,and the scores of the observation group were significantly higher than those of the control group(P<0.001);the total adherence rate of the patients in the observation group(90/95.75%)was significantly higher than that of the control group(80/90.10%)(χ^(2)=6.144,P<0.05);and the total satisfaction rate of patients in the observation group(92/97.87%)was significantly higher than that of the control group(78/82.98%)(χ^(2)=12.042,P<0.05).Conclusion:In patients with brittle diabetes mellitus,structured healthcare education can effectively control patients’blood glucose levels,improve patients’self-efficacy and adherence,and enhance patient satisfaction.
基金Financial support from the National Natural Science Foundation of China(22208329,22178378,22127812,21908116 and U19B2005)Jiangxi Provincial Natural Science Foundation of China(20232BAB213044)。
文摘The clathrate hydrate memory effect is a fascinating phenomenon with potential applications in carbon capture,utilization and storage(CCUS),gas separation,and gas storage as it can accelerate the secondary formation of clathrate hydrate.However,the underlying mechanism of this effect remains unclear.To gain a better understanding of the mechanism,we conducted molecular dynamic simulations to simulate the initial formation and reformation processes of methane hydrate.In this work,we showed the evolution process of hydrate residual structures into hydrate cages.The simulation results indicate that the residual structures are closely related to the existence of hydrate memory effect,and the higher the contribution of hydrate dissociated water to the hydrate nucleation process,the faster the hydrate nucleation.After hydrate dissociation,the locally ordered structures still exist after hydrate dissociation and can promote the formation of cluster structures,thus accelerating hydrate nucleation.Additionally,the nucleation process of hydrate and the formation process of clusters are inseparable.The size of clusters composed of cup-cage structures is critical for hydrate nucleation.The residence time at high temperature after hydrate decomposition will affect the strength of the hydrate memory effect.Our simulation results provide microscopic insights into the occurrence of the hydrate memory effect and shed light on the hydrate reformation process at the molecular scale.
基金supported by the National Natural Science Foundation of China(U21A20312,22172099,21975162,51902209)the Natural Science Foundation of Guangdong(2020A1515010840)the Shenzhen Science and Technology Program(SGDX20201103095802006,RCBS20200714114819161,JCYJ20190808111801674,JCYJ20200109105803806,RCYX20200714114535052)。
文摘Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.
文摘Aim: This paper aims to evaluate disparities of type 2 diabetes structured health education programmes that is utilised within the communities. Design: systematic review, (a type of secondary research design) aiming to summarize the results of prior primary research studies on available evidence Community type 2 diabetes structured education (CT2DSHE). Methods: Research question: Type 2 diabetic structured health education within a community how effective is it? Qualitative Systematic review, defined as a way to get reliable and objective picture of current available evidence on the specific topic—(CT2DSHE), (Denscombe, 2021) through reflexivity synthesis of available data as an example. This is valuable in time constraints such as project assignments that must be met within specific time and also to bring together available evidence together [1]. Results: This review has shown that CT2DSHE is effective with seven out of the eleven authors supporting, three authors against and one was neutral, further showed that knowledge and skills acquired can last longer with patient activation improved among T2DM patients ideal for sustaining their self-management of T2DM. Conclusion: This research provides suggestive answers to the research question: “Type 2 diabetic structured health education within a community how effective is it?”, This has demonstrated CT2DSHE effectiveness in knowledge acquisition and improving T2DM awareness among T2DM patients, whilst evidencing long effects beyond the study times of 3 - 9 months period in relation to patient activation. Also Identified diabetes education self-management on newly diagnosed (DESMOND) patient as CT2DSHE program for recommendation. Patient or Public Contribution: This work aspires to contribute to CT2DSHE in these areas;Influencing policy decision-making for community diabetes care within the UK and world at large., Contributing to already vast knowledge on diabetes self-management and reasons why?, Influencing educators on how CT2DSHEP are designed, delivered by putting the patient at the Centre and bringing different perspectives on CT2DSHEP in one place that is serving users time of having to consult several resources especially busy clinicians [2] [3].
基金the National Natural Science Foundation of China(Grant No.11975214)。
文摘Dielectric laser accelerators(DLAs)are considered promising candidates for on-chip particle accelerators that can achieve high acceleration gradients.This study explores various combinations of dielectric materials and accelerated structures based on the inverse Cherenkov effect.The designs utilize conventional processing methods and laser parameters currently in use.We optimize the structural model to enhance the gradient of acceleration and the electron energy gain.To achieve higher acceleration gradients and energy gains,the selection of materials and structures should be based on the initial electron energy.Furthermore,we observed that the variation of the acceleration gradient of the material is different at different initial electron energies.These findings suggest that on-chip accelerators are feasible with the help of these structures and materials.
基金Project (50925521) supported by the National Natural Science Fund for Distinguished Young Scholars of China
文摘Molecular dynamics (MD) simulations of monocrystalline copper (100) surface during nanomachining process were performed based on a new 3D simulation model. The material removal mechanism and system temperature distribution were discussed. The simulation results indicate that the system temperature distribution presents a roughly concentric shape, a steep temperature gradient is observed in diamond cutting tool, and the highest temperature is located in chip. Centrosymmetry parameter method was used to monitor defect structures. Dislocations and vacancies are the two principal types of defect structures. Residual defect structures impose a major change on the workpiece physical properties and machined surface quality. The defect structures in workpiece are temperature dependent. As the temperature increases, the dislocations are mainly mediated from the workpiece surface, while the others are dissociated into point defects. The relatively high cutting speed used in nanomachining results in less defect structures, beneficial to obtain highly machined surface quality.
基金Supported by Scientific Research Special Fund for Public Welfare Industry(2005DIB3J137)National Key Technology R & D Program in the 11th Five year Plan of China(2006BAD03A1402)+1 种基金948 Project of The State Forestry Administration(2006-4-34)The Doctoral Science Foundation of Hainan University(Rndy0703)
文摘The effects of tropical storm on the community structure of Sonneratia caseolaris-Sonneratia apetala(S.caseolaris-S.apetala) artificial mangroves and Ceriops tagal-Rhizophora stylosa(C.tagal-R.stylosa) natural mangroves were analyzed in Dongzhai Harbor in Hainan Island,and the results showed that the average tree height,crown width(CW) in east-west direction(E-W) and north-south direction(N-S) of S.caseolaris-S.apetala artificial mangroves were decreased by 2.8%,14.3% and 12.1% respectively,but the average clear bole height was increased by 60.0% after tropical storm.For C.tagal-R.stylosa natural mangroves,the average tree height and clear bole height were increased by 8.3% and 20.0%,but there was no change in CW(E-W) and CW(N-S).Therefore,tropical storm had greater effects on artificial mangroves than natural mangroves.After tropical storm,tree heights of different species increased in the following sequence:C.tagal>R.stylosa>S.apetala>S.caseolaris,and the sequence of effect degree on CW was C.tagal>R.stylosa>S.caseolaris>S.apetala,while it was C.tagal < R.stylosa < S.caseolaris < S.apetala for clear bole height.Under the effect of tropical storm,the average biomass loss and dry biomass loss of S.caseolaris-S.apetala artificial mangroves were 0.22 and 0.13 t/hm2 respectively,while there was a minimal biomass loss in C.tagal-R.stylosa natural mangroves.On the whole,the wind resistance of natural mangroves was better than artificial mangroves,and that of C.tagal was stronger than R.stylosa,while S.caseolaris was better than S.apetala.
基金This work was supported by the National Key Basic Research Special Foundation (No.2013CB834602 and No.2010CB923300) and the National Natural Science Foundation of China (No.20925311, No.21273211, and No.21103158).
文摘The structure difference between light and heavy liquid water has been systematically in- vestigated by high precision Raman spectroscopy over the temperature range of 5-85℃. Distinct difference between the Raman spectral profiles of two different liquid waters is clearly observed. By analyzing the temperature-dependent Raman spectral contour using global fitting procedure, it is found that the micro-structure of heavy water is more ordered than that of light water at the same temperature, and the structure difference between the light and heavy water decreases with the increase of the temperature. The temperature off- set, an indicator for the structure difference, is determined to vary from 28 ℃ to 18 ℃ for the low-to-high temperature. It indicates that quantum effect is significantly not only at low temperature, but also at room temperature. The interaction energy among water molecules has also been estimated from van't Hoff's relationship. The detailed structural information should help to develop reliable force fields for molecular modeling of liquid water.
基金financially supported by the Key Projects of the National Research and Development Program of China(2018YFD0400204)。
文摘In this study,Tremella fuciformis residues as raw material,dietary fibers from tremella were prepared by multiple enzymes.The structure of dietary fibers from tremella was studied by Fourier transform infrared(FTIR),X-ray diffraction analysis(XRD)and scanning electron microscopy(SEM).We analyzed their lipidlowering properties in vitro(water holding,oil holding swelling cholesterol and sodium cholate binding capacitises)and the hypolipidemic effects in mice.The results showed that tremella dietary fibers presented the infrared absorption spectrum characteristics of polysaccharides and the characteristic diffraction peaks of cellulose type I.SEM results indicated that the surface of insoluble dietary fiber(IDF)was porous,while the soluble dietary fiber(SDF)was relatively compact and spongy.IDF exhibited significantly higher water holding,oil holding,and swelling binding capacities than the corresponding SDF.However,SDF exhibited significantly higher viscosity than IDF.The results showed tremella dietary fibers were significant in swelling,water holding and oil holding,cholesterol and bile acids.In vivo experiment results in mice indicated that SDF has the best effect on hyperlipidemia mice than IDF and total dietary fiber(TDF).SDF showed that the total cholesterol(TC),triglyceride(TG)and low density lipoprotein cholesterol(LDL-C)contents dropped by 28.33%,18.65%,and 48.97%,respectively,while high density lipoprotein cholesterol(HDL-C)content increased by 43.80%.Compared with the high-fat control(HCM)group,the arteriosclerosis index(AI)and liver index(LI)of the SDF group mice showed significant differences,indicating that SDF has a good auxiliary effect of lowering blood lipids.The administration of tremella fibers improved the lipid metabolism disorderly situation of hyperlipidemia mice.These results provide a reference for further research and rational development of T.fuciformis.
文摘Because of the existence of gradient field of the urban center and the corridor effect. underthe drive of going merely after economic benefit, the city intrinsically has the trend of massive growth, and this will seriously destroy the urban reasonable landscape structure and the ecological equilibrium.By applying the theory of corridor effect. this paper studies the interactive process between artificialcorridors and natural corridors. At the same time, by studying the Beijing's spatial extension pattern in central urban area during different periods. this paper analyses the corridors extension volume.extension velocity and variant tendency of urban landscape on & directions. Moreover. this paperbrings forward the idea of incorporating the systen of natural corridors into the Beijing'smetropolitan planning, namely to form a star-shaped scattering-group pattern in which artificialcorridors and natural corridors are alternately distributed in order to effectively prevent built-up areafrom massive growth .
文摘Based on the results of two dimension velo city structure, 1∶100 000 aeromagnetic anomaly, 1∶200 000 bouguer gravity anom aly and seismic anisotropy of Jiaodong and neighboring region in Shandong, China , the information of geophysical field was divided into two parts: deep and sh allow focus fields. And then, the information of two different fields was c ombined with that of deep seated geology and ore deposit features. The syntheti c result was adopted to analyze three dimension structure, to probe into crust mantle coupling effects of mineralization and dynamics of ore formation system .
基金Supported by National Natural Science Foundation of China (No.50638030, 50528808)the National Key Technologies R&D Program of China (No.2006BAJ13B02)the Australian Research Council (No.DP0774061).
文摘Numerical method is popular in analysing the blast wave propagation and interaction with structures.However,because of the extremely short duration of blast wave and energy trans-mission between different grids,the numerical results are sensitive to the finite element mesh size.Previous numerical simulations show that a mesh size acceptable to one blast scenario might not be proper for another case,even though the difference between the two scenarios is very small,indicating a simple numerical mesh size convergence test might not be enough to guarantee accu-rate numerical results.Therefore,both coarse mesh and fine mesh were used in different blast scenarios to investigate the mesh size effect on numerical results of blast wave propagation and interaction with structures.Based on the numerical results and their comparison with field test re-sults and the design charts in TM5-1300,a numerical modification method was proposed to correct the influence of the mesh size on the simulated results.It can be easily used to improve the accu-racy of the numerical results of blast wave propagation and blast loads on structures.
基金supported NKBRSF,PR China,No.2002CB111507The National Key of Science and Technology,No.2004BA508B22+2 种基金the Chinese National Natural Science Foundation(90302006,90511026)the Hundred Talents Program(2004401,KZCX3-SW-339)of the Chinese Academy of Sciencesthe Project for 0utstanding Scientists(40121101)of the National Natural Science Foundation of China.
文摘The data of 16o national meteorological observatory stations including the long-term monthly temperature data in China were analyzed to study the seasonal variation of the spatial temperature structures across China in the past half century. It is found that temperature structures differ between seasons: a latitude temperature pattern in winter and a landform temperature pattern in summer, which indicate that the effect of landform on temperature structure is much stronger in summer than that in winter and the effect of latitudinal temperature is much stronger in winter than that in summer. The mechanisms of the seasonal difference in temperature structures are also discussed in this paper.
基金The research was supported by the National Basic Research Program of China (Grant 2012CB937500),the National Natural Science Foundation of China (Grants 91216108,11432014),and the CAS/SAFEA International Partnership Program for Creative Reserch Teams
文摘In the present research, hierarchical structure observation and mechanical property characterization for a type of biomaterial are carried out. The investigated bioma- terial is Hyriopsis cumingii, a typical limnetic shell, which consists of two different structural layers, a prismatic "pillar" structure and a nacreous "brick and mortar" structure. The prismatic layer looks like a "pillar forest" with variationsection pillars sized on the order of several tens of microns. The nacreous material looks like a "brick wall" with bricks sized on the order of several microns. Both pillars and bricks are composed of nanoparticles. The mechanical properties of the hierarchical biomaterial are measured by using the nanoindentation test. Hardness and modulus are measured for both the nacre layer and the prismatic layer, respectively. The nanoindentation size effects for the hierarchical structural materials are investigated experimentally. The results show that the prismatic nanostructured material has a higher stiffness and hardness than the nacre nanostructured material. In addition, the nanoindentation size effects for the hierarchical structural materials are described theoretically, by using the trans-scale mechanics theory considering both strain gradient effect and the surface/interface effect. The modeling results are consistent with experimental ones.
基金Project supported by the Science and Technology Major Projects of Zhejiang Province,China(Grant No.2013C03043-5)
文摘Digital structured light (SL) profilometry is increasingly used in three-dimensional (3D) measurement technology. However, the nonlinearity of the off-the-shelf projectors and cameras seriously reduces the measurement accuracy. In this paper, first, we review the nonlinear effects of the projector-camera system in the phase-shifting structured light depth measurement method. We show that high order harmonic wave components lead to phase error in the phase-shifting method. Then a practical method based on frequency domain filtering is proposed for nonlinear error reduction. By using this method, the nonlinear calibration of the SL system is not required. Moreover, both the nonlinear effects of the projector and the camera can be effectively reduced. The simulations and experiments have verified our nonlinear correction method.
基金supported by The Outstanding Youth Foundation Project, National Natural Science Foundation of China (Grant No. 40625004) the grant of the Western Project Program of the Chinese Academy of Sciences (No. KZCX2-XB2-10)
文摘Based on the analysis and comparison of soil temperature, thermal regime and permafrost table under the experimental embankment of crushed rock structures in Beiluhe, results show that crushed rock structures provide an extensive cooling effect, which produces a rising permafrost table and decreasing soil temperatures. The rise of the permafrost table under the embankment ranges from an increase of 1.08 m to 1.67 m, with an average of 1.27 m from 2004 to 2007. Mean annual soil temperatures under the crushed rock layer embankment decreased significantly from 2005 to 2007, with average decreases of ?1.03 °C at the depth of 0.5 m, ?1.14 °C at the depth of 1.5 m, and ?0.5 °C at the depth of 5 m. During this period, mean annual soil temperatures under the crushed rock cover embankment showed a slight decrease at shallow depths, with an average decrease of ?0.2 °C at the depth of 0.5 m and 1.5 m, but a slight rise at the depth of 5 m. After the crushed rock structures were closed or crammed with sand, the cooling effect of the crushed rock layer embankment was greatly reduced and that of the crushed rock cover embankment was just slightly reduced.