Enhanced gas separation performance of mixed matrix hollow fiber membranes containing post-functionalized S-MIL-53

Mixed matrix hollow fiber membranes（MMHFMs）filled with metal-organic frameworks（MOFs）have great potential for energy-efficient gas separation processes,but the major hurdle is polymer/MOFs interfacial defects and membrane plasticization.Herein,lab-synthesized MIL-53 was post-functionalized by aminosilane grafting and subsequently incorporated into Ultem-1000 polymer matrix to fabricate high performance MMHFMs.SEM,DLS,XRD and TGA were performed to characterize silane-modified MIL-53（S-MIL-53）and prepared MMHFMs.Moreover,the effect of MOFs loading was systematically investigated first;then gas separation performance of MMHFMs for pure and mixed gas was evaluated under different pressures.MMHFMs containing post-functionalized S-MIL-53 achieved remarkable gas permeation properties which was better than model predictions.Compared to pure HFMs,CO2permeance of MMHFM loaded with 15%S-MIL-53 increased by 157%accompanying with 40%increase for CO2/N2selectivity,which outperformed the MMHFM filled with naked MIL-53.The pure and mixed gas permeation measurements with elevated feed pressure indicated that incorporation of S-MIL-53 also increased the resistance against CO2plasticization.This work reveals that post-modified MOFs embedded in MMHFMs facilitate the improvement of gas separation performance and suppression of membrane plasticization.

Numerical simulation of influences of the earth medium's lateral heterogeneity on co- and post-seismic deformation

Many studies revealed that the Earth medium＇s lateral heterogeneity can cause considerable effects on the co- and post-seismic deformation field. In this study, the threedimensional finite element numerical method are adopted to quantify the effects of lateral heterogeneity caused by material parameters and fault dip angle on the co- and postseismic deformation in the near- and far-field. Our results show that： 1） the medium＇s lateral heterogeneity does affect the co-seismic deformation, with the effects increasing with the medium＇s lateral heterogeneity caused by material parameters; 2） the Lame parameters play a more dominant role than density in the effects caused by lateral heterogeneity; 3） when a fault＇s dip angle is smaller than 90, the effects of the medium＇s lateral heterogeneity on the hanging wall are greater than on the footwall; 4） the impact of lateral heterogeneity caused by the viscosity coefficient on the post-seismic deformation can affect a large area, including the near- and far-field.

Post Liver Transplantation Lympho Proliferative Disorder, Classical Hodgkins Lymphoma Type—A Case Report

Post transplantation lymphoproliferative disorder is a lymphoid/plasmacytic proliferation that develops as a consequence of immunosuppression in a recipient of a solid organ/bone marrow/stem cell allograft. The incidence reported in literature in post liver transplant patients is 1% - 2%. This case was of a 16-year-old boy who underwent liver transplantation for fulminant hepatic failure and subsequently developed PTLD. Morphologically and immunohistochemically, it was Hodgkin’s lymphoma like PTLD, which was the least common type reported in literature.

District Partisan Homogeneity, Communications, and the Electoral Motive: An Analysis of the Facebook Posts of Members of the U.S. House of Representatives

The research examines the way in which members of the U.S. House of Representative represent themselves on the social network site Facebook. Each member’s activity is observed on seven different occasions and the frequency and substantive character of posts made during the second half of 2013 are established. The focus is on position-taking posts versus posts which mention the district the member serves in. Our expectation is that members from electorally safe districts will be more likely to advertise their policy positions while members from marginal districts will be more inclined to advertise their district connections. We control for minority party status, gender, and ideological extremism among other concerns and learn electoral safety is a good predictor of both “position-taking” and “district mentions”. Consistent with an electoral motive, we also find members from the minority party less likely to take positions on the issues of the day and more likely to mention the district they serve in.

China's Post and Telecommunications Service

In 1994, the handling capacity and business volume of China’s posts and telecommunications fulfilled the target of the Eighth Five-Year Plan (1991-1995) a year ahead of schedule and that of quadrupling the business volume during the period of 1980-2000 six years in advance. 1. The comprehensive communications capacity further enhanced with the construction of the telecommunication mains transmission network mainly composed of optical fibre cables is now in place. Seven

Effect of mother’s knowledge on posteducation toward rehospitalization of young children with pneumonia

Objective:The rehospitalization rate of children<5 years old with pneumonia is still high.The risk of hospitalization becomes higher in mothers with low knowledge of their child’s disease.The purpose of this study was to determine the effect of post-health-education maternal knowledge in cases of rehospitalization and to determine the differences in rehospitalization rate based on the type of health education media.Methods:This study is a quasi-experiment.Health education was given to both groups:one group received education through audiovisual media and the other group through leaflet media.The level of post-health-education knowledge was measured on the third day,then followed up until the 30th day after the patient was discharged from the hospital.Results:Post-health-education knowledge significantly reduced the cases of rehospitalization in both groups.However,the rehospitalization rate in the audiovisual group was lower than in the leaflet group(P=0.047,odds ratio=5.870).Conclusions:Post-health-education knowledge is effective in reducing the risk of rehospitalization,and health education using audiovisual media is more effective,compared to health education using leaflets,in reducing the cases of rehospitalization in children<5 years of age with pneumonia.

DEVELOPMENT OF CHINA'S POST AND TELECOMMUNI-CATIONS

In handling patent disputes, China observes an operational method of mutual cooperation and coordination through two channels: judicial adjudication and administrative settlement. Over the past decade, practice has proved that the specific way of handling patent disputes by patent administrative organs has played an important role in the prompt resolu tion of patent disputes, protecting the legitimate rights and interests of patent-

Ethanolic Extract of <i>Nigella sativa</i>Seeds Lacks the Chemopreventive Efficacy in the Post Initiation Phase of DMH-Induced Colon Cancer in a Rat Model

Nigella sativa, belonging to the Ranunculacea family, is a versatile phytochemical mine bestowed with multi-dimensional medicinal effects. The current study was performed to investigate the chemopreventive efficacy, if any, of the ethanolic extract of indigenous Nigella sativa seeds (ENS) and to evaluate its potentials on tumor progression during the initiation and post initiation phases of Dimethylhydrazine-induced colon carcinogenesis in a rat model. ENS treatment during the initiation phase unveiled chemopreventive effect manifested by significant reductions in tumor incidence, multiplicity and tumor volumes. Histopathological findings and modified Duke’s classification of tumors provided evidence that ENS, administered in the initiation phase, is capable of delaying progression, restricting invasion and attenuating aggressiveness of colon tumors. These results imply that ENS may be a promising candidate in the primary prevention of colon cancer. On the contrary, we demonstrated that ENS lacked chemopreventive and tumorigenesis inhibitory effects in the post initiation phase. We speculate that the chemopreventive effect of ENS might be due to the synergistic actions of various constituents present in the extract. However, extensive studies are warranted and more efforts need to be dedicated to fractionate, analyze and to further appraise the anticancer effect of ENS before any definitive conclusions can be drawn.

A Historic Leap for China's Post and Telecommmunications

China’s post and telecomsector achieved furthergiant development in 1995,afterit accomplished its eighth five-year plan a year ahead ofschedule,and realized its targetof eight-fold expansion duringthe period of 1980-2000 sixyears ahead of schedule,thusresulting in a historic leap.

UPLC-MS/MS测定心悦胶囊中6个皂苷类成分的含量

目的:采用超高效液相色谱-质谱法(UPLC-MS/MS)建立心悦胶囊中主要成分人参皂苷Rg_(1)、人参皂苷Re、人参皂苷Rb_(1)、拟人参皂苷F_(11)、人参皂苷Rd和20(S)-人参皂苷F1的含量测定方法。方法:使用Waters ACQUITY BEH C_(18)色谱柱(100 mm×2.1 mm,1.7μm),以乙腈-水为流动相,梯度洗脱,流速为0.5 mL·min^(–1),柱温为40℃,电喷雾电离源,多反应离子监测扫描方式进行检测。结果:6个成分分别在质量浓度为9.638~963.800、9.839~983.900、9.951~995.100、5.270~1054.000、9.608~960.800、4.905~981.000 ng·mL^(–1)时与峰面积线性关系良好(r>0.998),平均加样回收率(RSD)分别为96.9%(2.2%)、100.1%(1.5%)、97.2%(1.8%)、98.5%(2.3%)、96.6%(2.8%)、100.2%(3.5%)。结论:所建立的方法快速、准确、灵敏度高,可用于心悦胶囊中西洋参茎叶总皂苷的质量控制。

Fiction with Influence Famous martial arts novelist Louis Cha Leung-yung’s passing leaves a growing legion of followers

There was an outpouring of grief across China on October 30 when fans of legendary wuxia （master of martial arts） novelist Jin Yong heard of his passing at age 94.

The change of the cationic peroxidase in the leaves at the fertile transformation period in Nongken 58s

Nongken 58s is a type of photoperiod sensitivegenie male sterile rice which gives rice to malesterility when illuminated time is longer than13.75 h/d.The photoperiod sensitive stagesare from the differentiation of primary branchprimordum(Ⅱ)in young ears to fullness ofcontents of the pollen(Ⅶ).The changes ofactivity and isoenzymes in cation peroxidase atph0toperiod sensitive stages and the relation-ship between this enzyme and feritility of rice

血清瘦素、NSE及S-100B水平与卒中后抑郁关系的前瞻性巢式病例对照研究

目的探讨脑卒中患者血清瘦素、神经元特异性烯醇化酶（NSE）及S-100B水平与卒中后发生抑郁的危险性的关系。方法 2010年6月-2012年12月入住郑州大学附属郑州中心医院的急性缺血性脑卒中患者121例,随访半年后42例患者确诊为卒中后抑郁（汉密尔顿抑郁量表评分≥8分）,按照入组时间、年龄、性别及脑损伤部位匹配原则,选择未患卒中后抑郁的脑卒中患者42例作为对照。收集出院时患者血清,采用酶联免疫吸附法检测患者血清瘦素、NSE及S-100B浓度,分析其与卒中后抑郁发生的相关性。采用受试者工作特征曲线（ROC）检验各组数据值对诊断卒中后抑郁的效率。结果卒中后抑郁组血清瘦素、NSE、S-100B浓度（分别为25.84±13.80、2.59±1.48、25.03±8.24μg/L）与对照组（分别为8.67±6.17、2.27±1.84、22.40±6.84μg/L）比较明显增高（P〈0.05）。卒中后抑郁患者血清瘦素水平与NSE及S-100B未见明显相关性;基于ROC曲线,卒中后患者血清瘦素曲线下面积为0.935（95%CI 0.885~0.984）,血清瘦素值16.17μg/L是诊断卒中后抑郁的最佳临界点,敏感性为81.0%,特异性为90.1%,是具有较高精准度的诊断指标。结论脑卒中患者血清瘦素水平升高与卒中后发生抑郁密切相关,可作为诊断卒中后抑郁的血清预测标志物。

西洋参叶中20(s)-人参皂苷-Rh_1,-Rh_2和人参皂苷Rh_3的分离与鉴定

目的:从西洋参叶中分离、鉴定20(s)人参皂苷Rh1,Rh2和人参皂苷Rh3,为了深入研究它们的生理活性。方法:以水提取,用多孔树脂吸附,再以体积分数为95%的乙醇洗脱,最后以硅胶柱层析分离。通过理化性质及IR,NMR光谱等方法测定,鉴定其结构。结果:共分得3个化合物,经鉴定后分别证明为20(s)人参皂苷Rh1,Rh2和人参皂苷Rh3。结论:人参皂苷Rh3为首次从西洋参叶中分离获得。

昆仑山口西Ms8.1地震的地壳变形特征

利用全球定位系统 1991～ 2 0 0 1年及震后 4期GPS观测数据 ,获得了 2 0 0 1年 11月 14日昆仑山口西地震 (Ms8.1)的同震和震后形变运动图像。跨破裂带GPS网最近两点测得的最大同震形变为 1.9m左右 ,而震后 4个月断层蠕滑引起的变形约为 80mm。破裂带两侧震后变形幅度具有非对称性 ,南侧震后变形基本是北侧的 2～ 3倍。研究结果显示破裂带南盘在震后向偏东方向有明显移动 ,预示本次地震后能量的重新分配与积累 ,根据近几十年以来东昆仑断裂带的大地震由西向东扩展的特点 ,未来地震有向东迁移的可能。

RP-HPLC测定西洋参叶皂苷碱降解物中20(S)-人参皂苷Rh_2的含量

目的：对西洋参叶皂苷碱降解物中20（S）-人参皂苷Rh2进行含量测定。方法：采用RP-HPLC，ZORBAX EXTEND C18柱（4．6mm×250mm，5μm），流动相甲醇-水（85：15），流速1．2mL·min^-1，检测波长203nm，柱温25℃。结果：20（S）-人参皂苷Rh2的进样量在0．5～25μg有良好的线性关系，r=0．9999；平均加样回收率为99．7％，RSD1．0％。结论：该方法测定20（S）-人参皂苷Rh2简便快捷，准确度高，测定结果证实该降解方法20（S），人参皂苷Rh2的转化率高。

烯效唑对罂粟(Papaver somniferum L.)不同叶位叶SPAD值变化规律研究

采用随机区组设计,以罂粟(Papaver somniferum L.)为供试材料,进行不同浓度烯效唑处理下主茎不同叶位叶SPAD(Soiland Plant Analyzer Development,土壤作物分析仪器开发)值的测定。分析了罂粟叶片SPAD值与叶绿素含量的关系,在此基础上研究不同浓度烯效唑对罂粟叶片SPAD值的影响,并确定SPAD值在不同叶位间的变化规律。结果表明:罂粟叶片的叶绿素含量与SPAD值呈极显著线性相关。在本试验设置的不同浓度烯效唑处理中,罂粟上部4片叶的SPAD值较高,SPAD值随叶位的下降而下降。因此,在考虑叶片大小的因素后,测定罂粟叶片SPAD值时,以选择倒3叶或倒4叶较为适宜。

江西乐安县咸口花岗岩体的锆石LA-ICP-MS定年及构造意义

江西乐安县咸口花岗岩体主要由中粗粒巨斑状黑云二长花岗岩、中粗粒少斑黑云二长花岗岩组成,另有较多细粒碱长花岗岩脉,总体呈偏心式环套状分布。锆石LA-ICP-MS U-Pb年龄分别为230±4Ma、235±3Ma和235±3Ma,形成于中三叠世。岩石具有高硅(SiO2=70.35%~76.89%),富碱(Na2O+K2O=6.77%~11.40%),弱过铝-强过铝(A/CNK=1.00~1.18,平均1.07)的特征。主体花岗岩富集稀土元素[∑REE=(121.52~383.33)×10-6]和高场强元素(Y、Zr、Nb等),晚期强分异并受流体作用的细粒碱长花岗岩稀土含量低[∑REE=(25.85~43.75)×10-6]。具有S型-铝质A型过渡型花岗岩的特征。(87Sr/86Sr)i为0.7082~0.7120,εNd(t)值介于-7.07^-8.10之间,平均值为-7.48,t2DM为1585~1669Ma,平均1618Ma,显示其物源以地壳物质为主,混有地幔组份,钾长石Pb同位素组成也显示壳幔混源的特征。提出咸口岩体形成于后造山的构造环境。

黑龙江完达山地区358高地岩金矿床花岗斑岩LA-ICP-MS锆石U-Pb定年及其地质意义

选取黑龙江省完达山地区358高地与成矿关系密切的花岗斑岩,进行系统的地质、岩相学、元素地球化学及LA-ICP-MS锆石U-Pb定年研究。结果显示：花岗斑岩具有富硅、钠、钾、铝,贫镁、钙的特征,里特曼指数（σ）为1.12～2.00（σ〈3.3）,A/NK为1.36～2.00,A/CNK为1.11～1.93（A/CNK〉1.1）;富集大离子亲石元素,亏损Nb、Ta,严重亏损Sr、P、Ti;轻稀土元素富集,重稀土元素亏损,具有负Eu异常。这些特征揭示,花岗斑岩是过铝质的S型花岗岩,岩浆来源可能为壳源。LA-ICP-MS锆石定年获得花岗斑岩的成岩年龄为128±1Ma,推断金矿成矿时代应为早白垩世晚期。构造判别图解显示,花岗斑岩具有碰撞后花岗岩的特征,斑岩体的形成很可能与太平洋板块俯冲作用后的伸展体制有密切关系。