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Origin of condensate oil and natural gas in Bozhong 19-6 gas field,Bohai Bay Basin
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作者 Jianyong Xu Wei Li 《Energy Geoscience》 EI 2024年第1期54-62,共9页
The discovery of the Bozhong 19-6 gas field has opened a new frontier for deep gas exploration in the Bohai Bay Basin,with a great potential for further gas exploration.However,poor understanding of oil and gas origin... The discovery of the Bozhong 19-6 gas field has opened a new frontier for deep gas exploration in the Bohai Bay Basin,with a great potential for further gas exploration.However,poor understanding of oil and gas origin has been limiting the exploration progress in this area.To clarify the origin of condensate oil and gas in Bozhong 19-6 gas field,this study adequately utilized the organic geochemical analysis data to investigate the composition and geochemical characteristics of condensate oil and natural gas,and analyzed the relationship between condensate oil and the three sets of source rocks in the nearby subsags.Results show that the lighter components dominate the condensate oil,with a forward type predominance.The parent material of crude oil was primarily deposited in a shallow,clay-rich,low-salinity,weakly reducing aquatic environment.The condensate and natural gas have similar parent source characteristics and maturity,with Ro ranging from 1.4%to 1.6%.Both are products of high maturity stage,indicating that they are hydrocarbon compounds produced by the same group of source rocks in the same stage.Oil-sources correlation shows that condensate oil and gas mainly originate from the source rocks of the third member of Shahejie Formation in the nearby subsags of the Bozhong 19-6 structural belt. 展开更多
关键词 Bozhong Sag Natural gas condensate oil light hydrocarbon Gas-source correlation oil-source correlation
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The effect of slight to minor biodegradation on C_6 to C_7 light hydrocarbons in crude oils: a case study from Dawanqi Oilfield in the Tarim Basin,NW China 被引量:6
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作者 Lu Yang Chunming Zhang +3 位作者 Meijun Li Jing Zhao Xuening Qi Jinxiu Du 《Acta Geochimica》 EI CAS CSCD 2016年第2期203-214,共12页
Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much infor- mation regarding the genetic origin and alteration of crude oils. But secondary alterations--especially biodegrad... Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much infor- mation regarding the genetic origin and alteration of crude oils. But secondary alterations--especially biodegrada- tion--have a significant effect on the composition of LHs in crude oils. Because most of the LHs affected in oils underwent only slight biodegradation (rank 1 on the biodegradation scale), the variation of LHs can be used to describe more the refined features of biodegradation. Here, 23 crude oils from the Dawanqi Oilfield in the Tarim Basin, NW China, eleven of which have been biodegraded to different extents, were analyzed in order to investigate the effect of slight to minor biodegradation on C6--C7 LHs. The study results showed that biodegradation resulted in the prior depletion of straight-chained alkanes, followed by branched alkanes. In slight and minor biodegraded oils, such biodegradation scale could not sufficiently affect C6- C7 cycloalkanes. For branched C6--C7 alkanes, generally, monomethylalkanes are biodegraded earlier than dimethylalkanes and trimethylalkanes, which indicates that branched alkanes are more resistant to biodegradation, with the increase of substituted methyl groups on parent rings. The degree of alkylation is one of the primary controlling factors on the biodegradation of C6-Cv LHs. There is a particular case: although 2,2,3-trimethylbutane has a rela- tive higher alkylation degree, 2,2-dimethylpentane is more resistant to biodegradation than 2,2,3-trimethylbutane. 2,2- Dimethylpentane is the most resistant to biodegradation in branched C6-C7 alkanes. Furthermore, the 2-methylpen- tane/3-methylpentane and 2-methylhexane/3-methylhexane ratios decreased steadily with increasing biodegradation, which implies that isomers of bilateral methyl groups are more prone to bacterial attack relative to mid-chain iso- mers. The position of the alkyls on the carbon skeleton is also one of the critical factors controlling the rate of biodegradation. With increasing biodegradation, Mango's LH parameters K1 values decrease and K2 values increase, the values of n-heptane and isoheptane decrease, and the indices of methylcyclohexane and cyclohexane increase. LH parameters should be applied cautiously for the biodegraded oils. Because biodegraded samples belong to slight or minor biodegraded oils, the values of n-heptane and isoheptane from Dawanqi Oilfield can better reflect and determine the "Biodegraded" zone. When the heptane value is 0-21 and the isoheptane value is 0-2.6, the crude oil in Dawanqi Oilfield is defined as the "Biodegraded" zone 展开更多
关键词 crude oils - light hydrocarbons BIODEGRADATION Dawanqi oilfield Tarim Basin
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Alkyl Naphthalenes and Phenanthrenes:Molecular Markers for Tracing Filling Pathways of Light Oil and Condensate Reservoirs 被引量:2
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作者 LI Meijun WANG Tieguan +4 位作者 LIU Ju ZHANG Meizhu LU Hong MA Qinglin GAO Lihui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2010年第5期1294-1305,共12页
Condensates and light oils are generally characterized by high maturity, low concentration of sterane and terpane biomarkers and low content of non-hydrocarbon fraction. As a result, some commonly-used sterane, terpan... Condensates and light oils are generally characterized by high maturity, low concentration of sterane and terpane biomarkers and low content of non-hydrocarbon fraction. As a result, some commonly-used sterane, terpane and carbazole migration parameters in conventional oil reservoirs may have a certain limitation in condensate and light oil reservoirs for their poor signal-noise ratios in the gas chromatography-mass spectrometry (GC-MS). Naphthalene, phenanthrene and their methylated substituents, however, are present in significant concentrations in condensates and light oils. Taking the Fushan depression (in the Beibuwan Basin, Northern South China Sea) as an example, this paper attempts for the first time to use polycyclic aromatic hydrocarbon (PAH)-related parameters to trace migration directions and filling pathways for condensate and light oil reservoirs. The result shows that TMNr (i.e. 1, 3, 7-TMN/(1, 3, 7-TMN + 1, 2, 5-TMN), TMN: trimethylnaphthalene)), MPI-1 (i.e. 1.5×(2-MP + 3-MP)/(P + 1-MP + 9-MP), P: phenanthrene MP: methyiphenanthrene), MN/DMN (∑methylnaphthalene/∑dimethylnaphthalene, %) and MN/TMN (∑nethylnaphthalene/∑trimethylna- phthalene, %) can be used to trace the filling pathways of condensate and light oil reservoirs. These parameters, together with geological consideration and other bulk oil properties (e.g. the gas to oil ratio and density), suggest that the condensates and light oils in the Huachang oil and gas field are mainly sourced from the Bailian sag that is located to the northeast of the Huachang uplift in the Fushan depression. 展开更多
关键词 condensATE light oil polycyclic aromatic hydrocarbon (PAH) NAPHTHALENE phenanthrene migration filling pathway Fushan depression
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Low-temperature oxidation of light crude oil in oxygen-reduced air flooding 被引量:1
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作者 QI Huan LI Yiqiang +7 位作者 CHEN Xiaolong LONG Anlin WEI Li LI Jie LUO Jianghao SUN Xuebin TANG Xiang GUAN Cuo 《Petroleum Exploration and Development》 CSCD 2021年第6期1393-1402,共10页
Light crude oil from the lower member of the Paleogene Xiaganchaigou Formation of Gaskule in Qinghai Oilfield was selected to carry out thermal kinetic analysis experiments and calculate the activation energy during t... Light crude oil from the lower member of the Paleogene Xiaganchaigou Formation of Gaskule in Qinghai Oilfield was selected to carry out thermal kinetic analysis experiments and calculate the activation energy during the oil oxidation process.The oxidation process of crude oi l in porous medium was modeled by crude oil static oxidation experiment,and the component changes of crude oil before and after low-temperature oxidation were compared through Fourier transform ion cy-clotron resonance mass spectrometry and gas chromatography;the dynamic displacement experiment of oxygen-reduced air was combined with NMR technology to analyze the oil recovery degree of oxygen-reduced air flooding.The whole process of crude oil oxidation can be divided into four stages:light hydrocarbon volatilization,low-temperature oxidation,fuel deposition,and high temperature oxidation;the high temperature oxidation stage needs the highest activation energy,followed by the fuel deposition stage,and the low-temperature oxidation stage needs the lowest activation energy;the concentration of oxygen in the reaction is negatively correlated with the activation energy required for the reaction;the higher the oxygen concentration,the lower the average activation energy required for oxidation reaction is;the low-temperature oxidation reaction between crude oil and air generates a large amount of heat and CO,CO_(2) and CH4,forming flue gas drive in the reservoir,which has certain effects of mixing phases,reducing viscosity,lowering interfacial tension and promoting expansion of crude oil,and thus helps enhance the oil recovery rate.Under suitable reservoir temperature condition,the degree of recovery of oxygen-reduced air flooding is higher than that of nitrogen flooding for all scales of pore throat,and the air/oxygen-reduced air flooding de-velopment should be preferred. 展开更多
关键词 light crude oil oxygen-reduced air flooding low-temperature oxidation thermal kinetics characteristics enhanced oil recovery
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Experimental investigation on CO_2-light crude oil interfacial and swelling behavior 被引量:3
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作者 Mostafa Lashkarbolooki Shahab Ayatollahi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第2期373-379,共7页
A systematic series of experiments are designed and performed including inteffacial tension (IFT) measurements concomitant with Bond (BN, the ratio of gravity forces to capillary forces) and swelling/extraction me... A systematic series of experiments are designed and performed including inteffacial tension (IFT) measurements concomitant with Bond (BN, the ratio of gravity forces to capillary forces) and swelling/extraction measurements. Dynamic IFT, BN and swelling/extraction are measured as a function of pressure at temperatures of 30, 50 and 80 ℃. In addition, in the light of measured IFT the minimum miscibility pressure (MMP) of CO2 and light crude oil is determined based on a method called vanishing inteffacial tension (VIT). The obtained results interestingly revealed that equilibrium IFT decreases linearly with pressure in two distinct pressure intervals while equilibrium BN shows an increasing trend as a function of pressure for all of the studied cases while no obvious trend is observed for swell- ing of crude oil and extraction of light-components regarding time, temperature and pressure. 展开更多
关键词 CO2 light crude oil IFT Bond number Swelling
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Compositional characteristics and geochemical significance of light hydrocarbons for crude oils in Tarim Basin, China 被引量:2
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作者 张敏 《Chinese Journal Of Geochemistry》 EI CAS 2005年第3期228-231,共4页
Light hydrocarbons, especially C-7 isoalkanes, cyclopentanes, cyclohexanes and n-heptane in 540 oils from the Tarim Basin were studied systematically. The results suggested the K-1 values [(2-MH+2,3-DMP)/(3-MH+2,4-DMP... Light hydrocarbons, especially C-7 isoalkanes, cyclopentanes, cyclohexanes and n-heptane in 540 oils from the Tarim Basin were studied systematically. The results suggested the K-1 values [(2-MH+2,3-DMP)/(3-MH+2,4-DMP)] of crude oils vary from a lowest value of {0.78}, to a highest value of {1.54}, but the K-1 values of the majority of oil samples (80%) range from {0.90} to {1.20}. However, the absolute contents of (2-methylhexane+ 2,3-dimethylpentane) and (3-methylhexane+2,4-dimethylpentane) in the total light hydrocarbons (C-4-C-7) show a similar variation trend. The variation of K-1 values of crude oils can suggest a typical sedimentary environment for source rocks. Therefore, according to the compositional characteristics of C-7 light hydrocarbons in light of the steady-state catalytic hypothesis, non-marine oils from the Yingmaili area and marine oils from the Tazhong uplift in the Tarim Basin were genetically classified. 展开更多
关键词 中国 塔里木盆地 碳氢化合物 天然气 石油 地质构造
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Changes in the Chemical Components of Light Crude Oil During Simulated Short Term Weathering
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作者 MA Qimin LUO Xia YU Zhigang 《Journal of Ocean University of China》 SCIE CAS 2007年第3期231-236,共6页
To unambiguously identify spilled oils and to link them to the known sources are extremely important in settling ques-tions of environmental impact and legal liability. The fate and behavior of spilled oils in the env... To unambiguously identify spilled oils and to link them to the known sources are extremely important in settling ques-tions of environmental impact and legal liability. The fate and behavior of spilled oils in the environment depend on a number of physicochemical and biological factors. This paper presents the results regarding changes in chemical composition of light crude oil during simulated short-term weathering based on natural environmental conditions. The results show that the saturated hydrocarbons of the light crude oil mainly distribute between n-C8 and n-C23 and the most abundant n-alkanes are found in the n-C10 to n-C16. The main chemical components of the light crude oil are n-alkanes and isoprenoids. The aromatic compounds are subordinate chemical components. Under the conditions of the weathering simulation experiment,n-alkanes less than n-C12,toluene and 1,3-dimethyl ben-zene are lost after 1 d weathering,the n-C13,n-C14,naphthalene and 2-methyl-naphthalene are lost on the fifth day of weathering,and n-C15 alkane components show certain weatherproof capability. The ratios n-C17/pristane and n-C18/phytane are unaltered and can be used to identify the source of the light crude oil during the first 8 d of weathering. After 21 d,the ratio pristine/phytane can not pro-vide much information on the source of the spilled light crude oil. Triterpanes(m/z 191) as biomarker compounds of light crude oil are more valuable. 展开更多
关键词 light crude oil WEATHERING GC/MS oil fingerprints RNA thermosensor
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The Relationship between Nigerian Bonnylight Crude Oil-Induced Hypoglycaemia and Endogenous Serum Insulin Concentration in Male Wistar Rats: The Role of Antioxidant Vitamins C and E
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作者 S. O. Ita E. O. Aluko +3 位作者 T. H. Olubobokun U. A. Okon A. B. Antai E. E. Osim 《American Journal of Molecular Biology》 2014年第2期81-88,共8页
The relationship between Nigerian Bonny Light crude oil (NBLCO) induced hypoglycaemia and endogenous serum insulin concentration;the role of antioxidant vitamin C or E supplementation was the focus of this study. Fort... The relationship between Nigerian Bonny Light crude oil (NBLCO) induced hypoglycaemia and endogenous serum insulin concentration;the role of antioxidant vitamin C or E supplementation was the focus of this study. Forty adult male Wistar rats were randomly divided into group I, which served as the control, group II, which was oral gavaged 6 ml/kg of NBLCO, groups III and IV, which were in addition to 6 ml/kg of NBLCO supplemented with 9 ml/kg and 1 mg/kg of vitamin E or C, respectively for 28 days. Results showed that NBLCO significantly (p < 0.05) lower body weight and food intake compared with control. These effects exerted by NBLCO were however significantly (p < 0.05) reversed by vitamin E or C supplementation. The NBLCO significantly (p < 0.05) reduced fasting blood glucose (FBG) when compared with control, the antioxidant vitamins supplementation significantly (p < 0.05) reversed the crude oil effect. The mean serum insulin level in NBLCO, vitamin E or C supplemented groups is not significantly different from the control. There was no significant correlation between FBG and fasting serum insulin concentrations in all the groups on day 28. It has been demonstrated in this study that direct oral ingestion of crude oil (NBLCO) could reduce food intake, body weight and cause hypoglycemia;the hypoglycemia may not be a function of serum insulin concentration. Interestingly, the hazardous effects of NBLCO could be ameliorated with antioxidant vitamin C or E supplementation. 展开更多
关键词 NIGERIAN Bonny light crude oil HYPOGLYCAEMIA Serum Insulin CONCENTRATION ANTIOXIDANT VITAMINS
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Oil geochemistry derived from the Qinjiatun–Qikeshu oilfields:insight from light hydrocarbons
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作者 Jin Li Ting Kong Min Zhang 《Acta Geochimica》 EI CAS CSCD 2018年第3期433-440,共8页
A suite of 27 oils from the Qinjiatun–Qikeshu oilfields in the Lishu Fault Depression of the Songliao Basin was analyzed using whole oil gas chromatography.In combination with the relative distribution of C27, C28,an... A suite of 27 oils from the Qinjiatun–Qikeshu oilfields in the Lishu Fault Depression of the Songliao Basin was analyzed using whole oil gas chromatography.In combination with the relative distribution of C27, C28,and C29 regular steranes, detailed geochemical analyses of light hydrocarbons in oil samples revealed crude oils characterized by the dual input of lower aquatic organisms and higher terrestrial plants. Several light hydrocarbon indicators suggest that the liquid hydrocarbons have maturities equivalent to vitrinite reflectances of around0.78%–0.93%. This is consistent with the maturity determination of steranes C2920 S/(20 S ? 20 R) and C29 aab/(aaa ? abb). Crude oils derived from the two distinct oilfields likely both have source rocks deposited in a lacustrine environment based on light hydrocarbon parameters and on higher molecular weight hydrocarbon parameters. The results show that light hydrocarbon data in crude oils can provide important information for understanding the geochemical characteristics of the Qinjiatun–Qikeshu oils during geologic evolution. 展开更多
关键词 light hydrocarbons crude oil Lishu FaultDepression GEOCHEMISTRY characteristic
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A Sand Control System for Light Oil Reservoir
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作者 Xiang Yuzhang(Xinjiang Petroleum Administration) 《China Oil & Gas》 CAS 1996年第1期42-42,共1页
ASandControlSystemforLightOilReservoirXiangYuzhang(XinjiangPetroleumAdministration)Keywords:Sandcontrol,Ligh... ASandControlSystemforLightOilReservoirXiangYuzhang(XinjiangPetroleumAdministration)Keywords:Sandcontrol,Lightcrudeoil,Sandsto... 展开更多
关键词 SAND control light crude oil SANDSTONE Argillaceous CEMENT
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塔里木盆地塔河油田塔深5井震旦系原油地球化学特征及地质意义 被引量:1
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作者 罗明霞 曹自成 +2 位作者 徐勤琪 刘永立 尚凯 《地质科技通报》 CAS CSCD 北大核心 2024年第1期135-149,共15页
塔深5(TS5)井于2021年完钻,井深9 017 m,是目前亚洲第一深井,同时也是塔里木盆地台盆区第一口在8 780~8 840 m的上震旦统白云岩段获得油气突破的钻井,也是继轮探1井寒武系盐下突破后,超深层白云岩领域的又一重大发现。为了探究其油气成... 塔深5(TS5)井于2021年完钻,井深9 017 m,是目前亚洲第一深井,同时也是塔里木盆地台盆区第一口在8 780~8 840 m的上震旦统白云岩段获得油气突破的钻井,也是继轮探1井寒武系盐下突破后,超深层白云岩领域的又一重大发现。为了探究其油气成因,分别对TS5井震旦系凝析油和上部奥陶系重质油,及其邻区寒武系挥发油和奥陶系凝析油进行了有机地球化学特征对比。结果表明,TS5井震旦系凝析油和白云岩储层氯仿抽提物的正构烷烃系列均分布完整,指示了其生烃母质形成于强还原环境;其与奥陶系正常油-超重质油和雅克拉地区凝析油总体具有相似的生物标志化合物和碳同位素分布特征,反映均具有相似的油源;其等效镜质体反射率(Rc)值为1.7%,成熟度高于奥陶系重质油、寒武系挥发油,与邻区凝析油相当,处于高成熟阶段。综合生物标志化合物和碳同位素证据,推测TS5井震旦系油气源来自下寒武统玉尔吐斯组,其与上覆玉尔吐斯组泥页岩构成良好的储盖组合,喜马拉雅晚期来自周边较低部位玉尔吐斯组生成的高成熟凝析油气,沿斜坡运移至震旦系白云岩构造圈闭内形成了一定规模的凝析气藏。TS5井震旦系油气突破,发现了新的含油气层系,丰富了超深层油气成藏过程,为塔里木盆地超深层勘探指明了新的探索方向。 展开更多
关键词 塔里木盆地 震旦系白云岩 凝析气藏 玉尔吐斯组 热成熟度 原油 塔河油田
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碳同位素分馏效应对深层原油来源判识的影响
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作者 王学军 张学军 +4 位作者 罗欢 王茹 林璐 翟正 康元勇 《油气地质与采收率》 CAS CSCD 北大核心 2024年第4期154-163,共10页
深层烃源岩演化程度高,随成熟度升高,原油中生物标志化合物含量大幅度减少,影响了利用常规生物标志化合物参数进行油源对比的可靠性。针对如何更好地利用δ^(13)C_(PDB)值进行深层原油来源判识,通过渤海湾盆地济阳坳陷东营凹陷烃源岩自... 深层烃源岩演化程度高,随成熟度升高,原油中生物标志化合物含量大幅度减少,影响了利用常规生物标志化合物参数进行油源对比的可靠性。针对如何更好地利用δ^(13)C_(PDB)值进行深层原油来源判识,通过渤海湾盆地济阳坳陷东营凹陷烃源岩自然演化剖面中可溶有机质、烃源岩生排烃物理模拟实验产物4种族组分δ^(13)C_(PDB)值的分析,结合烷烃质量分数特征,探讨了深层烃源岩原油碳同位素分馏效应,提出利用δ^(13)C_(PDB)值进行深层原油来源判识的工作思路和方法。深层烃源岩因高热演化程度而产生的碳同位素分馏效应是明显的,烃源岩可溶有机质的烷烃、芳烃、非烃和沥青质4种族组分δ^(13)C_(PDB)值随埋深的增加均发生了明显增大现象,其中烷烃δ^(13)C_(PDB)值变化最明显,达5‰以上,芳烃δ^(13)C_(PDB)值约为4‰,非烃和沥青质δ^(13)C_(PDB)的变化相对较小,约为2‰~3‰。随埋深的增加可溶有机质中烷烃质量分数由40%左右增至80%以上,相应烷烃δ^(13)C_(PDB)值由-30‰左右增至-24‰以上,且烷烃质量分数与其δ^(13)C_(PDB)值的变化有很好相关性。同一类型烃源岩样品生排烃物理模拟产物族组分δ^(13)C_(PDB)值也显示了相似的结果,烷烃δ^(13)C_(PDB)值的变化幅度最大可达4‰,而芳烃、非烃、沥青质的δ^(13)C_(PDB)值变化相对较小,约为1‰~3‰。利用碳同位素进行深层原油来源判识时,首先根据烷烃质量分数与烷烃δ^(13)C_(PDB)值的相关性判断是否存在热演化造成的碳同位素分馏效应,并对烷烃δ^(13)C_(PDB)值进行合理恢复,然后再利用恢复后的δ^(13)C_(PDB)值进行原油来源的合理判识。依照上述方法对准噶尔盆地西缘车排子凸起轻质油来源进行了判识,轻质油的碳同位素明显存在热演化造成的分馏效应,轻质油源自深部二叠系高成熟烃源岩的可能性很大,这对该地区油气勘探目标评价部署工作具有重要实践意义。 展开更多
关键词 深层 高成熟原油 碳同位素分馏 原油来源 车排子轻质油
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塔里木盆地库车坳陷克拉苏构造带轻质油/凝析油地球化学特征与成藏过程
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作者 邓晗宇 张海祖 +4 位作者 莫涛 程斌 陈乃东 王云鹏 廖泽文 《地球化学》 CAS CSCD 北大核心 2024年第5期668-680,共13页
塔里木盆地库车坳陷克拉苏构造带浅层–深层储层中广泛产出轻质油/凝析油气藏,其油气相态变化大,母质来源多样,油气充注与成藏过程复杂。本研究对克拉苏构造带上58个轻质油开展有机地球化学分析,探讨其母质来源、热成熟度及油气成藏过... 塔里木盆地库车坳陷克拉苏构造带浅层–深层储层中广泛产出轻质油/凝析油气藏,其油气相态变化大,母质来源多样,油气充注与成藏过程复杂。本研究对克拉苏构造带上58个轻质油开展有机地球化学分析,探讨其母质来源、热成熟度及油气成藏过程。结果显示,克拉苏构造带轻质油中正构烷烃以中、低碳数为主,烷基苯相对含量较高,全油稳定C同位素值主要分布在-29‰~-26‰之间。姥植比(Pr/Ph)、甲基环己烷指数(I_(MCH))、甲基菲比值等地球化学参数显示,克拉苏构造带轻质油主要来自湖相腐殖型、沉积于偏氧化环境烃源岩的贡献,经历了多期次油气充注成藏。其中,克深1-2段轻质油热成熟度普遍高于大北段,主要来自三叠系黄山街组烃源岩的贡献,经历了“早油晚气”2期烃类充注;大北段轻质油热成熟度偏低,主要来自侏罗系恰克马克组和三叠系黄山街组烃源岩的贡献,主要经历了3期油气充注与成藏。 展开更多
关键词 轻质油/凝析油 成藏过程 克拉苏构造带 塔里木盆地
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偏远井场油水分离与原油降凝技术研究
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作者 李杰 史静 +2 位作者 王丁 李鹤 刘立虎 《化学研究与应用》 CAS 北大核心 2024年第9期2156-2163,共8页
为解决延长油田部分偏远井场含水原油在井场脱水困难,冬季原油凝固流动性差外运难的问题,开展破乳剂类型、温度、浓度影响的破乳特性实验、微观形貌采集以及降凝流变特性实验,寻求高效脱水与降凝方案,通过实验结果制定生产改造方案实现... 为解决延长油田部分偏远井场含水原油在井场脱水困难,冬季原油凝固流动性差外运难的问题,开展破乳剂类型、温度、浓度影响的破乳特性实验、微观形貌采集以及降凝流变特性实验,寻求高效脱水与降凝方案,通过实验结果制定生产改造方案实现高效脱水与降凝。研究表明井场破乳脱水与降凝的关键在于药剂与产液的充分融合,同时破乳剂的加入使活性水的界面张力明显下降,浓度为100ppm时,活性水的界面张力达到了最低值。通过微观形貌观察,随着破乳剂浓度的增加,油滴的粒径先增大后减小,油滴分布先稀疏后密集,在浓度为100ppm时油滴的粒径达到最大,此时界面张力最低,活性较高,破乳剂能够快速取代天然表面活性物质,导致原油破乳,破乳率达到97%以上。当破乳后未加降凝剂时原油最优热处理温度在60至70℃之间,添加浓度为150ppm的J2降凝剂,加热至50℃,凝点降低至-2~4℃。 展开更多
关键词 破乳 原油 界面张力 降凝
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基于烃组成分离的原油催化裂解反应探究
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作者 魏晓丽 李泽坤 +3 位作者 史军军 赵明 王翠红 刘宪龙 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2024年第3期691-698,共8页
随着炼油行业高质量发展,石油资源加工将更加追求分子利用效率和全价值链优化与管理。从烃分子结构管理角度入手,尊重原油中原生分子结构,以产品分子结构为导向,通过原油组分分离,使催化裂解原料中优势组分富集,以提高催化反应效率与过... 随着炼油行业高质量发展,石油资源加工将更加追求分子利用效率和全价值链优化与管理。从烃分子结构管理角度入手,尊重原油中原生分子结构,以产品分子结构为导向,通过原油组分分离,使催化裂解原料中优势组分富集,以提高催化反应效率与过程选择性。详细研究了原油馏分油组分分离前后的催化裂解反应性能,提出原油组分分离-催化裂解技术方案。中间基科威特原油经组分优化后,低碳烯烃和轻芳烃的总产率达42%以上,实现了原油组分“宜烯则烯,宜芳则芳”,从分子角度最大化地利用了原油资源。 展开更多
关键词 原油 催化裂解 分离 低碳烯烃 轻芳烃 烃组成
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轻质原油脱水加热工艺优化研究
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作者 郭长会 辛迎春 《石油石化节能与计量》 2024年第1期12-15,共4页
为了保证原油脱水工艺系统的可靠运行,实现节能降耗的目的,热泵的利用也越来越广泛,但是使用热泵后加热介质温度会降低,需要对加热工艺进行优化。通过调整供热量,研究了温度等参数对轻质原油三相分离器脱水效果的影响规律。结果表明:分... 为了保证原油脱水工艺系统的可靠运行,实现节能降耗的目的,热泵的利用也越来越广泛,但是使用热泵后加热介质温度会降低,需要对加热工艺进行优化。通过调整供热量,研究了温度等参数对轻质原油三相分离器脱水效果的影响规律。结果表明:分离温度降低时,三相分离器分出原油含水率有所升高,但是利用储油罐的脱水能力,可以实现原油外输达标;加热工艺中原油含水率是脱水能耗的重要影响因素;将换热器设置在三相分离器和储油罐之间可以显著地降低能量消耗。采用热泵能够满足轻质原油脱水加热的需要,推广热泵加热技术可以节约能源,降低排放。 展开更多
关键词 轻质原油 重力沉降脱水 三相分离器 油气分离温度 脱水温度
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加氢催化裂化柴油中茚的催化裂化反应行为研究
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作者 耿素龙 唐津莲 +1 位作者 张现策 袁起民 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2024年第5期1321-1329,共9页
为进一步确定加氢催化裂化柴油(LCO)中生产轻质芳烃的理想组分,采用小型固定流化床和脉冲裂解实验装置,在反应温度为580℃时对比加氢LCO与茚的催化裂化反应行为,同时对茚的催化裂化反应路径进行研究。结果表明:与加氢LCO催化裂化反应类... 为进一步确定加氢催化裂化柴油(LCO)中生产轻质芳烃的理想组分,采用小型固定流化床和脉冲裂解实验装置,在反应温度为580℃时对比加氢LCO与茚的催化裂化反应行为,同时对茚的催化裂化反应路径进行研究。结果表明:与加氢LCO催化裂化反应类型完全不同,茚在该条件下主要发生缩合-脱氢反应生成重油和焦炭,缩合-脱氢反应选择性达到80%;其次发生氢转移反应生成茚满,是发生开环裂化反应生成轻质芳烃选择性的2倍;茚与茚满在反应过程中通过氢转移反应相互转化,且茚接近完全转化的反应温度远小于加氢LCO催化裂化生产轻质芳烃的反应温度,在低反应温度(460~520℃)时主要发生氢转移反应生成茚满,在高反应温度(520~640℃)时主要发生缩合-脱氢反应生成多环芳烃和焦炭;开环-裂化生成轻质芳烃的反应不是主导反应,表明茚类不是加氢LCO生产轻质芳烃的理想组分。 展开更多
关键词 加氢催化裂化柴油(LCO) 催化裂化 轻质芳烃 缩合-脱氢反应 氢转移反应 反应路径
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Development Situation and Future Tendency of Liaohe Oil Province
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作者 Cao Weigeng(E&D Research Institute, Liaohe Petroleum Administration) 《China Oil & Gas》 CAS 1995年第1期26-28,共3页
DevelopmentSituationandFutureTendencyofLiaoheOilProvinceCaoWeigeng(E&DResearchInstitute,LiaohePetroleumAdmin... DevelopmentSituationandFutureTendencyofLiaoheOilProvinceCaoWeigeng(E&DResearchInstitute,LiaohePetroleumAdministration)Keyword... 展开更多
关键词 Development evaluation light crude oil High POUR point crude HEAVY crude oil STIMULATION
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减氧空气与轻质原油低温氧化反应特征 被引量:3
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作者 王云飞 魏建光 《地质科技通报》 CAS CSCD 北大核心 2023年第2期207-213,共7页
塔河北区块轻质原油与减氧空气在温度和压力作用下,探究其组分变化情况和耗氧量规律。在室内使用高温高压反应釜开展原油静态氧化实验,较为系统地研究不同含氧量及不同注气量的减氧空气对原油的氧化作用;并利用色谱分析对烃类分析,收集... 塔河北区块轻质原油与减氧空气在温度和压力作用下,探究其组分变化情况和耗氧量规律。在室内使用高温高压反应釜开展原油静态氧化实验,较为系统地研究不同含氧量及不同注气量的减氧空气对原油的氧化作用;并利用色谱分析对烃类分析,收集反应气体进行气体分析,气体组分和原油组分都有不同程度的变化。研究结果表明:①原油样本与减氧空气发生低温氧化反应,重质组分C_(21)以上的组分均下降,低于C_(13)的轻质组分含量均上升;②原油氧化效果随着含氧量上升而增强,反应过程组分对应“拐点”靠前;③含氧量一定时,改变油气比,反应对应的“拐点”不变;含氧量为下降趋势后趋于平缓;④低温氧化过程生成的CO_(2)含量为上升趋势后趋于平缓;⑤在油藏温度(160℃)下,原油主要涉及2个反应热裂解和加氧反应。热裂解反应与含氧量无关,和温度有关,主要反应温度是160~200℃。高碳组分沥青质等重质组分会分解成饱和烃。加氧反应主要是芳香烃,胶质加氧反应也会生成沥青质。当2种反应同时存在时,沥青质参与热裂解的含量大于加氧反应芳香烃等生成的沥青质量,会导致沥青质含量减少。 展开更多
关键词 减氧空气 含氧量 低温氧化 轻质原油 组分变化
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轻质原油采出液低温破乳剂优选及作用机理 被引量:1
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作者 田淑杰 高伟 《日用化学工业(中英文)》 CAS 北大核心 2023年第7期773-780,共8页
低渗透油田原油属轻质原油,针对低渗透油田采出轻质原油乳状液破乳难度大,低温(<60℃)条件下常规破乳剂破乳效果不佳的问题,根据某油田现场采出液制备模拟乳状液,并分别采用瓶试法、稳定性分析仪研究不同类型破乳剂的破乳效果以及乳... 低渗透油田原油属轻质原油,针对低渗透油田采出轻质原油乳状液破乳难度大,低温(<60℃)条件下常规破乳剂破乳效果不佳的问题,根据某油田现场采出液制备模拟乳状液,并分别采用瓶试法、稳定性分析仪研究不同类型破乳剂的破乳效果以及乳状液的微观动力学变化特性,优选出较佳低温破乳剂配方;应用界面流变仪等探讨油水界面黏弹性、油水界面张力、破乳剂在油水界面的动态吸附规律,揭示低温破乳剂的作用机理;最后,分析模拟现场采出乳状液破乳状态,从乳状液脱水率、挂壁程度及破乳剂质量浓度等多个角度综合评价了不同类型破乳剂的低温破乳效果。为低渗透油田采出液低温破乳工艺技术的研发提供了理论及现场应用基础。 展开更多
关键词 轻质原油 采出液 低温破乳剂 破乳机理
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