Spatio-temporal imaging of light propagation is very important in photonics because it provides the most direct tool available to study the interaction between light and its host environment.Sub-ps time resolution is ...Spatio-temporal imaging of light propagation is very important in photonics because it provides the most direct tool available to study the interaction between light and its host environment.Sub-ps time resolution is needed to investigate the fine and complex structural features that characterize disordered and heterogeneous structures,which are responsible for a rich array of transport physics that have not yet been fully explored.A newly developed wide-field imaging system enables us to present a spatiotemporal study on light transport in various disordered media,revealing properties that could not be properly assessed using standard techniques.By extending our investigation to an almost transparent membrane,a configuration that has been difficult to characterize until now,we unveil the peculiar physics exhibited by such thin scattering systems with transport features that go beyond mainstream diffusion modeling,despite the occurrence of multiple scattering.展开更多
In this study the performance of organic light-emitting diodes (OLEDs) are enhanced significantly, which is based on dual electron transporting layers (13phen/CuPc). By adjusting the thicknesses of Bphen and CuPc,...In this study the performance of organic light-emitting diodes (OLEDs) are enhanced significantly, which is based on dual electron transporting layers (13phen/CuPc). By adjusting the thicknesses of Bphen and CuPc, the maximal luminescence, the maximal current efficiency, and the maximal power efficiency of the device reach 17570 cd/m^2 at 11 V, and 5.39 cd/A and 3.39 lm/W at 3.37 mA/cm^2 respectively, which are enhanced approximately by 33.4%, 39.3%, and 68.9%, respectively, compared with those of the device using Bphen only for an electron transporting layer. These results may provide some valuable references for improving the electron injection and the transportation of OLED.展开更多
We demonstrate that the electroluminescent performances of organic light-emitting diodes are significantly improved by employing a zinc phthalocyanine (ZnPc)-based composite hole transport layer (c-HTL). The optim...We demonstrate that the electroluminescent performances of organic light-emitting diodes are significantly improved by employing a zinc phthalocyanine (ZnPc)-based composite hole transport layer (c-HTL). The optimum ris-(8-hydroxyquinoline)aluminum (Alq3)-based organic light-emitting diode with a c-HTL exhibits a lower turn-on voltage of 2.8 V, a higher maximum current efficiency of 3.40 cd/A and a higher maximum power efficiency of 1.91 lm/W, which are superior to those of the conventional device (turn-on voltage of 3.8 V, maximum current efficiency of 2.60 cd/A, and maximum power efficiency of 1.21 lm/W). We systematically studied the effects of different kinds of N’-diphenyl-N,N’-bis(1-naphthyl)(1,1’-biphenyl)-4,4’diamine (NPB):ZnPc c-HTL. Meanwhile, we also investigate their mechanisms different from that in the case of using ZnPc as buffer layer. The specific analysis is based on the absorption spectra of the hole transporting material and current density–voltage characteristics of the corresponding hole-only devices.展开更多
Dynamic behaviors on polyacrylic acid (PAA) gels and mass (small molecules) transports in the gels have been studied mainly by dynamic light scattering (DLS). The cross-linking degree (fc), monomer concentration (Cm)...Dynamic behaviors on polyacrylic acid (PAA) gels and mass (small molecules) transports in the gels have been studied mainly by dynamic light scattering (DLS). The cross-linking degree (fc), monomer concentration (Cm) and temperature of the gels have significant influences on its dynamic behavior and mass transport in the gels. The increase of fc leads to decrease of the mesh sizes of the gels, thus the obstacle of the gels for mass transport is increased. As a result, small molecular diffusion Dk in the gels is decreased. So even if for small molecules, the Dk also is influenced.展开更多
Monte Carlo simulation of light propagation in turbid medium has been studied for years.A number of software packages have been developed to handle with such issue.However,it is hard to compare these simulation packag...Monte Carlo simulation of light propagation in turbid medium has been studied for years.A number of software packages have been developed to handle with such issue.However,it is hard to compare these simulation packages,especially for tissues with complex heterogeneous structures.Here,we first designed a group of mesh datasets generated by Iso2Mesh software,and used them to cross-validate the accuracy and to evaluate the performance of four Monte Carlo-based simulation packages,including Monte Carlo model of steady-state light transport in multi-layered tissues(MCML),tetrahedron-based inhomogeneous Monte Carlo optical simulator(TIMOS),Molecular Optical Simulation Environment(MOSE),and Mesh-based Monte Carlo(MMC).The performance of each package was evaluated based on the designed mesh datasets.The merits and demerits of each package were also discussed.Comparative results showed that the TIMOS package provided the best performance,which proved to be a reliable,efficient,and stable MC simulation package for users.展开更多
ZnO as a semiconductor photocatalyst is widely applied in the photodegradation of organic pollutants. Its photocatalytic activity is greatly decreased because of the recombination of photoexcited electrons and holes i...ZnO as a semiconductor photocatalyst is widely applied in the photodegradation of organic pollutants. Its photocatalytic activity is greatly decreased because of the recombination of photoexcited electrons and holes in the bulk. In this work, ZnO sheets are synthesized by adjusting the NaOH concentration under light irradiation at room temperature. Compared with ZnO particles, the ZnO sheets prepared with a light-assisted growth method exhibit a higher rate of photodegradation of methylene blue under UV visible light irradiation. The improved photodegradation rate is mainly attributed to the shortened transport distance of photoexcited electrons, the high surface area, and the surface atom structure modified by the light-assisted growth process. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.展开更多
In our experiment, an atomic layer MoS2structure grown on SiO2/Si substrates is used in transport test. The voltage U14,23 oscillates and the corresponding period varies with applied current. The largest period appear...In our experiment, an atomic layer MoS2structure grown on SiO2/Si substrates is used in transport test. The voltage U14,23 oscillates and the corresponding period varies with applied current. The largest period appears at 45 μA. The oscillation periods are different when samples are under laser radiation or in darkness. We discover that under the laser irradiation, the oscillation period occurs at lower current than in the darkness case. Meanwhile, the drift velocity is estimated at ~10~7 cm/s. Besides, by studying the envelope of U14,23 versus applied current, we see a beating phenomenon at a certain current value. The beating period in darkness is larger than under laser irradiation. The difference between beating periods reveals the energy difference of electrons. Similar results are obtained by using different laser power densities and different light sources. The possible mechanism behind the oscillation period is discussed.展开更多
The anisotropic transport property was investigated in a phase separation La(0.67)Ca(0.33)MnO3(LCMO) film grown on(001)-oriented Nd GaO3(NGO) substrate. It was found that the resistivity along the b-axis is ...The anisotropic transport property was investigated in a phase separation La(0.67)Ca(0.33)MnO3(LCMO) film grown on(001)-oriented Nd GaO3(NGO) substrate. It was found that the resistivity along the b-axis is much higher than that along the a-axis. Two resistivity peaks were observed in the temperature dependent measurement along the b-axis, one located at 91 K and the other centered at 165 K. Moreover, we also studied the response of the resistivities along the two axes to various electric currents, magnetic fields, and light illuminations. The resistivities along the two axes are sensitive to the magnetic field. However, the electric current and light illumination can influence the resistivity along the b-axis obviously, but have little effect on the resistivity along the a-axis. Based on these results, we believe that an anisotropicstrain-controlled MnO6 octahedra shear-mode deformation may provide a mechanism of conduction filaments paths along the a-axis, which leads to the anisotropic transport property.展开更多
In this work, we report the preparation of a series of electroluminescent (EL) devices based on a high-performance polymer, poly(p-phenylene benzobisoxazole) (PBO), and their optoelectronic properties, which hav...In this work, we report the preparation of a series of electroluminescent (EL) devices based on a high-performance polymer, poly(p-phenylene benzobisoxazole) (PBO), and their optoelectronic properties, which have been rarely explored. The device structure is optimised using a complex cathode structure of tris-(8-hydoxyquinoline) aluminium (Alq3)/LiF/Al. By tuning the thickness of the Alq3 layer, we improve the device efficiency dramatically in an optimized condition. Further analysis reveals that the Alq3 layer in the complex cathode structure acts as a hole blocker in addition to its electron-injection role. A green light emission with a maximum brightness of 8.7×103 cd/m2 and a moderate current efficiency of 4.8 cd/A is obtained. These values are the highest ever reported for PBO devices. The high operational stability demonstrated by the present device makes it a promising tool for display and lighting applications. A new material is added to the selection of polymers used in this field up to now.展开更多
Visible Light Communication( VLC) based on LED is a new wireless communication technology with high response rate and good modulation characteristics in the wavelengths of 380- 780 nm. Compared with conventional metho...Visible Light Communication( VLC) based on LED is a new wireless communication technology with high response rate and good modulation characteristics in the wavelengths of 380- 780 nm. Compared with conventional methods,the waveband of VLC is harmless to human and safe to communication because of no magnetism radiation. An audio information transmission system using LED traffic lights is presented based on VLC technology. The system is consisted of transmitting terminal,receiving terminal and communication channel. Some experiments were made under real communication environment. The experimental results showed that the traffic information transmission system works steadily with good communication quality and achieves the purpose of transmitting audio information through LED traffic lights,with a data transfer rate up to 250 kbps over a distance of 5 meters.展开更多
A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminesce...A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminescent materials for organic light-emitting diodes(OLEDs). The frontier molecular orbitals(FMOs) analysis has turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer(ICT). The calculated results show that the optical and electronic properties of star-shaped molecules are affected by the substituent groups in N-position of 1,8-naphthalimide ring. Our results suggest that star-shaped molecules with n-butyl(1),benzene(2),thiophene(3),thiophene S?,S?-dioxide(4),benzo[c][1,2,5]thiadiazole(5),and 2,7a-dihydrobenzo[d]thiazole(6) fragments are expected to be promising candidates for luminescent and electron transport materials for OLEDs. This study should be helpful in further theoretical investigations on such kind of systems and also to the experimental study for charge transport and/or luminescent materials for OLEDs.展开更多
基金supported by the European Network of Excellence Nanophotonics for Energy Efficiency and the ERC through the Advanced Grant PhotBots(Proj.Ref.291349).
文摘Spatio-temporal imaging of light propagation is very important in photonics because it provides the most direct tool available to study the interaction between light and its host environment.Sub-ps time resolution is needed to investigate the fine and complex structural features that characterize disordered and heterogeneous structures,which are responsible for a rich array of transport physics that have not yet been fully explored.A newly developed wide-field imaging system enables us to present a spatiotemporal study on light transport in various disordered media,revealing properties that could not be properly assessed using standard techniques.By extending our investigation to an almost transparent membrane,a configuration that has been difficult to characterize until now,we unveil the peculiar physics exhibited by such thin scattering systems with transport features that go beyond mainstream diffusion modeling,despite the occurrence of multiple scattering.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60906022 and 60876046)the Tianjin Natural Science Foundation of China (Grant No. 10JCYBJC01100)
文摘In this study the performance of organic light-emitting diodes (OLEDs) are enhanced significantly, which is based on dual electron transporting layers (13phen/CuPc). By adjusting the thicknesses of Bphen and CuPc, the maximal luminescence, the maximal current efficiency, and the maximal power efficiency of the device reach 17570 cd/m^2 at 11 V, and 5.39 cd/A and 3.39 lm/W at 3.37 mA/cm^2 respectively, which are enhanced approximately by 33.4%, 39.3%, and 68.9%, respectively, compared with those of the device using Bphen only for an electron transporting layer. These results may provide some valuable references for improving the electron injection and the transportation of OLED.
基金Project supported by the National Key Basic Research and Development Program of China(Grant No.2010CB327701)the National Natural Science Foundation of China(Grant No.61275033)
文摘We demonstrate that the electroluminescent performances of organic light-emitting diodes are significantly improved by employing a zinc phthalocyanine (ZnPc)-based composite hole transport layer (c-HTL). The optimum ris-(8-hydroxyquinoline)aluminum (Alq3)-based organic light-emitting diode with a c-HTL exhibits a lower turn-on voltage of 2.8 V, a higher maximum current efficiency of 3.40 cd/A and a higher maximum power efficiency of 1.91 lm/W, which are superior to those of the conventional device (turn-on voltage of 3.8 V, maximum current efficiency of 2.60 cd/A, and maximum power efficiency of 1.21 lm/W). We systematically studied the effects of different kinds of N’-diphenyl-N,N’-bis(1-naphthyl)(1,1’-biphenyl)-4,4’diamine (NPB):ZnPc c-HTL. Meanwhile, we also investigate their mechanisms different from that in the case of using ZnPc as buffer layer. The specific analysis is based on the absorption spectra of the hole transporting material and current density–voltage characteristics of the corresponding hole-only devices.
基金Project 29774011 was supported by the National Natural Science Foundation of China.
文摘Dynamic behaviors on polyacrylic acid (PAA) gels and mass (small molecules) transports in the gels have been studied mainly by dynamic light scattering (DLS). The cross-linking degree (fc), monomer concentration (Cm) and temperature of the gels have significant influences on its dynamic behavior and mass transport in the gels. The increase of fc leads to decrease of the mesh sizes of the gels, thus the obstacle of the gels for mass transport is increased. As a result, small molecular diffusion Dk in the gels is decreased. So even if for small molecules, the Dk also is influenced.
基金supported by the National Natural Science Foundation of China under Grant Nos.81571725 and 81230033.
文摘Monte Carlo simulation of light propagation in turbid medium has been studied for years.A number of software packages have been developed to handle with such issue.However,it is hard to compare these simulation packages,especially for tissues with complex heterogeneous structures.Here,we first designed a group of mesh datasets generated by Iso2Mesh software,and used them to cross-validate the accuracy and to evaluate the performance of four Monte Carlo-based simulation packages,including Monte Carlo model of steady-state light transport in multi-layered tissues(MCML),tetrahedron-based inhomogeneous Monte Carlo optical simulator(TIMOS),Molecular Optical Simulation Environment(MOSE),and Mesh-based Monte Carlo(MMC).The performance of each package was evaluated based on the designed mesh datasets.The merits and demerits of each package were also discussed.Comparative results showed that the TIMOS package provided the best performance,which proved to be a reliable,efficient,and stable MC simulation package for users.
基金support from the Institute of Metal Research,Chinese Academy of Sciencessupported by the National Science Fund of China(51202105,21366020)+1 种基金the Natural Science Foundation of Jiangxi Province(20151BAB216006)the Science and Technology Project of Education Department of Jiangxi Province(GJJ14109)
文摘ZnO as a semiconductor photocatalyst is widely applied in the photodegradation of organic pollutants. Its photocatalytic activity is greatly decreased because of the recombination of photoexcited electrons and holes in the bulk. In this work, ZnO sheets are synthesized by adjusting the NaOH concentration under light irradiation at room temperature. Compared with ZnO particles, the ZnO sheets prepared with a light-assisted growth method exhibit a higher rate of photodegradation of methylene blue under UV visible light irradiation. The improved photodegradation rate is mainly attributed to the shortened transport distance of photoexcited electrons, the high surface area, and the surface atom structure modified by the light-assisted growth process. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
基金Project supported by the Zhejiang Provincial Natural Science Foundation,China(Grant Nos.LY16F040003 and LY16A040007)the National Natural Science Foundation of China(Grant Nos.51401069 and 11204058)
文摘In our experiment, an atomic layer MoS2structure grown on SiO2/Si substrates is used in transport test. The voltage U14,23 oscillates and the corresponding period varies with applied current. The largest period appears at 45 μA. The oscillation periods are different when samples are under laser radiation or in darkness. We discover that under the laser irradiation, the oscillation period occurs at lower current than in the darkness case. Meanwhile, the drift velocity is estimated at ~10~7 cm/s. Besides, by studying the envelope of U14,23 versus applied current, we see a beating phenomenon at a certain current value. The beating period in darkness is larger than under laser irradiation. The difference between beating periods reveals the energy difference of electrons. Similar results are obtained by using different laser power densities and different light sources. The possible mechanism behind the oscillation period is discussed.
基金Project supported by the National Basic Research Program of China(Grant Nos.2011CB921801,2012CB921403,and 2013CB921701)the National Natural Science Foundation of China(Grant Nos.11074285,51372064,and 11134007)
文摘The anisotropic transport property was investigated in a phase separation La(0.67)Ca(0.33)MnO3(LCMO) film grown on(001)-oriented Nd GaO3(NGO) substrate. It was found that the resistivity along the b-axis is much higher than that along the a-axis. Two resistivity peaks were observed in the temperature dependent measurement along the b-axis, one located at 91 K and the other centered at 165 K. Moreover, we also studied the response of the resistivities along the two axes to various electric currents, magnetic fields, and light illuminations. The resistivities along the two axes are sensitive to the magnetic field. However, the electric current and light illumination can influence the resistivity along the b-axis obviously, but have little effect on the resistivity along the a-axis. Based on these results, we believe that an anisotropicstrain-controlled MnO6 octahedra shear-mode deformation may provide a mechanism of conduction filaments paths along the a-axis, which leads to the anisotropic transport property.
基金Project supported by the National Natural Science Foundation of China(Grant No.21174016)the Research Fund for the Doctoral Program of Higher Education of China(Grant No.20120009110031)the 111 Project of China(Grant No.B08002)
文摘In this work, we report the preparation of a series of electroluminescent (EL) devices based on a high-performance polymer, poly(p-phenylene benzobisoxazole) (PBO), and their optoelectronic properties, which have been rarely explored. The device structure is optimised using a complex cathode structure of tris-(8-hydoxyquinoline) aluminium (Alq3)/LiF/Al. By tuning the thickness of the Alq3 layer, we improve the device efficiency dramatically in an optimized condition. Further analysis reveals that the Alq3 layer in the complex cathode structure acts as a hole blocker in addition to its electron-injection role. A green light emission with a maximum brightness of 8.7×103 cd/m2 and a moderate current efficiency of 4.8 cd/A is obtained. These values are the highest ever reported for PBO devices. The high operational stability demonstrated by the present device makes it a promising tool for display and lighting applications. A new material is added to the selection of polymers used in this field up to now.
基金Sponsored by the National Science and Technology Innovation Fund for Small and Medium Enterprises(Grant No.10C26211200144)Tianjin Science and Technology Key Supporting Projects(Grant No.10ZCGYGX18300)
文摘Visible Light Communication( VLC) based on LED is a new wireless communication technology with high response rate and good modulation characteristics in the wavelengths of 380- 780 nm. Compared with conventional methods,the waveband of VLC is harmless to human and safe to communication because of no magnetism radiation. An audio information transmission system using LED traffic lights is presented based on VLC technology. The system is consisted of transmitting terminal,receiving terminal and communication channel. Some experiments were made under real communication environment. The experimental results showed that the traffic information transmission system works steadily with good communication quality and achieves the purpose of transmitting audio information through LED traffic lights,with a data transfer rate up to 250 kbps over a distance of 5 meters.
基金Support by the National Natural Science Foundation of China(No.21563002)the Natural Science Foundation of Inner Mongolia Autonomous Region(No.2015MS0201)the Research Program of Sciences at Universities of Inner Mongolia Autonomous Region(No.NJZZ235)
文摘A series of star-shaped molecules with benzene core and naphthalimides derivatives end groups have been designed to explore their optical,electronic,and charge transport properties as charge transport and/or luminescent materials for organic light-emitting diodes(OLEDs). The frontier molecular orbitals(FMOs) analysis has turned out that the vertical electronic transitions of absorption and emission are characterized as intramolecular charge transfer(ICT). The calculated results show that the optical and electronic properties of star-shaped molecules are affected by the substituent groups in N-position of 1,8-naphthalimide ring. Our results suggest that star-shaped molecules with n-butyl(1),benzene(2),thiophene(3),thiophene S?,S?-dioxide(4),benzo[c][1,2,5]thiadiazole(5),and 2,7a-dihydrobenzo[d]thiazole(6) fragments are expected to be promising candidates for luminescent and electron transport materials for OLEDs. This study should be helpful in further theoretical investigations on such kind of systems and also to the experimental study for charge transport and/or luminescent materials for OLEDs.