sensor based on light-induced thermoelastic spectroscopy(LITES)with a fiber-coupled multipass cell was demonstrated for carbon monoxide(CO)detection.The fiber-coupled structure has the merits of reducing optical inter...sensor based on light-induced thermoelastic spectroscopy(LITES)with a fiber-coupled multipass cell was demonstrated for carbon monoxide(CO)detection.The fiber-coupled structure has the merits of reducing optical interference and difficulty in optical alignment and increasing system robustness.A 1.57 nm continuous wave distributed feedback diode laser was used as the excitation source.A minimum detection limit of 9 ppm was obtained,and the calculated normalized noise equivalent absorption coefficient was 1.15×10^(-7)cm^(-1)•W•Hz^(-1/2).The reported CO-LITES sensor showed excellent linear concentration response and system stability.展开更多
The present paper covers the lipid-free rhodium tetrasulfonato-phthalocyanine (RhTSPc) films prepared on p-Si(111) by using Langmuir-Blodgett technique. Their surface photovoltage spectra were measured. It was found t...The present paper covers the lipid-free rhodium tetrasulfonato-phthalocyanine (RhTSPc) films prepared on p-Si(111) by using Langmuir-Blodgett technique. Their surface photovoltage spectra were measured. It was found that there is a strong interaction at the interface between the RhTSPc film and p-Si (111) and that the surface photovoltaic effect of the film system is maximum when only one monolayer of RhTSPc molecules coats p-Si(111), which is similar to that of CuTSPc films on p-Si(111) reported previously. These results confirm that only the monolayer of dye molecules being adjacent to the semiconductor surface plays a key role in the light-induced interfacial charge transfer process.展开更多
Light-induced infrared emission spectroscopy (LIRES) is a novel technique that permits to receive high-quality spectra in the mid-infrared region. Low-intensity visible light connected to a highly sensitive FTIR spect...Light-induced infrared emission spectroscopy (LIRES) is a novel technique that permits to receive high-quality spectra in the mid-infrared region. Low-intensity visible light connected to a highly sensitive FTIR spectrometer is more advantageous for studying any samples, including biological samples without any damage. This technique permits obtaining unique information on the molecule structure via vibrational excitation fundamental frequencies, overtones, and combination modes. It also enables a direct observation of vibrational radiation transitions in vibrationally excited molecules as well as the channels of vibration energy redistribution, which is not allowed with any other method. In this work, the LIRES is being tested as a technique for studying of vibrationally-excited molecules of carbon tetrachloride and benzene in the liquid phase. On the other hand, using transparent liquids, we had tried to understand some of the physical phenomena that can drive emission in mid-IR. The characteristics of the infrared emission of both liquid species produced by different wavelength radiation from various types of light systems (100 - watt Xe-lamp and Nd:YAG laser;lambda = 1064 nm (8 mW) and lambda = 532 nm (4 mW)) are presented. We demonstrated that the IR-signal, as well as spectral properties of carbon tetrachloride and benzene, was dependent on the wavelength and power of excitation beam. Results obtained with different light sources show that the visible light produces a nonlinear IR-emission signal in transparent liquids. We believe that the visible light is the source of the nonlinear response and is producing the vibration excitation as well as photostimulated transformations of the molecules possessing the high activity for the nonlinear response.展开更多
A highly sensitive light-induced thermoelectric spectroscopy(LITES)sensor based on a multi-pass cell(MPC)with dense spot pattern and a novel quartz tuning fork(QTF)with low resonance frequency is reported in this manu...A highly sensitive light-induced thermoelectric spectroscopy(LITES)sensor based on a multi-pass cell(MPC)with dense spot pattern and a novel quartz tuning fork(QTF)with low resonance frequency is reported in this manuscript.An erbi-um-doped fiber amplifier(EDFA)was employed to amplify the output optical power so that the signal level was further enhanced.The optical path length(OPL)and the ratio of optical path length to volume(RLV)of the MPC is 37.7 m and 13.8 cm^(-2),respectively.A commercial QTF and a self-designed trapezoidal-tip QTF with low frequency of 9461.83 Hz were used as the detectors of the sensor,respectively.The target gas selected to test the performance of the system was acetylene(C2H2).When the optical power was constant at 1000 mW,the minimum detection limit(MDL)of the C2H2-LITES sensor can be achieved 48.3 ppb when using the commercial QTF and 24.6 ppb when using the trapezoid-al-tip QTF.An improvement of the detection performance by a factor of 1.96 was achieved after replacing the commer-cial QTF with the trapezoidal-tip QTF.展开更多
The light-induced frequency shift(LIFS)of ultracold molecular ro-vibrational levels originates from the strong coupling of the atomic-scattering state and the bound-molecular state.In this paper,we present our experim...The light-induced frequency shift(LIFS)of ultracold molecular ro-vibrational levels originates from the strong coupling of the atomic-scattering state and the bound-molecular state.In this paper,we present our experimental determination of the LIFSs of the lowest vibrational levels(v=0,1)in the purely long-range 0^-g state of ultracold cesium molecules.A high-resolution double photoassociation spectroscopy is developed,which serves as frequency ruler to measure the frequency shifts of the lowest molecular levels for Cs2.The experimental results are qualitatively consistent with the theoretical expectations.展开更多
基金This work was supported by the National Natural Science Foundation of China(Nos.62022032,61875047,and 61505041)Natural Science Foundation of Heilongjiang Province of China(No.YQ2019F006)+1 种基金Fundamental Research Funds for the Central UniversitiesFinancial Grant from the Heilongjiang Province Postdoctoral Foundation(No.LBH-Q18052).
文摘sensor based on light-induced thermoelastic spectroscopy(LITES)with a fiber-coupled multipass cell was demonstrated for carbon monoxide(CO)detection.The fiber-coupled structure has the merits of reducing optical interference and difficulty in optical alignment and increasing system robustness.A 1.57 nm continuous wave distributed feedback diode laser was used as the excitation source.A minimum detection limit of 9 ppm was obtained,and the calculated normalized noise equivalent absorption coefficient was 1.15×10^(-7)cm^(-1)•W•Hz^(-1/2).The reported CO-LITES sensor showed excellent linear concentration response and system stability.
基金Supported by the National Natural Science Foundation of China
文摘The present paper covers the lipid-free rhodium tetrasulfonato-phthalocyanine (RhTSPc) films prepared on p-Si(111) by using Langmuir-Blodgett technique. Their surface photovoltage spectra were measured. It was found that there is a strong interaction at the interface between the RhTSPc film and p-Si (111) and that the surface photovoltaic effect of the film system is maximum when only one monolayer of RhTSPc molecules coats p-Si(111), which is similar to that of CuTSPc films on p-Si(111) reported previously. These results confirm that only the monolayer of dye molecules being adjacent to the semiconductor surface plays a key role in the light-induced interfacial charge transfer process.
文摘Light-induced infrared emission spectroscopy (LIRES) is a novel technique that permits to receive high-quality spectra in the mid-infrared region. Low-intensity visible light connected to a highly sensitive FTIR spectrometer is more advantageous for studying any samples, including biological samples without any damage. This technique permits obtaining unique information on the molecule structure via vibrational excitation fundamental frequencies, overtones, and combination modes. It also enables a direct observation of vibrational radiation transitions in vibrationally excited molecules as well as the channels of vibration energy redistribution, which is not allowed with any other method. In this work, the LIRES is being tested as a technique for studying of vibrationally-excited molecules of carbon tetrachloride and benzene in the liquid phase. On the other hand, using transparent liquids, we had tried to understand some of the physical phenomena that can drive emission in mid-IR. The characteristics of the infrared emission of both liquid species produced by different wavelength radiation from various types of light systems (100 - watt Xe-lamp and Nd:YAG laser;lambda = 1064 nm (8 mW) and lambda = 532 nm (4 mW)) are presented. We demonstrated that the IR-signal, as well as spectral properties of carbon tetrachloride and benzene, was dependent on the wavelength and power of excitation beam. Results obtained with different light sources show that the visible light produces a nonlinear IR-emission signal in transparent liquids. We believe that the visible light is the source of the nonlinear response and is producing the vibration excitation as well as photostimulated transformations of the molecules possessing the high activity for the nonlinear response.
基金National Natural Science Foundation of China(Grant Nos.62335006,62022032,62275065,and 61875047)Key Laboratory of Opto-Electronic Information Acquisition and Manipulation(Anhui University),Ministry of Education(Grant No.OEIAM202202)Fundamental Research Funds for the Central Universities(Grant No.HIT.OCEF.2023011).
文摘A highly sensitive light-induced thermoelectric spectroscopy(LITES)sensor based on a multi-pass cell(MPC)with dense spot pattern and a novel quartz tuning fork(QTF)with low resonance frequency is reported in this manuscript.An erbi-um-doped fiber amplifier(EDFA)was employed to amplify the output optical power so that the signal level was further enhanced.The optical path length(OPL)and the ratio of optical path length to volume(RLV)of the MPC is 37.7 m and 13.8 cm^(-2),respectively.A commercial QTF and a self-designed trapezoidal-tip QTF with low frequency of 9461.83 Hz were used as the detectors of the sensor,respectively.The target gas selected to test the performance of the system was acetylene(C2H2).When the optical power was constant at 1000 mW,the minimum detection limit(MDL)of the C2H2-LITES sensor can be achieved 48.3 ppb when using the commercial QTF and 24.6 ppb when using the trapezoid-al-tip QTF.An improvement of the detection performance by a factor of 1.96 was achieved after replacing the commer-cial QTF with the trapezoidal-tip QTF.
基金the National Key R&D Program of China(Grant No.2017YFA0304203)the Na-tional Natural Science Foundation of China(Grants Nos.61722507,61675121,and 61705123)+2 种基金PCSIRT(No.IRT-17R70),111 Project(Grant No.D18001)the Program for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi(OIT)the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province,and the Applied Basic Research Project of Shanxi Province,China(Grant Nos.201701D221002,201901D211191,and 201901D211188).
文摘The light-induced frequency shift(LIFS)of ultracold molecular ro-vibrational levels originates from the strong coupling of the atomic-scattering state and the bound-molecular state.In this paper,we present our experimental determination of the LIFSs of the lowest vibrational levels(v=0,1)in the purely long-range 0^-g state of ultracold cesium molecules.A high-resolution double photoassociation spectroscopy is developed,which serves as frequency ruler to measure the frequency shifts of the lowest molecular levels for Cs2.The experimental results are qualitatively consistent with the theoretical expectations.