To make high integrity lightweight metal castings,best practices are required in various stages of casting and heat treatment processes,including liquid metal composition and quality control,casting and gating/riser s...To make high integrity lightweight metal castings,best practices are required in various stages of casting and heat treatment processes,including liquid metal composition and quality control,casting and gating/riser system design,and process optimization.This paper presents best practices for liquid metal processing and quality assurance of molten metal in both melting and mold filling.Best practices for other aspects of lightweight metal casting will be published separately.展开更多
Coherent manipulation of the lithium plating pattern is at the heart of the safe operation of metallic anodes in the battery technologies. In this article,a lightweight (~0.3 mg cm^(-2)), dual-functionalized carbon sp...Coherent manipulation of the lithium plating pattern is at the heart of the safe operation of metallic anodes in the battery technologies. In this article,a lightweight (~0.3 mg cm^(-2)), dual-functionalized carbon spheres are anchored onto the Cu foil as the interfacial protective layer via the chelation process of the catechol groups in the polydopamine precursor and the copper foil. The dual-functionalized carbon spheres exhibit the intriguing complementary features:Lithiophilic nitrogen dopants favor the Li+ion absorption and mitigate the nucleation barrier, while the micro/mesopore reservoir spatially homogenizes the ion flux distribution, confining the metallic propagation without dendrite-like protrusions. The metallic anode exhibits an ultra-stable plating/stripping process for 1 400 hr with the average Coulombic efficiency of ~99%. A full-cell prototype is constructed by pairing the N-doped carbon spheres on the bare Cu (NCS-Cu) electrode with the high-mass-loading LiVPO4F (12.5 mg cm^(-2)) cathode that can deliver a high energy density of 421.2 Wh kg^(-1) with the highest power density of 2106 W kg^(-1) to promise the anode use for high-power/energy-dense metallic batteries.展开更多
Atomically dispersed metals on N-doped carbon supports(M-N_(xCs)) have great potential applications in various fields.However,a precise understanding of the definitive relationship between the configuration of metal s...Atomically dispersed metals on N-doped carbon supports(M-N_(xCs)) have great potential applications in various fields.However,a precise understanding of the definitive relationship between the configuration of metal single atoms and the dielectric loss properties of M-N_(xCs) at the atomic-level is still lacking.Herein,we report a general approach to synthesize a series of three-dimensional(3D)honeycomb-like M-N_xC(M=Mn,Fe,Co,Cu,or Ni) containing metal single atoms.Experimental results indicate that 3D M-N_(xCs) exhibit a greatly enhanced dielectric loss compared with that of the NC matrix.Theoretical calculations demonstrate that the density of states of the d orbitals near the Fermi level is significantly increased and additional electrical dipoles are induced due to the destruction of the symmetry of the local microstructure,which enhances conductive loss and dipolar polarization loss of 3D M-N_(xCs),respectively.Consequently,these 3D M-N_(xCs) exhibit excellent electromagnetic wave absorption properties,outperforming the most commonly reported absorbers.This study systematically explains the mechanism of dielectric loss at the atomic level for the first time and is of significance to the rational design of high-efficiency electromagnetic wave absorbing materials containing metal single atoms.展开更多
The catalytic cracking of coal tar asphaltene(CTA)pyrolysis vapors was carried out over transition metalion modified zeolites to promote the generation of light aromatic hydrocarbons(L-ArHs)in a pyrolysisgas chromatog...The catalytic cracking of coal tar asphaltene(CTA)pyrolysis vapors was carried out over transition metalion modified zeolites to promote the generation of light aromatic hydrocarbons(L-ArHs)in a pyrolysisgas chromatography/mass spectrometry(Py-GC/MS)micro-reactor system.The effects of ultra stable Y(USY),Co/USY and Mo/USY on the selectivity and yield of L-ArHs products and the extent of deoxygenation(Edeoxygenation),lightweight(Elightweight)from CTA pyrolysis volatiles were investigated.Results showed that the yields of L-ArHs are mainly controlled by the acid sites and specific surface area of the catalysts,while the deoxygenation effect is determined by theirs pore size.The Eligltweight of CTA pyrolysis volatiles over USY is 9.65%,while the Edeoxygenation of CTA pyrolysis volatiles over Mo/USY reaches 20.85%.Additionally,the modified zeolites(Mo/USY and Co/USY)exhibit better performance than USY on L-ArHs production,owing to the synergistic effect of metal ions(Mo,Co)and acid sites of USY.Compared with the non-catalytic fast pyrolysis of CTA,the total yield of L-ArHs obtained over USY(4032 mg·kg^(-1)),Co/USY(4363 mg·kg^(-1))and Mo/USY(4953 mg·kg^(-1))were increased by 27.03%,38.19%and 54.78%,respectively.Furthermore,the possible catalytic conversion mechanism of transition metal ion(Co and Mo)modified zeolites was proposed based on the distribution of products and the characterizations of catalysts.展开更多
Along with strict environmental regulation, new-energy vehicles are becoming increasingly popular due to their low emissions, and they will inevitably replace existing fossil-fuel-based buses in China. To achieve a li...Along with strict environmental regulation, new-energy vehicles are becoming increasingly popular due to their low emissions, and they will inevitably replace existing fossil-fuel-based buses in China. To achieve a lightweight bus body ,high-strength steels are commonly used for the bus frame,but these grades are susceptible to corrosion. From the perspective of "lower life-cycle cost", high-strength stainless steel is a better bus structure choice than high-strength carbon steels, since stainless steel bus frames last 10-15 years without requiring any maintenance. The low-cost high-strength stainless steels developed by Baosteel are introduced,the yield and tensile strengths of which can be controlled to within the range of 350-700 MPa and 900-1 200 MPa,respectively, and the elongation values are above 30%. Measurements of the toughness and fatigue resistance of these high-strength stainless steels and their joints indicate that the structural integrity requirements for bus frames can be met. The results of salt spray corrosion studies indicate that stainless steels will substantially increase the service life of bus frames in wet and icy winter conditions where deicing with CaC12 is necessary for road safety. The results of our investigation clearly indicate that high-strength stainless steel is a potential bus-frame material that makes it possible to achieve substantial weight savings, excellent corrosion resistance, and prolonged operational life.展开更多
Existing Metal Additive Manufacturing processes are fast approaching a matured stage in which a wide range of possibilities are available for the incorporation of the rapid fabrication technology to current industrial...Existing Metal Additive Manufacturing processes are fast approaching a matured stage in which a wide range of possibilities are available for the incorporation of the rapid fabrication technology to current industrial practices. In terms of design conventions, the limitless geometrical freedom allows complex structures including cellular internal grids and lattices to be formed without additional tooling. Repair parts and leveraging components can also be produced on demand when required especially for military assets where large volume of inventory is constantly maintained to ensure operational readiness. In this exemplary work, a feasibility study on using stainless steel material with integrated cellular design to manufacture a guide bracket found on a military vehicle via Selective Laser Melting process was conducted. The results showed appreciably better mechanical performance in using a stainless steel honeycomb as compared to the aluminum alloy used for the original component together with a faster production route through SLM.展开更多
The synthesis, processing and mechanical properties of the light metals, aluminum,magnesium and titanium Produced by advanced techniques are reviewed. Synthesis techniques to be addressed will include rapid solidifica...The synthesis, processing and mechanical properties of the light metals, aluminum,magnesium and titanium Produced by advanced techniques are reviewed. Synthesis techniques to be addressed will include rapid solidification, spray deposition, mechanical alloying, plasma Processing and vapor deposition.展开更多
纤维金属层板(fiber metal laminate,FML)是一种新型轻量化混杂材料,逐渐被应用于汽车等运载装备领域,但其成形过程受多种参数影响,成形过程中的应力应变分布规律尚不清楚。选用T300碳纤维铝合金复合层板为研究对象,利用ABAQUS有限元软...纤维金属层板(fiber metal laminate,FML)是一种新型轻量化混杂材料,逐渐被应用于汽车等运载装备领域,但其成形过程受多种参数影响,成形过程中的应力应变分布规律尚不清楚。选用T300碳纤维铝合金复合层板为研究对象,利用ABAQUS有限元软件对其冲压成形过程进行模拟,并进行了精度验证。主要研究了FML在预浸料种类、层板厚度和层板数等因素的影响下,应力分布及壁厚变化规律。结果表明,建立的FML冲压模型计算精度准确,预浸料种类主要影响纤维层的应力分布和壁厚变化,层板厚度和层板数对各层的壁厚变化产生影响,通过减薄层板厚度或增加层板数可以缓解过度减薄问题,层板厚度和层数也会影响铝合金层的应力分布,随着厚度和层数的增加,铝合金层的应力分布趋于均匀。展开更多
The heterojunctions between metal and polymer have become the effective ways to produce the lighter,safer and more environmental friendly vehicles for the manufacturing fields of automotive and aerospace.The state-of-...The heterojunctions between metal and polymer have become the effective ways to produce the lighter,safer and more environmental friendly vehicles for the manufacturing fields of automotive and aerospace.The state-of-the-art frictionbased welding techniques are characterized by low peak temperature,severe plastic deformation,energy efficiency and nonpollution,which can simultaneously realize the mechanical and chemical bonding,improving mechanical performances.In this review,the current progress about friction-based welding techniques is summarized,containing technical development,welding tool design,microstructural characteristic,process optimization,surface modification and joining mechanism.The conclusions and prospects are presented,which focus on the practical implications for the manufacturing sectors and recommendations for further research and development.The purpose of this review is to elucidate the benefits of friction-based welding techniques so that these methods may be better exploited and industrialized.展开更多
文摘To make high integrity lightweight metal castings,best practices are required in various stages of casting and heat treatment processes,including liquid metal composition and quality control,casting and gating/riser system design,and process optimization.This paper presents best practices for liquid metal processing and quality assurance of molten metal in both melting and mold filling.Best practices for other aspects of lightweight metal casting will be published separately.
基金financial support of this work by the National Natural Science Foundation of China (51602261 and 51711530037)the Research Fund of the State Key Laboratory of Solidification Processing (NWPU)+1 种基金the Fundamental Research Funds for the Central Universities (3102019JC005)the Key R&D Program of Shanxi (No. 2019ZDLGY04-05)
文摘Coherent manipulation of the lithium plating pattern is at the heart of the safe operation of metallic anodes in the battery technologies. In this article,a lightweight (~0.3 mg cm^(-2)), dual-functionalized carbon spheres are anchored onto the Cu foil as the interfacial protective layer via the chelation process of the catechol groups in the polydopamine precursor and the copper foil. The dual-functionalized carbon spheres exhibit the intriguing complementary features:Lithiophilic nitrogen dopants favor the Li+ion absorption and mitigate the nucleation barrier, while the micro/mesopore reservoir spatially homogenizes the ion flux distribution, confining the metallic propagation without dendrite-like protrusions. The metallic anode exhibits an ultra-stable plating/stripping process for 1 400 hr with the average Coulombic efficiency of ~99%. A full-cell prototype is constructed by pairing the N-doped carbon spheres on the bare Cu (NCS-Cu) electrode with the high-mass-loading LiVPO4F (12.5 mg cm^(-2)) cathode that can deliver a high energy density of 421.2 Wh kg^(-1) with the highest power density of 2106 W kg^(-1) to promise the anode use for high-power/energy-dense metallic batteries.
基金financial supports from the NNSF of China(Grant No.51972077)the Fundamental Research Funds for the Central Universities(Grant No.3072020CF2518,3072020CFT2505+1 种基金3072021CFT2506,3072021CF2523 and 3072021CF2524)Heilongjiang Touyan Innovation Team Program.
文摘Atomically dispersed metals on N-doped carbon supports(M-N_(xCs)) have great potential applications in various fields.However,a precise understanding of the definitive relationship between the configuration of metal single atoms and the dielectric loss properties of M-N_(xCs) at the atomic-level is still lacking.Herein,we report a general approach to synthesize a series of three-dimensional(3D)honeycomb-like M-N_xC(M=Mn,Fe,Co,Cu,or Ni) containing metal single atoms.Experimental results indicate that 3D M-N_(xCs) exhibit a greatly enhanced dielectric loss compared with that of the NC matrix.Theoretical calculations demonstrate that the density of states of the d orbitals near the Fermi level is significantly increased and additional electrical dipoles are induced due to the destruction of the symmetry of the local microstructure,which enhances conductive loss and dipolar polarization loss of 3D M-N_(xCs),respectively.Consequently,these 3D M-N_(xCs) exhibit excellent electromagnetic wave absorption properties,outperforming the most commonly reported absorbers.This study systematically explains the mechanism of dielectric loss at the atomic level for the first time and is of significance to the rational design of high-efficiency electromagnetic wave absorbing materials containing metal single atoms.
基金financed by the projects of the National Natural Science Foundation of China(21776229,21908180,22078266)the National Key Research&Development Program of China(2018YFB0604603)the Key Research and Development Program of Shaanxi(2020ZDLGY11-02,2018ZDXM-GY-167)。
文摘The catalytic cracking of coal tar asphaltene(CTA)pyrolysis vapors was carried out over transition metalion modified zeolites to promote the generation of light aromatic hydrocarbons(L-ArHs)in a pyrolysisgas chromatography/mass spectrometry(Py-GC/MS)micro-reactor system.The effects of ultra stable Y(USY),Co/USY and Mo/USY on the selectivity and yield of L-ArHs products and the extent of deoxygenation(Edeoxygenation),lightweight(Elightweight)from CTA pyrolysis volatiles were investigated.Results showed that the yields of L-ArHs are mainly controlled by the acid sites and specific surface area of the catalysts,while the deoxygenation effect is determined by theirs pore size.The Eligltweight of CTA pyrolysis volatiles over USY is 9.65%,while the Edeoxygenation of CTA pyrolysis volatiles over Mo/USY reaches 20.85%.Additionally,the modified zeolites(Mo/USY and Co/USY)exhibit better performance than USY on L-ArHs production,owing to the synergistic effect of metal ions(Mo,Co)and acid sites of USY.Compared with the non-catalytic fast pyrolysis of CTA,the total yield of L-ArHs obtained over USY(4032 mg·kg^(-1)),Co/USY(4363 mg·kg^(-1))and Mo/USY(4953 mg·kg^(-1))were increased by 27.03%,38.19%and 54.78%,respectively.Furthermore,the possible catalytic conversion mechanism of transition metal ion(Co and Mo)modified zeolites was proposed based on the distribution of products and the characterizations of catalysts.
基金sponsored by Shanghai Committee of Science and Technology with the project No.15XD1520100
文摘Along with strict environmental regulation, new-energy vehicles are becoming increasingly popular due to their low emissions, and they will inevitably replace existing fossil-fuel-based buses in China. To achieve a lightweight bus body ,high-strength steels are commonly used for the bus frame,but these grades are susceptible to corrosion. From the perspective of "lower life-cycle cost", high-strength stainless steel is a better bus structure choice than high-strength carbon steels, since stainless steel bus frames last 10-15 years without requiring any maintenance. The low-cost high-strength stainless steels developed by Baosteel are introduced,the yield and tensile strengths of which can be controlled to within the range of 350-700 MPa and 900-1 200 MPa,respectively, and the elongation values are above 30%. Measurements of the toughness and fatigue resistance of these high-strength stainless steels and their joints indicate that the structural integrity requirements for bus frames can be met. The results of salt spray corrosion studies indicate that stainless steels will substantially increase the service life of bus frames in wet and icy winter conditions where deicing with CaC12 is necessary for road safety. The results of our investigation clearly indicate that high-strength stainless steel is a potential bus-frame material that makes it possible to achieve substantial weight savings, excellent corrosion resistance, and prolonged operational life.
文摘Existing Metal Additive Manufacturing processes are fast approaching a matured stage in which a wide range of possibilities are available for the incorporation of the rapid fabrication technology to current industrial practices. In terms of design conventions, the limitless geometrical freedom allows complex structures including cellular internal grids and lattices to be formed without additional tooling. Repair parts and leveraging components can also be produced on demand when required especially for military assets where large volume of inventory is constantly maintained to ensure operational readiness. In this exemplary work, a feasibility study on using stainless steel material with integrated cellular design to manufacture a guide bracket found on a military vehicle via Selective Laser Melting process was conducted. The results showed appreciably better mechanical performance in using a stainless steel honeycomb as compared to the aluminum alloy used for the original component together with a faster production route through SLM.
文摘The synthesis, processing and mechanical properties of the light metals, aluminum,magnesium and titanium Produced by advanced techniques are reviewed. Synthesis techniques to be addressed will include rapid solidification, spray deposition, mechanical alloying, plasma Processing and vapor deposition.
文摘纤维金属层板(fiber metal laminate,FML)是一种新型轻量化混杂材料,逐渐被应用于汽车等运载装备领域,但其成形过程受多种参数影响,成形过程中的应力应变分布规律尚不清楚。选用T300碳纤维铝合金复合层板为研究对象,利用ABAQUS有限元软件对其冲压成形过程进行模拟,并进行了精度验证。主要研究了FML在预浸料种类、层板厚度和层板数等因素的影响下,应力分布及壁厚变化规律。结果表明,建立的FML冲压模型计算精度准确,预浸料种类主要影响纤维层的应力分布和壁厚变化,层板厚度和层板数对各层的壁厚变化产生影响,通过减薄层板厚度或增加层板数可以缓解过度减薄问题,层板厚度和层数也会影响铝合金层的应力分布,随着厚度和层数的增加,铝合金层的应力分布趋于均匀。
基金supported by the National Natural Science Foundation of China(Nos.52205350 and 52175301)the China Postdoctoral Science Foundation(Nos.2021M690820 and 2021T140151)and the Heilongjiang Postdoctoral Fund(LBH-Z20055).
文摘The heterojunctions between metal and polymer have become the effective ways to produce the lighter,safer and more environmental friendly vehicles for the manufacturing fields of automotive and aerospace.The state-of-the-art frictionbased welding techniques are characterized by low peak temperature,severe plastic deformation,energy efficiency and nonpollution,which can simultaneously realize the mechanical and chemical bonding,improving mechanical performances.In this review,the current progress about friction-based welding techniques is summarized,containing technical development,welding tool design,microstructural characteristic,process optimization,surface modification and joining mechanism.The conclusions and prospects are presented,which focus on the practical implications for the manufacturing sectors and recommendations for further research and development.The purpose of this review is to elucidate the benefits of friction-based welding techniques so that these methods may be better exploited and industrialized.