Lightweight refractories for the working lining of high-temperature furnaces play an important role in the smelting of advanced steels and superalloys.To prepare lightweight refractories for the working lining of high...Lightweight refractories for the working lining of high-temperature furnaces play an important role in the smelting of advanced steels and superalloys.To prepare lightweight refractories for the working lining of high-temperature furnaces,the synthesis of lightweight aggregates is the basis.Recently,the research on the synthesis of lightweight aggregates with high service temperature,low thermal conductivity,high strength,and good slag resistance has received widespread attention.The available literature on the synthesis of lightweight aggregates was summarized,including corundum,mullite,mullite-corundum,spinel,corundum-spinel,cordierite,cordierite-mullite,calcium hexaluminate,corundum-calcium hexaluminate,bauxite,magnesia,magnesia-based,and forsterite-based aggregates.Finally,the future development trend of lightweight aggregates was proposed.展开更多
To solve the problem of over-high density of lightweight insulation refractory bricks prepared with fly ash, new lightweight insulation refractory materials with density 〈 0. 89 g · cm^-3 were .synthesized using...To solve the problem of over-high density of lightweight insulation refractory bricks prepared with fly ash, new lightweight insulation refractory materials with density 〈 0. 89 g · cm^-3 were .synthesized using pyrophyl-lite, .fly ash, and Suzhou clay as the main starting materials and saw dast as the pore forming substance, and controlling the addition of the pyrophyllite （20%, 30% , and 40% by mass ） and the treating temperature （1 250, 1 300, 1 350, and 1 400 ℃ ）. The synthesized materials were characterized by the XRD, SEM and the thermal conductivity measuring in.strument. The results show at pyrophyllite addition of 30% and treat temperature of l 400 ℃ , the material can achieve linear shrinkage of 6. 6%, apparent porosity of 57%, bulk density of 0. 75 g · cm^-3, compressive strength of 2.7 MPa, and thermal conductivity at 350 ℃ of 0. 152 -0. 216 W·（ m·K）^-1.This indicates that the pyrophyllite decomposition at high temperatures forms mullite and amorphous quartz introducing volume expansion, which counteracts some shrinkage at high temperatures. So it is feasible to use pyrophyllite, fly ash waste and clay to prepare lightweight insulation refractory materials.展开更多
When the castable refractory linings are installed without drying out sufficiently and exposed to high humidity for a long time,white fibrous or powdery substance appears on the surface,which is called“efflorescence...When the castable refractory linings are installed without drying out sufficiently and exposed to high humidity for a long time,white fibrous or powdery substance appears on the surface,which is called“efflorescence”.The main reason is the cement of castable refractory linings contacts with C02 and moisture in the atmosphere to form calcium carbonate(CaC03).In general,efflorescence takes place more readily in lightweight castable refractories.In the walking beam reheating furnace construction project,there are many white powdery substances in the walking beams,because the construction procedure causes poor ventilation in the surrounding area,and the internal moisture of castable refractory linings cannot be evaporated effectively.In future,the project programming should consider the environmental humidity and surrounding ventilation.展开更多
Micro-pored CA6 -MA lightweight material with CAM： MA mass ratio of 7：3 was prepared using Al（OH） 3, MgCO3 and CaCO3 as starting materials, and anthracite. sweet potato starch and anthracite ＋ sweet potato starch...Micro-pored CA6 -MA lightweight material with CAM： MA mass ratio of 7：3 was prepared using Al（OH） 3, MgCO3 and CaCO3 as starting materials, and anthracite. sweet potato starch and anthracite ＋ sweet potato starch as pore forming agent （PFA） with an addition of 10 mass%, 20 mass% and 30 mass%, respectively. The starting materials were dry mixed, wet co-milled in a ball mill for 1 h. slip cast into cylindrical specimens with a diameter of 60 ram. and then calcined at 1 450 ℃ for 3 h. With the increase of PFA addition,, apparent porosity increases, and bulk density decreases. The influence of different PFAs on properties of the micro-pored LW CAM -MA aggregate was investigated. The achieved CAM - MA, by adding 30% sweet potato starch, has a porosity of 76. 8%, bulk density of 0. 78 g · cm^ - 3 and median pore size of 1.90 μm.展开更多
基金supported by the Starting Grants of Institute of Metal Research,Chinese Academy of Science(E255L401).
文摘Lightweight refractories for the working lining of high-temperature furnaces play an important role in the smelting of advanced steels and superalloys.To prepare lightweight refractories for the working lining of high-temperature furnaces,the synthesis of lightweight aggregates is the basis.Recently,the research on the synthesis of lightweight aggregates with high service temperature,low thermal conductivity,high strength,and good slag resistance has received widespread attention.The available literature on the synthesis of lightweight aggregates was summarized,including corundum,mullite,mullite-corundum,spinel,corundum-spinel,cordierite,cordierite-mullite,calcium hexaluminate,corundum-calcium hexaluminate,bauxite,magnesia,magnesia-based,and forsterite-based aggregates.Finally,the future development trend of lightweight aggregates was proposed.
基金financial support from the National Nature Science Foundation of China(51502213)
文摘To solve the problem of over-high density of lightweight insulation refractory bricks prepared with fly ash, new lightweight insulation refractory materials with density 〈 0. 89 g · cm^-3 were .synthesized using pyrophyl-lite, .fly ash, and Suzhou clay as the main starting materials and saw dast as the pore forming substance, and controlling the addition of the pyrophyllite （20%, 30% , and 40% by mass ） and the treating temperature （1 250, 1 300, 1 350, and 1 400 ℃ ）. The synthesized materials were characterized by the XRD, SEM and the thermal conductivity measuring in.strument. The results show at pyrophyllite addition of 30% and treat temperature of l 400 ℃ , the material can achieve linear shrinkage of 6. 6%, apparent porosity of 57%, bulk density of 0. 75 g · cm^-3, compressive strength of 2.7 MPa, and thermal conductivity at 350 ℃ of 0. 152 -0. 216 W·（ m·K）^-1.This indicates that the pyrophyllite decomposition at high temperatures forms mullite and amorphous quartz introducing volume expansion, which counteracts some shrinkage at high temperatures. So it is feasible to use pyrophyllite, fly ash waste and clay to prepare lightweight insulation refractory materials.
文摘When the castable refractory linings are installed without drying out sufficiently and exposed to high humidity for a long time,white fibrous or powdery substance appears on the surface,which is called“efflorescence”.The main reason is the cement of castable refractory linings contacts with C02 and moisture in the atmosphere to form calcium carbonate(CaC03).In general,efflorescence takes place more readily in lightweight castable refractories.In the walking beam reheating furnace construction project,there are many white powdery substances in the walking beams,because the construction procedure causes poor ventilation in the surrounding area,and the internal moisture of castable refractory linings cannot be evaporated effectively.In future,the project programming should consider the environmental humidity and surrounding ventilation.
文摘Micro-pored CA6 -MA lightweight material with CAM： MA mass ratio of 7：3 was prepared using Al（OH） 3, MgCO3 and CaCO3 as starting materials, and anthracite. sweet potato starch and anthracite ＋ sweet potato starch as pore forming agent （PFA） with an addition of 10 mass%, 20 mass% and 30 mass%, respectively. The starting materials were dry mixed, wet co-milled in a ball mill for 1 h. slip cast into cylindrical specimens with a diameter of 60 ram. and then calcined at 1 450 ℃ for 3 h. With the increase of PFA addition,, apparent porosity increases, and bulk density decreases. The influence of different PFAs on properties of the micro-pored LW CAM -MA aggregate was investigated. The achieved CAM - MA, by adding 30% sweet potato starch, has a porosity of 76. 8%, bulk density of 0. 78 g · cm^ - 3 and median pore size of 1.90 μm.
