The effect of the severity of an organosolv treatment of Miscanthus x giganteus on antioxidant capacity of the obtained lignin was studied. Four organosolv lignins extracted with different severity conditions were cho...The effect of the severity of an organosolv treatment of Miscanthus x giganteus on antioxidant capacity of the obtained lignin was studied. Four organosolv lignins extracted with different severity conditions were chosen and tested. Results obtained using the methyl linoleate method have shown a correlation between oxygen uptake index and the combined severity. It was found that lignin extracted at higher severity pre-treatment and with a higher phenolic hydroxyl content, lower aliphatic hydroxyl content, molecular weight and polydispersity has the highest antioxidant capacity.展开更多
分子量是聚合物的重要特性之一,木质素的分子量及其分布是研究苯丙烷类结构的反应、物理化学特性和评价其改性产物质量的内容之一。本研究以陆地棉TM-1成熟纤维为材料,分别利用酶解-温和酸解木质素法和二氧六环法提取棉纤维中木质素,结...分子量是聚合物的重要特性之一,木质素的分子量及其分布是研究苯丙烷类结构的反应、物理化学特性和评价其改性产物质量的内容之一。本研究以陆地棉TM-1成熟纤维为材料,分别利用酶解-温和酸解木质素法和二氧六环法提取棉纤维中木质素,结合凝胶渗透色谱法(gel permeation chromatography,GPC)调查和评价2种方法获得的棉纤维中木质素的相对分子量。结果表明,经二氧六环处理提取的棉花纤维中的木质素(dioxane lignin,DL)的重均分子量为2924g mol^(–1)、数均分子量2403 g mol^(–1),略高于由酶解-温和酸解处理提取的木质素(enzymatic hydrolysis-mild acidolysis lignin,EMAL)的重均分子量(2169 g mol^(–1))和数均分子量(1970 g mol^(–1)),EMAL的多分散系数稍低,说明木质素的均一性比DL高。表明EMAL法提取的木质素更适用于分析棉纤维中木质素的相对分子量。利用EMAL法分析棉纤维中木质素相对分子量表明,不同棉花品种的木质素重均分子量分布范围为938~2169 g mol^(–1),数均分子量分布范围为857~1970 g mol^(–1),多分散性系数在1.09~1.74间,均小于2。重均分子量与纤维马克隆值呈显著负相关,数均分子量与纤维长度呈显著负相关,与纤维马克隆值呈极显著负相关。展开更多
文摘The effect of the severity of an organosolv treatment of Miscanthus x giganteus on antioxidant capacity of the obtained lignin was studied. Four organosolv lignins extracted with different severity conditions were chosen and tested. Results obtained using the methyl linoleate method have shown a correlation between oxygen uptake index and the combined severity. It was found that lignin extracted at higher severity pre-treatment and with a higher phenolic hydroxyl content, lower aliphatic hydroxyl content, molecular weight and polydispersity has the highest antioxidant capacity.
文摘分子量是聚合物的重要特性之一,木质素的分子量及其分布是研究苯丙烷类结构的反应、物理化学特性和评价其改性产物质量的内容之一。本研究以陆地棉TM-1成熟纤维为材料,分别利用酶解-温和酸解木质素法和二氧六环法提取棉纤维中木质素,结合凝胶渗透色谱法(gel permeation chromatography,GPC)调查和评价2种方法获得的棉纤维中木质素的相对分子量。结果表明,经二氧六环处理提取的棉花纤维中的木质素(dioxane lignin,DL)的重均分子量为2924g mol^(–1)、数均分子量2403 g mol^(–1),略高于由酶解-温和酸解处理提取的木质素(enzymatic hydrolysis-mild acidolysis lignin,EMAL)的重均分子量(2169 g mol^(–1))和数均分子量(1970 g mol^(–1)),EMAL的多分散系数稍低,说明木质素的均一性比DL高。表明EMAL法提取的木质素更适用于分析棉纤维中木质素的相对分子量。利用EMAL法分析棉纤维中木质素相对分子量表明,不同棉花品种的木质素重均分子量分布范围为938~2169 g mol^(–1),数均分子量分布范围为857~1970 g mol^(–1),多分散性系数在1.09~1.74间,均小于2。重均分子量与纤维马克隆值呈显著负相关,数均分子量与纤维长度呈显著负相关,与纤维马克隆值呈极显著负相关。
