Mathematical Modeling of the Oxidation of Polyunsaturated Fatty Acids in Emulsions with Stirring and Limited Oxygen Compensation

The oxidation of polyunsaturated fatty acids （PUFA） in emulsion with stirring and limited oxygen compensation was studied. A mathematical model of diffusion-oxidation was developed considering the mass transfer resistance of a gas-liquid boundary, the resistance of the boundary layer from the emulsifier membrane, and the autocatalytic-type autoxidation reaction of PUFA. The dynamic mass transfer coefficient of the emulsifier membrane, k0, was introduced. The model was verified by comparing the predictions of the model with the experi- mental data. The results indicated that the model was in good agreement with the oxygen diffusion and linoleic acid oxidation in the emulsion, and showed good applicability in the prediction of the effect of the emulsifier type on the oxidation of PUFA in the emulsion. It indicated that the oxidation of PUFA in emulsions, with stirring and limited oxygen compensation from the atmosphere, was controlled mostly by mass transfer resistance from the emulsifier membrane.

Research on Alkaline Filler Flame-Retarded Asphalt Pavement

Used as flame returdant of tunnel asphalt pavement, organic bromides produce a large amount of poisons and smoke in construction and flame retardation stage. The alkaline filler was found to replace mineral filler, and the flame- retarded asphalt mixtures were produced. Experimental results show that these asphalt mixtures are smoke restrained ; the performances and construction technology of asphalt pavement are not influenced; also the alkaline filler is of low-price. So this kind of flame-retarded asphalt mixtures is suitable for tunnel patement.

Research on the effect of the common flame retardant in reducing the flammability of the bitumen

The bituminous defect that the binder is flammable will bring road safety risk.Once it catches fires,large quantities of heat,smoke and poisonous gas are produced,released and spread quickly,which seriously hinder escape and rescue and harms heavily traffic safety.The common flame retardant system is used to modify the asphalt.Cone Calorimeter is adopted to evaluate the burning property of asphalt.The performance of the flame retardant is evaluated by limiting oxygen index and orthogonal design method.The paper analyzes the synergism of the asphalt and flame-retardant,and analyzes the effect of the flame on preventing the smoke to spread and demonstrates that the use of common flame retardants which is added into binder is good at reducing the flammability of the binder.This way can increase the safety of asphalt pavement when fire occurs in the tunnel.The study suggests that flame retardancy of asphalt can be evaluated by Limit Oxygen Index (LOI) and the flame retardancy property of asphalt has marked change according to the content of flame retardant.SB has perfect flame retardancy property,and ATH is better than MH in the effect of flame retardant.

Limiting current oxygen sensor based on Y,In co-doped SrTiO_(3)as a dense diffusion barrier layer

A novel dense diffusion barrier material(Y_(x)Sr_(1−x)Ti_(0.9)In_(0.1)O_(3−δ)(x=0.03,0.05,0.07))was prepared by using a sol-gel method.The crystal structure,microstructures,electrical conductivity and ionic conductivity of barrier material were characterized.The results show that the samples exhibit the formation of cubic perovskite structure phase.The increase of Y-doping amount on A-site improved electrical conductivity and sinterability of materials.A limiting current oxygen sensor based on Y_(0.07)Sr_(0.97)Ti_(0.9)In_(0.1)O_(3–δ)as a dense diffusion barrier shows excellent sensing performance.The linear relationship between limiting current logIL and 1000/T can described logIL=4.603,8−3.847,5·1,000/T.At 750°C,0.25%≤x(O_(2))≤5.0%,the linear relationship between limiting current(IL)and oxygen amount(x(O_(2)))can described as I_(L)=7.047,6+3.875,1·x(O_(2)).

RESEARCH THE CHANGE RULE OF OXIDATION ZONE WIDTH CAUSED BY NITROGEN INJECTION IN GOB

On the basis of heat transfer and chemical kinetics theory, both connections coal self ignite with oxygen concentration and range of oxidation zone with air leak intensity are analyzed, and calculating method is deduced to gain the lower limit of oxygen concentration and the range of oxidation zone. The change rule of correlative parameter is quantitatively researched between before nitrogen injection and after nitrogen injection in gob, such as oxygen concentration, oxidation zone width, etc. According to theoretical calculation, the relation position and flow of nitrogen injection with oxidation zone width is conformed, and computational formulas of the best flow and position of nitrogen injection are obtained. It offers a theoretic criterion for preventing and controlling float coal self ignite by nitrogen injection in gob.

Control of redox potential by oxygen limitation in selective bioleaching of chalcocite and pyrite

Based on the bioleaching mechanism and electrochemical studies of metal sulfides, the dissolution rates of chalcocite and pyrite are controlled by redox potentials. Experiment on the bioleaching of chalcocite and pyrite under constant redox potential by sparging with nitrogen gas was demonstrated. By leaching at low and constant redox potential（〈760 mV, vs SHE）, copper recoveries of 90 %–98 % are achieved, which are 10 times more than iron recoveries. The iron-oxidizing bacterial populations are observed to continue to reduce under oxygen limitation conditions, but the Acidithiobacillus that have only sulfur-oxidizing capabilities are an attractive alternative for redox-controlled bioleaching of chalcocite.Thus, the described redox control technique might be one of the effective approaches to balance acid and iron in Zijinshan copper bio-heap leaching practice.

SYNTHESIS AND CHARACTERIZATION OF POLYBENZOXAZINE CONTAINING PHOSPHORUS

The novel benzoxazine monomer containing phosphorus has been synthesized based on multifianctional amine route from bis（4-aminophenyl）phenylphosphate, p-cresol and formaldehyde. Subsequently, the benzoxazine monomer was thermo-cured into polybenzoxazine containing phosphorus. The chemical structures were identified by nuclear magnetic resonance （NMR）, Fourier transform infrared spectroscopy （FT-IR）. The curing reaction was monitored by differential scanning calorimetry （DSC） and FT-IR. The thermal and flame-retardant properties of obtained polybenzoxazine were evaluated by dynamic mechanical thermal analysis （DMA）, thermal gravimetric analysis （TGA） and oxygen index meter, respectively. The results show that the novel polybenzoxazine has high limiting oxygen index （38.1） and glass transition temperature （232℃）.

Study on fire extinguishing performance of ultrafine water mist in a cup burner

Two simplified models for predicting minimum extinguishing concentration(MEC) of ultrafine water mist(UFM)(<10 m) were developed based on limiting oxygen concentration(LOC) and combustion limit temperature(CLT),respectively.Experiment was conducted using a modified cup burner which can reduce the surface adsorption of UFM.Two typical liquid fuels,n-heptane and ethanol,were used in the experiment.Tests using the same scenario were repeated 20 times or 10 times according to the variance of extinguishing time.The average and the standard deviations of extinguishing time were used to evaluate the fire extinguishing performance of UFM.Experimental results agree well with the model based on LOC,and disagree with the model based on CLT.The disagreements were explained by analyzing flow behavior of UFM.It was concluded that the primary mechanism of fire extinguishment with UFM was oxygen dilution.

OPTICALLY ACTIVE AND FLAME-RETARDANT POLY(AMIDE-IMIDE)S BASED ON PHOSPHINE OXIDE MOIETY AND N,N′-(PYROMELLITOYL)BIS-L-AMINO ACID IN THE MAIN CHAIN:SYNTHESIS AND CHARACTERIZATION

Six new optically active and flame-retardant poly（amide-imide）s PAls 5a-5f containing phosphine oxide moiety as a flame-retardant unit in the main chain were synthesized from direct polycondensation reaction of six chiral N,N＇-（pyromellitoyl）-bis-L-amino acid 3a-3f with bis（3-aminophenyl）phenyl phosphine oxide 4 in a medium consisting of N-methyl-2-pyrrolidone （NMP）, triphenyl phosphite （TPP）, calcium chloride （CaCl2） and pyridine. The polymerization reactions produced a series of optically active poly（amide-imide）s with good yield and good inherent viscosity of 0.34-0.70 dLg^-1. The resulted polymers were fully characterized by means of FTIR and ^1H-NMR spectroscopy, gel permeation chromatography （GPC）, elemental analyses, inherent viscosity and solubility tests. Thermal properties and flameretardant behavior of the PAIs 5a-5f were investigated using thermal gravimetric analysis （TGA and DTG） and limiting oxygen index （LOI）. Data obtained by thermal analysis （TGA and DTG） revealed that these polymers showed good thermal stability. Furthermore, high char yield in TGA and good LOI values indicated that the resulting polymers were capable of exhibiting good flame retardant properties. N,N＇-（pyromellitoyl）-bis-L-amino acids 3a-3f were prepared in quantitative yields by the condensation reaction of pyromellitic dianhydride （1,2,4,5-benzenetetracarboxylicacid-1,2,4,5-dianhydride） 1 with L-alanine 2a, L-valine 2b, L-leucine 2c, L-isoleucine 2d, L-phenyl alanine 2e and L-2-aminobutyric acid 2f in acetic acid solution.

Cold adaptation does not alter ATP homeostasis during cold exposure in Drosophila melanogaster

In insects and other ectotherms,cold temperatures cause a coma resulting from loss of neuromuscular function,during which ionic and metabolic homeostasis are progressively lost.Cold adaptation improves homeostasis during cold exposure,but the ultimate targets of selection are still an open question.Cold acclimation and adaptation remodels mitochondrial metabolism in insects,suggesting that aerobic energy production during cold exposure could be a target of selection.Here,we test the hypothesis that cold adaptation improves the ability to maintain rates of aerobic energy production during cold exposure by using^(31)P NMR on live flies.Using lines of Drosophila melanogaster artificially selected for fast and slow recovery from a cold coma,we show that cold exposure does not lower ATP levels and that cold adaptation does not alter aerobic ATP production during cold exposure.Cold-hardy and cold-susceptible lines both experienced a brief transition to anaerobic metabolism during cooling,but this was rapidly reversed during cold exposure,suggesting that oxidative phosphorylation was sufficient to meet energy demands below the critical thermal minimum,even in cold-susceptible flies.We thus reject the hypothesis that performance under mild low temperatures is set by aerobic ATP supply limitations in D.melanogaster,excluding oxygen and capacity limitation as a weak link in energy supply.This work suggests that the modulations to mitochondrial metabolism resulting from cold acclimation or adaptation may arise from selection on a biosynthetic product(s)of those pathways rather than selection on ATP supply during cold exposure.