High surface area activated carbons were produced by thermal activation of waste bamboo scaffolding with phosphoric acid.Single component equilibrium dye adsorption was conducted on the carbons produced and compared w...High surface area activated carbons were produced by thermal activation of waste bamboo scaffolding with phosphoric acid.Single component equilibrium dye adsorption was conducted on the carbons produced and compared with a commercially available carbon.Two acid dyes with different molecular sizes,namely Acid Yellow 117(AY117) and Acid Blue 25(AB25),were used to evaluate the adsorption capacity of the produced carbons.It was found that the dye with smaller molecular size,AB 25,was readily adsorbed onto the produced carbon,nearly three times higher than a commercially available carbon,while the larger size dye,AY117,showed little adsorption.The experimental data were analyzed using isotherm equations including Langmuir,Freundlich,Tempkin,Toth,Redlich-Peterson and Sips equations.The equilibrium data were then analyzed using five different non-linear error analysis methods.展开更多
以益阳地区某木材加工厂的废弃生物质杉木屑为原料,对其进行真空化学活化。活性炭产物微孔结构发达,微孔体积占总孔体积的90.02%;根据IUPAC(International Union of Pure and Applied Chemistry)分类,其对氮气的吸附等温线属于典型的I...以益阳地区某木材加工厂的废弃生物质杉木屑为原料,对其进行真空化学活化。活性炭产物微孔结构发达,微孔体积占总孔体积的90.02%;根据IUPAC(International Union of Pure and Applied Chemistry)分类,其对氮气的吸附等温线属于典型的I型吸附等温线,可以使用Langmiur方程描述;吸附平衡常数为2.70 kPa-1;标准状态下的饱和吸附量为360.81 cm3.g-1。展开更多
基金the support of the Research Grant Council of Hong Kong SARthe Innovation and Technology Fund of Hong Kong SAR+1 种基金the Hong Kong University of Science and TechnologyGreen Island International
文摘High surface area activated carbons were produced by thermal activation of waste bamboo scaffolding with phosphoric acid.Single component equilibrium dye adsorption was conducted on the carbons produced and compared with a commercially available carbon.Two acid dyes with different molecular sizes,namely Acid Yellow 117(AY117) and Acid Blue 25(AB25),were used to evaluate the adsorption capacity of the produced carbons.It was found that the dye with smaller molecular size,AB 25,was readily adsorbed onto the produced carbon,nearly three times higher than a commercially available carbon,while the larger size dye,AY117,showed little adsorption.The experimental data were analyzed using isotherm equations including Langmuir,Freundlich,Tempkin,Toth,Redlich-Peterson and Sips equations.The equilibrium data were then analyzed using five different non-linear error analysis methods.
文摘以益阳地区某木材加工厂的废弃生物质杉木屑为原料,对其进行真空化学活化。活性炭产物微孔结构发达,微孔体积占总孔体积的90.02%;根据IUPAC(International Union of Pure and Applied Chemistry)分类,其对氮气的吸附等温线属于典型的I型吸附等温线,可以使用Langmiur方程描述;吸附平衡常数为2.70 kPa-1;标准状态下的饱和吸附量为360.81 cm3.g-1。
