Effect of droplet characteristics on liquid-phase distribution in spray zone of internal mixing air-mist nozzle

In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In order to study the behavior of atomized droplets after reaching the slab surface and to optimize the spray cooling effect,the influence of droplet diameter and droplet velocity on the migration behavior of droplets in the secondary cooling zone was analyzed by FLUENT software.Results show that the droplets in the spray zone and on the slab surface are mainly concentrated in the center,thus,the liquid volume fraction in the center is higher than that of either side.As the droplet diameter increases,the region of high liquid volume fraction on the slab surface becomes wider,and the liquid phase distribution in the slab width direction becomes uneven.Although increasing the droplet velocity at the nozzle exit has little effect on droplet diffusion in the spray zone,the distribution becomes more uneven due to more liquid reaches the slab surface per unit time.A prediction formula of the maximum water flow rate on the slab surface for specific droplet characteristics was proposed based on dimensionless analysis and validated by simulated data.A nozzle spacing of 210 mm was recommended under the working conditions in this study,which ensures effective coverage of the spray water over the slab surface and enhances the distribution uniformity of water flow rate in the transverse direction.

Expressions of the radius and the surface tension of surface of tension in terms of the pressure distribution for nanoscale liquid threads

The expressions of the radius and the surface tension of surface of tension Rs and γs in terms of the pressure distribution for nanoscale liquid threads are of great importance for molecular dynamics （MD） simulations of the interfacial phenomena of nanoscale fluids; these two basic expressions are derived in this paper. Although these expressions were derived first in the literature[Kim B G, Lee J S, Han M H, and Park S, 2006 Nanoscale and Microscale Thermophysical Engineering, 10, 283] and used widely thereafter, the derivation is wrong both in logical structure and physical thought. In view of the importance of these basic expressions, the logic and physical mistakes appearing in that derivation are pointed out.

Influence of Pt/Ru anodic ratio on the valorization of ethanol by PEM electrocatalytic reforming towards value-added products

The ethanol electro-reforming process was studied over PtRu/C catalysts synthesized by the modified polyol method with different compositions.In particular,this work reports the influence of anodic Pt:Ru ratio(5:1,2:1 and 1:2)on the organic product distribution(acetaldehyde,acetic acid and ethyl acetate)and pure hydrogen generation at different current densities operation levels.Physicochemical characterization of the catalysts was made by X-ray diffraction(XRD),temperature-programmed reduction(TPR)and N_(2) adsorption-desorption measurements.XRD patterns showed that Ru is introduced into the Pt structure,forming an alloy between both metals.Also,the degree of alloy was higher by increasing the Ru amounts.From TPR profiles Pt was found to be properly reduced while Ru was both in metallic state and forming RuO2.The electrochemical behaviour of each catalyst towards ethanol electroreforming process was investigated through electrochemical techniques in a half cell and a single proton exchange membrane(PEM)cell systems.An intermediate Pt:Ru ratio was found to result in high current density and electrochemical surface area(ECSA)values along with lower amounts of adsorbed species.Also,Ru addition seems to diminish the degree of degradation of the catalyst.Based on characterization and in agreement with essays carried out in a PEM cell at mild conditions(80℃ and 1 atm),PtRu/C 2:1 anode provided the best electrocatalytic results in terms of current density(740 mA cm^(-2)),hydrogen production and selectivity toward acetic acid(up to 15%apart from acetaldehyde and ethyl acetate)while requiring the lowest energy consumption.

A 2D numerical study on the condensation characteristics of three non-azeotropic binary hydrocarbon vapor mixtures on a vertical plate

To improve the transportation efficiency and reduce the supply cost,the liquefaction becomes an important technology to store and transport the natural gas.During the liquefaction,the various components(e.g.propane,ethane,methane etc.)undergo fractional condensation phenomenon due to their different boiling points.This means that when one component condenses,others play a role of non-condensable gas(NCG).In order to reveal the influence mechanism of NCG on this condensation process,a numerical method was employed in this paper to study the condensation characteristics of three non-azeotropic binary hydrocarbon vapor mixtures,namely the propane/methane(80%–95%),ethane/methane(65%–85%)and methane/nitrogen(2%–13%)mixtures,on a vertical plate.The model was proposed based on the diffusion layer model,and the finite volume method was used to solve the governing equations.A user defined function was developed by cell iterative method to obtain the source terms in the condensation process.The numerical results show that the gas phase boundary layer formed by the NCG becomes the main resistance to the reduction of heat transfer coefficient.And for the above three mixtures,there is a negative correlation between the NCG concentration and the heat transfer coefficient.Meanwhile,the results show a good agreement with the experimental data,meaning that the proposed model is reliable.Three mixtures within same non-condensable mole fraction of 20%were also investigated,indicating that the mixtures with a higher binary hydrocarbon molecular ratio have a lower heat transfer coefficient.As a result,the presence of the lighter NCG contributes to a thicker boundary layer.

Distributed TLDs in RC floors and their vibration reduction efficiency

A novel distributed tuned liquid damper （DTLD） for reducing vibration in structures is proposed in this paper. The basic working principle of the DTLDs is to fill the empty space inside the pipes or boxes of cast-in-situ hollow reinforced concrete （RC） floor slabs with water or other liquid. The pipes or boxes then work as a series of small TLDs inside the structure, to increase the damping ratio of the entire structural system. Numerical simulation that accounts for the fluid- structure conpling effect is carried out to evaluate the vibration-reduction efficiency of the DTLDs. The results show that the DTLDs are able to considerably increase the damping of the structure and thus reduce its vibration. An additional benefit is that the DTLDs do not require architectural space to be added to the structure.

Charge distribution into illuminated dye-doped surface stabilized ferroelectric liquid crystal cell

Surface stabilized （anti） ferroelectric liquid crystal cells can be used as an optically addressed media for optical data processing. The structure of the cell has to contain a photo sensible agent, i.e, an absorbing dye-doped orienting layer. The all-optical generation of the diffractive grating can be done due to the switching parameters of the smectic slab within cells with a sensitive layer. This Letter considers a study of the optically induced charge generation into the dye-doped layer, and the explanation of the phenomena of the selective molecular director reorientation, while cell driving what leads to the induction of phase grating.

Numerical study of liquid coverage in a gas-liquid-solid packed bed

In this work, computational fluid dynamics （CFD） simulations using the volume-of-fluid （VOF） model were employed to investigate the effects of liquid properties, liquid and gas flow rates, and wettability of particles on liquid maldistribution at the microscopic level in a fixed bed reactor. The simulation results show that the number of wetted particles decreases with increasing gas velocity, consequently leading to lower liquid-solid contact areas. The radial liquid distribution is greatly enhanced by increasing the liquid flow rate, whereas the time for the liquid to pass through the whole bed is decreased, as expected. Based on simulation results, it was found that the liquid-solid contact area can be increased by using liquids of high viscosities and more wettable particles. However, the flow-through time increases with increasing liquid viscosity. An increase in the gas density showed a minimal impact on the liquid flow- through time, and the liquid density does not impact the radial liquid distribution or the liquid flow time within a range of liquid densities typically encountered in the petrochemical industry.

Phase behavior of gas condensate in porous media using real-time computed tomography scanning

The phase behavior of gas condensate in reservoir formations differs from that in pressure-volume-temperature(PVT)cells because it is influenced by porous media in the reservoir formations.Sandstone was used as a sample to investigate the influence of porous media on the phase behavior of the gas condensate.The pore structure was first analyzed using computed tomography(CT)scanning,digital core technology,and a pore network model.The sandstone core sample was then saturated with gas condensate for the pressure depletion experiment.After each pressure-depletion state was stable,realtime CT scanning was performed on the sample.The scanning results of the sample were reconstructed into three-dimensional grayscale images,and the gas condensate and condensate liquid were segmented based on gray value discrepancy to dynamically characterize the phase behavior of the gas condensate in porous media.Pore network models of the condensate liquid ganglia under different pressures were built to calculate the characteristic parameters,including the average radius,coordination number,and tortuosity,and to analyze the changing mechanism caused by the phase behavior change of the gas condensate.Four types of condensate liquid(clustered,branched,membranous,and droplet ganglia)were then classified by shape factor and Euler number to investigate their morphological changes dynamically and elaborately.The results show that the dew point pressure of the gas condensate in porous media is 12.7 MPa,which is 0.7 MPa higher than 12.0 MPa in PVT cells.The average radius,volume,and coordination number of the condensate liquid ganglia increased when the system pressure was between the dew point pressure(12.7 MPa)and the pressure for the maximum liquid dropout,Pmax(10.0 MPa),and decreased when it was below Pmax.The volume proportion of clustered ganglia was the highest,followed by branched,membranous,and droplet ganglia.This study provides crucial experimental evidence for the phase behavior changing process of gas condensate in porous media during the depletion production of gas condensate reservoirs.

Relationship between Tissue Distributions of Modified Wuzi Yanzong Prescription(加味五子衍宗方) in Rats and Meridian Tropism Theory

Objective： To investigate the relationship between tissue distributions of modified Wuzi Yanzong prescription（加味五子衍宗方, MWP） in rats and meridian tropism theory. Methods： A high-performance liquid chromatography with Fourier transform-mass spectrometry（HPLC-FT） method was used to identify the metabolites of MWP in different tissues of rats after continued oral administration of MWP for 7 days. The relationship between MWP and meridian tropism theory was studied according to the tissue distributions of the metabolites of MWP in rats and the relevant literature. Results： Nineteen metabolites, mainly flavanoid compounds, were detected in the different rat tissues and classified to each herb in MWP. Further, it was able to establish that the tissue distributions of the metabolites of MWP were consistent with the descriptions of meridian tropism of MWP available in literature, this result might be useful in clarifying the mechanism of MWP on meridian tropism. In the long run, these data might provide scientific evidence of the meridian tropism theory to further promote the reasonable, effective utilization, and modernization of Chinese medicine. Conclusion： The tissue distributions of MWP in vivo were consistent with the descriptions of meridian tropism of MWP.