Interfacial charge-transfer engineering by ionic liquid for high performance planar CH3NH3PbBr3 solar cells

The energy barrier at the CH3NH3Pb Br3/TiO2interface hinders the electron transfer from CH3NH3Pb Br3to compact TiO2（cp-TiO2）.Ionic liquid（IL）,that forms dipoles pointing away from TiO2,can adjust the work function of TiO2resulting in suitable energy level for charge transfer from CH3NH3Pb Br3to TiO2.The time-resolved photoluminescence spectroscopy（TRPL）measurements confirm faster electron transfer from the CH3NH3Pb Br3film to TiO2after modification by IL.Solar cells based on IL modified cp-TiO2demonstrate efficiency of～6%,much higher than the devices（0.2%）fabricated using untreated cp-TiO2as the electron transport layer.

Analysis of combustion instability via constant volume combustion in a LOX/RP-1 bipropellant liquid rocket engine

Turbulent two-phase reacting flow in the chamber of LOX/RP-1 bipropellant liquid rocket engine is numerically investigated in this paper. The predicted pressure and mean axial velocity are qualitatively consistent with the experimental measurements. The self-excited pressure oscillations are obtained without any disturbance introduced through the initial and boundary conditions. It is found that amount of abrupt pressure peaks appear frequently and stochastically in the head regions of the chamber, which are the important sources to drive and strengthen combustion instability. Such abrupt pressures are induced by local constant volume combustion, because local combustible gas mixtures with high temperature are formed and burnt out suddenly due to some fuel droplets reaching their critical state in a rich oxygen surrounding. A third Damkhler number is defined as the ratio of the characteristic time of a chemical reaction to the characteristic time of a pressure wave expansion to measure the relative intensity of acoustic propagation and combustion process in thrusters. The analysis of the third Damkhler number distributions in the whole thrust chamber shows that local constant volume combustion happens in the head regions, while constant pressure combustion presents in the downstream regions. It is found that the combustion instability occurs in the head regions within about 30 mm from the thruster head.

Numerical study of operational processes in a GOx-kerosene rocket engine with liquid film cooling

Combustion process inside kerosene-GOx rocket combustor with kerosene Alm cooling is studied,and a modeling approach is proposed.The paper suggests to use the Lagrangian particle tracking technique to model fuel film behavior while the continuous fluid is simulated via the Navier-Stokes system of Favre-averaged equations.The approach is validated over the 12 experimental regimes by the criterions of characteristic velocity and pressure,ence on the adiabatic wall temperatures and relatively low impact on the pressure.In general,phenomena,the calculation of operational processes becomes fast and robust yet precise en-the design process.

新型空间站氢/氧变轨发动机研究(英文)

Hydrogen and oxygen orbital maneuver thruster, based on gas-dynamic resonance ignition, is a new liquid rocket propulsion technology, and is especially applicable to space station. By means of theoretic thermodynamic calculation of the hydrogen and oxygen thruster, combined with the experimental exploration on the coaxial hydrogen and oxygen resonance ignition, a scheme of the thruster head configuration is designed as the combination of a coaxial hydrogen/oxygen resonance igniter and an oxygen augmentation injector. Through ignition tests on coaxial hydrogen/oxygen resonance igniter characterization, the thruster head ignition tests have been conducted successfully in sequence of resonance ignition and oxygen augmentation combustion. Finally, the thruster ground tests are successfully carried out in forms of single impulse, successive double impulses and 3.0 seconds continuous running, which verify the reliability and feasibility of the thruster. The response time of the thruster starting is restricted within 0.2 second.

Coupled Lagrangian impingement spray model for doublet impinging injectors under liquid rocket engine operating conditions

To predict the effect of the liquid rocket engine combustion chamber conditions on the impingement spray, the conventional uncoupled spray model for impinging injectors is extended by considering the coupling of the jet impingement process and the ambient gas field. The new coupled model consists of the plain-orifice sub-model, the jet-jet impingement sub-model and the droplet collision sub-model. The parameters of the child droplet are determined with the jet-jet impingement sub-model using correlations about the liquid jet parameters and the chamber conditions.The overall model is benchmarked under various impingement angles, jet momentum and offcenter ratios. Agreement with the published experimental data validates the ability of the model to predict the key spray characteristics, such as the mass flux and mixture ratio distributions in quiescent air. Besides, impinging sprays under changing ambient pressure and non-uniform gas flow are investigated to explore the effect of liquid rocket engine chamber conditions. First, a transient impingement spray during engine start-up phase is simulated with prescribed pressure profile. The minimum average droplet diameter is achieved when the orifices work in cavitation state, and is about 30% smaller than the steady single phase state. Second, the effect of non-uniform gas flow produces off-center impingement and the rotated spray fan by 38°. The proposed model suggests more reasonable impingement spray characteristics than the uncoupled one and can be used as the first step in the complex simulation of coupling impingement spray and combustion in liquid rocket engines.

中国航天主动力液体火箭发动机技术进展

Liquid propellant rocket engines for a launch vehicle are an essential aerospace technology, representing the advanced level of hi-tech in a country. In recent years, China’s aerospace industry has made remarkable achievements, and liquid rocket engine technology has also been effectively developed. In this article, the development processes of China’s liquid rocket engines are discussed. Then, the performance features of China’s new generation liquid rocket engines as well as the flight tests of the new-generation launch vehicles are introduced. Finally, the development direction and the most recent progress of the next generation large-thrust liquid rocket engine is presented.

可重复使用液体火箭发动机关键技术研究

Based on current research,the development trend of reusable liquid rocket engines was analyzed.Key technologies and research focuses of the reusable liquid rocket engine have been analyzed and summarized,and then suggestions on the development of future key technologies are proposed.

Study of pressure surge during priming phase of start transient in an initially unprimed pump-fed liquid rocket engine

In this paper, transient phenomenon during start up process of a pump fed liquidrocket engine is investigated through numerical simulation. The engine studied in this workis designed such that engine systems are not wetted with propellant until the engine is com-manded to start. This is achieved by positioning the valves for propellant admission at the inter-face of test stand/flight stage and the engine. To evaluate engine performance during starttransient for such systems, unsteady flow simulation was conducted using Method of Charac-teristics and equations for priming. The same has been reported in this work. The results indi-cated a brief period of abrupt pressure rise at pump upstream after opening of the propellantadmission valves, during the process of priming of engine systems at valve downstream.The peak pressure obtained was significantly higher than the propellant tank pressure as wellas the steady state pump suction pressure. The transitory pressure rise was found to occurdue to flow resistance at impeller inlet caused by formation of a forced vortex for orientingthe flow through impeller blades during off design transient regime. The maximum pressureat pump upstream, as computed from start transient simulation, was used as a design inputfor pump inlet feed lines. The engine was realized and subsequently qualified in a ground test facility. Hot test data obtained for pressure and flow rate during transient regime were found tobe in good agreement with the simulation results.

Dynamic interaction between clustered liquid propellant rocket engines under their asynchronous start-ups

A nonlinear mathematical model of the low-frequency dynamics of the clustered multi-engine rocket propulsion system has been developed and the computations of the engine transient processes during the start-ups of the four-engine propulsion system with a shared feed system have been made applied.Based on propulsion system start-up modeling the influence of the connectivity of engines in a cluster on the starting characteristics of individual engines is shown.In particular,an advanced nonlinear mathematical model of the pump cavitation phenomena is a distinctive feature of the mathematical model.The computation results showed that the asynchronous engines start-ups during rocket lift-off lead to severely nonlinear engine transients and clustered engine thrust misbalance.The influence of the rocket engines asynchronous start-ups on the clustered feed system transients depends on many factors,mainly on from the clustered feed system low-frequency dynamics,the magnitude of the disturbance and the phase difference between disturbances acting on different branches of the feed system.The deep lingering dips in the flow rate and pressure transients are possible due to the nonlinear dynamic interaction of the engines.In case of great pressure dips at the pump inlet(up to the pressure of saturated vapors during significant periods of start-up time)the cavitation breakdowns of the pumps of one or more engines from the cluster are possible.This can disrupt the operation of the entire propulsion system and leads to the failure of the launch vehicle mission.

空化诱导轮内流动不稳定性的最大似然估

The article illustrates the application of Bayesian estimation to the identification of flow instabilities,with special reference to rotating cavitation,in a three-bladed axial inducer using the unsteady pressure readings of a single transducer mounted on the casing just behind the leading edges of the impeller blades.The typical trapezoidal pressure distribution in the blade channels is parametrized and modulated in time and space for theoretically reproducing the expected pressure generated by known forms of cavitation instabilities(cavitation auto-oscillations and higher-order surge cavitation modes,n-lobed subsynchronous/synchronous/super-synchronous rotating cavitation).The Fourier spectra of the theoretical pressure so obtained in the rotating frame are transformed in the stationary frame,frequency broadened to better approximate the experimental results,and parametrically fitted by maximum likelihood estimation to the measured auto-correlation spectra.Each form of instability generates a characteristic distribution of sidebands in addition to its fundamental frequency.The identification makes use of this information for effective detection and characterization of multiple simultaneous flow instabilities with intensities spanning over about 20 db down to about 4 db signal-to-noise ratios.The same information also allows for effectively bypassing the aliasing limitations of traditional cross-correlation methods in the discrimination of multiple-lobed azimuthal instabilities from the measurements returned by arrays of equally spaced sensors.The method returns both the estimates of the model parameters and their standard deviations,providing the information needed for the assessment of the statistical significance of the results.The proposed approach represents therefore a promising tool for experimental research on flow instabilities in high-performance turbopumps.

Experiment, acoustic model for the self-oscillation of coaxial swirl injector and its influence to combustion of liquid rocket engine

During the experiment of gas/liquid coaxial swirl injector conducted with air and water under atmosphere environment, it is observed that the injector may selfoscillate. The self oscillation periodically occurs and vanishes with the increasing velocity of the gas flow.A theoretical model is presented based on the experiment investigation. Simulation of the acoustic process has been performed and conclusions consistent with the experiment can be drawn from the theoretical model, which explains the exPeriment phenomena quite well. At last, the comparison between phenomena of the self oscillation and some experiments of LRE indicates that some instability phenomena in oxygen/hydrogen propellant rocket engine may be the related to self oscillation in coaxial injectors

New Power for Boosting China's Aerospace Industry

China's new-generation launch vehicle LM-5 successfully completed its maiden launch in November 2016.Among the new technologies applied in the launch vehicle,four types of liquid rocket engines attracted extensive attention.These engines feature advanced concepts and technologies such as a staged combustion cycle and expander cycle.The engines are the results of hard effort of more than ten years,which is also an epitome of the development history of China's aerospace industry.This paper gives a brief introduction to the technological schemes,main parameters,development process and application of the four types of engines that powered the new-generation launch vehicle.Finally,proposals for new liquid propulsion technology development in the future in China are presented.

Numerical simulation of axial liquid film cooling in rocket combustor

Numerical simulation has been done for liquid film cooling in liquid rocket combustor.Multiple species of axial Navier-Stokes equations have been solved for liquid-film / hot-gas flow field,and k-εequations have been used for compressible turbulent flow.The results of the model agree well with the results of software FLUENT.The results show that :(1) Liquid film can decrease the wall heat flux and temperature effectively,and the cold border area formed by the film covers the whole combustor and nozzle wall.(2) The turbulent viscosity is higher than the physical viscosity,and its biggest value is in the border area of the convergent area in nozzle.The effect of turbulent flow on the whole simulation field can not be ignored.(3) The mass fraction of kerosene at the film inlet is 1,but it decreases along the nozzle wall and achieves its lowest value at the outlet.However,the mass fraction of kerosene near the wall is the biggest at any axial location.

Improving the performance of LOX/kerosene upper stage rocket engines

Improved liquid rocket engine cycles were proposed and analyzed via comparison with existing staged combustion and gas-generator cycles.The key features of the proposed cycles are regenerative cooling of thrust chamber by oxygen and subsequent use of this oxygen for driving one or two oxygen pumps.The fuel pump(s)are driven in a conventional manner,for example,using a fuel-rich gas-generator cycle.Comparison with staged combustion cycle based on oxygen-rich pre-burner showed that one of the proposed semi-expander cycles has a specific impulse only on 0.4%lower while providing much lower oxygen temperature,more efficient tank pressurizing system and built-in roll control.This semi-expander cycle can be considered as a more reliable and cost-effective alternative of staged combustion cycle.Another semi-expander cycle can be considered as an improvement of gas-generator cycle.All proposed semi-expander cycles were developed as a derivative of thrust chamber regenerative cooling performed by oxygen.Analysis of existing oxygen/kerosene engines showed that replacing of kerosene regenerative cooling with oxygen allows a significant increase of achievable specific impulse,via optimization of mixture ratio.It is especially the case for upper stage engines.The increasing of propellants average density can be considered as an additional benefit of mixture ratio optimization.It was demonstrated that oxygen regenerative cooling of thrust chamber is a feasible and the most promising option for oxygen/kerosene engines.Combination of oxygen regenerative cooling and semi-expander cycles potentially allows creating the oxygen/kerosene propulsion systems with minimum specific impulse losses.It is important that such propulsion systems can be fully based on inherited and well-proven technical solutions.A hypothetic upper stage engine with thrust 19.6 kN was chosen as a prospective candidate for theoretical analysis of the proposed semi-expander cycles.The newly-developed software RECS was used for the comparative analysis of engine cycles.

Gas film/regenerative composite cooling characteristics of the liquid oxygen/liquid methane (LOX/LCH4) rocket engine

The thermal protection of rocket engines is a crucial aspect of rocket engine design.In this paper,the gas film/regenerative composite cooling of the liquid oxygen/liquid methane(LOX/LCH4)rocket engine thrust chamber was investigated.A gas film/regenerative composite cooling model was developed based on the Grisson gas film cooling efficiency formula and the one-dimensional regenerative cooling model.The accuracy of the model was validated through experiments conducted on a 6 kg/s level gas film/regenerative composite cooling thrust chamber.Additionally,key parameters related to heat transfer performance were calculated.The results demonstrate that the model is sufficiently accurate to be used as a preliminary design tool.The temperature rise error of the coolant,when compared with the experimental results,was found to be less than 10%.Although the pressure drop error is relatively large,the calculated results still provide valuable guidance for heat transfer analysis.In addition,the performance of composite cooling is observed to be superior to regenerative cooling.Increasing the gas film flow rate results in higher cooling efficiency and a lower gas-side wall temperature.Furthermore,the position at which the gas film is introduced greatly impacts the cooling performance.The optimal introduction position for the gas film is determined when the film is introduced from a single row of holes.This optimal introduction position results in a more uniform wall temperature distribution and reduces the peak temperature.Lastly,it is observed that a double row of holes,when compared to a single row of holes,enhances the cooling effect in the superposition area of the gas film and further lowers the gas-side wall temperature.These results provide a basis for the design of gas film/regenerative composite cooling systems.

Periodic atomization characteristics of simplex swirl injector induced by klystron effect

The atomization dynamic characteristics of a simplex swirl injector was investigated experimentally by using a hydrodynamic mechanical pulsator and the shadow photography technique. The frequency response characteristics of the fluid film and atomization fluctuations and their correlations with pressure fluctuations were obtained by using an in-house code of image processing. It is demonstrated that the klystron effect induced by periodic pressure fluctuations results in periodic liquid film fluctuation with large amplitudes, periodic superposition of droplets and reduction of the breakup length. It was found that the atomization of the simplex swirl injector only responds to the pressure fluctuation in frequency range approximately from 0 to 300 Hz, and it is particularly sensitive to pressure fluctuations at frequencies from 100 to 200 Hz. According to this experiment, the responsive frequency limitation is merely affected by injector configuration, rather than the supply line.

Periodic atomization characteristics of an impinging jet injector element modulated by Klystron effect

An experimental study on the Klystron effect of periodic injection modulated by pressure drop fluctuations on subsequent atomization is conducted. Time-resolved atomization backlit images and atomization Mie scatter images are captured by using the high speed camera. It is found that periodicity of forced atomization relies on pressure drop fluctuation amplitude and phase differences between atomization and pressure drop fluctuations relate to fluctuation frequencies. This feature of periodic atomization induced by Klystron effect corresponds to periodicities and high amplitudes of pressure fluctuations in unstable combustion chambers and chaos and low amplitudes of pressure fluctuations in stable combustions chambers. Drastically periodic varying of gross surface area of droplets with time was shown in Mie scatter images. The importance of periodic impinging jet atomization modulated by pressure drop fluctuations for acoustic liquid propellant combustion instabilities is illustrated.

Experimental of combustion instability in NTO/MMH impinging combustion chambers

This paper presents an experimental study into dynamics of chamber pressure and heat release rate during self-excited spinning and standing azimuthal mode in NTO/MMH (nitrogen tetroxide/monomethylhydrazine) impinging combustion chambers.Nine cases including two combustion chamber configurations were conducted.The operating conditions of all unstable cases were located in the instability region according to Hewitt empirical correlation.The results show that chamber pressure oscillations keep pace with the corresponding OH*chemiluminescence intensity over the whole combustion region in the spinning and standing modes.It is indicated that the Rayleigh index is positive over the whole combustion area in all the unstable cases.A significant supersonic flame front structure of the first-order spinning mode was found in a cylindrical chamber,which means that a detonation wave could exist in the cylindrical chamber without a center body.The pressure and heat release rate oscillations at the pressure node are nonnegligible although their amplitudes are lower than those at the pressure antinode in the first-order standing mode with an annular chamber.Besides,the dominant frequency of pressure and heat release rate oscillations at the pressure node is twice as high as that at the pressure antinode.

Chebyshev super spectral viscosity method for water hammer analysis

In this paper,a new fast and efficient algorithm,Chebyshev super spectral viscosity(SSV)method,is introduced to solve the water hammer equations.Compared with standard spectral method,the method's advantage essentially consists in adding a super spectral viscosity to the equations for the high wave numbers of the numerical solution.It can stabilize the numerical oscillation(Gibbs phenomenon)and improve the computational efficiency while discontinuities appear in the solution.Results obtained from the Chebyshev super spectral viscosity method exhibit greater consistency with conventional water hammer calculations.It shows that this new numerical method offers an altemative way to investigate the behavior of the water hammer in propellant pipelines.

Numerical investigation of low cycle fatigue life for channel wall nozzles

The thermal-structural response and low cycle fatigue life of a three-dimensional(3D)channel wall nozzle with regenerative cooling were numerically investigated by coupling the finite volume fluid-thermal method,nonlinear finite element thermal-structural analysis and local strain methods.The nozzle had a high area ratio(nozzle exit area divided by throat area)under cyclic working loads.Parametric studies were carried out to evaluate the effects of channel structural parameters such as channel width,channel height,liner thickness and rib width.Results showed that the integrated effects of three-dimensional channel structure and load distribution caused serious strain,which mainly occurred at the intersectant regions of liner wall on the gas side and the symmetric planes of channel and rib.The cooling effect and channel structural strength were significantly improved as the channel width and height decreased,leading to substantial extension of the nozzle service life.On the other hand,the successive decrease in liner thickness and rib width apparently increased the strain amplitude and residual strain of channel wall nozzle during cyclic work,significantly shortening the service life.The present work is of value for design of the channel wall nozzle to prolong its cyclic service life.